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At least 865 records · Page 48

Noble gases in presolar diamonds I: Three distinct components and their implications for diamond origins

High-purity separates of presolar diamond were prepared from 14 primitive chondrites from 7 compositional groups. Their noble gases were measured using stepped pyrolysis. Three distinct noble gas components are present in diamonds, HL, P3, and P6, each of which is found to consist of five noble gases. P3, released between 200 C and 900 C, has a 'planetary' elemental abundance pattern and roughly 'normal' isotopic ratios. HL, consisting of isotopically anomalous Xe-HL and Kr-H, Ar with high Ar-38/Ar-36, and most of the gas making up Ne-A2 and He-A, is released between 1100 C and 1600 C. HL has 'planetary' elemental ratios, except that it has much more He and Ne than other known 'planetary' components. HL gases are carried in the bulk diamonds, not in some trace phase. P6 has a slightly higher median release temperature than HL and is not cleanly separated from HL by stepped pyrolysis. Our data suggest that P6 has roughly 'normal' isotopic compositions and 'planetary' elemental ratios. Both P3 and P6 seem to be isotopically distinct from P1, the dominant 'planetary' noble-gas component in primitive chondrites. Release characteristics suggest that HL and P6 are sited in different carriers within the diamond fractions, while P3 may be sited near the surfaces of the diamonds. We find no evidence of separability of Xe-H and Xe-L or other isotopic variations in the HL component. However, because approximately 10(exp 10) diamonds are required to measure a Xe composition, a lack of isotopic variability does not constrain diamonds to come from a single source. In fact, the high abundance of diamonds in primitive chondrites and the presence of at least three distinct noble-gas components strongly suggest that diamonds originated in many sources. Relative abundances of noble-gas components in diamonds correlate with degree of thermal processing, indicating that all meteorites sampled essentially the same mixture of diamonds. That mixture was probably inherited from the Sun's parent molecular cloud.

Huss, Gary R.↗

Spectroscopic Determination of the Physical Conditions in Hot Optically Thin Sources

The Astrophysics Plasma Emission Code and Database (APEC/APED), developed in part under this grant, have been upgraded to Version 1.3.0 and are now beginning to find widespread applications to X-ray spectral data from Chandra and XMM-Newton. These models represent the best theoretical data currently available and are reasonably complete below about 30 A. We are making significant progress in improving the spectral models between 30 and 90 A, by the addition of HULLAC calculations and NIST wavelengths for L-shell ions of Ne, Mg, Si, S, Ar, and Ca. While the output models are now public, the code itself is not ready for public release. We have made significant progress toward this goal through programming improvements, including optimized error codes, a major (elusive) bug fix, and additions to our testing protocols. Secondarily, we are beginning to investigate limited uses of APEC for X-ray photoionized plasma, as for opacity modeling. Stellar coronae are being used to benchmark the atomic data in APED as part of the Emission Line Project. The models appear to be in good agreement with the observations for most of the strong lines; however, we have identified significant discrepancies in the 3s/3d line ratios not only for Fe XVII, but also for Fe XVIII and XIX. The careful analysis of these high quality X-ray spectra has also shown that there are serious problems with some of the analysis techniques in widespread use. There are several manifestations of the problem, but the main problem is that line-to-continuum ratios may be seriously mismeasured. We continue to collaborate widely with atomic physicists in order to find the best atomic data, and to solicit calculations and measurements that are needed.

Brickhouse, Nancy↗

Characteristics of Total Column CO2 Retrievals from the OCO Missions: Biases, Information Content and Implications for Flux Inversions

The Orbiting Carbon Observatory-2 and Orbiting Carbon Observatory-3, launched in 2015 and 2019, respectively, are intended to collect and deliver high-resolution observations of CO2 with unprecedented space and time coverage. Observations of CO2 from these remote-sensing missions (also known as XCO2, or column-based average, dry air mole fraction of CO2) are then used by the global carbon cycle community to answer a wide range of science questions, from the distribution and quantification of global and regional CO2 source-sink patterns to quantification of anthropogenic sources at urban scales. Even though we have had the OCO-2 mission flying for a few years now, the retrieval algorithms are continuously evolving and improving to deliver XCO2 retrievals with very high precision and high accuracy (or low biases). In this presentation, we will discuss a simple yet effective quantitative framework that has been developed by the OCO-2 flux team to evaluate the information content of these XCO2 retrievals as soon as they are released, i.e., with lower latency than full-scale flux inversions. This framework serves as a precursor to advanced inverse modeling frameworks and is intended to provide an early but accurate assessment of the signal present in the satellite retrievals, the robustness of that signal, and the ability of these retrievals to resolve patterns in CO2 surface fluxes that cannot be resolved by our current network of surface sites. Specific results will tackle a tiered set of questions that are being addressed using this framework: (a) what are the distribution of retrievals in the different modes of operation and how do they vary in space and time? (b) what is the information that is being given to the inverse modeling frameworks from the space-based data, information above and beyond what is provided by the in-situ data? and (c) how do these factors influence our choices for doing flux inversions with the satellite retrievals? While the primary focus of the results will be on application of this technique to mature OCO-2 retrievals, we will show early results for a couple of months of OCO-3 retrievals. For the time-period that the retrievals from the two missions overlap, we will highlight how this framework allows us to effortlessly put the information from OCO-3 and OCO-2 on an equal footing, thus enabling easy comparison between the two pioneering missions.

Chatterjee, Abhishek↗

Identification of a Local Sample of Gamma-Ray Bursts Consistent with a Magnetar Giant Flare Origin

Cosmological gamma-ray bursts (GRBs) are known to arise from distinct progenitor channels: short GRBs mostly from neutron star mergers and long GRBs from a rare type of core-collapse supernova (CCSN) called collapsars. Highly magnetized neutron stars called magnetars also generate energetic, short-duration gamma-ray transients called magnetar giant flares (MGFs). Three have been observed from the Milky Way and its satellite galaxies, and they have long been suspected to constitute a third class of extragalactic GRBs. We report the unambiguous identification of a distinct population of four local (<5 Mpc) short GRBs, adding GRB 070222 to previously discussed events. While identified solely based on alignment with nearby star-forming galaxies, their rise time and isotropic energy release are independently inconsistent with the larger short GRB population at >99.9% confidence. These properties, the host galaxies, and non-detection in gravitational waves all point to an extragalactic MGF origin. Despite the small sample, the inferred volumetric rates for events above 4 × 10(exp 44) erg of R(sub MGF) =3.8(sup +4.0)(sub -3.1) ×10(exp 5) Gpc(exp -3) yr(exp -1) make MGFs the dominant gamma-ray transient detected from extragalactic sources. As previously suggested, these rates imply that some magnetars produce multiple MGFs, providing a source of repeating GRBs. The rates and host galaxies favor common CCSN as key progenitors of magnetars.

Gamma-ray bursts↗

Ion sputtering from satellite surfaces

The manifestations of the induced surface currents as observed by the magnetic ion mass spectrometer (MIMS) and retarding potential analyzer (RPA) instruments on AE-C and AE-D are described. Data from these instruments are used to infer the source of some of the different secondary ions observed, as well as their time history and emission energy. It is noted that the emitted particles have a characteristic energy of approximately 1 eV in the spacecraft frame of reference and lack the normal ram energy possessed by the ambient ions. Alkali ions Na(+) and K(+), in addition to nonionospheric NO(+) and O2(+), are observed at low altitudes. With the exception of NO(+), all these are thought to be released by impacts of neutral N2 or O2 with the surfaces. These ion currents decrease with a time constant of about six weeks for the alkali and four weeks for the O2 ions.

Hanson, W. B.↗

N157B: X-ray evidence for a Crab-like supernova remnant

The X-ray observation of the supernova remnant N 157B is described. The Rosat High Resolution Imager (HRI) X-ray emission from the remnant was decomposed into point-like sources. The spectra showed abundance-enhanced neon and magnesium lines, indicating that the remnant originated in a massive progenitor. The flat and featureless data from the Advanced Satellite for Cosmology and Astrophysics (ASCA) confirm the Crab-like nature of the remnant. By interpreting both the thermal spectral component and the shell as representing the remnant's outer shock, the age of the remnant was estimated to be 4 x 10(exp 3) yr and the energy release approximately 2 x 10(exp 50) erg.

Gotthelf, Eric V.↗

Rotational Variation of Daughter Species Production Rates in Comet 103P/Hartley: Implications for the Progeny of Daughter Species and the Degree of Chemical Heterogeneity

We present analysis of high spectral resolution optical spectra of Comet 103P/Hartley taken during its Fall 2010 apparition. These spectra include transitions belonging to CN, C2, CH, NH2, and OI. We measure production rates and mixing ratios from these spectra. We find evidence for large changes in production rates (factors of a few) over the course of a nucleus rotation, in agreement with other measurements. We also measure variability with rotational phase in the CN/H2O and C2/CN ratios, which has not been previously reported for any comet. There may also be variability in the NH2/H2O ratio with rotational phase, but this trend is not as clear as for CN/H2O. We interpret the changing mixing ratios as due to H2O and C2 being released primarily from the icy grain halo, while the CN parent molecule comes directly from the nucleus. There is evidence that the CH/CN ratio is higher pre-perihelion than post-perihelion. We conclude that the observed CN and NH2 abundances are consistent with HCN and NH3 being the dominant parent molecules for these species. The C2 and CH abundances are higher than those of candidate parent molecules (C2H2 and CH4 respectively), so there must be another source for these molecules in 103P's coma. Carbonaceous dust grains could serve as this source.

Comets↗

Coronal Mass Ejections: a Summary of Recent Results

Coronal mass ejections (CMEs) have been recognized as the most energetic phenomenon in the heliosphere, deriving their energy from the stressed magnetic fields on the Sun. This paper highlights some of the recent results on CMEs obtained from the Solar and Heliospheric Observatory (SOHO) and the Solar Terrestrial Relations Observatory (STEREO) missions. The summary of the talk follows. SOHO observations revealed that the CME rate is almost a factor of two larger than previously thought and varied with the solar activity cycle in a complex way (e.g., high-latitude CMEs occurred in great abundance during the solar maximum years). CMEs were found to interact with other CMEs as well as with other large-scale structures (coronal holes), resulting in deflections and additional particle acceleration. STEREO observations have confirmed the three-dimensional nature of CMEs and the shocks surrounding them. The EUV signatures (flare arcades, corona) dimming, filament eruption, and EUV waves) associated with CMEs have become vital in the identification of solar sources from which CMEs erupt. CMEs with speeds exceeding the characteristic speeds of the corona and the interplanetary medium drive shocks, which produce type II radio bursts. The wavelength range of type II bursts depends on the CME kinetic energy: type II bursts with emission components at all wavelengths (metric to kilometric) are due to CMEs of the highest kinetic energy. Some CMEs, as fast as 1600 km/s do not produce type II bursts, while slow CMEs (400 km/s) occasionally produce type II bursts. These observations can be explained as the variation in the ambient flow speed (solar wind) and the Alfven speed. Not all CME-driven shocks produce type II bursts because either they are subcritical or do not have the appropriate geometry. The same shocks that produce type II bursts also produce solar energetic particles (SEPs), whose release near the Sun seems to be delayed with respect to the onset of type II bursts. This may indicate a subtle difference in the acceleration of the ions and 10 keV electrons needed to produce type II bursts. Surprisingly, some shocks lacking type II bursts are associated with energetic storm particle events (ESPs) pointing to the importance of electron escape from the shock for producing the radio emission. CMEs slow down or accelerate in the interplanetary medium because of the drag force, which modifies the transit time of CMEs and shocks. Halo CMEs that appear to surround the occulting disk were known before the SOHO era as occasional events. During the SOHO era, they became very prominent because of their ability to impact Earth and producing geomagnetic storms. Halo CMEs are generally more energetic than ordinary CMEs, which means they can produce severe impact on Earth's magnetosphere. Their origin close to the disk center of the Sun ensures direct impact on the magnetosphere, although their internal magnetic structure is crucial in causing storms. The solar sources of CMEs that produce SEP events at Earth, on the other hand, are generally in the western hemisphere because of the magnetic connectivity. Thus, CMEs are very interesting from the point of view of plasma physics as well as practical implications because of their space weather impact.

Gopalswamy, Nat↗

Producing the universal spectrum of cosmological gamma-ray bursts with the Klein-Nishina cross section

A power-law spectrum attenuated through Compton scattering by an optically thick medium produces spectra that have a characteristic energy of several hundred keV. Add a redshift, and one finds that this model can qualitatively reproduce the color-color diagrams found for individual gamma-ray bursts. This model is easily tested through model fits to burst spectra and through comparisons of the parameters derived from model fits to the limits on parameters derived from the burst log N - log P(sub max) curve. The heavy attenuation makes the amount of energy released in the burst approximately equal to 10(exp 3) times larger than is inferred from the observed flux. The requirements of high optical depth and no photon-photon pair creation place a lower limit on the size of the scattering region. This size suggests that the attenuation occurs in giant molecular clouds in the cores of galaxies. This indicates that gamma-ray bursts are probably from supermassive black holes. If the Lorentz factor of the radiation source is large, the optical depth, and therefore the hardness ratio of a burst, can change over the duration of the burst.

Brainerd, J. J.↗

X-Ray Photoelectron Spectroscopy

The interaction of photon and the electron goes back to the early part of 19th century emanating from the photo-electric effect depicted by none other than Albert Einstein (Ref 1) described in 1905, and the redistribution of kinetic energy resulting from the interaction of x-ray and solids reported during early part of the century (Ref.2). The spectrum resolutions obtained at that time was not sufficient to observe distinct peaks in spectra for materials. Thus, these phenomena hardly attracted any attention for many years following these discoveries. The modern X-ray Photoelectron Spectroscopy (XPS) has been possible by the extensive and significant contribution from Kai Siegbahn and others (Ref.3, 4) of Uppsala University. Siegbahn developed and employed a high-resolution electron spectrometer that revealed electron peaks in a spectrum emerging from the interaction of x-rays and solids. Eventually, Kai Siegbahn received Nobel Prize in 1981 for his contributions to XPS. Around 1958, shifts in elemental peaks were realized in compounds when the same elements are bound to other but different elements. This discovery resulted in the chemical state identification in various chemicals as well as the oxidation states of atoms in compounds. Because of these useful physical effects, the Uppsala group named XPS with a synonymous name of ESCA (Electron Spectroscopy for Chemical Analysis) used widely today and will be used here alternatively. Therefore, XPS or ESCA not only identifies the element, but also the compound these elements form, from their chemical shifts. Compared to other micro-analytical techniques such as Energy Dispersive (EDS) or Wavelength Dispersive (WDS) techniques, XPS analyzes only few atomic layers present on the surface. This was discovered early in 1966 (Ref. 5). While this has awarded a merit to the analytical technique to analyze very thin layers such as films and coatings, it often analyzes the adsorbed superficial gases and contaminations on a sample introduced to its analytical chamber. This necessitates the surface is cleaned and the underlying material, material of interest, is exposed in a clean environment such that the material of interest is analyzed. The cleaning is accomplished by a scanning ion gun within the analytical chamber of the instrument. Ion gun uses an argon gas and is commonly attached in most modern machines. Reliable and efficient vacuum systems employed in modern machines does not allow adsorbed layers to rebuild after the surface is cleaned. Development of efficient and reliable vacuum pumps over these developmental years is yet another important step in the commercialization of XPS machines. Vacuum levels of better than 10-7 torr are essential to increase the mean free path of electrons released from the sample surface. Thus, modern machines are equipped with high capacity ion, turbo or cryogenic pumps in their analytical chambers. Today, XPS has advanced from an applied physics laboratory to industry for use in quality control as well as analysis of contaminants and has taken a dominant role in microanalysis. Its uniqueness arises from the fact that it is considered non-destructive compared to other common micro-analytical techniques using the electron and ion excitation sources. Polymers and plastics could be analyzed since the binding energies of saturated and unsaturated bonds in atoms could be separated. Extremely thin layers could be analyzed including materials with layered structures. The technique, though did not advance for many years, has now opened a new window for research as well as applications in industry due to its ability to separate and measure the chemical shifts in bound elements. Principles

Panda, Binayak↗

Atmospheric Sulfur Hexafluoride: Sources, Sinks and Greenhouse Warming

Model calculations using estimated reaction rates of sulfur hexafluoride (SF6) with OH and 0('D) indicate that the atmospheric lifetime due to these processes may be very long (25,000 years). An upper limit for the UV cross section would suggest a photolysis lifetime much longer than 1000 years. The possibility of other removal mechanisms are discussed. The estimated lifetimes are consistent with other estimated values based on recent laboratory measurements. There appears to be no known natural source of SF6. An estimate of the current production rate of SF6 is about 5 kt/yr. Based on historical emission rates, we calculated a present-day atmospheric concentrations for SF6 of about 2.5 parts per trillion by volume (pptv) and compared the results with available atmospheric measurements. It is difficult to estimate the atmospheric lifetime of SF6 based on mass balance of the emission rate and observed abundance. There are large uncertainties concerning what portion of the SF6 is released to the atmosphere. Even if the emission rate were precisely known, it would be difficult to distinguish among lifetimes longer than 100 years since the current abundance of SF6 is due to emission in the past three decades. More information on the measured trends over the past decade and observed vertical and latitudinal distributions of SF6 in the lower stratosphere will help to narrow the uncertainty in the lifetime. Based on laboratory-measured IR absorption cross section for SF6, we showed that SF6 is about 3 times more effective as a greenhouse gas compared to CFC 11 on a per molecule basis. However, its effect on atmospheric warming will be minimal because of its very small concentration. We estimated the future concentration of SF6 at 2010 to be 8 and 10 pptv based on two projected emission scenarios. The corresponding equilibrium warming of 0.0035 C and 0.0043 C is to be compared with the estimated warming due to CO2 increase of about 0.8 C in the same period.

Sze, Nien Dak↗

Regenerative Fuel Cell Test Rig Completed and Operational at Glenn Research Center

The NASA Glenn Research Center has completed construction of its first closed-cycle hydrogen-oxygen regenerative fuel cell (RFC). The RFC is an electrochemical system that collects and stores solar energy during the day then releases that energy at night, thus making the Sun's energy available all 24 hours. It consists of a dedicated hydrogen-oxygen fuel cell stack and an electrolyzer stack, the interconnecting plumbing and valves, cooling pumps, water transfer pumps, gas recirculation pumps, phase separators, storage tanks for oxygen (O2) and hydrogen (H2), heat exchangers, isolation valves, pressure regulators, nitrogen purge provisions, instrumentation, and other components. It includes all the equipment required to (1) absorb electrical power from an outside source and store it as pressurized hydrogen and oxygen and (2) make electrical power from the stored gases, saving the product water for reuse during the next cycle.

Bents, David J.↗

Building access and community standards for opacity data at the onset of next-generation atmosphere observations

The characterization of a diverse set of exoplanet atmosphere observations, ranging from hot gas giants to small temperate rocky worlds, will be one of the legacies of upcoming facilities such as the James Webb Space Telescope (JWST). Our understanding and interpretation of such observations will hinge on our ability to link observations with atmospheric theoretical studies that critically rely on fundamental molecular and atomic opacities. Computing such opacities is a highly non-trivial and inaccessible process which requires several terabytes of available disk space, hours of CPU time per pressure-temperature combination, and requires users to carefully aggregate line lists data from various sources, which limits access and intercomparison of opacity data in the exoplanet community. Here we present MAESTRO (Molecules and Atoms in Exoplanet Science: Tools and Resources for Opacities) an opacity database that can be accessed by the community via a web interface and python API. MAESTRO was built with community input to create a version-controlled opacity database that is easily queryable, includes informative metadata to ensure reproducibility, and exports relevant citations for inclusion in publications. Scheduled for community release in 2022, MAESTRO will prove to be an invaluable community resource in the era of JWST and beyond.

Natasha Batalha↗

Neutron Stars and Black Holes Seen with the Rossi X-Ray Timing Explorer (RXTE)

Astrophysical X-rays bring information about location, energy, time, and polarization. X-rays from compact objects were seen in the first explorations to vary in time. Eclipses and pulsations have simple explanations that identified the importance of X-ray binaries and magnetic neutron stars in the first decade of X-ray astronomy. The dynamics of accretion onto stellar and supermassive black holes and onto neutron stars with relatively low magnetic fields shows up as more complex variations, quasi-periodic oscillations, noise with characteristic frequency spectra, broad-band changes in the energy spectra. To study these variations, RXTE instruments needed to have large area and operational flexibility to find transient activity and observe when it was present. Proportional counters and Phoswich scintillators provided it in a modest mission that has made textbook level contributions to understanding of compact objects. The first seen, and the brightest known, X-ray binary, Sco X-1 is one of a class of neutron stars with low mass companions. Before RXTE, none of these had been seen to show pulsations, though they were hypothesized to be the precursors of radio pulsars with millisecond periods and low magnetic fields. RXTE's large area led to identifying coherent millisecond pulsars in a subset which are relatively faint transients. It also led to identifying short episodes of pulsation during thermonuclear bursts, in sources where a steady signal is not seen. The X-ray stage verifies the evolution that produces millisecond radio pulsars.Masses and radii of neutron stars are being determined by various techniques, constraining the equation of state of matter at nuclear densities. Accretion should lead to a range of neutron star masses. An early stage of superstrong magnetic field neutron stars is now known to produce X-ray and gamma-ray bursts in crust quakes and magnetic field reconnection releases of energy. Soft Gamma Repeaters, Anomolous X-ray Pulsars, and high magnetic field rotation-powered pulsars are all now called magnetars, because they have pulse periods indicating they are slowing down as they would with magnetic dipole radiation for a surface field above 5x1013 gauss. The accretion disk has been connected to the launching of radio jets from black holes, and even from neutron stars. Estimates of the angular momenta of black holes are being made from different approaches, modelling a high frequency oscillation that may be related to how close the inner part of the accretion disk is to the black hole, modelling the continua spectra of the X-ray emission, and modeling the emission of red-shifted iron that may be emitted from the accretion disk. These investigations require early discovery of the black hole transient with the All Sky Monitor on RXTE or other monitoring information, frequent extended observations, and coordinated observations with missions that give higher energy resolution, or radio and infrared information.

Swank, Jean↗

Design, Development and Test Challenges: Separation Mechanisms for the Orion Pad Abort-1 Flight Test

On May 6, 2010, NASA launched the first successful integrated flight test, Pad Abort-1, of the Orion Project from the White Sands Missile Range in Las Cruces, New Mexico. This test demonstrated the ability to perform an emergency pad abort of a full-scale 4.8 m diameter, 8200 kg crew capsule. During development of the critical separation mechanisms for this flight test, various challenges were overcome related to environments definition, installation complications, separation joint retraction speed, thruster ordnance development issues, load path validation and significant design loads increases. The Launch Abort System retention and release (LAS R&R) mechanism consisted of 6 discrete structural connections between the LAS and the crew module (CM) simulator, each of which had a preloaded tension tie, Superbolt torque-nut and frangible nut. During the flight test, the frangible nuts were pyrotechnically split, permitting the CM to separate from the LAS. The LAS separation event was the driving case in the shock environment for many co-located hardware items. During development testing, it was necessary to measure the source shock during the separation event so the predicted shock environment could be validated and used for certification testing of multiple hardware items. The Lockheed Martin test team measured the source separation shock due to the LAS R&R function, which dramatically decreased the predicted environment by 90% at 100 Hz. During development testing a hydraulic tensioner was used to preload the joint; however, the joint relaxation with the tensioner proved unsatisfactory so the design was modified to include a Superbolt torque-nut. The observed preload creep during lab testing was 4% after 30 days, with 2.5% occurring in the first 24 hours. The conversion of strain energy (preload) to kinetic energy (retraction) was measured to be 50-75%. Design features and careful monitoring of multiple strain gauges on each tension tie allowed a pure tensile load to be applied after stacking at the launch pad. Following installation, preload in each joint was monitored for 24 hours. Due to unforeseen complications and the influence of temperature on the portable data acquisition system, the team encountered difficulty in tracking the joint relaxation. In some cases, bond-line failure of the strain gauges occurred.

Dinsel, Alison↗

Energy, frequency, and distance of moonquakes at the Apollo 17 site

'Thermal' moonquakes have been detected at the Apollo 17 site. A typical event releases about 1 to 10 million ergs of energy. The annual seismic energy release for the events observed in the Taurus-Littrow Valley is estimated at 100 billion ergs. Such small events would not cause impossibly rapid erosion on either the North Massif or within the craters of the Central Cluster. Seismic events become increasingly frequent after sunrise and reach a maximum at sunset. The largest events, however, occur most commonly near lunar noon. Rise times of the seismic signals, after being calibrated by the well-located Lunar Seismic Profiling Experiment (LSPE) seismic sources, were used to estimate distances to the seismic events. Most seismic events (about 90%) appear to occur within 2.5 km of the seismometer array.

Cooper, M. R.↗

ISO Key Project: Exploring the Full Range of Quasar/AGN Properties

The ISOPHOT team have developed new recommendations for observing faint sources with ISHPOHT which involve small rasters rather than chopping. This was finalized around Feb 1997 and following this we re-designed the observations for the remainder of our observing time. We had put our program on hold in September when it became clear that chopped observations had major problems. The revised program, which included re-observation at long wavelengths using rasters for a number of high-priority targets and re-specification of new observations of others, was released in April 1997. The latest prediction for the satellite lifetime has extended its life until April 1998. Our project has been allocated a 15% increase in our observing time as a result of this life extension. We are currently working on setting priorities in order to determine which targets to include in this additional time. This will help to offset some of the targets lost due to the significant decrease in detector sensitivity over pre-flight predictions.

Wilkes, Belinda J.↗

Possible Detection of Perchlorates by the Sample Analysis at Mars (SAM) Instrument: Comparison with Previous Missions

The first chemical analysis of soluble salts in the soil was carried out by the Phoenix Lander in the Martian Arctic [1]. Surprisingly, chlorine was present as magnesium or calcium perchlorate at 0.4 to 0.6 percent. Additional support for the identification of perchlorate came from the evolved gas analysis which detected the release of molecular oxygen at 350-550C [1]. When Mars-like soils from the Atacama Desert were spiked with magnesium perchlorate (1 percent) and heated using the Viking GC-MS protocol, nearly all the organics were combusted but a small amount was chlorinated, forming chloromethane and dichloromethane [2]. These chlorohydrocarbons were detected by the Viking GC-MS experiments when the Martian soil was analyzed but they were considered to be terrestrial contaminants [3]. Reinterpretation of the Viking results suggests <0.1 percent perchlorate and ppm levels of organic carbon at landing site 1 and 2 [2]. The suggestion of perchlorate in the Viking sites [2] has been challenged on the grounds that the detected compounds (CH3Cl and CH2Cl2) were carried from Earth [4]. Recently the Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory (MSL) ran four samples from an aeolian bedform named Rocknest. The samples analyzed were portioned from the fifth scoop at this location. The samples were heated to 835C at 35C/min with a He flow. The SAM QMS detected a major oxygen release (300-500C) [5], coupled with the release of chlorinated hydrocarbons (chloromethane, dichloromethane, trichloromethane, and chloromethylpropene) detected both by SAM QMS and GC-MS derived from known Earth organic contaminants in the instrument [6]. Calcium perchlorate appears to be the best candidate for evolved O2 in the Rocknest samples at this time but other Cl species (e.g., chlorates) are possible and must be evaluated. The potential detection of perchlorates in Rocknest material adds weight to the argument that both Viking Landers measured signatures of perchlorates. Even if the source of the organic carbon detected is still unknown, the chlorine source was likely Martian. Two mechanisms have been hypothesized for the formation of soil perchlorate: (1) Atmospheric oxidation of chlorine; and (2) UV photooxidation of chlorides catalyzed by mineral catalysts [7]. The presence of soil perchlorates in the Martian surface has important implications for the detection of organics [2], carbonates [8] and nitrates [9] by SAM.

Navarro-Gonzalex, Rafael↗