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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Hydrodynamic Characterization of a Shallow Rectangular Spouted Bed Using Bed Pressure Signals and Image Processing Methods

To support the design of spouted bed reactors, experiments are performed in a rectangular spouted bed to measure the peak pressure drop (Δ P max ) and the internal and external spouting velocities ( U is and U es ). Four particle types spanning under Geldart D and B are used. U is and U es are measured from bed pressure drop and expansion ratio profiles, respectively, with the U es / U is ratio of each particle type obtained. Additionally, correlations predicting the Δ P max of Geldart D and B particles are developed by reviewing published correlations and investigating the nozzle effect. Good prediction is achieved with a slope of 0.997 and an adjusted R 2 of 0.998 in a 95% confidence interval. U es is predicted through correlations developed by adding effects of d p / D i and H 0 in the Mathur–Gishler equation. The calculated U es agrees well with the experimental data, achieving a slope of 0.998 and an adjusted R 2 of 0.998 in a 95% confidence interval.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comparable Enhancement of TERS Signals from WSe 2 on Chromium and Gold

Plasmonic tip-sample junctions, at which the incident and scattered optical fields are localized and optimally enhanced, are often exploited to achieve ultrasensitive and highly spatially localized tip-enhanced Raman scattering (TERS). Recent work has demonstrated that the sensitivity and spatial resolution that are required to probe single molecules are attainable in such platforms. In this work, we observe and rationalize comparable TERS from few-layer WSe 2 single crystals exfoliated onto Au- and Cr-coated Si substrates, using a plasmonic TERS probe excited with a 638-nm laser. Our experimental observations are supported by finite-difference time-domain simulations that illustrate that the attainable field enhancement factors at the Au-Au and Au-Cr tip-sample nanojunctions are comparable in magnitude. Furthermore, through a combined experimental and theoretical analysis, we propose that besides Au/Ag, several metallic substrates may be used to record bright TERS spectral images.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Could Irradiation Introduce Oxidized Oxygen Signals in Resonant Inelastic X-ray Scattering of Battery Electrodes?

The characterization of oxidized oxygen states through high-efficiency mapping of resonant inelastic X-ray scattering (mRIXS) has become a crucial approach for studying the oxygen redox activities in high-energy battery cathodes. However, this approach has been recently challenged due to the concern of irradiation damage. In this work, we revisited a typical Li-rich electrode, Li 1.144 Ni 0.136 Mn 0.544 Co 0.136 O 2 , in both lithiated and delithiated states and evaluated the X-ray irradiation effect in the lengthy mRIXS experiments. Our results show that irradiation cannot introduce any oxidized oxygen feature, and the features of oxidized oxygen are weakened with a high X-ray dose. The results confirm again that mRIXS detects the intrinsic oxidized oxygen state in battery electrodes. However, the distinct irradiation effects in different systems imply that irradiation could selectively target the least stable elemental or chemical states, which should be analyzed with caution in the study of active chemical states.

25 ENERGY STORAGE↗

Distinctive Signals in 1-min Observations of Overshooting Tops and Lightning Activity in a Severe Supercell Thunderstorm

This work examines a severe weather event that took place over central Argentina on December 11, 2018. The evolution of the storm from its initiation, rapid organization into a supercell, and eventual decay was analyzed with high-temporal resolution observations. This work provides insight into the spatio-temporal co-evolution of storm kinematics (updraft area and lifespan), cloud-top cooling rates, and lightning production that led to severe weather. The analyzed storm presented two convective periods with associated severe weather. An overall decrease in cloud-top local minima IR brightness temperature (MinIR10.3), increase in overshooting top area, and lightning jump (LJ) preceded both periods. LJs provided the highest lead time to the occurrence of severe weather, with the ground-based lightning networks providing the maximum warning time of around 30 min. Lightning flash counts from the Geostationary Lightning Mapper (GLM) were underestimated when compared to detections from ground-based lightning networks. Among the possible reasons for GLM’s lower detection efficiency were an optically dense medium located above lightning sources and the occurrence of flashes smaller than GLM’s footprint. The minimum MinIR provided the shorter warning time to severe weather occurrence. However, secondary minima in MinIR10.3 that preceded the absolute minima improved this warning time by more than 10 min. Furthermore, trends in MinIR10.3 for time scales shorter than 6 min revealed shorter cycles of fast cooling and warming, which provided information about the lifecycle of updrafts within the storm. The advantages of using observations with high-temporal resolution to analyze the evolution and intensity of convective storms are discussed.

54 ENVIRONMENTAL SCIENCES↗

Climate Change Signal in Atlantic Tropical Cyclones Today and Near Future

This manuscript discusses the challenges in detecting and attributing recently observed trends in the Atlantic tropical cyclone (TC) and the epistemic uncertainty we face in assessing future risk. We use synthetic storms downscaled from five CMIP5 models by the Columbia HAZard model (CHAZ), and directly simulated storms from high-resolution climate models. We examine three aspects of recent TC activity: the upward trend and multi-decadal oscillation of the annual frequency, the increase in storm wind intensity, and the decrease in forward speed. Some data sets suggest that these trends and oscillation are forced while others suggest that they can be explained by natural variability. Projections under warming climate scenarios also show a wide range of possibilities, especially for the annual frequencies, which increase or decrease depending on the choice of moisture variable used in the CHAZ model and on the choice of climate model. The uncertainties in the annual frequency lead to epistemic uncertainties in TC risk assessment. Here, we investigate the potential for reduction of these epistemic uncertainties through a statistical practice, namely likelihood analysis. We find that historical observations are more consistent with the simulations with increasing frequency than those with decreasing frequency, but we are not able to rule out the latter. We argue that the most rational way to treat epistemic uncertainty is to consider all outcomes contained in the results. In the context of risk assessment, since the results contain possible outcomes in which TC risk is increasing, this view implies that the risk is increasing.

54 ENVIRONMENTAL SCIENCES↗