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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Optical Properties of Wigglers for EIC Ring Electron Cooler

Electron Ion Collider (EIC) requires cooling of protons at top energy (275 GeV) to achieve the average design luminosity. Such a cooler must be capable of counteracting an IBS-driven emittance growth in proton bunches. The Ring Electron Cooler (REC) is a candidate for the EIC top energy cooler. The REC is a non-magnetized RF-based 150 MeV electron cooler, in which electrons are kept in the storage ring and re-utilized for several million turns. The REC is equipped with 18 damping wigglers, which keep electrons’ emittance constant by counteracting both electrons’ IBS and a proton electron beam-beam scattering happening in the cooling section. These wigglers operate at a relatively low energy but must have a rather high field to provide the required radiation cooling of electrons. As a result of this unique range of parameters, the wigglers’ optics exhibits interesting features The actual design parameters of the wigglers will be finalized in the REC lattice optimization.

43 PARTICLE ACCELERATORS↗
NASA NTRS1973

Quantum theory of an optical maser. VI - Transient behavior.

The transient behavior of a laser is discussed using the quantum theory as did Scully and Lamb. The formal solution of the density-matrix equation is expressed in terms of exponentially decaying eigenmodes. Some of the lower decay constants are obtained numerically. The equations for the moments of the density matrix are then derived and solved by a truncation method. The equations of motion are integrated numerically for the case where the average number of photons in a laser cavity has the realistically large value 1.3 x 100,000. An alternative Fokker-Planck-equation approach is discussed.

Wang, Y. K.↗
NASA NTRS1976

Optical observation of WRA 977 (3U 1233-62?)

UBV photometry of WRA 977 on 36 nights between January and July of 1974 shows that this object is active on a time scale of days at the 0.1 mag level, but that it remains quite constant during monitoring intervals lasting up to 1 hour. Periodogram analysis reveals no significant periodic variation in the brightness of this object.

Bord, D. J.↗
DOE OSTI2022

Weak-Bonding Elements Lead to High Thermoelectric Performance in BaSnS 3 and SrSnS 3 : A First-Principles Study

SnS2, an earth-abundant and ecofriendly material, is limited as a thermoelectric material because of the high lattice thermal conductivity κ L and low carrier mobility μ. By introducing weak-bonding elements Ba or Sr into the SnS 2 framework, we discovered two SnS 2 -based materials BaSnS3 and SrSnS3 with the calculated low κL values of 0.15 and 0.17 W m -1 K -1 , respectively, along the a-axis. The low group velocity and high lattice anharmonicity originating from the weakened and distorted Sn–S bonding network are found in both systems. Moreover, the vibrations of Ba and Sr induce low-lying optical phonons, which strongly couple with the acoustic phonons and strengthen the phonon scattering rates. Compared to SnS 2 , both compounds present lower single-band effective masses, smaller deformation potential constants, and better band convergence, which enhance μ with an insignificantly reduced effective mass. By solving the linearized Boltzmann transport equation with a nonempirical carrier lifetime, we predict excellent ZT values of 2.89 and 2.77 along the a-axis at 900 K in BaSnS 3 and SrSnS 3 , respectively. Further phase diagram calculations of Ba 1–x Sr x SnS 3 solid solutions propose a new compound, Ba 0.5 Sr 0.5 SnS 3 , with an even higher ZT of 3.0. Our work analyzes explicitly how weak-bonding elements enhance μ and suppress κL simultaneously in SnS 2 -analogous systems with a series of compounds nominated as potential high-performance thermoelectric materials.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Free energy difference to create the M-OH* intermediate of the oxygen evolution reaction by time-resolved optical spectroscopy

Theoretical descriptors differentiate the catalytic activity of materials for the oxygen evolution reaction by the strength of oxygen binding in the reactive intermediate created upon electron transfer. Recently, time-resolved spectroscopy of a photo-electrochemically driven oxygen evolution reaction followed the vibrational and optical spectra of this intermediate, denoted M-OH*. However, these inherently kinetic experiments have not been connected to the relevant thermodynamic quantities. Here we discover that picosecond optical spectra of the Ti-OH* population on lightly doped SrTiO 3 are ordered by the surface hydroxylation. A Langmuir isotherm as a function of pH extracts an effective equilibrium constant relatable to the free energy difference of the first oxygen evolution reaction step. Thus, time-resolved spectroscopy of the catalytic surface reveals both kinetic and energetic information of elementary reaction steps, which provides a critical new connection between theory and experiment by which to tailor the pathway of water oxidation and other surface reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Aqueous processing of organic semiconductors enabled by stable nanoparticles with built-in surfactants

The introduction of oligoether side chains onto a polymer backbone can help to stabilise polymeric dispersions in water without the necessity of surfactants or additives when conjugated polymer nanoparticles are prepared. A series of poly(3-hexylthiophene) (P3HT) derivatives with different content of a polar thiophene derivative 3-((2-methoxyethoxy)methyl)thiophene was interrogated to find the effect of the polar chains on the stability of the formed nanoparticles, as well as their structural, optical, electrochemical, and electrical properties. Findings indicated that incorporation of 10–20 percent of the polar side chain led to particles that are stable over a period of 42 days, with constant particle size and polydispersity, however the particles from the polymer with 30 percent polar side chain showed aggregation effects. The polymer dispersions showed a stronger solid-like behaviour in water with decreasing polar side chain content, while thin film deposition from water was found to afford globular morphologies and crystallites with more isotropic orientation compared to conventional solution-processed films. As a proof-of-principle, field-effect transistors were fabricated directly from the aqueous dispersions demonstrating that polymers with hydrophilic moieties can be processed in water without the requirement of surfactants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

Anti-reflection coatings on large area glass sheets

Antireflective coatings which may be suitable for use on the covers of photovoltaic solar modules can be easily produced by a dipping process. The coatings are applied to glass by drawing sheets of glass vertically out of dilute aqueous sodium silicate solutions at a constant speed, allowing the adherent liquid film to dry, then exposing the dried film to concentrated sulfuric acid, followed by a water rinse and dry. The process produces coatings of good optical performance (96.7 percent peak transmission at 0.540 mu M wavelength) combined with excellent stain and soil resistance, and good resistance to abrasion. The process is reproduceable and easily controlled.

Pastirik, E.↗
NASA NTRS1982

30/20 GHz communications satellite multibeam antenna

A 20 GHz downlink satellite antenna design is described. The aperture simultaneously radiates 18 fixed, 0.3 deg width pencil beams directed at 18 cities distributed over CONUS for Trunking Service. All beams use the same trunk frequency allocation for 18 reuses of the band. The same aperture also radiates six additional 0.3 deg spot beams for Customer Premises Service (CPS) for TDMA beam hopping operation to small terminals anywhere in CONUS. Each CPS beam scans one sector of CONUS and all six beams are frequency reused in a CPS band. Offset dual reflector optics are used with a feed array and multiport beam forming network (BFN). For so many frequency reuses, sidelobes per beam must be 30 to 40 dB down over CONUS. Novel dual reflector optics were devised with shaped surfaces providing low aberrations for all beam positions over CONUS (+ or - 12 BW by + or - 5 BW). Scan loss under 1 dB is calculated with nearly constant sidelobes. For each beam position, a 7-element cluster of feeds is activated in the feed array with coefficients adjusted by the BFN to maintain low sidelobes and thus high beam isolation for frequency reuse.

Scott, W. G.↗
NASA NTRS1987

Molecular and atomic clouds associated with infrared cirrus in Ursa Major

Observations of CO and H I revealed that in Ursa Major the high-latitude far-infrared 'cirrus' emission discovered by the Infrared Astronomical Satellite comes from molecular and atomic clouds. These clouds differ sufficiently from the large clouds in the Galactic plane so that the ratio of H2 column density to velocity-integrated CO radiation temperature, N(H2)/W(CO), derived from Galactic plane surveys, may not apply to them. On the assumption of a constant gas-to-dust ratio, it is argued that the cirrus emission in Ursa Major is a good mass tracer, since both the atomic and the molecular gas are probably optically thin at visual wavelengths, and the grains are heated not by local sources but by the background field of Galactic starlight. The N(H2)/W(CO) ratio thus derived for those diffuse clouds, is significantly lower than the ratio applicable to Galactic plane surveys.

De Vries, Hendrik Willem↗
NASA NTRS1988

Analysis of IUE data on V426 Ophiuchi - Outburst and orbital variability

Time-resolved IUE spectra throughout two orbits of the dwarf nova V426 Oph during quiescence are presented. It is found that the visual and C IV fluxes remain relatively constant during both orbits, whereas the UV coninua and Mg II lines vary by 20-30 percent. The time scales of this variability are discussed. Analysis of other spectra at brighter optical magnitudes shows that the UV lags the optical during a probable rise to outburst, similar to the behavior of SS Cyg. The reddening of V426 Oph is determined to be E(B-V) = 0.1. The contribution of the white dwarf to the UV flux at quiescence is estimated to be 25 percent, based on the system parameters of Hessman (1988) and the period-temperature relation of Sion (1987).

Szkody, Paula↗
NASA NTRS1994

High-Speed Hubble Space Telescope Ultraviolet photometry of two DB white dwarfs: Nonradial and radial pulsations

We observed two DB white dwarf stars with the High Speed Photometer aboard the Hubble Space Telescope. The two targets, the nonradial pulsator GD 358, and PG 0112+104, a non-pulsating white dwarf with similar temperature, were each observed for 1800 s with a time resolution of 10 ms. We used the F140LP configuration, which gives a broadband response in the UV between 1400 and 3000 A. The data clearly show the long period (about 700 s) pulsations in GD 358. Comparison with optical observations obtained two weeks earlier shows that the amplitude of the pulsations in the UV is approximately 1.4 times higher, consistent with nonradial pulsations due solely to temperature changes at constant radius. The high time resolution of these observations allows us to search for high-frequency pulsations (such as p modes or high overtone radial modes). No firm evidencefor high-frequency pulsations was seen in either object between 1 and 12 Hz. Correlation analysis of GD 358 shows no clear signal of multifrequency high overtone radial pulsations at the 0.00075 mag level, with no individual modes above the 0.0016 mag level. Upper limits for PG 0112+104 are approximately 2 times higher than for GD 358. Implications of this study for the theory of white dwarf pulsations are discussed.

Kawaler, Steven D.↗
NASA NTRS2017

Precision Asteroid Astrometry

Among the methods used to guide spacecraft to their destinations, Optical Navigation (OpNav) remains an effective option. OpNav makes use of star fields and small body ephemerides to precisely locate spacecraft. To facilitate accurate OpNav, the small body ephemerides must be constantly updated; asteroid orbits accumulate errors each year of a few milliarcseconds. Through extended exposures, taken with strategic offsets, a least-squares solution can be found that determines updated ephemeris data. This updated data can also be used by occultation astronomers to gain further information about the small bodies, including their size and shape. Using the 24-inch telescope at the Caltech Table Mountain Observatory (TMO), we capture two or more 180 second exposures of each target. These images, combined with a file for the predicted background star field and two reference files, are then processed through a series of scripts and programs. Starting with a prediction file and two to five exposures of the asteroid, the data is processed. This original data is about 32MB per observation. Once the data are reduced to only Right Ascension and Declination for each target, the data are ready for delivery. This consists of text only, and for each target takes about 80 bytes; this resulting data reduction is about five orders of magnitude. This method produces observed positions that are refined by about 12 milliarcseconds, a refinement that is accomplished almost nowhere else. The occultation observations that are facilitated by the ephemerides being refined also produce results that are not possible in any other way from ground-based observations.

Dial, Jason↗
NASA NTRS2006

Monitoring Temperatures of Tires Using Luminescent Materials

A method of noncontact, optical monitoring of the surface temperature of a tire has been devised to enable the use of local temperature rise as an indication of potential or impending failures. The method involves the use of temperature-sensitive paint (or filler): Temperature-sensitive luminescent dye molecules or other luminescent particles are incorporated into a thin, flexible material coating the tire surface of interest. (Alternatively, in principle, the luminescent material could be incorporated directly into the tire rubber, though this approach has not yet been tested.) The coated surface is illuminated with shorter-wavelength light to excite longer-wavelength luminescence, which is observed by use of a charge-coupled-device camera or a photodetector (see Figure 1). If temporally constant illumination is used, then the temperature can be deduced from the known temperature dependence of the intensity response of the luminescence. If pulsed illumination is used, then the temperature can be deduced from the known temperature dependence of the time or frequency response of the luminescence. If sinusoidally varying illumination is used, then the temperature can be deduced from the known temperature dependence of the phase response of the luminescence. Unlike a prior method of monitoring the temperature at a fixed spot on a tire by use of a thermocouple, this method is not restricted to one spot and can, therefore, yield information on the spatial distribution of temperature: in particular, it enables the discovery of newly forming hot spots where damage may be starting. Also unlike in the thermocouple method, the measurements in this method are not vulnerable to breakage of wires in repeated flexing of the tire. Moreover, unlike in another method in which infrared radiation is monitored as an indication of surface temperature, the luminescence measurements in this method are not significantly affected by changes in infrared emissivity. This method has been demonstrated in application to the outside surface of a tire (see Figure 2), using both constant and pulsed light sources for illumination and cooled, slow-scan, gated CCD cameras for detection. For observing the temperature of the inside surface of a tire (this has not yet been done), it would probably be necessary to use fiber optics and/or windows for coupling excitation light into, and coupling luminescence out of, the interior volume.

Bencic, Timothy J↗
NASA NTRS2012

Optical Phase Recovery and Locking in a PPM Laser Communication Link

Free-space optical communication holds great promise for future space missions requiring high data rates. For data communication in deep space, the current architecture employs pulse position modulation (PPM). In this scheme, the light is transmitted and detected as pulses within an array of time slots. While the PPM method is efficient for data transmission, the phase of the laser light is not utilized. The phase coherence of a PPM optical signal has been investigated with the goal of developing a new laser communication and ranging scheme that utilizes optical coherence within the established PPM architecture and photon-counting detection (PCD). Experimental measurements of a PPM modulated optical signal were conducted, and modeling code was developed to generate random PPM signals and simulate spectra via FFT (Fast Fourier Transform) analysis. The experimental results show very good agreement with the simulations and confirm that coherence is preserved despite modulation with high extinction ratios and very low duty cycles. A real-time technique has been developed to recover the phase information through the mixing of a PPM signal with a frequency-shifted local oscillator (LO). This mixed signal is amplified, filtered, and integrated to generate a voltage proportional to the phase of the modulated signal. By choosing an appropriate time constant for integration, one can maintain a phase lock despite long dark times between consecutive pulses with low duty cycle. A proof-of-principle demonstration was first achieved with an RF-based PPM signal and test setup. With the same principle method, an optical carrier within a PPM modulated laser beam could also be tracked and recovered. A reference laser was phase-locked to an independent pulsed laser signal with low-duty-cycle pseudo-random PPM codes. In this way, the drifting carrier frequency in the primary laser source is tracked via its phase change in the mixed beat note, while the corresponding voltage feedback maintains the phase lock between the two laser sources. The novelty and key significance of this work is that the carrier phase information can be harnessed within an optical communication link based on PPM-PCD architecture. This technology development could lead to quantum-limited efficient performance within the communication link itself, as well as enable high-resolution optical tracking capabilities for planetary science and spacecraft navigation.

Aveline, David C.↗
NASA NTRSDate not supplied

The Effects of Pressure and Optical Thickness on Radiative Losses in Spherical Diffusion Flames in Microgravity

In microgravity combustion, heat loss due to radiation plays a large role. Combustion products are able to accumulate in the flame region and radiate heat, while the heat release from the flame remains relatively constant. This causes the flame temperature to decrease until combustion can no longer be sustained, a phenomenon known as radiative extinction.

Kendyl A. Waddell↗
NASA NTRS1972

Radiative transfer effects on reflected shock waves. II - Absorbing gas.

Radiative cooling effects behind a reflected shock wave are calculated for an absorbing-emitting gas by means of an expansion procedure in the small density ratio across the shock front. For a gray gas shock layer with an optical thickness of order unity or less the absorption integral is simplified by use of the local temperature approximation, whereas for larger optical thicknesses a Rosseland diffusion type of solution is matched with the local temperature approximation solution. The calculations show that the shock wave will attenuate at first and then accelerate to a constant velocity. Under appropriate conditions the gas enthalpy near the wall may increase at intermediate times before ultimately decreasing to zero. A two-band absorption model yields end-wall radiant-heat fluxes which agree well with available shock-tube measurements.

Su, F. Y.↗
NASA NTRS1979

Optical correlation of surface displacement

A coherent optical correlation technique is used to measure surface displacements. In the event that the surface roughness of the test object is invariant during the object's translation, the correlation intensity peak remains constant. A simple relationship between the displacement of the surface and the displacement of the peak correlation signal is found and experimentally verified.

Owen, R. B.↗
NASA NTRS1980

The JPL flux mapper

The flux mapper is a device that can map the intensity distribution in three dimensions of concentrated solar energy at the focus of a concentrator. Intensities to 10,000 solar constants can be measured. Constructed to assist in concentrator and receiver development, it consists of a radiometer which is moved through the concentrated sunlight in a series of planes perpendicular to the optical axis by means of a mechanical rastering device. Various radiometer probes can be utilized depending on the time and accuracy requirements of the program. Energy levels are recorded as a function of location. Reduction of this data can be in various formats, e.g., contour maps, digital arrays, isometric visualizations and other displays as the user requires.

Owen, W. A.↗