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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

The Prediction and Observation of the 1997 July 18 Stellar Occultation by Triton: More Evidence for Distortion and Increasing Pressure in Triton's Atmosphere

We used CCD (charge coupled device) astrometric data to predict where the occultation path of the star Tr 176 was located, on July 18, 1997. It could be seen from northern Australia and the southern section of North America. We set up an array of portable and mixed telescopes which had high-speed photometric equipment to observe the occultation. Goals included the following: (1) mapping the central flash; (2) obtaining light curves for the signal-to-noise ratio; (3) acquiring light curves from Triton's disk. We combined these with data from others to find the radius and geometry of the half-light surface of the atmosphere, as well as the equivalent-isothermal temperature latitudes below the occultation on Triton.

Elliot, J. L.↗
NASA NTRS2000

Far Ultraviolet Imaging from the Image Spacecraft: Wideband FUV Imaging - 2

The Far Ultraviolet Wideband Imaging Camera (WIC) complements the magnetospheric images taken by the IMAGE satellite instruments with simultaneous global maps of the terrestrial aurora. Thus, a primary requirement of WIC is to image the total intensity of the aurora in wavelength regions most representative of the aurora] source and least contaminated by dayglow, have sufficient field of view to cover the entire polar region from spacecraft apogee and have resolution that is Sufficient to resolve auroras on a scale of 1 to 2 latitude degrees, The instrument is sensitive in the spectral region from 140- 190 nm. The WIC is mounted on the rotating, IMAGE spacecraft viewing radially outward and has a field of view of 17 deg in the direction parallel to the spacecraft spin axis. Its field of view is 30 deg in the direction perpendicular to the spin axis, although only a 17 deg x 17 deg image of the Earth is recorded. The optics was an all-reflective, inverted Cassegrain Burch camera using concentric optics with a small convex primary and a large concave secondary mirror. The mirrors were coated by a special multi-layer coating, which has low reflectivity in the visible and near UV region, The detector consists of a MCP-Intensified CCD. The MCP is curved to accommodate the focal surface of the concentric optics. Tile phosphor of the image intensifier is deposited on a concave fiberoptic window, which is then Coupled to the CCD with a fiberoptic taper. The camera head operates in a fast frame transfer mode with the CCD being read approximately 30 full frames (512 by 256 pixel) per second with an exposure time of 0.033 s. The image motion (file to the satellite spin is minimal during such a short exposure. Each image is electronically distortion corrected using the look up table scheme. An offset is added to each memory address that is proportional to the image shift due to satellite rotation, and the charge signal is digitally summed in memory. On orbit, approximately 300 frames will be added to produce one WIC image in memory. The advantage of the electronic motion compensation and distortion correction is that it is extremely flexible, permitting several kinds of corrections including motions parallel and perpendicular to the predicted axis of rotation. File instrument was calibrated by applying ultraviolet light through a vacuum monochromator and measuring the absolute responsivity of the instrument. To obtain the data for the distortion look up table the camera was turned through various angles and the input angles corresponding to a pixel matrix were recorded. It was found that the spectral response peaked at 150 nm and fell off in either direction. The equivalent aperture of the camera, including mirror reflectivities and effective photocathode quantum efficiency, is about 0.04 sq cm. Thus, a 100 Rayleigh LBH aurora is expected to produce 23 equivalent counts per pixel per 10 s exposure at the peak of instrument response.

Mende, S. B.↗
NASA NTRS1995

Hot gas in superclusters and microwave background distortions

Variations in the electron pressure can produce significant distortions of the cosmic microwave background radiation (CMBR) spectrum through the Sunyaev-Zel'dovich effect. In this paper, we compute the amplitude of these distortions in various cosmological scenarios using the results of hydrodynamical simulations combined with analytic theory. For reionized cold dark matter (CDM) with h = 0.5 probed with the OVRO experiment (Theta approximately = 0.1 deg), we find that the amplitude of these fluctuations is (Delta T/T)(sub rms) = 1 x 10(exp -5) (Omega(sub i)/0.06) if the experiment looks at a random part of the sky and 6 x 10(exp -6)(Omega(sub i)/(0.06) if bright areas are avoided. Here Omega is the density of ionized baryons in units of the critical density, rho(sub c) = 2.78 x 10(exp 11)h(exp 2)/cu Mpc. Primary fluctuations would generate (Delta T/T)(sub rms) approximately = 2 x 10(exp -6) for this model. These distortions could be a dominant source of CMBR anisotropics on small and intermediate angular scales. It is important to note that these signals are generated relatively recently, when nonlinear effects are improtant, and do not require early reionization. We also examine the contribution to anisotropies from the Doppler effect, in both the linear and nonlinear regimes. In this case, the bulk of the signal is generated before a redshift of 10, provided that the intercluster medium is ionized back to the surface of last scattering. On the smallest scales thermal effects are bigger, while, on larger scales the Doppler-induced fluctuations are greater with the exact boundary determined by the scenario. However, over a wide range of scales, the two signals are equal to within a factor of a few.

Persi, Fred M.↗
NASA NTRS1999

New Method for Calibration for Hyperspectral Pushbroom Imaging Systems

A new, easy-to-implement approach for achieving highly accurate spectral and radiometric calibration of array-based, hyperspectral pushbroom imagers is presented in this paper. The equivalence of the plane of the exit port of an integrating sphere to a Lambertian surface is utilized to provide a field-filling radiance source for the imager. Several different continuous wave lasers of various wavelengths and a quartz-tungsten-halogen lamp internally illuminate the sphere. The imager is positioned to "stare" into the port, and the resultant data cube is analyzed to determine wavelength calibrations, spectral widths of channels, radiometric characteristics, and signal-to-noise ratio, as well as an estimate of signal-to-noise performance in the field. The "smile" (geometric distortion of spectra) of the system can be quickly ascertained using this method. As the price and availability of solid state laser sources improve, this technique could gain wide acceptance.

Ryan, Robert↗
NASA NTRS2023

Assessment of Pseudoshock Models Against Experiment in a Low-Aspect-Ratio Isolator

A highly confined shock train is investigated in a direct-connect isolator facility with a Mach 2 inflow and a constant-area low-aspect-ratio rectangular test section. High-speed schlieren imaging, wall static pressure measurements, surface oil-flow visualization, and particle image velocimetry from this isolator are synthesized into a three-dimensional schematic of the shock train structure. Against this, the prevailing pseudoshock models in the literature are assessed to evaluate the validity of their underlying assumptions. None of the prevailing pseudoshock models are found to simultaneously model the pressure and Mach number profiles, indicating a gap in the model formation and underlying assumptions when applied to the experimental isolator of interest. The presence of distortion in the isolator flowfield, such as a wall-bounded vortex, is found to skew the structure of the shock train, altering the strength and distribution of the compressive pressure gradient. It is further observed that the separated flow morphology surrounding the shock train is not monolithic, as is typically assumed, adjusting the balance of compressive forces within the shock cells. These findings lead to the conclusion that existing flux-conserved modeling approaches require modification to be effective in distorted and highly confined cases, including closure models that capture the three-dimensional distorted structure of the approach flow and its evolution along the shock train.

Shock Train↗
DOE OSTI2020

How good are polarizable and flexible models for water: Insights from a many-body perspective

We present a systematic analysis of state-of-the-art polarizable and flexible water models from a many-body perspective, with a specific focus on their ability to represent the Born–Oppenheimer potential energy surface of water from the gas to the liquid phase. Using coupled cluster data in the completed basis set limit as a reference, we examine the accuracy of the polarizable models in reproducing individual many-body contributions to interaction energies and harmonic frequencies of water clusters and compare their performance with that of MB-pol, an explicit many-body model that has been shown to correctly predict the properties of water across the entire phase diagram. Based on these comparisons, we use MB-pol as a reference to analyze the ability of the polarizable models to reproduce the energy landscape of liquid water under ambient conditions. We find that, while correctly reproducing the energetics of minimum-energy structures, the polarizable models examined in this study suffer from inadequate representations of many-body effects for distorted configurations. To investigate the role played by geometry-dependent representations of 1-body charge distributions in reproducing coupled cluster data for both interaction and many-body energies, we introduce a simplified version of MB-pol that adopts fixed atomic charges and demonstrate that the new model retains the same accuracy as the original MB-pol model. Based on the analyses presented in this study, we believe that future developments of both polarizable and explicit many-body models should continue in parallel and would benefit from synergistic efforts aimed at integrating the best aspects of the two theoretical/computational frameworks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Theoretical search for possible Li–Ni–B crystal structures using an adaptive genetic algorithm

The structural diversity of rare-earth and transition metal borides indicates that alkali-transition metal borides (A-T-B) show tremendous promise in exhibiting a variety of crystal structures with different dimensionalities of T-B frameworks. On the other hand, the A-T-B ternary systems are severely underexplored because of the synthetic challenges associated with their preparation. Accurate and efficient computational predictions of low-energy stable and metastable phases can identify the optimal compositions of the hypothetical compounds in the A-T-B systems to guide the synthesis. As such, in this work, we have computationally discovered several new phases in the Li–Ni–B ternary system. The newly discovered LiNiB, Li 2 Ni 3 B, and Li 2 NiB phases expand the existing theoretical database, and the convex-hull surface of Li–Ni–B has been re-constructed. The lowest energy structure of the LiNiB compound has been found by an adaptive genetic algorithm with layered motif, which matches with the experimentally determined structure. According to our electrochemical calculations, LiNiB and another predicted layered Li 2 NiB compounds have great potential as anode materials for lithium batteries. The Li 2 Ni 3 B compound with the space group P4 3 32 was predicted to crystallize in a cubic structure composed of distorted octahedral units of BNi 6 , which is isostructural to two noncentrosymmetric superconductors Li 2 Pd 3 B and Li 2 Pt 3 B. While we were unable to experimentally confirm the Li 2 Ni 3 B compound utilizing the hydride synthetic route, attempts to synthesize this compound by alternate methods remain highly desirable, considering its potential superconducting properties.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Evaluation of F/A-18A HARV inlet flow analysis with flight data

The F/A-18A aircraft has experienced engine stalls at high angles-of-attack and yaw flight conditions which were outside of its flight envelope. Future aircraft may be designed to operate routinely in this flight regime. Therefore, it is essential that an understanding of the inlet flow field at these flight conditions be obtained. Due to the complex interactions of the fuselage and inlet flow fields, a study of the flow within the inlet must also include external effects. Full Navier-Stokes (FNS) calculations on the F/A-18A High Alpha Research Vehicle (HARV) inlet for several angles-of-attack with sideslip and free stream Mach numbers have been obtained. The predicted forebody/fuselage surface static pressures agreed well with flight data. The surface static pressures along the inlet lip are in good agreement with the numerical predictions. The major departure in agreement is along the bottom of the lip at 30 deg and 60 deg angle-of-attack where a possible streamwise flow separation is not being predicted by the code. The circumferential pressure distributions at the engine face are in very good agreement with the numerical results. The variation in surface static pressure in the circumferential direction is very small with the exception of 60 angle-of-attack. Although the simulation does not include the effect of the engine, it appears that this omission has a second order effect on the circumferential pressure distribution. An examination of the unsteady flight test data base has shown that the secondary vortex migrates a significant distance with time. In fact, the extent of this migration increases with angle-of-attack with increasing levels of distortion. The effects of the engine on this vortex movement is unknown. This implies that the level of flow unsteadiness increases with increasing distortion. Since the computational results represent an asymptotic solution driven by steady boundary conditions, these numerical results may represent an arbitrary point in time. A comparison of the predicted total pressure contours with flight data indicates that the numerical results are within the excursion range of the unsteady data which is the best the calculations can attain unless an unsteady simulation is performed.

Smith, C. Frederic↗
DOE OSTI2026

2D nanoconfinement distorts the solvation structure of hydroxide but not of hydronium

Understanding ion-specific behavior in nanoconfined water is essential for controlling charge transport and selectivity in two-dimensional membranes. Motivated by recent experiments revealing anomalous dielectric and transport behavior of water confined between hBN sheets, we use machine-learning-accelerated first-principles molecular dynamics to investigate the interfacial propensities of hydronium and hydroxide ions under similar confinement. We find that hydronium remains interfacial across all confinement regimes, whereas hydroxide shifts toward the interior as the environment becomes more bulk-like. This contrasting behavior reflects the combined influence of hydrogen bonding, interfacial water layering, and the polarization of hBN, which collectively stabilize hydronium at the surface while making hydroxide slightly more favorable within the structured interior. These findings expose an asymmetry in ion-surface coupling and establish a microscopic origin for hydronium’s enhanced interfacial affinity. The results provide mechanistic insight into ion partitioning in two-dimensional channels and highlight the collective structuring of confined water as a key determinant of interfacial ion thermodynamics.

organic↗
NASA NTRS1983

Radiant heating tests of several liquid metal heat-pipe sandwich panels

Integral heat pipe sandwich panels, which synergistically combine the thermal efficiency of heat pipes and the structural efficiency of honeycomb sandwich construction, were conceived as a means of alleviating thermal stress problems in the Langley Scramjet Engine. Test panels which utilized two different wickable honeycomb cores, facesheets with screen mesh sintered to the internal surfaces, and a liquid metal working fluid (either sodium or potassium) were tested by radiant heating at various heat load levels. The heat pipe panels reduced maximum temperature differences by 31 percent with sodium working fluid and 45 percent with potassium working fluid. Results indicate that a heat pipe sandwich panel is a potential, simple solution to the engine thermal stress problem. Other interesting applications of the concept include: cold plates for electronic component and circuit card cooling, radiators for large space platforms, low distortion large area structures (e.g., space antennas) and laser mirrors.

Camarda, C. J.↗
NASA NTRS1982

Quadrupole distortions of the heliospheric current sheet in 1976 and 1977

Latitudinal variations in the position of the heliospheric current sheet were investigated using interplanetary measurements from Helios A, Helios B, IMP 8, and white light corona measurements in the period May 1976 to May 1977. The latitude of the heliospheric current sheet between 0.3 AU and I AU is consistent with that of the maximum brightness curve of white light polarization brightness at 1.75 solar radii within approximately + or - 7 deg. The combined data sets show that the four-sector magnetic sector pattern observed in the ecliptic plane for most of this epoch could be attributed to a warped current sheet whose shape near the sun resembles a saddle surface that is nearly symmetrical about the equatorial plane. The latitudinal extent of the current sheet is on the average 8 deg and the maximum extent is 15 deg (except on one rotation, when it is 20 deg). These results can be interpreted as a consequence of the solar magnetic field, the dominant components of the field being due to a dipole nearly aligned with the sun's spin axis and a quadrupole component whose strength is about 17 percent of the dipole.

Bruno, R.↗
DOE OSTI2020

Characterization of flowing liquid films as a regenerating plasma mirror for high repetition-rate laser contrast enhancement

In this paper, we characterize a high repetition-rate regenerating plasma mirror produced by the thin film of liquid formed when two laminar streams collide. The use of a flowing liquid film is inexpensive and the interaction surface refreshes automatically, avoiding buildup of on-target debris. The composition of the liquid material and the relative angle of the film-generating nozzles was optimized for this application. Spectra measured in reflection from a water-based plasma mirror showed a blue shift but an optical reflectivity of up to 30%. The thickness of the film was found to be of the order of 2 μm, and the stability of the reflected spot was ≈1 mrad. The reflected beam profile was highly distorted but stable. Further optimization of the nozzles to affect the fluid flow should enable significant improvements in control of the fluid films and increase in the reflectivity of these mirrors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Restricted Partition Function Semiclassical Transition State Theory (RPF-SCTST): Applications to Reactions Involving Hydrogen Cyanide, Hydrogen Peroxide, and Formaldehyde Oxide

We demonstrate the efficiency of the numerical calculation of thermal semiclassical transition state theory (SCTST) rates across several representative chemical reactions using the restricted partition function (RPF)─viz a function that depends only on the imaginary action associated with a reaction. Here, we treat the potential energy surfaces (PESs) through fourth order expansions around the saddle point and integrate the Hamiltonian up to second order in employing vibrational perturbation theory. We apply this formalism to uni- and bimolecular reactions with different─though relatively high─barrier heights to uncover the influence of the barrier properties, minimal energies, and separability of the rotational motion on rate constants and tunneling corrections. Although all modes are coupled within the RPF, we found in our numerical examples that the rotational component in the absence of significant rotational distortions can be separated from the vibrational contributions. Moreover, a classical treatment of the rotational contribution is adequate over the temperature range from approximately 100 to 1000 K. We also found that the choice of DFT basis set can lead to variations in rate constants of up to an order of magnitude. Lastly, different schemes for counting eligible energy levels result in rate constants that differ by no more than a factor of 2, with the remaining discrepancies attributed to the treatment of near-convergent levels in perturbation theory.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS2002

Large Coded Aperture Mask for Spaceflight Hard X-ray Images

The 2.6 square meter coded aperture mask is a vital part of the Burst Alert Telescope on the Swift mission. A random, but known pattern of more than 50,000 lead tiles, each 5 mm square, was bonded to a large honeycomb panel which projects a shadow on the detector array during a gamma ray burst. A two-year development process was necessary to explore ideas, apply techniques, and finalize procedures to meet the strict requirements for the coded aperture mask. Challenges included finding a honeycomb substrate with minimal gamma ray attenuation, selecting an adhesive with adequate bond strength to hold the tiles in place but soft enough to allow the tiles to expand and contract without distorting the panel under large temperature gradients, and eliminating excess adhesive from all untiled areas. The largest challenge was to find an efficient way to bond the > 50,000 lead tiles to the panel with positional tolerances measured in microns. In order to generate the desired bondline, adhesive was applied and allowed to cure to each tile. The pre-cured tiles were located in a tool to maintain positional accuracy, wet adhesive was applied to the panel, and it was lowered to the tile surface with synchronized actuators. Using this procedure, the entire tile pattern was transferred to the large honeycomb panel in a single bond. The pressure for the bond was achieved by enclosing the entire system in a vacuum bag. Thermal vacuum and acoustic tests validated this approach. This paper discusses the methods, materials, and techniques used to fabricate this very large and unique coded aperture mask for the Swift mission.

Vigneau, Danielle N.↗
DOE OSTI2021

Migration of inclusions in a matrix due to a spatially varying interface energy

An interfacial energy can be a function of a bulk field such as temperature or electric field. Here we find that in a system with a gradient in temperature or electric potential, the resulting variation in interfacial energy can induce a particle to migrate by either surface or bulk diffusion. For a circular particle under a constant unidirectional gradient in the bulk field, the field dependence of the interfacial energy induces a circular particle to move as a circle at a constant velocity along the direction from higher to lower interfacial energy. A linear stability analysis of this steady state migration suggests that perturbations will damp out as time evolves, and thus under these conditions a migrating circular particle is morphologically stable. Other spatial distributions of interface energy can lead to the distortion of an initially circular shaped particle during migration. A phase field model is developed that captures these distortions and verifies the theoretical results mentioned above.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Structural phase transition, s ± -wave pairing, and magnetic stripe order in bilayered superconductor La 3 Ni 2 O 7 under pressure

Motivated by the recently discovered high-T c superconductor La 3 Ni 2 O 7 , we comprehensively study this system using density functional theory and random phase approximation calculations. At low pressures, the Amam phase is stable, containing the Y 2- mode distortion from the Fmmm phase, while the Fmmm phase is unstable. Because of small differences in enthalpy and a considerable Y 2- mode amplitude, the two phases may coexist in the range between 10.6 and 14 GPa, beyond which the Fmmm phase dominates. In addition, the magnetic stripe-type spin order with wavevector (π, 0) was stable at the intermediate region. Pairing is induced in the s ± -wave channel due to partial nesting between the M = (π, π) centered pockets and portions of the Fermi surface centered at the X = (π, 0) and Y = (0, π) points. This resembles results for iron-based superconductors but has a fundamental difference with iron pnictides and selenides. Moreover, our present efforts also suggest La 3 Ni 2 O 7 is qualitatively different from infinite-layer nickelates and cuprate superconductors.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Elucidating Cathode Degradation Mechanisms in LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811)/Graphite Cells Under Fast Charge Rates Using Operando Synchrotron Characterization

Li-ion batteries capable of extreme fast charging (XFC) are in demand to facilitate widespread electric vehicle (EV) adoption. While the impact of fast charge on the negative electrode has been studied, degradation of state-of-the-art NMC811 under XFC conditions has not been studied in detail. Herein, cathode degradation is probed in NMC811/graphite batteries by analysis of structural and chemical changes for recovered samples previously cycled under XFC conditions and during typical cycling. NMC surface reconstruction, as determined by soft X-ray absorption, was not detected for recovered electrodes. Furthermore, bulk redox activity from X-ray absorption near edge structure measurements showed more change in the oxidation state of Ni and Co under the 1C charge rate compared to the 4C rate consistent with the electrochemistry. Increased unit cell volume contraction under the 1C rate as determined by operando X-ray diffraction suggests that higher charge rates may provide a protective effect on the cathode by reducing structural distortion due to less delithiation.

25 ENERGY STORAGE↗
DOE OSTI2023

Calibration of the ProtoDUNE Horizontal-Drift position reconstruction using a laser system

Forthcoming in the next decade of neutrino physics advancements is the construction of the Deep Underground Neutrino Experiment (DUNE), a long baseline neutrino oscillation experiment which has the potential to answer fundamental questions such as why there is more matter than antimatter in the universe, and ultimately why we exist at all. A prototype of this experiment, ProtoDUNE, sits in a charged particle test beam at the European Organization for Nuclear Research (CERN) and uses Liquid Argon time projection chambers to image interactions of these particles. ProtoDUNE Single-Phase (ProtoDUNESP) had positively charged hadrons as well as positrons in its initial 2018 beam data run. Because ProtoDUNE is a surface-based time projection chamber, it experiences a constant influx of cosmic rays. These cosmic rays ionize the liquid argon within the detector, resulting in an accumulation of slow moving positive ions towards the cathode. This local charge distribution results in electric field non uniformities, which can have a significant effect on the accuracy of the event reconstruction. This paper outlines a monte carlo simulation study which adapts methodology from the MicroBooNE experiment, another neutrino oscillation experiment, to derive electric field correction maps which can correct for distortions of the electric field within the detector. These correction maps accurately estimate the electric field throughout the detector volume and correct for uncertainties in reconstructed event data enabling for physics discoveries.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗