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At least 865 records · Page 48
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NASA NTRS2013

Metal-Silicate Partitioning of Bi, In, and Cd as a Function of Temperature and Melt Composition

The origin of volatile elements in the Earth, Moon and Mars is not known; however, several theories have been proposed based on volatile elements such as In, As, Se, Te and Zn which are in lower concentration in the Earth, Moon, and Mars than in chondrites. Explanations for these low concentrations are based on two contrasting theories for the origin of Earth: equilibrium core formation versus late accretion. One idea is that the volatiles were added during growth of the planets and Moon, and some mobilized into the metallic core while others stayed in the mantle (e.g., [1]). The competing idea is that they were added to the mantles after core formation had completed (e.g., [2]). Testing these ideas involves quantitative modeling which can only be performed after data is obtained on the systematic metal-silicate partitioning behavior of volatile elements with temperature, pressure and melt composition. Until now, such data for Bi, In, and Cd has been lacking. After conducting a series of high pressure, high temperature experiments, the metal-silicate partition coefficients of Bi, In, and Cd as a function of temperature and melt composition can be used to evaluate potential conditions under which terrestrial planets differentiated into core and mantle, and how they acquired volatiles.

Marin, Nicole↗
NASA NTRS2013

The Virtual Observatory Service TheoSSA: Establishing a Database of Synthetic Stellar Flux Standards I. NLTE Spectral Analysis of the DA-Type White Dwarf G191-B2B *,**,***,****

Hydrogen-rich, DA-type white dwarfs are particularly suited as primary standard stars for flux calibration. State-of-the-art NLTE models consider opacities of species up to trans-iron elements and provide reliable synthetic stellar-atmosphere spectra to compare with observations. Aims. We will establish a database of theoretical spectra of stellar flux standards that are easily accessible via a web interface. Methods. In the framework of the Virtual Observatory, the German Astrophysical Virtual Observatory developed the registered service TheoSSA. It provides easy access to stellar spectral energy distributions (SEDs) and is intended to ingest SEDs calculated by any model-atmosphere code. In case of the DA white dwarf G191−B2B, we demonstrate that the model reproduces not only its overall continuum shape but also the numerous metal lines exhibited in its ultraviolet spectrum. Results. TheoSSA is in operation and contains presently a variety of SEDs for DA-type white dwarfs. It will be extended in the near future and can host SEDs of all primary and secondary flux standards. The spectral analysis of G191−B2B has shown that our hydrostatic models reproduce the observations best at Teff =60 000 +/- 2000K and log g=7.60 +/- 0.05.We newly identified Fe vi, Ni vi, and Zn iv lines. For the first time, we determined the photospheric zinc abundance with a logarithmic mass fraction of −4.89 (7.5 × solar). The abundances of He (upper limit), C, N, O, Al, Si, O, P, S, Fe, Ni, Ge, and Sn were precisely determined. Upper abundance limits of about 10% solar were derived for Ti, Cr, Mn, and Co. Conclusions. The TheoSSA database of theoretical SEDs of stellar flux standards guarantees that the flux calibration of all astronomical data and cross-calibration between different instruments can be based on the same models and SEDs calculated with different model-atmosphere codes and are easy to compare.

Observatory↗
NASA NTRS2021

The Role of Hydrated Minerals and Space Weathering Products in the Bluing of Carbonaceous Asteroids

The surfaces of airless bodies such as lunar and S-type asteroids typically become spectrally redder in visible to near-infrared reflectance with longer exposures to space weathering. However, some carbonaceous asteroids instead become spectrally bluer. Space weathering experiments on carbonaceous meteorites have provided some clues as to the space weathering products that could produce spectral bluing. We applied these experimental results to our Hapke radiative transfer model, with which we modeled spectral data from the OSIRIS-REx mission in order to determine whether these space weathering products—specifically, nanophase and microphase metallic iron, troilite, and magnetite—could explain the globally blue spectrum of the carbonaceous asteroid (101955) Bennu. The model suggests that the surface of Bennu has microphase iron, nanophase magnetite, and nanophase and microphase troilite. Considering previous space weathering experiments together with our spectral modeling of Bennu, we posit that the presence of nanophase magnetite is what causes a carbonaceous asteroid to become spectrally bluer with exposure time. Nanophase magnetite can form on asteroids that have Fe-bearing hydrated minerals (phyllosilicates). On anhydrous carbonaceous asteroids, nanophase iron forms instead of magnetite, leading to spectral reddening. We therefore predict that samples returned by the OSIRIS-REx mission from Bennu will have more nanophase magnetite than nanophase iron with nanophase and microphase sulfides, whereas samples returned by the Hayabusa2 mission from the carbonaceous asteroid (162173) Ryugu, which is spectrally red, will contain nanophase and microphase sulfides as well as more nanophase iron than nanophase magnetite.

David Trang↗
NASA NTRS2010

Determining the Metal/Silicate Partition Coefficient of Germanium: Implications for Core and Mantle Differentiation.

Currently there are several hypotheses for the thermal state of the early Earth. Some hypothesize a shallow magma ocean, or deep magma ocean, or heterogeneous accretion which requires no magma ocean at all. Previous models are unable to account for Ge depletion in Earth's mantle relative to CI chondrites. In this study, the element Ge is used to observe the way siderophile elements partition into the metallic core. The purpose of this research is to provide new data for Ge and to further test these models for Earth's early stages. The partition coefficients (D(sub Ge) = c(sub metal)/c(sub silicate), where D = partition coefficient of Ge and c = concentration of Ge in the metal and silicate, respectively) of siderophile elements were studied by performing series of high pressure, high temperature experiments. They are also dependent on oxygen fugacity, and metal and silicate composition. Ge is a moderately siderophile element found in both the mantle and core, and has yet to be studied systematically at high temperatures. Moreover, previous work has been limited by the low solubility of Ge in silicate melts (less than 100 ppm and close to detection limits for electron microprobe analysis). Reported here are results from 14 experiments studying the partitioning of Ge between silicate and metallic liquids. The Ge concentrations were then analyzed using Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) which is sensitive enough to detect ppm levels of Ge in the silicate melt.

King, C.↗
NASA NTRS2001

A theoretical analysis of vacuum arc thruster performance

In vacuum arc discharges the current is conducted through vapor evaporated from the cathode surface. In these devices very dense, highly ionized plasmas can be created from any metallic or conducting solid used as the cathode. This paper describes theoretical models of performance for several thruster configurations which use vacuum arc plasma sources. This analysis suggests that thrusters using vacuum arc sources can be operated efficiently with a range of propellant options that gives great flexibility in specific impulse. In addition, the efficiency of plasma production in these devices appears to be largely independent of scale because the metal vapor is ionized within a few microns of the cathode electron emission sites, so this approach is well-suited for micropropulsion.

thruster↗
NASA NTRS1995

Macroscopic and bulk-controlled elastic modes in an interaction of interstitial alcali metal cations within a face-centered cubic crystalline fullerine

The calculations in a majority of previous works for the fulleride (AqC-60) crystals were performed within the framework of the rigid-lattice model, neglecting the distortion relaxation of the host fullerene (C-60) crystal caused by the interstitial alkali-metal (A) cations. However, an each cation is a source of a static distortion field, and the resulting field is a superposition of such fields generated by all cations. This is a reason why the host-crystal distortions depend on the A-cations configurations, i.e. on a type of a spatial bulk distribution of interstitial cations. The given paper seeks to find a functional relation between the amplitudes of the doping-induced structure-distortion waves and of static concentration ones. A semiphenomenological model is constructed here within the scope of statistical-thermodynamic treatment and using the lattice-statistics simulation method(*). In this model the effects due to the presence of q solute A cations over available interstices (per unit cell) on the static inherent reorientation and/or displacements of the solvent molecules from the 'average-lattice' sites' as well as on the lattice parameter a of a elastically-anysotropic 'cubic' C-60 crystal are taken into account.

Tatarenko, Valentine A.↗
NASA NTRS1998

Thermal Modelling of Various Thermal Barrier Coatings in a High Flux Rocket Engine

A thermal model was developed to predict the thermal response of coated and uncoated tubes tested in a H2/O2 rocket engine. Temperatures were predicted for traditional APS ZrO2-Y2O3 thermal barrier coatings, as well as APS and LPPS ZrO2-Y2O3/NiCrAlY cermet coatings. Good agreement was observed between predicted and measured metal temperatures at locations near the tube surface or at the inner tube wall. The thermal model was also used to quantitatively examine the effect of various coating system parameters on the temperatures in the substrate and coating. Accordingly, the effect of the presence a metallic bond coat and the effect of radiation from the surface of the ceramic layer were examined. In addition, the effect of a variation in the values of the thermal conductivity of the ceramic layer was also investigated. It was shown that a variation in the thermal conductivity of the ceramic layer, on the order of that reported in the literature for plasma sprayed ZrO2-Y2O3 coatings, can result in temperature differences in the substrate greater than 100 C, a much greater effect than that due to the presence of a bond coat or radiation from the ceramic layer. The thermal model was also used to predict the thermal response of a coated rod in order to quantify the difference in the metal temperatures between the two substrate geometries in order to explain the previously-observed increased life of coatings on rods over that on tubes. It was shown that for the short duration testing in the rocket engine, the temperature in a tube could exceed that in a rod by more than 100 C. Lastly, a two-dimensional model was developed to evaluate the effect of tangential heat transfer around the tube and its impact on reducing the stagnation point temperature. It was also shown that tangential heat transfer does not significantly reduce the stagnation point temperature, thus allowing application of a simpler, one-dimensional model for comparing measured and predicted stagnation point temperatures.

Nesbitt, James A.↗
NASA NTRS1990

Infrared reflectance measurements of the insulator-metal transition in solid hydrogen

Reflectance measurements on solid hydrogen to 177 GPa (1.77 Mbar) have been performed from near-infrared to ultraviolet wavelengths (0.5 to 3 eV). Above 150 GPa characteristic free-electron behavior in the infrared region is observed to increase sharply with increasing pressure. Analysis of volume dependence of the plasma frequency obtained from Drude-model fits to the spectra indicates that the pressure of the insulator-metal transition is 149 (+ or - 10) GPa at 295 K. The measurements are consistent with metallization by closure of an indirect gap in the molecular solid.

Mao, H. K.↗
NASA NTRS1991

From wind to superwind - The evolution of mass-loss rates for Mira models

Dynamical atmosphere models were calculated for a large grid of variables with Mira-like properties satisfying the Iben radius-luminosity-mass relationship for evolving AGB stars. Their masses ranged from 0.7 to 2.4 solar masses, and their periods from 150 to 800 days. All were fundamental-mode pulsators, had solar metallicity, and included effects of dust. The mass-loss rate increases as an approximately exponential function of time, reaching 0.00001-0.0001 solar masses/yr. Further evolution is dominated by the powerful wind, which strips the star's envelope from the core. This 'superwind', a remarkably robust effect, occurs for all initial stellar masses and all modeling parameters that have been tested. Models with very low metallicity also show the effect, but at higher luminosities, which has intriguing implications for the number of supernovae in early low-metallicity populations and for the chemical evolution of galaxies.

Bowen, G. H.↗
NASA NTRS1970

Rensselaer's roving vehicle for Mars

Single module unmanned Mars roving vehicle with flexible metal toroidal hoop-spoked wheels, discussing remote controlled scale model design for simulation on earth

Rayfield, W. P.↗
NASA NTRS1973

The abundance and age distributions of 500 F stars in the solar neighbourhood

The uvby catalog of Perry has been used, in conjunction with theoretical uvby colors and stellar evolutionary tracks, to obtain the metal abundance distribution and age distribution of F and G type dwarf stars within 100 pc of the sun. Eighty-three per cent of stars with spectral type F5-G2 have metal content within a factor of 2.5 of the solar abundance, and only 2% have less than one-quarter the solar abundance. The metal abundance distribution, which contains more metal-rich stars than found in previous investigations of F and G dwarfs, has also been compared with the observed metal abundance distribution of G and K giants and the model galaxy calculations of Truran and Cameron (1971). A comparison of the age distribution with evolutionary calculations implies that the rate of star formation in the galaxy may not have decreased by a large factor in the last 10 billion years.

Clegg, R. E. S.↗
NASA NTRS1974

Methodological questions of creating tissue-equivalent phantoms

On the basis of analysis and generalization of literature data, the composition of tissue equivalent plastic was justified, parameters of a standard man were determined, plaster and metal forms were created for casting dummies, and an experimental model was produced from tissue equivalent material.

Kolodkin, A. V.↗
NASA NTRS1981

Analytical and experimental evaluation of biaxial contact stress

Contact stress analysis was conducted for ceramic-metal and ceramic-ceramic interfaces using a finite element model. Ceramics investigated included NC-132 hot-pressed silicon nitride, NC-350 reaction-bonded silicon nitride, Hexaloy SA SiC, and RBN104 reaction-bonded silicon nitride. The results are shown to be well correlated with closed-form solution both for normal and normal-tangential loading. The latter load condition is found to be especially critical for ceramic materials due to the presence of a high tensile stress at the trailing edge of the ceramic surface contact zone. It is shown that during sliding contact or biaxial loading, the magnitude of this tensile stress increases with the coefficient of friction.

Richerson, D. W.↗
NASA NTRS1980

Time-dependent lunar density models

Simple models of the geochemical and geophysical evolution of the moon were constructed with the particular aim of investigating the mass density distribution within the moon as a function of time. The strongly inverted (densest material on top) density distribution resulting from fractional crystallization of the lunar magma ocean was found to rearrange itself into a highly stable stratification. Density stratification due to compositional variation dominated gravitational stability; thus, thermally driven convection was found to be suppressed in regions with relaxed (rearranged so as to minimize the gravitational potential energy) compositional density variation. The suppression of convection as a heat transfer process results in considerable modification of thermal evolution. The models produced sufficient density segregation from magma oceans of a few hundred km thickness, such that relaxation to the most stable rearrangement yielded a polar moment of inertia approximating that measured for the present-day moon. Thus, lunar models matching moment-of-inertia constraints but lacking a metallic core are motivated.

Herbert, F.↗
NASA NTRS1986

Modeling of transient heat pipe operation

Mathematical models and associated solution procedures which can be used to design heat pipe cooled structures for use on hypersonic vehicles are being developed. The models should also have the capability to predict off-design performance for a variety of operating conditions. It is expected that the resulting models can be used to predict startup behavior of liquid metal heat pipes to be used in reentry vehicles, hypersonic aircraft, and space nuclear reactors. Work to date related to numerical solutions of governing differential equations for the outer shell and the combination capillary structure and working fluid is summarized. Finite element numerical equations using both implicit, explicit, and combination methods were examined.

Colwell, G. T.↗
NASA NTRS1986

Brown dwarfs and Jovian planets: A comparison

The recent detection of a subluminous companion to the M dwarf star VB8 has renewed interest in the characteristics of objects spanning the mass range from Jupiter to hydrogen burning stars. Atmospheric and interior models were constructed for objects in this mass regime, up to 30 Jupiter masses, with emphasis on understanding the relationship of brown dwarfs such as the VB8 companion to the better-studied Jovian planets. The atmospheric model solves the equation of radiative transfer assuming frequency dependent molecular opacity sources H2, He, H2O, CO, and CH4 which are important by virtue of the high cosmic abundance of their constituent atoms. Condensation of cosmochemically important materials, iron and silicates, in the atmosphere is possible, and the effect of such grains as opacity sources is assessed. The luminosity of the object is presumed due to degenerate cooling following a collapse phase and possibly deuterium burning and an interior model is constructed using as an outer boundary condition the temperature and pressure level at which the atmosphere becomes convective. The interior model is analogous to Jupiter, with a large liquid metallic-hydrogen core and a thinner molecular-hydrogen envelope. The oxidation state of carbon in the outer envelope of a brown dwarf of similar age to Jupiter is a function of the object's mass. This makes the wavelength dependence of the atmospheric opacity sensitive to the carbon to oxygen ratio, since the abundance of the primary source of molecular opacity, H2O, decreases as more oxygen is tied up as CO.

Lunine, J. I.↗
NASA NTRS1983

Constitutive relationships for anisotropic high-temperature alloys

A constitutive theory is presented for representing the anisotropic viscoplastic behavior of high-temperature alloys that possess directional properties resulting from controlled grain growth or solidification. The theory is an extension of a viscoplastic model that has been applied in structural analyses involving isotropic metals. Anisotropy is introduced through the definition of a vector field that identifies a preferential (solidification) direction at each material point. Following the development of a full multiaxial theory, application is made to homogeneously stressed elements in pure shear and to a uniaxially stressed rectangular block in plane stress with the stress direction oriented at an arbitrary angle with the material direction. It is shown that an additional material parameter introduced to characterize the degree of anisotropy can be determined on the basis of simple creep tests.

Robinson, D. N.↗
NASA NTRS1990

A review of the analytical simulation of aircraft crash dynamics

A large number of full scale tests of general aviation aircraft, helicopters, and one unique air-to-ground controlled impact of a transport aircraft were performed. Additionally, research was also conducted on seat dynamic performance, load-limiting seats, load limiting subfloor designs, and emergency-locator-transmitters (ELTs). Computer programs were developed to provide designers with methods for predicting accelerations, velocities, and displacements of collapsing structure and for estimating the human response to crash loads. The results of full scale aircraft and component tests were used to verify and guide the development of analytical simulation tools and to demonstrate impact load attenuating concepts. Analytical simulation of metal and composite aircraft crash dynamics are addressed. Finite element models are examined to determine their degree of corroboration by experimental data and to reveal deficiencies requiring further development.

Fasanella, Edwin L.↗