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At least 865 records · Page 48

The effect of shear strain and shear localization on fault healing

The seismic cycle of repeated earthquake failure requires that faults regain frictional strength during the interseismic phase, when the fault is locked or undergoing quasi-static creep. Fault healing plays a central role in determining earthquake stress drop, recurrence interval, elastic radiation frequency and other source parameters. In particular, the longer a fault remains quasi-stationary, the stronger it becomes and the larger the potential stress drop can be for the next event. Here, we address the role of shear strain and strain localization on fault healing and healing rate. We performed slide-hold-slide friction experiments on quartz gouge in the double-direct shear configuration for shear strain up to 25 and hold times from 10 to 1000 s. The results show that both healing and healing rate increase nonlinearly with increasing shear strain. Frictional healing scales with volumetric strain within the laboratory fault zone. Using the volumetric strain upon reshear as a proxy for strain localization, we demonstrate that the capacity of a fault to heal is directly proportional to shear bandwidth and degree of strain localization. The more the deformation is localized, the higher are the healing and healing rate, and thus, the fault strength. Our data provide a framework for understanding variations in fault strength over the seismic cycle and the role of brecciation and strain localization on spatiotemporal variations in fault strength.

58 GEOSCIENCES↗

Magnetic Field Optimization of an In-Vacuum Undulator at NSLS-II Transactions on Applied Superconductivity

A 3.0 m long In-Vacuum Undulator (IVU) is employed at the National Synchrotron Light Source II (NSLS-II) for the Hard X-ray Nanoprobe (HXN) beamline providing structural and X-ray fluorescence imaging with world-leading spatial resolution. On July 1 st 2018 a gearbox shaft in the gap drive train assembly sheared due to corrosion fatigue caused by stress due to mechanical misalignment. Furthermore, the device was extracted from the storage ring and measured. The magnetic field measurements detected a degradation of the magnetic performance as well as a localized demagnetization of the magnetic modules of the first 3 upstream periods. We describe here the mechanical repairs and the magnetic phase shimming optimization implemented to restore the spectral performance of the device.

43 PARTICLE ACCELERATORS↗

GeSn alloys with ∼21% Sn grown by effusion cell molecular beam epitaxy

We report the epitaxial growth of high quality GeSn alloys with Sn compositions up to 21.25 ± 1% by effusion-cell molecular beam epitaxy (MBE). Achieving such a high Sn content with effusion cells is particularly significant, since these sources typically impose stronger radiative heating on the substrate, which is a factor long considered a major obstacle to high-Sn GeSn epitaxy. Contrary to the prevailing assumption that high growth rates are good for suppressing Sn segregation, we demonstrate that carefully controlled low fluxes, combined with stable ultra-low substrate temperatures, enable significant Sn incorporation even under effusion-cell conditions. Structural analyses by high-resolution x-ray diffraction, reciprocal space mapping, atomic force microscopy, and transmission electron microscopy confirm sharp interfaces, high crystallinity, and smooth surfaces at high Sn contents. Furthermore, these findings establish the feasibility of MBE-grown high-Sn GeSn even under diffusion cells, thereby broadening opportunities for Si-compatible photonic and quantum devices.

Alloys↗

Aerosol and Cloud Optical Properties from the ARM Raman Lidars: The Feature Detection and Extinction (RLPROF-FEX) Value-Added Product

Aerosols and their interactions and influence on clouds are among the main sources of uncertainties in radiative direct and indirect forcing (IPCC 2013). Continuous height-resolved measurements of cloud and aerosol optical properties are needed to reduce these uncertainties. Here we describe the Raman Lidar Profiles – Feature detection and Extinction (RLPROF-FEX) Value-Added Product (VAP) derived using Raman lidar data at multiple U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility sites. RLPROF-FEX provides estimates of extinction, backscatter, and depolarization using the algorithm described by Thorsen et al. 2015 and Thorsen and Fu 2015. This document provides a description of the FEX algorithm, its input and output data, and related details about the Raman lidar (RL) system.

54 ENVIRONMENTAL SCIENCES↗

Passivated Interfaces and Surface Recombination Velocities in Halide Perovskites

Surfaces and charge-extracting contacts remain major sources of non-radiative recombination loss; limiting the performance of perovskite PV compared to theoretical limits. We investigate mixed-cation mixed-halide perovskites and demonstrate that, with chemical surface passivation, they can achieve >4 μs minority carrier lifetimes, and >20% external PL quantum yields (PLQY), and nearly single-exponential decay kinetics. This high PLQY observed corresponds to ~97% of the Shockley-Queisser theoretical quasi-fermi level splitting, a first for MA-free mixed-cation mixed-halide compositions. The high PLQY and long PL lifetimes allow us to measure average surface recombination velocities (SRV) <10cm/s, with a champion low of ~1cm/s (a conservative estimate). We show how such improvements in SRV should lead to an absolute improvement in PCE of >4% even with the best of contact alignments. We investigate different MA-free high bandgap compositions, including bandgaps relevant for tandem applications (1.7-1.8eV), and demonstrate performance improvements across all these compositions with our surface passivation strategy. Lastly, using a combination of surface characterization techniques, we show Lewis base interactions of the passivating agent with the perovskite surfaces.

14 SOLAR ENERGY↗

Passivated Interfaces and Surface Recombination Velocities in Halide Perovskites

Surfaces and charge-extracting contacts remain major sources of non-radiative recombination loss; limiting the performance of perovskite PV compared to theoretical limits. We investigate mixed-cation mixed-halide perovskites and demonstrate that, with chemical surface passivation, they can achieve >4 μs minority carrier lifetimes, and >20% external PL quantum yields (PLQY), and nearly single-exponential decay kinetics. This high PLQY observed corresponds to ~97% of the Shockley-Queisser theoretical quasi-fermi level splitting, a first for MA-free mixed-cation mixed-halide compositions. The high PLQY and long PL lifetimes allow us to measure average surface recombination velocities (SRV) <10cm/s, with a champion low of ~1cm/s (a conservative estimate). We show how such improvements in SRV should lead to an absolute improvement in PCE of >4% even with the best of contact alignments. We investigate different MA-free high bandgap compositions, including bandgaps relevant for tandem applications (1.7-1.8eV), and demonstrate performance improvements across all these compositions with our surface passivation strategy. Lastly, using a combination of surface characterization techniques, we show Lewis base interactions of the passivating agent with the perovskite surfaces.

passivation↗

Algorithm Theoretical Basis Document For PreMevE 2.0 Model

Man-made satellites operating in medium- and high-altitude Earth orbits are continuously exposed to hazardous space radiation originated from different sources. Among them, one major contributor is the relativistic electron population—with kinetic energies comparable to or larger than their rest energy of 0.511 Megaelectron-volt (MeV)—trapped inside Earth’s outer Van Allen belt. Owing to their high penetration capability, these MeV electrons are difficult to be fully stopped by normal shielding. Particularly, during MeV electron events when electron intensities across the outer belt are greatly elevated to sustaining high levels—up to 10 3 - 10 4 times as observed in the geosynchronous (GEO) orbit and low-Earth-orbits (LEOs), space-borne electronic systems with inadequate hardening are susceptible to deep-dielectric charging and discharging phenomenon caused by those electrons, and thus may suffer severe damages or even stop functioning. Therefore, protecting critical space infrastructures from harsh space weather conditions– including MeV electron events – has high priority for many space sectors, such as the aerospace industry, service providers and government agencies.

79 ASTRONOMY AND ASTROPHYSICS↗

ML based control systems for nuclear physics experiments

The Experimental Physics Software and Computing Infrastructure (EPSCI) group at Jefferson Lab is leading the use of machine learning (ML) to enhance control systems in nuclear physics experiments. Collaborating closely with domain experts and data scientists, we have developed an ML-based control system that uses a Gaussian process to dynamically adjust the high voltage of the GlueX Central Drift Chamber. This results in stable detector performance by adapting to environmental changes, thereby reducing the offline calibration effort. Furthermore, we are developing ML-driven systems for optimizing the polarization of photon beams and polarized cryotargets. These systems will maintain the optimal microwave frequency in cryogenic targets and make real-time adjustments to diamond radiators for polarized photon sources, tasks traditionally handled by human operators. By automating these functions, we aim to optimize the polarization, reduce downtime, and minimize human error. This talk will highlight the development of reliable ML-based control systems and the policies to ensure they are both effective and trustworthy.

Jeske, Torri↗

Assessment of Hydroxyl Radical Reactivity in Sulfur-Containing Amino Acid Models Under Acidic pH

Methionine residues in proteins and peptides are frequently oxidized by losing one electron. The presence of nearby amide groups is crucial for this process, enabling methionine to participate in long-range electron transfer. Hydroxyl radical (HO•) plays an important role being generated in aerobic organisms by cellular metabolisms as well as by exogenous sources such as ionizing radiations. The reaction of HO• with methionine mainly affords the one-electron oxidation of the thioether moiety through two consecutive steps (HO• addition to the sulfur followed by HO− elimination). We recently investigated the reaction of HO• with model peptides mimicking methionine and its cysteine-methylated counterpart, i.e., CH3C(O)NHCHXC(O)NHCH3, where X = CH2CH2SCH3 or CH2SCH3 at pH 7. The reaction mechanism varied depending on the distance between the sulfur atom and the peptide backbone, but, for a better understanding of various suggested equilibria, the analysis of the flux of protons is required. We extended the previous study to the present work at pH 4 using pulse radiolysis techniques with conductivity and optical detection of transient species, as well as analysis of final products by LC-MS and high-resolution MS/MS following γ-radiolysis. Comparing all the data provided a better understanding of how the presence of nearby amide groups influences the one-electron oxidation mechanism.

Biochemistry & Molecular Biology↗

General Relativistic Stability and Gravitational Wave Content of Rotating Triaxial Neutron Stars

Triaxial neutron stars can be sources of continuous gravitational radiation detectable by ground-based interferometers. The amplitude of the emitted gravitational wave can be greatly affected by the state of the hydrodynamical fluid flow inside the neutron star. In this work, we examine the most triaxial models along two sequences of constant rest mass, confirming their dynamical stability. We also study the response of a triaxial figure of quasiequilibrium under a variety of perturbations that lead to different fluid flows. Starting from the general relativistic compressible analog of the Newtonian Jacobi ellipsoid, we perform simulations of Dedekind-type flows. We find that in some cases the triaxial neutron star resembles a Riemann-S-type ellipsoid with minor rotation and gravitational wave emission as it evolves towards axisymmetry. The present results highlight the importance of understanding the fluid flow in the interior of a neutron star in terms of its gravitational wave content.

Luo, Yufeng (ORCID:0000000246230683)↗

Simulating dust grain-radiation coupling on a moving mesh

ABSTRACT We present a model for the interaction between dust and radiation fields in the radiation hydrodynamic code arepo-rt, which solves the moment-based radiative transfer equations on an unstructured moving mesh. Dust is directly treated using live simulation particles, each of which represent a population of grains that are coupled to hydrodynamic motion through a drag force. We introduce methods to calculate radiation pressure on and photon absorption by dust grains. By including a direct treatment of dust, we are able to calculate dust opacities and update radiation fields self-consistently based on the local dust distribution. This hybrid scheme coupling dust particles to an unstructured mesh for radiation is validated using several test problems with known analytic solutions, including dust driven via spherically symmetric flux from a constant luminosity source and photon absorption from radiation incident on a thin layer of dust. Our methods are compatible with the multifrequency scheme in arepo-rt, which treats UV, optical photons as single scattered and IR photons as multi scattered. At IR wavelengths, we model heating of and thermal emission from dust. Dust and gas are not assumed to be in local thermodynamic equilibrium but transfer energy through collisional exchange. We estimate dust temperatures by balancing these dust-radiation and dust-gas energy exchange rates. This framework for coupling dust and radiation can be applied in future radiation hydrodynamic simulations of galaxy formation.

79 ASTRONOMY AND ASTROPHYSICS↗

The Zwicky Transient Facility phase I sample of hydrogen-rich superluminous supernovae without strong narrow emission lines

ABSTRACT We present a sample of 14 hydrogen-rich superluminous supernovae (SLSNe II) from the Zwicky Transient Facility (ZTF) between 2018 and 2020. We include all classified SLSNe with peaks Mg < −20 mag with observed broad but not narrow Balmer emission, corresponding to roughly 20 per cent of all hydrogen-rich SLSNe in ZTF phase I. We examine the light curves and spectra of SLSNe II and attempt to constrain their power source using light-curve models. The brightest events are photometrically and spectroscopically similar to the prototypical SN 2008es, while others are found spectroscopically more reminiscent of non-superluminous SNe II, especially SNe II-L. 56Ni decay as the primary power source is ruled out. Light-curve models generally cannot distinguish between circumstellar interaction (CSI) and a magnetar central engine, but an excess of ultraviolet (UV) emission signifying CSI is seen in most of the SNe with UV data, at a wide range of photometric properties. Simultaneously, the broad H α profiles of the brightest SLSNe II can be explained through electron scattering in a symmetric circumstellar medium (CSM). In other SLSNe II without narrow lines, the CSM may be confined and wholly overrun by the ejecta. CSI, possibly involving mass lost in recent eruptions, is implied to be the dominant power source in most SLSNe II, and the diversity in properties is likely the result of different mass loss histories. Based on their radiated energy, an additional power source may be required for the brightest SLSNe II, however – possibly a central engine combined with CSI.

Kangas, T. (ORCID:0000000254770217)↗

Development of the Mobile Systems for Conditioning of Disused Sealed Radioactive Sources in Serbia - 20105

Sealed radioactive sources (SRS) are being used worldwide in the field of medicine, agriculture, industry and research. They can be found in mobile as well as stationary devices. SRS contains radioactive material that is (a) permanently sealed in a capsule or (b) closely bounded and in a solid form. The capsule or material of an SRS should be strong enough to maintain leak tightness under the conditions of use and purpose for which the source was designed, also in case of accidents. In this case only emitted radiation is utilized. Firstly, the hazard from external radiation has to be considered, but the possibility of contamination due to fracture of the capsule should not be disregarded. The radioactive sources are composed of the radiating isotope contained in the filling medium, the single or double isotope holder that partially or totally surrounds the filling medium, the outer cover that contains the parts mentioned above and the capsule closed airtightly by welding or using some other method. The capsule must be tested for leakage periodically. If the SRS is no longer needed (e.g. replaced by a different technique) or it becomes useless for the intended application (e.g. the activity becomes too weak, the equipment containing the source works poorly or becomes obsolete, the source is damaged or leaking) it is considered disused. Disused sealed radioactive sources (DSRS) are typically conditioned and disposed if a facility is available. If the disposal option is not available, conditioned DSRS should be stored under proper conditions. In some cases, the radionuclide(s) in DSRS can be recovered/recycled or the DSRS can be repurposed for other applications. Conditioning of DSRS ensures containment of the radioactive material, provides confinement for leaking sources, provides sufficient radiation shielding, reduces storage/disposal volume by allowing consolidation of multiple sources into a single storage/disposal container, facilitates transport operations and contributes to safety and security as well. Typically, conditioning technologies are deployed either as permanently installed stationary systems in centralized or mobile on-site waste processing facilities, or in a mobile configuration. Centralized stationary facilities provide a single processing location for multiple users that requires transport of the waste to the facility. On the other hand, mobile systems may be provided for the selection and application of the optimum technology for a specific waste stream (such as DSRS) by bringing the process to the point where the waste is generated. In addition, mobile systems could offer additional flexibility by sharing equipment among multiple waste generating sites for processing campaigns that vary in duration, from very short periods to several years. The term 'mobile processing system' refers to any radioactive waste processing system or component which is designed to be transportable and which is not considered permanently installed. Two mobile system for conditioning of disused sealed radioactive sources are developed in the Public Company Nuclear Facilities of Serbia. Development of these mobile systems was supported by SRB9005 national project via Technical Cooperation of the IAEA. The first mobile system, built inside the 20 feet ISO container, will be used for conditioning of DSRS category 3 to 5. The second mobile system, built inside the 7 m long vehicle (Iveco Daily Van), will be used for dismantling of ionizing smoke detectors mostly with Am-241 sources. Designs of the mobile systems were defined in cooperation with two companies from Belgium (Belgoprocess and Leniko) and a Croatian company Ekoteh as well as with the support of the IAEA experts. The generic safety assessment and operational procedures for the mobile systems are developed. Based on safety assessment the acceptance criteria and operational limits and conditions are established. Operational procedures include: (a) equipment and material requirements, (b) assembling procedure of the mobile unit, (c) procedure for acceptance of devices for dismantling and conditioning, (d) dismantling procedure for devices to recover the DSRS, (e) characterization of DSRS, (f) encapsulation procedure of DSRS, (g) disassembling procedure of the mobile unit, and (h) keeping records, identification and traceability. In addition, radiation safety, health safety, security and emergency preparedness plans are prepared. The generic safety assessment and operational procedures could be updated with site specific requirements, DSRS inventory, and different needs for future customers. Developed mobile systems could be used in all situations when it is feasible to perform conditioning of DSRS on the spot in the county and worldwide. Development of these mobile units was just the first step to create the Reference Center for Radioactive Waste Treatment and Disused Radioactive Sources Conditioning for Small Facilities which can become a regional training center in the future, and/or as a tool for comprehensive national search and secure programmes. In the next phases development of e-learning platforms and blended learning packages as well as application for the IAEA Qualified Technical Centre (QTC) for the management of DSRS is foreseen. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cloud water adjustments to aerosol perturbations are buffered by solar heating in non-precipitating marine stratocumuli

Abstract. Marine low-level clouds are key to the Earth's energy budget due to their expansive coverage over global oceans and their high reflectance of incoming solar radiation. Their responses to anthropogenic aerosol perturbations remain the largest source of uncertainty in estimating the anthropogenic radiative forcing of climate. A major challenge is the quantification of the cloud water response to aerosol perturbations. In particular, the presence of feedbacks through microphysical, dynamical, and thermodynamical pathways at various spatial and temporal scales could augment or weaken the response. Central to this problem is the temporal evolution in cloud adjustment, governed by entangled feedback mechanisms. We apply an innovative conditional Monte Carlo subsampling approach to a large ensemble of diurnal large-eddy simulation of non-precipitating marine stratocumulus to study the role of solar heating in governing the evolution in the relationship between droplet number and cloud water. We find a persistent negative trend in this relationship at night, confirming that the role of microphysically enhanced cloud-top entrainment. After sunrise, the evolution in this relationship appears buffered and converges to ∼-0.2 in the late afternoon. This buffering effect is attributed to a strong dependence of cloud-layer shortwave absorption on cloud liquid water path. These diurnal cycle characteristics further demonstrate a tight connection between cloud brightening potential and the relationship between cloud water and droplet number at sunrise, which has implications for the impact of the timing of advertent aerosol perturbations.

Zhang, Jianhao (ORCID:0000000169882935)↗

Source Attribution of Methane Enhancements at the Southern Great Plains Atmospheric Radiation Measurement Site Field Campaign Report

Tower data from 2017 to 2020 revealed that the U.S. Department of Energy’s Southern Great Plains (SGP) Atmospheric Radiation Measurements (ARM) observatory in Oklahoma exhibited significant CH 4 enhancements compared to other U.S. tower sites. On average, near-surface CH 4 at the ARM site was higher, had larger diurnal and seasonal variations, and had sharper near-surface increases at night compared to other tower sites in the U.S. A field campaign was conducted in June 2024 to identify and quantify the surrounding CH 4 emission sources by two researchers from the University of Oklahoma. During the campaign, a mobile measurement was conducted using a LI-COR 7810 tracer gas analyzer mounted on a vehicle during June 23-26, 2024 near the SGP site (within 7 km distance). We sampled CH 4 along predefined routes surrounding a suspected source, i.e., a large animal feeding operation (AFO) farm 5.8 km northwest of the SGP ARM site. Measurements were collected between 04:30 and 09:00 local time when the planetary boundary layer (PBL) was shallow, increasing sensitivity to surface emissions. Driving speed was kept below 5 mph to minimize pressure-related artifacts. CH 4 concentrations downwind of the AFO exceeded 6000 ppb on the early morning of June 26, corresponding to an emission rate of ~95 kg⋅hr -1 estimated using the mass balance method. Additional sources identified during the campaign include nearby open-range cattle and leaks from a nearby natural gas pipeline.

54 ENVIRONMENTAL SCIENCES↗

Empirical Acoustic Source Model for Chemical Explosions in Air

Chemical explosions generate pressure disturbances in air that radiate as nonlinear shock waves near the source and transition into acoustic waves with distance. Because low-frequency acoustic waves generally travel large distances without significant loss of energy, they are often used for explosion monitoring and yield estimation. However, quantitative relationships between acoustic energy and explosion yields are required for accurate yield estimation. Here, we develop an empirical acoustic source model for chemical explosions from experimental data. The empirical model returns the acoustic pressure waveform for the detonation of 1 kg of trinitrotoluene, which is conventionally used to represent the explosive release of 4.184 MJ of explosion energy. The full-waveform model can be used to predict acoustic signals for an arbitrary yield of a high-explosive detonation based on the standard scaling law and to estimate acoustic energies in a specific frequency range. We evaluate the accuracy of the acoustic source model independently by estimating the yield of other explosive events that are not included in the model development. Finally, statistical characteristics of the model and their implications for the uncertainty quantification of estimated yields are discussed.

58 GEOSCIENCES↗

Investigation of Best-Practices and Computationally Inexpensive Radiative Exchange Models for Discrete Element Method Modeling of Aluminosilicate Particles in Concentrating Solar Power Environments

Chemically inert, aluminosilicate based particles have been investigated as both a thermal transport and sensible energy storage medium for concentrating solar power facilities. These particles will experience a wide range of operating temperatures (300-1000 K) and handling conditions (dense to dilute falling particle curtains, dense granular flows, or dense structures), requiring specially-designed and optimized infrastructures. The relative influence of collisional and frictional interactions between particles varies based on temperature-dependent particulate properties and greatly impacts the bulk, granular flow behavior. These underlying physics are captured using discrete element method modeling tools. However, this modeling method is computationally expensive as each particle position and interaction is tracked during the simulation. These modeling methods are further complicated by introducing temperature-dependent particle properties, high-temperature radiative exchange, and directional irradiation sources experienced by granular flows in concentrating solar power environments. In this study, coupled experimental and numerical slump testing of aluminosilicate particles was performed and computationally efficient radiative exchange models were evaluated to establish best-practices for discrete element method models for concentrating solar power environments. The three particle types investigated included Carbobead HSP 30 /60, Carbobead CP 30/60, and Granusil 4030. Existing modeling limitations and computationally-efficient multi-modal heat transfer models were evaluated using Aspherix®, a commercial discrete element method software. High-temperature (< 1073 K) slump testing of aluminosilicate particles was performed to investigate the deviation between experimentally-observed and numerically-predicted angles of repose introduced by computation-time reduction practices including the relaxation of the particle elastic modulus and coarse-graining. Coarse-graining is used to use a single modeled particle that is representative of a collection of smaller particles, decreasing the computational cost at the expense of geometric accuracy. Additionally, relaxation of the elastic modulus is used to reduce computational time at the expense of an increased, modeled particle overlap. Prior studies have determined that aluminosilicate particles retain a high elastic modulus at high temperatures (< 1073 K), requiring small simulation timesteps to ensure resolved contact forces resemble appropriate solid mechanics. A parametric study was performed to evaluate the influence of computation time improvements on the deviation between experimental and modeled angle of repose across high temperatures < 1073 K. Additionally, numerical case studies were performed on candidate particle systems at varying porosities and temperatures. These studies were performed to investigate the influence of computationally-efficient radiative-exchange modeling methods coupled to Aspherix® on modeled accuracy and computation time. The recently-developed distance-based approximation was evaluated in estimating radiative exchange between particles and participating surfaces located in close proximity. The distance based approximation was developed to use tabulated estimates of the radiative distribution factor between individual particles and surfaces in close proximity (< 40 particle radii). These methods were expanded to the aluminosilicate particles of interest, including the influence of particle size distributions. To capture radiative exchange between particles and surfaces not in close proximity (> 40 particle radii) and to capture the absorption of directional irradiation from concentrating solar resources, a volumetrically-averaged radiative distribution factor was calculated between the modeled granular flow and surfaces using Monte Carlo ray-tracing for participating media. Volume-averaged absorption and scattering coefficients were predicted using a volumetric discretization of the modeled domain with monodisperse approximations based on geometric optics and experimentally-determined scattering phase functions for aluminosilicate particles.

14 SOLAR ENERGY↗