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At least 865 records · Page 48

Synthesis of N{sup 1},N{sup 1},N{sup 3},N{sup 3}-tetrasubstituted diethylenetriamines

Preparative procedures for the synthesis of N{sup 1},N{sup 1},N{sup 3},N{sup 3}-tetrasubstituted diethylenetriamines via aminoalkylation of N,N-disubstituted ethylenediamines with N,N-disubstituted 2-chloroethylamines were developed. Aminoalkylation of N,N-dimethylethylenediamine under heating gave simultaneously secondary N{sup 1},N{sup 1},N{sup 3},N{sup 3}-tetrasubstituted diethylenetriamines and quaternary ammonium salts, N-(2-aminoethyl)-N-(2-dialkylaminoethyl)-N,N-dimethylammonium chlorides. Structures of the synthesized compounds were established by IR spectroscopy, {sup 1}H and {sup 13}C NMR spectroscopy, and electrospray ionization mass spectrometry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A UNIVERSAL MODEL FOR HALO CONCENTRATIONS

We present a numerical study of dark matter halo concentrations in ΛCDM and self-similar cosmologies. We show that the relation between concentration, c, and peak height, ν, exhibits the smallest deviations from universality if halo masses are defined with respect to the critical density of the universe. These deviations can be explained by the residual dependence of concentration on the local slope of the matter power spectrum, n, which affects both the normalization and shape of the c-ν relation. In particular, there is no well-defined floor in the concentration values. Instead, the minimum concentration depends on redshift: at fixed ν, halos at higher z experience steeper slopes n, and thus have lower minimum concentrations. We show that the concentrations in our simulations can be accurately described by a universal seven-parameter function of only ν and n. This model matches our ΛCDM results to ≲ 5% accuracy up to z = 6, and matches scale-free Ω{sub m} = 1 models to ≲ 15%. The model also reproduces the low concentration values of Earth-mass halos at z ≈ 30, and thus correctly extrapolates over 16 orders of magnitude in halo mass. The predictions of our model differ significantly from all models previously proposed in the literature at high masses and redshifts. Our model is in excellent agreement with recent lensing measurements of cluster concentrations.

79 ASTRONOMY AND ASTROPHYSICS↗

Spectral energy distribution analysis of class I and class II FU Orionis stars

FU Orionis stars (FUors) are eruptive pre-main sequence objects thought to represent quasi-periodic or recurring stages of enhanced accretion during the low-mass star-forming process. We characterize the sample of known and candidate FUors in a homogeneous and consistent way, deriving stellar and circumstellar parameters for each object. We emphasize the analysis in those parameters that are supposed to vary during the FUor stage. We modeled the spectral energy distributions of 24 of the 26 currently known FUors, using the radiative transfer code of Whitney et al. We compare our models with those obtained by Robitaille et al. for Taurus class II and I sources in quiescence periods by calculating the cumulative distribution of the different parameters. FUors have more massive disks: we find that ∼80% of the disks in FUors are more massive than any Taurus class II and I sources in the sample. Median values for the disk mass accretion rates are ∼10{sup –7} M {sub ☉} yr{sup –1} versus ∼10{sup –5} M {sub ☉} yr{sup –1} for standard young stellar objects (YSOs) and FUors, respectively. While the distributions of envelope mass accretion rates for class I FUors and standard class I objects are similar, FUors, on average, have higher envelope mass accretion rates than standard class II and class I sources. Most FUors (∼70%) have envelope mass accretion rates above 10{sup –7} M {sub ☉} yr{sup –1}. In contrast, 60% of the classical YSO sample has an accretion rate below this value. Our results support the current scenario in which changes experimented by the circumstellar disk explain the observed properties of these stars. However, the increase in the disk mass accretion rate is smaller than theoretically predicted, although in good agreement with previous determinations.

79 ASTRONOMY AND ASTROPHYSICS↗

BANYAN. VI. Discovery of a companion at the Brown dwarf/planet-mass limit to a Tucana–horologium M dwarf

We report the discovery of a substellar companion to 2MASS J02192210–3925225, a young M6 γ candidate member of the Tucana–Horologium association (30–40 Myr). This L4 γ companion has been discovered with seeing-limited direct imaging observations; at a 4″ separation (160 AU) and a modest contrast ratio, it joins the very short list of young low-mass companions amenable to study without the aid of adaptive optics, enabling its characterization with a much wider suite of instruments than is possible for companions uncovered by high-contrast imaging surveys. With a model-dependent mass of 12–15 M{sub Jup}, it straddles the boundary between the planet and brown dwarf mass regimes. We present near-infrared spectroscopy of this companion and compare it to various similar objects uncovered in the last few years. The J0219–3925 system falls in a sparsely populated part of the host mass versus mass ratio diagram for binaries; the dearth of known similar companions may be due to observational biases in previous low-mass companion searches.

79 ASTRONOMY AND ASTROPHYSICS↗

CYGNUS X-3's LITTLE FRIEND

Using the unique X-ray imaging capabilities of the Chandra X-ray observatory, a 2006 observation of Cygnus X-3 has provided insight into a singular feature associated with this well-known microquasar. This extended emission, located {approx}16'' from Cygnus X-3, varies in flux and orbital phase (shifted by 0.56 in phase) with Cygnus X-3, acting like a celestial X-ray 'mirror'. The feature's spectrum, flux, and time variations allow us to determine the location, size, density, and mass of the scatterer. We find that the scatterer is a Bok Globule located along our line of sight, and we discuss its relationship to Cygnus X-3. This is the first time such a feature has been identified with Chandra.

79 ASTRONOMY AND ASTROPHYSICS↗

EXPLORING THE DIVERSITY OF GROUPS AT 0.1 < z < 0.8 WITH X-RAY AND OPTICALLY SELECTED SAMPLES

We present the global group properties of two samples of galaxy groups containing 39 high-quality X-ray-selected systems and 38 optically (spectroscopically) selected systems in coincident spatial regions at 0.12 < z < 0.79. The total mass range of the combined sample is {approx}(10{sup 12}-5) Multiplication-Sign 10{sup 14} M{sub Sun }. Only nine optical systems are associable with X-ray systems. We discuss the confusion inherent in the matching of both galaxies to extended X-ray emission and of X-ray emission to already identified optical systems. Extensive spectroscopy has been obtained and the resultant redshift catalog and group membership are provided here. X-ray, dynamical, and total stellar masses of the groups are also derived and presented. We explore the effects of utilizing different centers and applying three different kinds of radial cut to our systems: a constant cut of 1 Mpc and two r{sub 200} cuts, one based on the velocity dispersion of the system and the other on the X-ray emission. We find that an X-ray-based r{sub 200} results in less scatter in scaling relations and less dynamical complexity as evidenced by results of the Anderson-Darling and Dressler-Schectman tests, indicating that this radius tends to isolate the virialized part of the system. The constant and velocity dispersion based cuts can overestimate membership and can work to inflate velocity dispersion and dynamical and stellar mass. We find L{sub X} -{sigma} and M{sub stellar}-L{sub X} scaling relations for X-ray and optically selected systems are not dissimilar. The mean fraction of mass found in stars, excluding intracluster light, for our systems is {approx}0.014 with a logarithmic standard deviation of 0.398 dex. We also define and investigate a sample of groups which are X-ray underluminous given the total group stellar mass. For these systems the fraction of stellar mass contributed by the most massive galaxy is typically lower than that found for the total population of groups implying that there may be less intragroup medium contributed from the most massive member in these systems. Eighty percent of 15 underluminous groups have less than 40% of their stellar mass in the most massive galaxy which happens in less than 1% of cases with samples matched in stellar mass, taken from the combined group catalog.

79 ASTRONOMY AND ASTROPHYSICS↗

SIMP J2154–1055: A NEW LOW-GRAVITY L4β BROWN DWARF CANDIDATE MEMBER OF THE ARGUS ASSOCIATION

We present SIMP J21543454–1055308, a new L4β brown dwarf identified in the SIMP survey that displays signs of low gravity in its near-infrared spectrum. Using BANYAN II, we show that it is a candidate member of the Argus association, albeit with a 21% probability that it is a contaminant from the field. Measurements of radial velocity and parallax will be needed to verify its membership. If it is a member of Argus (age 30-50 Myr), then this object would have a planetary mass of 10 ± 0.5 M {sub Jup}.

79 ASTRONOMY AND ASTROPHYSICS↗

Physical properties of emission-line galaxies at z ∼ 2 from near-infrared spectroscopy with Magellan fire

We present results from near-infrared spectroscopy of 26 emission-line galaxies at z ∼ 2.2 and z ∼ 1.5 obtained with the Folded-port InfraRed Echellette (FIRE) spectrometer on the 6.5 m Magellan Baade telescope. The sample was selected from the WFC3 Infrared Spectroscopic Parallels survey, which uses the near-infrared grism of the Hubble Space Telescope Wide Field Camera 3 (WFC3) to detect emission-line galaxies over 0.3 ≲ z ≲ 2.3. Our FIRE follow-up spectroscopy (R ∼ 5000) over 1.0-2.5 μm permits detailed measurements of the physical properties of the z ∼ 2 emission-line galaxies. Dust-corrected star formation rates for the sample range from ∼5-100 M {sub ☉} yr{sup –1} with a mean of 29 M {sub ☉} yr{sup –1}. We derive a median metallicity for the sample of 12 + log(O/H) = 8.34 or ∼0.45 Z {sub ☉}. The estimated stellar masses range from ∼10{sup 8.5}-10{sup 9.5} M {sub ☉}, and a clear positive correlation between metallicity and stellar mass is observed. The average ionization parameter measured for the sample, log U ≈ –2.5, is significantly higher than what is found for most star-forming galaxies in the local universe, but similar to the values found for other star-forming galaxies at high redshift. We derive composite spectra from the FIRE sample, from which we measure typical nebular electron densities of ∼100-400 cm{sup –3}. Based on the location of the galaxies and composite spectra on diagnostic diagrams, we do not find evidence for significant active galactic nucleus activity in the sample. Most of the galaxies, as well as the composites, are offset diagram toward higher [O III]/Hβ at a given [N II]/Hα, in agreement with other observations of z ≳ 1 star-forming galaxies, but composite spectra derived from the sample do not show an appreciable offset from the local star-forming sequence on the [O III]/Hβ versus [S II]/Hα diagram. We infer a high nitrogen-to-oxygen abundance ratio from the composite spectrum, which may contribute to the offset of the high-redshift galaxies from the local star-forming sequence in the [O III]/Hβ versus [N II]/Hα diagram. We speculate that the elevated nitrogen abundance could result from substantial numbers of Wolf-Rayet stars in starbursting galaxies at z ∼ 2.

79 ASTRONOMY AND ASTROPHYSICS↗

Cosmic Ray Energetics and Mass (CREAM)

The CREAM instrument was flown on a Long Duration Balloon in Antarctica in December 2004 and January 2005, achieving a flight duration record of nearly 42 days. It detected and recorded cosmic ray primary particles ranging in type from hydrogen to iron nuclei and in energy from 1 TeV to several hundred TeV. With the data collected we will have the world's best measurement of the energy spectra and mass composition of nuclei in the primary cosmic ray flux at these energies, close to the astrophysical knee . The instrument utilized a thin calorimeter, a transition radiation detector and a timing charge detector, which also provided time-of-flight information. The responsibilities of our group have been with the timing charge detector (TCD), and with the data acquisition electronics and ground station support equipment. The TCD utilized fast scintillators to measure the charge of the primary cosmic ray before any interactions could take place within the calorimeter. The data acquisition electronics handled the output of the various detectors, in a fashion fully integrated with the payload bus. A space-qualified flight computer controlled the acquisition, and was used for preliminary trigger information processing and decision making. Ground support equipment was used to monitor the health of the payload, acquire and archive the data transmitted to the ground, and to provide real-time control of the instrument in flight.

Coutu, Stephane↗

Herschel photometry of disks around low-mass stars in the R CrA cloud

We report photometric results from a subset of a Herschel-PACS program to observe cool dust in disks around low-mass stars as a complement to our earlier program to measure far-infrared emission from brown dwarfs. In this latest study we observed five low-mass objects in the nearby R Corona Australis region and detected at least three at 70 μm. Using a Monte Carlo radiative transfer code we have investigated the disk masses and geometry based on detailed spectral energy distribution (SED) modeling, and we compare these new results to those from our earlier larger sample of brown dwarfs. In particular, our SED analysis for these five objects shows again that disk geometries of brown dwarfs or low-mass stars are generally similar to their higher mass counterparts like T Tauri disks, but the range of disk mass extends to well below the value found in T Tauri stars.

79 ASTRONOMY AND ASTROPHYSICS↗

Heterospin biradicals based on new piperidineoxyl-substituted 3,6-di-tert-butyl-o-benzoquinone

A nucleophilic addition reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl (OH-TEMPO) to 3,6-di-tert-butyl-o-benzoquinone was used to obtain a new sterically hindered o-benzoquinone (1) containing 2,2,6,6-tetramethylpiperidineoxyl functional group, which was characterized by IR spectroscopy, mass spectrometry, elemental analysis, and X-ray diffraction. A one-electron reduction of 1 with potassium and thallium is an efficient method for the generation of earlier unknown heterospin biradicals 5a and 5b, respectively, containing nitroxide and o-semiquinone radical centers. Analysis of the hyperfine structure of the ESR spectra of biradicals 5a and 5b in solution showed that they belong to the group of heterospin biradicals with strong (J >> a) and fast exchange interaction between the radical centers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Exact solutions for a Maxwell-Kalb-Ramond action with dilaton: Localization of massless and massive modes in a sine-Gordon brane-world

We analytically find the exact propagation modes of the electromagnetic and the Kalb-Ramond fields together in a five-dimensional curved space-time. The existence and localization of gauge particles into our four-dimensional world (4D) is studied in detail on a brane-world scenario in which two gauge fields interact with a dilaton and a gravitational background. The coupling to the dilaton is different in each case causing the splitting between gauge spectra. The gauge-field zero-modes and an infinite tower of Kaluza-Klein massive states are analytically obtained. Relevant conditions on the dilaton coupling constant are found in order to identify with precision every finite tensor and vector eigenstate in the theory. An exact quantization condition on the whole mass spectrum, depending on the dilaton coupling constant and the bulk Planck mass, is inherited from the extra-dimension. This allows finding an exact rule to prevent tachyons in the theory and, by the same token, predicting a possible tensor zero-mode in 4D world. We also show that KK massive-modes contributions onto 4D physics are strongly suppressed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

MODELING COLLISIONAL CASCADES IN DEBRIS DISKS: STEEP DUST-SIZE DISTRIBUTIONS

We explore the evolution of the mass distribution of dust in collision-dominated debris disks, using the collisional code introduced in our previous paper. We analyze the equilibrium distribution and its dependence on model parameters by evolving over 100 models to 10 Gyr. With our numerical models, we confirm that systems reach collisional equilibrium with a mass distribution that is steeper than the traditional solution by Dohnanyi. Our model yields a quasi-steady-state slope of n(m) {approx} m{sup -1.88} [n(a) {approx} a{sup -3.65}] as a robust solution for a wide range of possible model parameters. We also show that a simple power-law function can be an appropriate approximation for the mass distribution of particles in certain regimes. The steeper solution has observable effects in the submillimeter and millimeter wavelength regimes of the electromagnetic spectrum. We assemble data for nine debris disks that have been observed at these wavelengths and, using a simplified absorption efficiency model, show that the predicted slope of the particle-mass distribution generates spectral energy distributions that are in agreement with the observed ones.

79 ASTRONOMY AND ASTROPHYSICS↗

Dusty WDs in the WISE all sky survey ∩ SDSS

A recent cross-correlation between the Sloan Digital Sky Survey (SDSS) Data Release 7 White Dwarf Catalog with the Wide-Field Infrared Survey Explorer (WISE) all-sky photometry at 3.4, 4.6, 12, and 22 μm performed by Debes et al. resulted in the discovery of 52 candidate dusty white dwarfs (WDs). However, the 6'' WISE beam allows for the possibility that many of the excesses exhibited by these WDs may be due to contamination from a nearby source. We present MMT+SAO Wide-Field InfraRed Camera J- and H-band imaging observations (0.''5-1.''5 point spread function) of 16 of these candidate dusty WDs and confirm that four have spectral energy distributions (SEDs) consistent with a dusty disk and are not accompanied by a nearby source contaminant. The remaining 12 WDs have contaminated WISE photometry and SEDs inconsistent with a dusty disk when the contaminating sources are not included in the photometry measurements. We find the frequency of disks around single WDs in the WISE ∩ SDSS sample to be 2.6%-4.1%. One of the four new dusty WDs has a mass of 1.04 M {sub ☉} (progenitor mass 5.4 M {sub ☉}) and its discovery offers the first confirmation that massive WDs (and their massive progenitor stars) host planetary systems.

79 ASTRONOMY AND ASTROPHYSICS↗

Broad-lined Supernova 2016coi with a Helium Envelope

We present the early-phase spectra and the light curves of the broad-lined (BL) supernova (SN) 2016coi from t = 7 to 67 days after the estimated explosion date. This SN was initially reported as a BL Type SN Ic (SN Ic-BL). However, we found that spectra up to t = 12 days exhibited the He i λ 5876, λ 6678, and λ 7065 absorption lines. We show that the smoothed and blueshifted spectra of normal SNe Ib are remarkably similar to the observed spectrum of SN 2016coi. The line velocities of SN 2016coi were similar to those of SNe Ic-BL and significantly faster than those of SNe Ib. Analyses of the line velocity and light curve suggest that the kinetic energy and the total ejecta mass of SN 2016coi are similar to those of SNe Ic-BL. Together with BL SNe 2009bb and 2012ap, for which the detection of He i was also reported, these SNe could be transitional objects between SNe Ic-BL and SNe Ib, and be classified as BL Type “Ib” SNe (SNe “Ib”-BL). Our work demonstrates the diversity of the outermost layer in BL SNe, which should be related to the variety of the evolutionary paths.

79 ASTRONOMY AND ASTROPHYSICS↗

Wrong-Higgs interactions without flavor problems and their effects on physical observables

We consider the wrong-Higgs interactions such as type-III two Higgs doublet models. Generally, such interactions cause flavor problems. However, if new Yukawa interactions have the same flavor structure as that of the standard model, we do not have any flavor problems. In this work we propose a microscopic model for the wrong-Higgs interactions aligned with the standard model ones in the context of supersymmetry and show their phenomenological implications. Low energy contraints from muon g-2 and rare B decays can be relieved and it can be viable to have low mass superparticle spectra with light dark matter which is preferred by recent experiments such as DAMA/LIBRA, CDMS-II, and CoGeNT. We also briefly discuss modification of Higgs decay in colliders.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

WFIRST PLANET MASSES FROM MICROLENS PARALLAX

I present a method using only a few ground-based observations of magnified microlensing events to routinely measure the parallaxes of WFIRST events if WFIRST is in an L2 orbit. This could be achieved for all events with A{sub max} > 30 using target-of-opportunity observations of select WFIRST events, or with a complementary, ground-based survey of the WFIRST field, which can push beyond this magnification limit. When combined with a measurement of the angular size of the Einstein ring, which is almost always measured in planetary events, these parallax measurements will routinely give measurements of the lens masses and hence the absolute masses of the planets. They can also lead to mass measurements for dark, isolated objects such as brown dwarfs, free-floating planets, and stellar remnants if the size of the Einstein ring is measured.

79 ASTRONOMY AND ASTROPHYSICS↗

Searching for Cool Dust. II. Infrared Imaging of The OH/IR Supergiants, NML Cyg, VX Sgr, S Per, and the Normal Red Supergiants RS Per and T Per

New MMT/MIRAC (9–11 μm), SOFIA/FORCAST (11–37 μm), and Herschel/PACS (70 and 160 μm) infrared (IR) imaging and photometry is presented for three famous OH/IR red supergiants (NML Cyg, VX Sgr, and S Per) and two normal red supergiants (RS Per and T Per). We model the observed spectral energy distributions (SEDs) using radiative-transfer code DUSTY. Azimuthal average profiles from the SOFIA/FORCAST imaging, in addition to dust mass distribution profiles from DUSTY, constrain the mass-loss histories of these supergiants. For all of our observed supergiants, the DUSTY models suggest that constant mass-loss rates do not produce enough dust to explain the observed infrared emission in the stars’ SEDs. Combining our results with Shenoy et al. (Paper I), we find mixed results with some red supergiants showing evidence for variable and high mass-loss events while others have constant mass loss over the past few thousand years.

79 ASTRONOMY AND ASTROPHYSICS↗