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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Subtask 2.6 – Optimization of Aerosol Mitigation Technology for Postcombustion CO 2 Capture

Growing concerns over the impact of CO 2 emissions from combustion sources on global climate change have prompted numerous research and development projects aimed at developing cost-effective technologies for CO 2 capture. One family of technologies being demonstrated at pilot and full scale globally is postcombustion CO 2 capture (PCCC) systems that employ amine-based solvents. The captured CO 2 can be compressed and permanently stored underground or used for enhanced oil recovery (EOR). The proximity of North Dakota’s lignite-fired fleet of power plants to potential CO 2 storage options creates a unique atmosphere for PCCC within the state. However, the aerosols present in lignite flue gas present a challenge for large-scale PCCC at North Dakota power plants. Aerosols can negatively impact the long-term performance of amine-based solvents for CO 2 capture. Amine-based solvents are volatile, and aerosols provide nucleation sites where amine vapors can condense. Because aerosols cannot be easily captured at the column outlet using conventional technologies, the amine-laden aerosols escape the system and lead to accelerated solvent losses. Moreover, aerosol components can chemically react with amines to form degradation products that can permanently deactivate the amine, cause fouling, and lead to hazardous emissions. Many of the elements that have been shown to catalyze solvent degradation are present in lignite coals and can exacerbate solvent replacement economics. Understanding this issue is critical to the implementation of solvent-based CO 2 capture systems as applied to lignite-fired generation systems. The Energy & Environmental Research Center (EERC) designed and carried out this project to optimize aerosol mitigation technology for PCCC at a lignite-fired power plant. To meet the goal of this project, the following objectives were identified: Determine the effectiveness of a wet electrostatic precipitator (WESP) on collection of aerosols at a low-rank coal-fired power station. Determine the impact of aerosols on the efficiency and degradation products of amine-based carbon capture systems fired with low-rank fuels. Work was conducted at Minnkota Power Cooperative’s (MPC’s) Milton R. Young (MRY) Station Unit 2 using a slipstream of flue gas from the outlet of the plant’s flue gas desulfurization (FGD) unit. To gather initial data for sizing and specifying a WESP for this system, a temporary pilot-scale WESP was rented and installed on-site. Several different conditions were tested to examine the impact of flow rate, voltage, and current on WESP performance. The WESP was effective at removing large particulate (>200 nm) but caused an increase in fine particulate (<75 nm). Fine particulate material at the inlet and outlet of the WESP was collected, analyzed, and showed that crystalline sulfates carried over from the plant’s FGD unit were being converted to fine aerosols and SO 2 was being converted to SO 3 through the WESP. Additionally, the high moisture content of the flue gas stream at this sample location also contributed to an overall increase in aerosol mass under some of the test conditions. Using the results from the rented WESP, the project team installed a smaller-scale WESP upstream of the EERC’s slipstream CO 2 capture system. Flue gas was routed through a pilot-scale FGD unit to remove SO 2 to very low levels (~1 ppm) and then through a direct contact cooler (DCC) to further cool the gas and to remove moisture. The gas exiting the DCC was then routed through the new WESP before passing to the CO 2 absorber columns. Fluor’s amine-based solvent was used to scrub CO 2 from the slipstream through a set of two absorber columns. The rich solvent was regenerated in a stripper column by heating to drive off captured CO 2 . The system operated using a catch-and-release method where the CO 2 was separated to provide data on the process, but the captured CO 2 was released back into the host site stack. Aerosols and sulfur species were measured at multiple locations throughout the pilot-scale system. The inlet FGD and DCC removed much of the particulate matter and gaseous sulfur upstream of the WESP. With this configuration, the WESP achieved >95% particulate capture. The new WESP did not show any of the increases in SO 3 or other aerosol species that had been consistently observed with the larger-scale WESP installed immediately downstream of the plant’s full-scale FGD unit. Particulate samples captured and analyzed from the WESP inlet did not show any presence of crystalline sulfate materials, indicating that the pilot-scale FGD and DCC were efficient at reducing carryover from the plant’s full-scale FGD unit. A set of parametric tests were conducted on the new WESP to assess the impacts of flow rate, voltage, number of online WESP fields, and gas-phase sulfur content on aerosol and sulfur transformations. The results showed that the WESP performed similarly well at all sets of conditions. Sulfur and particulate matter exiting the WESP were further reduced through the absorber column as the amine-based solvent captured some of the residual contaminants. Solvent analysis showed that these species were slowly concentrating in the solvent over the duration of the test. When the WESP was taken offline and the sulfur slip through the FGD allowed to rise, the sulfate content in the solvent rose sharply, showing that the extra FGD and WESP were effective at reducing sulfate and cation uptake. This would be expected to extend amine-based solvent life by slowing the formation of heat-stable salts and other degradation products. This subtask was cofunded through the EERC–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233. Nonfederal funding was provided by the North Dakota Industrial Commission and MPC.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1998

Results of a 24-inch Hybrid Motor Performance Uncertainty Analysis

The subscale (11 and 24-inch) hybrid motors at the Marshall Space Flight Center (MSFC) have been used as versatile and cost effective testbeds for developing new technology. Comparisons between motor configuration, ignition systems, feed systems, fuel formulations, and nozzle materials have been carried out without detailed consideration as to haw "good" the motor performance data were. For the 250,000 lb/thrust motor developed by the Hybrid Propulsion Demonstration Program consortium, this shortcoming is particularly risky because motor performance will likely be used as put of a set of downselect criteria to choose between competing ignition and feed systems under development. This analysis directly addresses that shortcoming by applying uncertainty analysis techniques to the experimental determination of the characteristic velocity, theoretical characteristic velocity, and characteristic velocity efficiency for a 24-inch motor firing. With the adoption of fuel-lined headends, flow restriction, and aft mixing chambers, state of the an 24-inch hybrid motors have become very efficient However, impossibly high combustion efficiencies (some computed as high as 108%) have been measured in some tests with 11-inch motors. This analysis has given new insight into explaining how these efficiencies were measured to be so high, and into which experimental measurements contribute the most to the overall uncertainty.

Sims, Joseph D.↗
DOE OSTI2021

Massachusetts Institute of Technology Reactor LEU Fuel Element Flow Test Conceptual Design – Hydraulic Reactor Design Parameters

The Massachusetts Institute of Technology Reactor (MITR-II, also referred to as MITR) is one of six U.S. high performance research reactors (USHPRR), including one critical facility, that is actively collaborating with the U.S. National Nuclear Security Administration (NNSA) Material Management and Minimization (M 3 ) Reactor Conversion Program to convert to the use of low-enriched uranium (LEU, < 20 wt% 235 U) fuel. The MIT Nuclear Reactor Laboratory has been working with the USHPRR Reactor Conversion (RC) Pillar at Argonne National Laboratory to perform fuel element design and fuel cycle performance analyses, steady-state thermal hydraulics safety analyses, and accident safety analyses in preparation for the conversion of MITR and support a preliminary Safety Analysis Report (SAR) for conversion to LEU fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Catalytic Removal of Oxygen and Pollutants in Exhaust Gases from Pressurized Oxy-Combustors

The primary goal of this project was to develop and validate advanced catalytic materials and systems for purifying the flue gas generated from pressurized oxy-combustors in an effort to achieve the purity specifications of carbon dioxide (CO 2 ) streams required by the U.S. Department of Energy (USDOE) for application in enhanced oil recovery. The technology has shown great potential for improving energy efficiency, simplifying process complexity, and lowering costs compared with current state-of-the-art oxy-combustion flue gas purification technologies. Laboratory studies were conducted for the development, characterization, and screening of metal catalysts for residual oxygen (O 2 ) reduction with methane (CH 4 ) and multifunctional carbon catalysts for combined nitrogen oxides (NO x ), sulfur oxides (SO x ), and mercury (Hg) removal. A bench-scale reverse-flow fixed-bed (RFFB) reactor and a trickle-bed direct-contact cooler (DCC) reactor capable of treating 15 standard liters per min of pressurized oxy-combustion flue gas were fabricated and tested with both a simulated flue gas in the laboratory and a slipstream of actual flue gas at a 100 kW th Staged, Pressurized Oxy-Combustion (SPOC) pilot facility. Process simulation and techno-economic studies were performed to evaluate the energy efficiency and cost of the developed catalytic flue gas purification process integrated into a conceptual 550-MWe SPOC power plant. The goal and objectives of the project have been successfully accomplished. A cobalt-manganese (CoMn) oxide catalyst was developed and demonstrated in the bench-scale RFFB reactor in either a reverse-flow or one-direction flow mode of operation that met the success criterion of performance for residual O 2 reduction. A carbon catalyst was developed and demonstrated in the bench-scale DCC reactor that met the success criterion of performance for combined NO x /SO x /Hg removal. Slipstream testing of the integrated DCC-RFFB system at the SPOC pilot facility demonstrated stable operation and verified the superior performance obtained in the laboratory. The techno-economic analysis showed that a 550-MWe SPOC plant integrated with the catalytic flue gas purification process would result in costs of electricity of $\$$96.94/MWh and $\$$80.27/MWh in two assessed cases compared with $\$$91.07/MWh reported for the USDOE’s Current Technology Case, which generated only a partially pure CO 2 stream. On the basis of the results and findings from this project, scale-up studies of materials production and system demonstration and optimization studies of reactors and processes are recommended at the next stage of technology development.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2020

Using optical fibers to examine thermal mixing of liquid sodium in a pool-type geometry

Sodium fast reactors (SFR) are poised to be a leading candidate for the next generation of commercial nuclear reactor deployment. Companies are commissioning designs for SFR increasing the need for experimental and computational analysis to improve the economics and safety of these reactors. Analysis of SFR behavior during reactor transients directly informs the understanding of reactor safety. Particularly, investigating the thermal transients associated with the reactor loss of flow transient allows for informed design decisions to be made regarding reactor safety. During loss of flow transients the flow rate of the coolant is significantly reduced, but not necessarily stopped. The reduction in flow rate results in coolant temperatures exiting the reactor core that can be drastically different than the coolant in upper pool. When these different temperature fluids interact, thermally stratified layers can form causing cyclic thermal fatigue on the reactor vessel potentially leading to pre-material failure. Past experimental studies have lacked high resolution temperature measurements. This research focuses on demonstrating the reliability of novel techniques for acquiring high resolution temperature measurements in a scaled liquid sodium facility. Tests are conducted that simulate postulated loss of flow transients and provide unprecedented spatial temperature distribution measurements.

42 ENGINEERING↗
DOE OSTI2021

Microfluidic Liquid-Liquid Extraction Chip with Integrated Raman Sensors (Phase I and Phase II Final Report)

As demand for electricity continues to increase worldwide, the world’s nuclear power generating capacity will continue to grow. Nuclear power is the most environmentally benign way of producing electricity on a large scale. The long-term successful use of nuclear power, however, is critically dependent upon adequate and safe processing and disposal of spent nuclear fuels. A very important feature of nuclear energy is that spent fuels can be reprocessed to recover fissile and fertile materials that can then be used as fresh fuel for nuclear power plants. The DOE-NE Fuel Cycle Research and Development (FCR&D) is currently developing nuclear material reprocessing technologies. In a typical nuclear fuel reprocessing system, centrifugal contactors are used as liquid-liquid extraction devices where two immiscible liquids are mixed at high speeds using a rotor, which creates a fine dispersion of droplets of organic phase in an aqueous phase that contains the analyte. Understanding the extraction efficiency at these contactors through modeling and simulation is important in the development of reprocessing technologies and the optimization of current technologies such as the PUREX process. The outcome of this program will be a liquid-liquid microfluidic flow cell chip with embedded spectroscopic sensors for the analysis of extracted analytes. This device will be useful in the optimization of new fuel reprocessing schemes as well as existing reprocessing processes by providing a microfluidic modeling platform to optimize extraction parameters. The Phase I and Phase II work developed a microfluidic chip design that allows integration of Raman and absorption fiber optic probes and successfully demonstrated the feasibility of using Raman and absorption probes to detect key analytes that partition into the aqueous and organic phases.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Analysis of an Elasto-Hydrodynamic Seal by Using the Reynolds Equation

This paper reports numerical studies of an Elasto-Hydrodynamic (EHD) seal, which is being developed for supercritical CO2 (sCO2) turbomachinery applications. Current sCO2 turbomachinery suffers from high leakage rates, which is creating a major roadblock to the full realization of sCO2 power technology. The high leakage rates not only penalize the efficiencies but also create environmental concerns due to greenhouse effects caused by the increased CO2 discharge to the atmosphere. The proposed EHD seal needs to work at elevated pressures (10–35 MPa) and temperatures (350–700 °C) with low leakage and minimal wear. The unique mechanism of the EHD seal provides a self-regulated constriction effect to restrict the flow without substantial material contact, thereby minimizing leakage and wear. This work utilizes a physics-based modeling approach. The flow through the gradually narrowing seal clearance is modeled by the well-known Reynolds equation in EHD lubrication theory, while the deformation of the seal is modeled by using the governing equations of three-dimensional solid mechanics. As for the solution methodology, COMSOL’s Thin-Film Flow and Solid Mechanics modules were employed with their powerful capabilities. The numerical results were presented and discussed. It was observed that the Reynolds equation fully coupled with the surface deformation was able to successfully capture the constriction effect. The maximum and minimum leakages were calculated to be 2.25 g/s and 0.1 g/s at P = 5.5 MPa and P = 11 MPa for the design seal, respectively. It was interesting to observe that the seal leakage followed a quadratic trend with increasing pressure differential, which can become advantageous for high-pressure applications such as sCO2 power generation technology.

42 ENGINEERING↗
DOE OSTI2021

Performance and lifetime of intercalative water deionization cells for mono- and divalent ion removal

We report intercalative deionization (IDI) uses two cation intercalation electrodes separated by an anion exchange membrane in a symmetric cell design that has the potential to deliver electrochemically desalinated water in an energy- and water-efficient way. Here, we define and measure metrics to describe the performance and lifetime of IDI cells and compare them for NaCl and CaCl 2 feed solutions. With 20 mM NaCl, NiHCF/AEM/NiHCF flow cells achieve 10 mM average concentration change at a productivity of 20 l/h/m 2 and 5 mM average concentration change at 130 l/h/m 2 . In both cases the cells are operated at a 3C current rate and consume ~30 Wh/m 3 of energy. With 10 mM CaCl 2 , the specific capacity and salt removal of IDI flow cells is ~4 times lower. NiHCF/NiHCF beaker cells with CaCl 2 electrolyte suffer from strong capacity fade, while the same cells with NaCl electrolyte achieve 500 cycles without any capacity fade. Our post-mortem analysis using X-ray diffraction, secondary electron microscopy, energy dispersive X-ray spectroscopy, synchrotron-based X-ray absorption spectroscopy and micro X-ray fluorescence mapping reveals that NiHCF dissolves upon repeated intercalation with Ca 2+ , releasing residual K + , Ni 2+ and Fe(CN) 6 3 , which precipitates as a crystalline decomposition product on the electrodes. This side reaction deprives the active material NiHCF of charge compensating Fe, and thus accounts for the observed capacity fade.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Fluid Flow in Crystal Growth: Analysis of the Verticle Bridgman and Floating Zone Process

Research is aimed at the fundamental understanding of the interactions of heat and mass transport and fluid mechanics in crystal growth from the melt, especially in how it pertains to experiments supported by the Microgravity Science and Applications program. Emphasis has been on studies of the vertical Bridgman system, on small-scale floating zone systems proposed for space flight, and on quantitative prediction of nonlinear transitions in melt/solid interface morphologies leading to the formation of dendrites in directional solidification. The analysis of vertical Bridgman growth has lead to the complete numerical analysis of transport phenomena in directional solidification and to a detailed comparison of calculations to the GaGe growth experiments of Wang and Witt. Calculations show the central role of the ampoule material in determining the radial temperature gradients in the melt and thus, the intensity of convection. Results indicate that diffusion-controlled growth can not be achieved on Earth with conventional growth systems, but are feasible in microgravity

Brown, R. A.↗
NASA NTRS1994

Dynamics and X-ray emission of a galactic superwind interacting with disk and halo gas

There is a general agreement that the conspicuous extranuclear X-ray, optical-line, and radio-contiuum emission of starbursts is associated with powerful galactic superwinds blowing from their centers. However, despite the significant advances in observational studies of superwinds, there is no consensus on the nature of the emitting material and even on the emission mechanisms themselves. This is to a great extent a consequence of a poor understanding of dynamical processes in the starburst superwind regions. To address this issue, we have conducted two-dimensional hydrodynamical simulations of galactic superwinds. While previous similar studies have used a single (disk) component to represent the ISM of the starburst galaxy, we analyze the interaction of the wind with a two-component disk-halo ambient interstellar medium and argue that this two-component representation is crucial for adequate modeling of starbursts. The emphasis of this study is on the geometry and structure of the wind region and the X-ray emission arising in the wind material and the shocked gas in the disk and the halo of the galaxy. The simulation results have shown that a clear-cut bipolar wind can easily develop under a range of very different conditions. On the other hand, a complex 'filamentary' structure associated with the entrained dense disk material is found to arise within the hot bubble blown out by the wind. The flow pattern within the bubble is dominated equally by the central biconic outflow and a system of whirling motions r elated to the origin and development of the 'filaments'. The filament parameters make them a good candidate for optical-emission-line filamentary gas observed in starburst halos. We find that the history of mass and energy deposition in the starburst region of the galaxy is crucial for wind dynamics. A 'mild' early wind, which arises as a result of the cumulative effect of stellar winds from massive stars, produces a bipolar vertical cavity in the disk and halo gas without strongly affecting the gaseous disk, thus creating conditions for virtually free vertical escape of the hot gas at the later, much more violent supernova-dominated phases of the starburst. We calculate the luminosity, mass, and effective temperature of the X-ray emitting gas in the 'soft' (0.1 to 0.7 keV, 0.7 to 2.2 keV, and 0.1 to 2.2 keV) and 'hard' (1.6 to 8.3 keV) energy bands and estimate the contribution of different gaseous components to the X-ray flux in these bands. Analysis of these parameters enables us to make conclusions regarding the nature of the X-ray-emitting material. We have inferred that the bulk of the soft thermal X-ray emission from starbursts arises in the wind-shocked material of the disk and halo gas rather than in the wind material itself. This enables us to predict that the integrated soft X-ray spectra of starbursts need not show an overabundance of heavy elements which are believed to be produced copiously in the centers of starbursts. Unlike soft X-ray emission, the hard component of thermal X-ray emission is found to originate in the wind material ejected from the starburst region. However, the derived ratio of hard-to-soft X-ray luminosities is too small compared to that observed in starbursts. We conclude therefore that the observed hard X-ray emission of starbursts is probably not associated with the thermal emission of hot wind or ambient shocked gas. Typical temperatures of the bulk of the soft X-ray-emitting material in our very different models have been found to agree well with the ones estimated on the basis of the ROSAT data for the soft component of X-ray emission of nearby starbursts. We predict that temperatures of the extranuclear soft X-ray-emitting gas in starburst galaxies with heavy element abundances near solar should be close to T(sub Xs = 2 to 5 x 10(exp 6)K.

Suchkov, Anatoly A.↗
DOE OSTI2023

An adjoint-based optimization method for jointly inverting heterogeneous material properties and fault slip from earthquake surface deformation data

SUMMARY Analysis of tectonic and earthquake-cycle associated deformation of the crust can provide valuable insights into the underlying deformation processes including fault slip. How those processes are expressed at the surface depends on the lateral and depth variations of rock properties. The effect of such variations is often tested by forward models based on a priori geological or geophysical information. Here, we first develop a novel technique based on an open-source finite-element computational framework to invert geodetic constraints directly for heterogeneous media properties. We focus on the elastic, coseismic problem and seek to constrain variations in shear modulus and Poisson’s ratio, proxies for the effects of lithology and/or temperature and porous flow, respectively. The corresponding nonlinear inversion is implemented using adjoint-based optimization that efficiently reduces the cost function that includes the misfit between the calculated and observed displacements and a penalty term. We then extend our theoretical and numerical framework to simultaneously infer both heterogeneous Earth’s structure and fault slip from surface deformation. Based on a range of 2-D synthetic cases, we find that both model parameters can be satisfactorily estimated for the megathrust setting-inspired test problems considered. Within limits, this is the case even in the presence of noise and if the fault geometry is not perfectly known. Our method lays the foundation for a future reassessment of the information contained in increasingly data-rich settings, for example, geodetic GNSS constraints for large earthquakes such as the 2011 Tohoku-oki M9 event, or distributed deformation along plate boundaries as constrained from InSAR.

Geochemistry & Geophysics↗
DOE OSTI2020

Low-Temperature Plasma Treatment for Enhanced Recovery of Highly Valued Critical REEs from Coal (Final Technical Report)

The principle objective of this project was to develop a novel process flowsheet using low-temperature plasma treatment (LTP) integrated with conventional hydrometallurgical processes to recover rare earth elements (REEs), especially highly valued REEs (i.e. scandium and critical REEs), from coal and coal byproducts. LTP treatment was used to pretreat the solid feed material prior to leaching in an effort to improve the leaching characteristics of the REEs and potentially reduce acid consumption. Initially, a detailed experimental program was performed on a laboratory LTP furnace to identify a set of process parameter values to be used for assessing the enhanced leaching performance achieved on four specific gravity fractions of West Kentucky No. 13 and Fire Clay coarse coal refuse materials. High-temperature oxidation (HTO)) was also evaluated as a means for improving REE leachability on the same fractions of both coal sources. The lixiviants used to assess leachability improvements included i) untreated water, ii) 0.1 M ammonium sulfate solution and iii) 1.2 M sulfuric acid solution at a temperature of 75°C. The laboratory data was used to develop multiple process flow sheets using HTO only to produce a rare earth oxide mix concentrate or utilizing both LTP and HTO treatment processes to generate a high purity heavy REO mix concentrate and a light REO mix concentrate. A techno-economic analysis was performed on each circuit.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1956

Theoretical investigation of flutter of two-dimensional flat panels with one surface exposed to supersonic potential flow

A Rayleigh type analysis involving chosen modes of the panel as degrees of freedom is used to treat the flutter of a two-dimensional flat panel supported at its leading and trailing edges and subjected to a middle-plane tensile force. The panel has a supersonic stream passing over its upper surface and still air below. The aerodynamic forces due to the supersonic stream are obtained from the theory for linearized two-dimensional unsteady flow and the forces due to the still air are obtained from acoustical theory. In order to study the effect of increasing the number of modes in the analysis, two and then four modes are employed. The modes used are the first four natural modes of the panel in a vacuum with no tensile force acting. The analysis includes these variables: Mach number, structural damping, tensile force, density of the still air, and edge fixity (clamped and pinned). For certain combinations of these variables, stability boundaries are obtained which can be used to determine the panel thickness required to prevent flutter for any panel material and altitude.

Nelson, Herbert C↗
NASA NTRS1993

Analysis of Radiation-natural Convection Interactions in 1-g and low-g Environments using the Discrete Exchange Factor Method

A new numerical method is presented for the analysis of combined natural convection and radiation heat transfer with applications in many engineering situations such as materials processing, combustion and fire research. Because of the recent interest in the low gravity environment of space, attention is devoted to both 1-g and low-g applications. The two-dimensional mathematical model is represented by a set of coupled nonlinear integro-partial differential equations. Radiative exchange is formulated using the Discrete Exchange Factor method (DEF). This method considers point to point exchange and provides accurate results over a wide range of radiation parameters. Numerical results show that radiation significantly influences the flow and heat transfer in both low-g and 1-g applications. In the low-g environment, convection is weak, and radiation can easily become the dominant heat transfer mode. It is also shown that volumetric heating by radiation gives rise to an intricate cell pattern in the top heated enclosure.

Kassemi, M.↗
NASA NTRS2000

Future Challenges and Opportunities in Aerodynamics

Investments in aeronautics research and technology have declined substantially over the last decade, in part due to the perception that technologies required in aircraft design are fairly mature and readily available. This perception is being driven by the fact that aircraft configurations, particularly the transport aircraft, have evolved only incrementally, over last several decades. If however, one considers that the growth in air travel is expected to triple in the next 20 years, it becomes quickly obvious that the evolutionary development of technologies is not going to meet the increased demands for safety, environmental compatibility, capacity, and economic viability. Instead, breakthrough technologies will he required both in traditional disciplines of aerodynamics, propulsion, structures, materials, controls, and avionics as well as in the multidisciplinary integration of these technologies into the design of future aerospace vehicles concepts. The paper discusses challenges and opportunities in the field of aerodynamics over the next decade. Future technology advancements in aerodynamics will hinge on our ability, to understand, model, and control complex, three-dimensional, unsteady viscous flow across the speed range. This understanding is critical for developing innovative flow and noise control technologies and advanced design tools that will revolutionize future aerospace vehicle systems and concepts. Specifically, the paper focuses on advanced vehicle concepts, flow and noise control technologies, and advanced design and analysis tools.

Kumar, Ajay↗
NASA NTRS2015

NASAs Evolvable Mars Campaign: Mars Moons Robotic Precursor

Human exploration missions to the moons of Mars are being considered within NASA's Evolvable Mars Campaign (EMC) as an intermediate step for eventual human exploration and pioneering of the surface of Mars. A range of mission architectures is being evaluated in which human crews would explore one or both moons for as little as 14 days or for as long as 500 days with a variety of orbital and surface habitation and mobility options being considered. Relatively little is known about the orbital, surface, or subsurface characteristics of either moon. This makes them interesting but challenging destinations for human exploration missions during which crewmembers must be able to effectively conduct scientific exploration without being exposed to undue risks due to radiation, dust, micrometeoroids, or other hazards. A robotic precursor mission to one or both moons will be required to provide data necessary for the design and operation of subsequent human systems and for the identification and prioritization of scientific exploration objectives. This paper identifies and discusses considerations for the design of such a precursor mission based on current human mission architectures. Objectives of a Mars' moon precursor in support of human missions are expected to include: 1) identifying hazards on the surface and the orbital environment at up to 50-km distant retrograde orbits; 2) collecting data on physical characteristics for planning of detailed human proximity and surface operations; 3) performing remote sensing and in situ science investigations to refine and focus future human scientific activities; and 4) prospecting for in situ resource utilization. These precursor objectives can be met through a combination or remote sensing (orbital) and in-situ (surface) measurements. Analysis of spacecraft downlink signals using radio science techniques would measure the moon's mass, mass distribution, and gravity field, which will be necessary to enable trajectory planning. Laser altimetry would precisely measure the moon's shape and improve the accuracy of radio science measurements. A telescopic imaging camera would map the moon at submeter resolution and photograph selected areas of interest at subcentimeter resolution and a visible and near-infrared (0.4-3.0 mm) imaging spectrograph would produce a global map of mineral composition variations at a resolution of tens of meters and maps of selected areas of interest at meter resolution. Additional remote sensing capabilities could include a thermal infrared imager (heat flow, thermal inertia, and grain size distributions), a gamma-ray and neutron detector (atomic composition), a ground-penetrating radar (internal structure), and a magnetometer and Langmuir probe (magnetic properties and plasma field). Once on the surface of Phobos or Deimos, necessary instrumentation would include a penetrometer (regolith compressive strength), a motion-imagery camera (to observe the penetrometer tests before, during, and after contact), a dust-adhesion witness plate and camera (dust levitation), a microimager (dust particle sizes and shapes), and an alpha-proton-X-ray, X-ray fluorescence, Mossbauer, or Raman spectrometer (atomic and mineral composition of surface materials) and an optional temperature probe (regolith thermal properties). A variety of robotic mission design options to enable both orbital and surface measurements are being considered that include fully integrated and modular approaches. In-situ measurements from at least one surface location would be required, with additional measurement locations possible through use of multiple landers, through propulsive relocation of a single lander, or through electromechanical surface translation by a walking or hopping lander vehicle, which could also serve to evaluate such mobility capabilities for subsequent human missions. Preliminary orbital analysis suggests that remote sensing would likely be performed while in a distant retrograde orbit around the target moon. Mission design options to enable characterization of both Mars’ moons in a single mission are also being studied.

Gernhardt, Michael L.↗
DOE OSTI2021

Higher Ion Selectivity with Lower Energy Usage Promoted by Electro-osmotic Flow in the Transport through Conical Nanopores

The tradeoff between selectivity and throughput presents fundamental challenges to improve desalination and charge storage, salinity gradient-based energy harvesting, memory device/circuit development, and so forth. The well-known ion-current rectification and the recently resolved time-dependent transport hysteresis in conical nanopores or asymmetric nanointerfaces offer new opportunities for the selective transport of matter. This report shows that electro-osmotic flow (EOF) is an overlooked factor that increases ion selectivity while maintaining enhanced transport throughput in rectified nanoscale electrokinetic transport. The increased selectivity originates primarily from the suppression of anion flux by the fluid flow in the opposite direction under the applied electrical field. By solving the Poisson and Nernst–Planck (PNP) equations without and with coupled Navier–Stokes (PNP–NS) equations, the EOF effects on cation and anion transport are unequivocally revealed in asymmetric nanopipettes. The flux of cations and anions as well as the transference number and flow velocity are elucidated using the models and boundary conditions validated by previous experiments. A dimensionless parameter, radius over the Debye length, reveals optimal ion selectivity and energy cost at intermediate ion concentrations and nanopore sizes, up to hundreds of millimolars and tens of nanometers under time-dependent potential stimulus. Furthermore, the fundamental insights into EOF at nanointerfaces suggest new routes/strategies for better separation, analysis, and energy applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2022

Low-Speed Performance Enhancement Using Localized Active Flow Control: Localized Active Flow Control Simulations on a Reference Aircraft (2/4)

A study of the potential implementations of localized active flow control (AFC) technology onto future airplanes is presented. This collaborative investigation addresses key objectives of the NASA Advanced Air Transport Technology (AATT) Project, in terms of reduction in fuel consumption and lower emission. It specifically targets the goals set forth in a roadmap developed by the NASA/Boeing team. The roadmap is a result of a series of meetings held between the two parties over the years and it represents a shared vision for practical implementations, leading up to flight demonstrations of localized flow control. If successful, localized flow control may lead to important ramifications for next generation airplanes from both the economic and environmental perspectives. Under this contract localized AFC has been used to improve aerodynamic performance during high-lift operations using Computational Fluid Dynamics (CFD). Specifically, AFC has been applied at the aileron and at various location in the wing leading edge (LE) regions. The applications target reduced drag and enhanced lift over the range of practical angles of attack, including stall. These benefits translate to airplane performance improvements, such as longer range or larger payload. The CFD results are used to quantify potential aerodynamic benefits, as well as the input required for actuation. This helps identify the most promising candidates, which potentially provide material net airplane level enhancements using onboard fluidic sources. The airplane configuration selected for the CFD study is a representative of a future short/medium-range twin-engine airplane dubbed the Reference Aircraft. A slew of AFC applications has been explored and their aerodynamic performance enhancements were benchmarked against the baseline Reference Aircraft. Promising AFC candidates have been deemed practical and potentially suitable for both the aileron and the wing LE implementations. The findings on the Reference Aircraft are used to guide the development of the AFC-enhanced aileron for the CRM-HL. The wind-tunnel model of the CRM-HL will be used by NASA to validate the AFC concepts, complementing the CFD-based analysis and the integration study (final report document #3).

CFD↗