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DOE OSTI2016

Low Group Delay Dispersion Optical Coating for Broad Bandwidth High Reflection at 45° Incidence, P Polarization of Femtosecond Pulses with 900 nm Center Wavelength

We describe an optical coating design suitable for broad bandwidth high reflection (BBHR) at 45° angle of incidence (AOI), P polarization (Ppol) of femtosecond (fs) laser pulses whose wavelengths range from 800 to 1000 nm. The design process is guided by quarter-wave HR coating properties. Our design must afford low group delay dispersion (GDD) for reflected light over the broad, 200 nm bandwidth in order to minimize temporal broadening of the fs pulses due to dispersive alteration of relative phases between their frequency components. The design should also be favorable to high laser-induced damage threshold (LIDT). We base the coating on TiO 2 /SiO 2 layer pairs produced by means of e-beam evaporation with ion-assisted deposition, and use OptiLayer Thin Film Software to explore designs starting with TiO 2 /SiO 2 layers having thicknesses in a reverse chirped arrangement. This approach led to a design with R > 99% from 800 to 1000 nm and GDD < 20 fs 2 from 843 to 949 nm (45° AOI, Ppol). The design’s GDD behaves in a smooth way, suitable for GDD compensation techniques, and its electric field intensities show promise for high LIDTs. Reflectivity and GDD measurements for the initial test coating indicate good performance of the BBHR design. Subsequent coating runs with improved process calibration produced two coatings whose HR bands satisfactorily meet the design goals. Lastly, for the sake of completeness, we summarize our previously reported transmission spectra and LIDT test results with 800 ps, 8 ps and 675 fs pulses for these two coatings, and present a table of the LIDT results we have for all of our TiO 2 /SiO 2 BBHR coatings, showing the trends with test laser pulse duration from the ns to sub-ps regimes.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Reflectance-Based Vegetation Index Assessment of Four Plant Species Exposed to Lithium Chloride

This study considers whether a relationship exists between response to lithium (Li) exposure and select vegetation indices (VI) determined from reflectance spectra in each of four plant species: Arabidopsis thaliana, Helianthus annuus (sunflower), Brassica napus (rape), and Zea mays (corn). Reflectance spectra were collected every week for three weeks using an ASD FieldSpec Pro spectroradiometer with both a contact probe (CP) and a field of view probe (FOV) for plants treated twice weekly in a laboratory setting with 0 mM (control) or 15 mM of lithium chloride (LiCl) solution. Plants were harvested each week after spectra collection for determination of relevant physical endpoints such as relative water content and chlorophyll content. Mixed effects analyses were conducted on selected endpoints and vegetation indices (VI) to determine the significance of the effects of treatment level and length of treatment as well as to determine which VI would be appropriate predictors of treatment-dependent endpoints. Of the species considered, A. thaliana exhibited the most significant effects and corresponding shifts in reflectance spectra. Depending on the species and endpoint, the most relevant VIs in this study were NDVI, PSND, YI, R1676/R1933, R750/R550, and R950/R750.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2016

TESTING RELATIVISTIC REFLECTION AND RESOLVING OUTFLOWS IN PG 1211+143 WITH XMM-NEWTON AND NuSTAR

We analyze the broad-band X-ray spectrum (0.3–50 keV) of the luminous Seyfert 1/quasar PG 1211+143—the archetypal source for high-velocity X-ray outflows—using near-simultaneous XMM-Newton and NuSTAR observations. We compare pure relativistic reflection models with a model including the strong imprint of photoionized emission and absorption from a high-velocity wind, finding a spectral fit that extrapolates well over the higher photon energies covered by NuSTAR . Inclusion of the high signal-to-noise ratio XMM-Newton spectrum provides much tighter constraints on the model parameters, with a much harder photon index/lower reflection fraction compared to that from the NuSTAR data alone. We show that pure relativistic reflection models are not able to account for the spectral complexity of PG 1211+143 and that wind absorption models are strongly required to match the data in both the soft X-ray and Fe K spectral regions. In confirming the significance of previously reported ionized absorption features, the new analysis provides a further demonstration of the power of combining the high throughput and resolution of long-look XMM-Newton observations with the unprecedented spectral coverage of NuSTAR .

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1995

A Survey of Near Infrared Emission in Visual Reflection Nebulae

We present a survey for extended 2.2 emission in 20 new visual reflection nebulae, illuminated by stars with temperatures of 3,600 - 33,000 K. We detect extended 2.2 emission in 13 new nebulae we have measured J - K, H - K, and K - L', as well as obtaining surface brightness measurements of the 3.3 emission feature. All of the reflection nebulae with extended near infrared emission in excess over scattered starlight have very similar near infrared colors and show the 3.3 feature in emission with similar feature-to-continuum ratios. The 3.3 feature-to-continuum ratio ranges from 3 to 9, both within individual nebulae and from nebula to nebula, which suggests that the 3.3 feature and its underlying continuum arises from different materials, or from different ranges of sizes within a size distribution of particles. No dependence on the temperature of the illuminating star is seen in the near infrared colors or 3.3 feature-to-continuum ratio, over a factor of two in stellar temperature. This is similar to our previous IRAS results, in which we found no dependence of the ratio 12 to 100 surface brightness in reflection nebulae illuminated by stars with temperatures of 5,000-33,000 K.

Visual Reflection Nebulae↗

NASA NTRS1993

Retrieval of Surface Directional Reflectance and Hemispherical Albedo Using Multi-angle Measurements, I. Ground Level Observations

Knowledge of the directional reflectance properties of natural surfaces such as soils and vegetation canopies is essential for classification studies and canopy model inversions. Atmospheric correction schemes, using various levels of approximation, are described to retrieve surface bidirectional reflectance factors (BRFs) and directional-hemispherical reflectances (albedos) from multi-angle radiance measurements taken at ground level.

factors (BRFs) radiometric calibration sun-view an↗

NASA NTRS1992

Laboratory Reflectance Spectra of 160 Minerals, 0.4 to 2.5 Micrometers

This reports provides reflectance spectra of 160 minerals in both digital and printed form. In order to demonstrate the effect of particle size on reflectance, the spectral data for 135 of the minerals are presented at three different grain sizes. These are 125-500 microns, 45-125 microns and less than 45 microns. Ancillary information is provided with each mineral spectrum, which includes the mineral name, minerology, supplier, sampling locality and our designated sample number. The purity of every mineral sample was evaluated by X-ray diffraction (XRD). The composition of certain minerals known to deviate strongly from idealized end-member compositions was determined by electron microprobe analysis. The compositional information obtained by microbe analysis and accessory minerals identified by XRD are noted with the ancillary information. In addition, the spectrum acquired from the coarsest grain size available for each sample was processed with a feature-finding algorithm to quantify the characteristics of the spectral absorption features. All the reflectance spectra presented here are provided in digital form on IBM-compatible 3.5" diskettes. Also included on diskette is a program for displaying the spectral data and searching for spectral features that runs on an IBM-compatible PC with standard VCA graphics.

reflectance spectra↗

NASA NTRS2016

Optical Evaluation of Digital Micromirror Devices (DMDs) with UV-Grade Fused Silica, Sapphire, and Magnesium Fluoride Windows and Longterm Reflectance of Bare Devices

Digital micromirror devices (DMDs) are commercial micro-electromechanical systems, consisting of millions of mirrors which can be individually addressed and tilted into one of two states (+/-12deg). These devices were developed to create binary patterns in video projectors, in the visible range. Commercially available DMDs are hermetically sealed and extremely reliable. Recently, DMDs have been identified as an alternative to microshutter arrays for space-based multi-object spectrometers (MOS). Specifically, the MOS at the heart of the proposed Galactic Evolution Spectroscopic Explorer (GESE) uses the DMD as a reprogrammable slit mask. Unfortunately, the protective borosilicate windows limit the use of DMDs in the UV and IR regimes, where the glass has insufficient throughput. In this work, we present our efforts to replace standard DMD windows with custom windows made from UV-grade fused silica, low-absorption optical sapphire (LAOS) and magnesium fluoride (MgF2). We present transmission measurements of the antireflection coated windows and the reflectance of bare (window removed) DMDs. Furthermore, we investigated the long-term stability of the DMD reflectance and experiments for coating DMD active area with a layer of pure aluminum (Al) to boost reflectance performance in the UV spectral range (200−400 nm).

reflectance↗

NASA NTRS2017

A 30+ Year AVHRR Land Surface Reflectance Climate Data Record and Its Application to Wheat Yield Monitoring

The Advanced Very High Resolution Radiometer (AVHRR) sensor provides a unique global remote sensing dataset that ranges from the 1980's to the present. Over the years, several efforts have been made on the calibration of the different instruments to establish a consistent land surface reflectance time-series and to augment the AVHRR data record with data from other sensors such as the Moderate Resolution Imaging Spectroradiometer (MODIS). In this paper, we present a summary of all the corrections applied to the AVHRR Surface Reflectance and NDVI Version 4 Product, developed in the framework of the National Oceanic and Atmospheric Administration (NOAA) Climate Data Record (CDR) program. These corrections result from assessment of the geo-location, improvement of the cloud masking and calibration monitoring. Additionally, we evaluate the performance of the surface reflectance over the AERONET sites by a cross-comparison with MODIS, which is an already validated product, and evaluation of a downstream Leaf Area Index (LAI) product. We demonstrate the utility of this long time-series by estimating the winter wheat yield over the USA. The methods developed by [1] and [2] are applied to both the MODIS and AVHRR data. Comparison of the results from both sensors during the MODIS-era shows the consistency of the dataset with similar errors of 10%. When applying the methods to AVHRR historical data from the 1980's, the results have errors equivalent to those derived from MODIS.

AVHRR↗

NASA NTRS2018

Synoptic Ozone, Cloud Reflectivity, and Erythemal Irradiance from Sunrise to Sunset for the Whole Earth as Viewed by the DSCOVR Spacecraft from the Earth-Sun Lagrange 1 Orbit

EPIC (Earth Polychromatic Imaging Camera) on board the DSCOVR (Deep Space Climate Observatory) spacecraft is the first earth science instrument located near the earth-sun gravitational plus centrifugal force balance point, Lagrange 1. EPIC measures earth-reflected radiances in 10 wavelength channels ranging from 317.5 to 779.5 nm. Of these channels, four are in the UV range 317.5, 325, 340, and 388 nm, which are used to retrieve O3, 388 nm scene reflectivity (LER: Lambert equivalent reflectivity), SO2, and aerosol properties. These new synoptic quantities are retrieved for the entire sunlit globe from sunrise to sunset multiple times per day as the earth rotates in EPIC's field of view. Retrieved ozone amounts agree with ground-based measurements and satellite data to within 3 %. The ozone amounts and LER are combined to derive the erythemal irradiance for the earth's entire sunlit surface at a nadir resolution of 1818 km2 using a computationally efficient approximation to a radiative transfer calculation of irradiance. The results show very high summertime values of the UV index (UVI) in the Andes and Himalayas (greater than 18), and high values of UVI near the Equator at equinox.

Cloud reflectivity↗

NASA NTRS2017

GEO-LEO Reflective Band Inter-Comparison with BRDF and Atmospheric Scattering Corrections

The inter-comparison of the reflective solar bands (RSB) between the instruments onboard a geostationary orbit satellite and a low Earth orbit satellite is very helpful in assessing their calibration consistency. Himawari-8 was launched 7 October 2014 and GOES-R was launched on 19 November 2016. Unlike previous GOES instruments, the Advanced Himawari Imager (AHI) on Himawari-8 and the Advanced Baseline Imager (ABI) on GOES-R have onboard calibrators for the RSB. Independent assessment of calibration is nonetheless important to enhance their product quality. MODIS (Moderate Resolution Imaging Spectroradiometer) and VIIRS (Visible Infrared Imaging Radiometer Suite) can provide good references for sensor calibration. In this work, the inter-comparison between AHI and VIIRS is performed over a pseudo-invariant target. The use of stable and uniform calibration sites provides comparison with accurate adjustment for band spectral difference, reduction of impact from pixel mismatching, and consistency of BRDF (Bidirectional Reflectance Distribution Function) and atmospheric correction. The site used is the Strzelecki Desert in Australia. Due to the difference in solar and view angles, two corrections must be applied in order to compare the measurements. The first is the atmospheric scattering correction applied to the top of atmosphere reflectance measurements. The second correction is applied to correct the BRDF effect. The atmospheric correction is performed using a vector version of the Second Simulation of a Satellite Signal in the Solar Spectrum (6SV) model and the BRDF correction is performed using a semi-empirical model. Our results show that AHI band 1 (0.47 microns) has a good agreement with VIIRS band M3 within 0.15 percent. AHI band 5 (1.61 microns) shows the largest difference (5.09 percent) with VIIRS band M10, while AHI band 5 shows the least difference (1.87 percent) in comparison with VIIRS band I3. The methods developed in this work can also be directly applied to assess GOES-16/ABI (Geostationary Operational Environment Satellite16 / Advanced Baseline Imager) calibration consistency, a topic we will address in the future.

The inter-comparison of the reflective solar bands↗

NASA NTRSDate not supplied

Uncertainty Analysis of the GeoNEX Top-of-Atmospheric Reflectance Products Generated from the Third-Generation Geostationary Satellite Sensors

The GeoNEX (Geostationary-NASA Earth eXchange) Level-1G products consist of top-of-atmosphere (TOA) bi-directional reflectance factor (BRF) and brightness temperature generated with data streams from the latest geostationary (GEO) sensors including GOES-16/17 ABI, Himawari-8/9 AHI, and GK-2A AMI on a global tiled common grid (60oN-60o and 180oW-180oE) in geographic coordinates. With their 16 spectral bands, 0.01o/0.02o nadir spatial resolution, and 10-minute temporal resolutions, these products provide exciting opportunity to monitor Earth surface processes. However, the unique Sun-Target-Satellite geometry of geostationary sensors demands special attention in analyzing/interpreting these datasets. In this study we present a systematic analysis on the relationship between the radiometric uncertainties of the GeoNEX TOA reflectance and the corresponding solar/satellite zenith angles. We show that the signal-to-noise ratio (SNR) of the BRF are positively proportional to the square roots of the cosine of solar illuminating zenith angles. That is, the BRF data are noisier earlier in the morning or later in the afternoon than in the mid of the day. The cosine of satellite viewing zenith angles do not directly influence the SNR of the TOA BRF. However, they positively regulate the relative importance of the surface component in the TOA BRF. This means that variations in surface reflectance are more difficult to detect for pixels with larger view zenith angles, even when the SNR of the TOA BRF is the same. We are developing metrics to specify such illumination-view geometry related uncertainties in the GeoNEX L1G TOA BRF products so that this key information can be easily accessed by the user community.

Geostationary satellite↗

NASA NTRS2019

Surface Polarized Reflectance Analysis For Aerosol Remote Sensing

We study the Earth surface polarized reflectance using data collected by a space-based lidar. Accurate modelling of the surface reflectance supports retrieval algorithm development for the current and future Earth Science missions. Strong polarization of the laser light from Cloud-Aerosol Transport System (CATS) instrument, operated in 2015-2017, and nighttime measurements yield higher signal-to-noise ratio for polarization compared to the previous analysis of reflected, initially unpolarized, solar light.

Earth surface polarized reflectance↗

NASA NTRS2019

Evaluation of the Surface Reflectance Long-Term Data Record from AVHRR over Multiple Land Surface Types

In this work, we evaluate the performance of the AVHRR surface reflectance LTDR V4 using Landsat-5 Thematic Mapper (TM5) Collection-1 surface reflectance data over 440 globally distributed sites, which give a representative set of land surface types and climate conditions. Surface reflectance anisotropy effects were normalized using the VJB method, and spectral response differences were accounted for with spectral band adjustment factors (SBAFs) computed as a function of the Normalized Difference Vegetation Index (NDVI) from a set of over 100,000 hyperspectral spectra from Hyperion. The performance of the AVHRR record is reported in terms of the accuracy, precision, and uncertainty, as compared to the specifications of the reference product. Results show that the AVHRR record performance is close to the 0.071ρ+0.0071 specification defined in the original TM5 product evaluation.

LTDR↗

NASA NTRS2021

Characterization of Bidirectional Transmissive and Reflective Properties of Black Silicon

This paper describes the initial work of characterizing the transmissive and reflective properties of black silicon diffusers. The diffusers were fabricated from a 100 mm diameter black silicon sample at NASA’s Goddard Space Flight Center (GSFC). The directional hemispherical reflectance from 250 nm to 2500 nm and BRDF/BTDF measurements at 632.8 nm, 1064 nm, and 1550 nm were measured using the GSFC Diffuser Calibration Laboratory’s (DCL) spectrophotometer and optical scatterometer. The diffusers exhibit a low level of specular reflection up to ~1100 nm with no evidence of retroscatter. The measurements are traceable to those made at the National Institute of Standards and Technology (NIST).

Bidirectional Reflectance Distribution Function↗

NASA NTRS2021

MODIS Reflective Solar Bands Calibration Improvements for Collection 7

Calibration of Terra and Aqua MODIS reflective solar bands (RSB) has evolved significantly since the launch of the first MODIS instrument on the Terra satellite more than 21 years ago. In NASA’s current Collection 6 and 6.1 Level 1B products (C6/C6.1 L1B), the RSB calibration algorithm continues to rely primarily on the onboard solar diffuser to calibrate the instrument gain. Lunar observations are used to track on-orbit changes in the response versus scan angle (RVS), and data from pseudo-invariant desert sites are used to apply adjustments to the gain and RVS calibration for select bands. The resulting reflectance products have in general shown a very stable performance. In recent years, some performance degradation has been noted for a few bands and algorithm changes have been tested to further improve the calibration accuracy for the upcoming Collection 7 (C7) L1B reprocess. In this paper, we present the MODIS RSB calibration improvements that will be included in C7. Major improvements include: applying polarization correction to the desert data before using it to generateRVS for Terra bands 8, 9, 3, and 10; using ocean scene data and an interband calibration approach to correct for long-term drift of Terra bands 11 and 12; applying an updated crosstalk correction to Terra SWIR bands over the entire mission; and using data from deep convective clouds in Terra SWIR band calibration, including the addition of time-dependent RVS for bands 5 and 26. All other minor calibration changes are also covered. Overall, the reflectance differences at nadir between C6.1 and C7 are within a few percent, though the differences increase in some cases at large scan angles. The Terra visible (3, 8-12) and SWIR bands (5-7, 26) have the most significant improvements. For all other Terra bands and all Aqua bands, the C7-C6.1 differences are mostly within 1%

MODIS↗

NASA NTRS2020

Assessment of MODIS and VIIRS Calibration Consistency for Reflective Solar Bands Using Vicarious Approaches

The Moderate-Resolution Imaging Spectroradiometer (MODIS) is the key instrument of the NASA’s Earth Observing System (EOS) Terra and Aqua missions, launched in December 1999 and May 2002, respectively. The Visible Infrared Imaging Radiometer Suite (VIIRS) expands the MODIS legacy, launched onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite in October 2011 and NOAA20 satellite in November 2017, respectively. The MODIS and VIIRS sensors have a similar design with spectrally matched reflective solar spectral bands (RSB). Their on-board calibration components include a solar diffuser and a solar diffuser stability monitor for RSB, a V-grooved blackbody for the thermal emissive bands (TEB), and a space view as a background reference. This study evaluates the calibration consistency of the Terra and Aqua MODIS RSB based on the current Collection 6.1 L1B data products generated by the NASA MODAPS, which have used consistent calibration coefficient look up tables (LUT) for the entire data-record. In the case of SNPP and NOAA20 VIIRS, the latest L1B data produced by NASA Land SIPS are used. Several independent vicarious approaches are used to examine the stability and consistency of the at-sensor reflectance among MODIS and VIIRS instruments. Vicarious approaches include observations from simultaneous nadir overpasses (SNO), the Libya-4 desert and Dome C snow sites, as well as deep convective clouds (DCC). Impact of existing band spectral difference on the reflectance is corrected using hyperspectral observations provided by Europe Space Agency’s SCIAMACHY sensor. Results of this study provide comprehensive assessments of calibration performance, radiometric agreement and associated uncertainties.

MODIS↗

NASA NTRS2022

Determining the Primary Sources of Uncertainty in Retrieval of Marine Remote Sensing Reflectance From Satellite Ocean Color Sensors

Uncertainties in the retrieval of the remote sensing reflectance, R_rs, from Ocean Color (OC) satellite sensors have a strong impact on the performance of algorithms for the estimation of chlorophyll-a, mineral concentrations, and inherent optical properties (IOPs). The uncertainties are highest in the blue bands. The total radiance measured at the top of the atmosphere captures the instantaneous state of the atmosphere-ocean system: the in-water conditions, sky and Sun glint reflected from the wind-roughened ocean surface, as well as light scattered from molecules and aerosols in the atmosphere. Each of these components has associated uncertainties, and when combined with the additional uncertainties from the instrument noise and the atmospheric correction process, they contribute to the total uncertainty budget for the retrieved R_rs. We analyzed the contribution of each component uncertainties to the total R_rs uncertainties in SNPP-VIIRS level 2 products, taking advantage of the spectral differences between the components. We examined multiple scenes in the open ocean and coastal waters at spatial resolutions ranging from 2250 to 5250 m by comparing the retrieved R_rs to in situ measurements made at several AERONET-OC sites and at the MOBY site. It was shown that uncertainties associated with the molecular (Rayleigh) scattering play the most significant role, while the contributions of other components are usually smaller. Uncertainties in Rayleigh scattering are primarily attributed to the variability of Rayleigh optical thickness (ROT) with a standard deviation of approximately 1.5% of ROT, which can largely explain the frequency of negative R_rs retrievals as observed using the current standard atmospheric correction process employed by NASA. Variability of the sky light reflected from the ocean surface in some conditions also contributed to uncertainties in the blue; water variability proportional to R_rs had a very pronounced peak in the green at coastal sites.

remote sensing reflectance↗

NASA NTRSDate not supplied

Methods for Analytic Reflected Light Flux modelling in Observing Human Made Space Vehicles

During the Artemis I mission, the Orion Optical Navigation (OpNav) camera was used in a flight test to capture images of the Interim Cryogenic Propulsion Stage (ICPS) at long range. Novel methods in reflectance modelling were developed to estimate the reflected light flux as a function of range to inform the camera settings used to obtain the images. Postflight analysis was performed with the obtained images and telemetry. Techniques were developed using specialized star identification and attitude determination software to localize ICPS and positively identify it. The images were then used to verify the preflight reflected light flux as a function of range prediction and provide insight into the vehicle’s attitude dynamics.

Reflectance↗