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NASA NTRS1980

A theory for the origin of a self-replicating chemical system. I - Natural selection of the autogen from short, random oligomers

A general theory is presented for the origin of a self-replicating chemical system, termed an autogen, which is capable of both crude replication and translation (protein synthesis). The theory requires the availability of free energy and monomers to the system, a significant background low-yield synthesis of kinetically stable oligopeptides and oligonucleotides, the localization of the oligomers, crude oligonucleotide selectivity of amino acids during oligopeptide synthesis, crude oligonucleotide replication, and two short peptide families which catalyze replication and translation, to produce a localized group of at least one copy each of two protogenes and two protoenzymes. The model posits a process of random oligomerization, followed by the random nucleation of functional components and the rapid autocatalytic growth of the functioning autogen to macroscopic amounts, to account for the origin of the first self-replicating system. Such a process contains steps of such high probability and short time periods that it is suggested that the emergence of an autogen in a laboratory experiment of reasonable time scale may be possible.

White, D. H.↗

NASA NTRS1981

Amino acids and hydrocarbons approximately 3,800-Myr old in the Isua rocks, southwestern Greenland

Results of an analysis of amino acids and hydrocarbons found in the Isua banded iron formation, which contains the oldest known rocks on earth, are discussed. Similarities are pointed out between the relative amino acid abundances of the Isua rocks and those of lichens found on their surfaces, and a lack of substantial racemization indicated by the low D/L ratios in the 3800-million year old rock samples is noted. Experimental results showing the possibility of amino acid diffusion from lichens into the rocks are presented. Comparisons of the Isua rock amino acid D/L ratios with those reported for samples from other regions indicates that none of the Isua amino acids are older than a few tens of thousands to a few hundred thousand years. Analyses of the saturated hydrocarbons of the Isua samples reveals no odd carbon number preference, which may indicate antiquity, however laboratory experiments have shown that amino acids and aromatic and saturated aliphatic hydrocarbons could not have survived the metamorphic history of the Isua rocks. The evidence presented thus suggests that the amino acids and hydrocarbons found are not of the age of the sediments.

Nagy, B.↗

NASA NTRS1980

Simultaneous radiation damage and annealing of GaAs solar cells

In this report, concepts and equations are developed to describe the simultaneous radiation damage and annealing of solar cells. The annealing characteristics of three types of defects are employed to study three examples of continuous irradiation and annealing. One example shows that the effective damage could be reduced by a factor of fifty. The difficulty of a laboratory experiment properly simulating the effects in space are discussed. Potential advantages of continuous annealing such as reduction of stable defect formation and omission of radiation cover glasses are presented.

Heinbockel, J. H.↗

NASA NTRS1981

Exceedance statistics of accelerations resulting from thruster firings on the Apollo-Soyuz mission

Spacecraft acceleration resulting from firings of vernier control system thrusters is an important consideration in the design, planning, execution and post-flight analysis of laboratory experiments in space. In particular, scientists and technologists involved with the development of experiments to be performed in space in many instances required statistical information on the magnitude and rate of occurrence of spacecraft accelerations. Typically, these accelerations are stochastic in nature, so that it is useful to characterize these accelerations in statistical terms. Statistics of spacecraft accelerations are summarized.

Fichtl, G. H.↗

NASA NTRS1981

Laboratory measurements of the cometary photochemical phenomena

Laboratory experiments are described that provide fundamental information about photochemical processes in comets. The yield of cometary radicals such as CN, OH, etc. can be determined as a function of photolyzing wavelength. Quantum state distributions of the internal energy of the cometary radicals can also be measured as a function of wavelength permitting one to define the recoil velocity of the fragments. This type of information supplies the data needed for more elaborate models to interpret the data being obtained on comets.

Jackson, W. M.↗

NASA NTRS1982

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents on Titan are calculated for solar ultraviolet radiation, the solar wind, Saturn magnetospheric particles, the Saturn co-rotating plasma, and cosmic rays. Laboratory experiments show that a variety of simple gas phase organic molecules and more complex organic solids called tholins are produced by such irradiations of simulated Titanian atmospheres. Except for ultraviolet wavelengths longward of the methane photodissociation continuum, most dissociation events occur between about 3100 and 3600 km altitude, corresponding well to the region of EUV opacity detected by Voyager. For a wide variety of simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at about 2825 km. It is proposed that such condensates, beginning with CH4 at about 2615 km, comprise the principal mass of the Titan clouds. There is a distinct tendency for the atmosphere of Titan to act as a fractional distillation device, molecules of greater complexity condensing out at higher altitudes.

Sagan, C.↗

NASA NTRS1981

Absorption and emission of extraordinary-mode electromagnetic waves near cyclotron frequency in nonequilibrium plasmas

An investigation is presented of two cases: (1) weakly relativistic electrons with a loss-cone type distribution, and (2) electrons with a drift velocity parallel to the ambient magnetic field. Numerical computations are given for physical parameters close to those in the polar region of the earth magnetosphere and laboratory experiments, with attention to the fast extraordinary-mode radiation whose frequency is near that of the electron cyclotron frequency. The fast extraordinary mode can escape from a strong field region to the weaker field region and may therefore be measured outside the plasma. It is found that the X mode radiation can be amplified by means of a cyclotron maser effect when the electrons have a loss-cone distribution, and it is concluded that, when the electron energy is sufficiently high, the X mode cutoff frequency may be lower than the cyclotron frequency.

Wu, C. S.↗

NASA NTRS1981

Reduction of thionucleosides - A prebiotic pathway to deoxyribonucleosides

A mechanism is proposed for the prebiotic synthesis of deoxyribonucleotides and possible nucleic acid analogs from ribonucleotides by a pathway involving 2'-thio-2'-deoxyribonucleosides. The mechanism is supported by laboratory experiments in which 2'-thio-2'-deoxycytidine was synthesized from anhydro arabinosyl cytosine in dithiophosphate and CS2. The subsequent reduction of the thio-analogs has been achieved with ferrous ion, and photochemically. It is noted that the proposed pathway for prebiotic deoxyribonucleotide synthesis is in harmony with the Principle of Continuity, as both the proposed and present pathways rely on the reduction of a 2' functional group.

Patel, A. D.↗

NASA NTRS1982

Dynamical features of moving double layers

Numerical simulations of the dynamics of double layers that form in response to an applied potential drop across a plasma are carried out for plasmas of lengths much greater than previously considered. The evolution of finite-size plasmas of lengths 100, 200 and 400 Debye lengths at the low-potential end of the simulation region was followed by the solution of the Vlasov and Poisson equations. Results show that the double layer moves towards the high-potential side of the layer, at a speed directly dependent on the length of the plasma. The moving double layer is accompanied by a moving density front which is similar to an ion acoustic shock created by the expansion of a high-density plasma into a low-density plasma, as well as plasma heating and evacuation, electron and ion current interruptions and recovery. Double layer formation, motion, and accompanying phenomena are found to repeat periodically. Results are in good agreement with laboratory experiments, and may be used to explain certain phenomena observed in auroral plasmas.

Singh, N.↗

NASA NTRS1981

Long wavelength gravity and topography anomalies

It is shown that gravity and topography anomalies on the earth's surface may provide new information about deep processes occurring in the earth, such as those associated with mantle convection. Two main reasons are cited for this. The first is the steady improvement that has occurred in the resolution of the long wavelength gravity field, particularly in the wavelength range of a few hundred to a few thousand km, mainly due to increased coverage of terrestrial gravity measurements and the development of radar altimeters in orbiting satellites. The second reason is the large number of numerical and laboratory experiments of convection in the earth, including some with deformable upper and lower boundaries and temperature-dependent viscosity. The oceans are thought to hold the most promise for determining long wavelength gravity and topography anomalies, since their evolution has been relatively simple in comparison with that of the continents. It is also shown that good correlation between long wavelength gravity and topography anomalies exists over some portions of the ocean floor

Watts, A. B.↗

NASA NTRS1982

Computed laser backscattering from turbid liquids - Comparison with laboratory results

A recently developed semianalytic Monte Carlo radiative transfer model applicable to oceanographic lidar systems (SALMON) has been used to simulate a series of laboratory experiments studying the backscatter of laser light from dispersions of Teflon spheres. Results obtained with SALMON, using best estimates of pertinent optical parameters, compared quite well with experimental data in both a qualitative and quantitative sense, with the largest relative discrepancies being approximately 30%. The results firmly establish the validity of SALMON in studying the performance of real oceanographic lidar systems.

Poole, L. R.↗

NASA NTRS1982

The mechanisms of fine particle generation and electrification during Mount St. Helens volcanic eruption

Microscopical investigation of volcanic ash collected from ground stations during Mount St. Helens eruptions reveal a distinctive bimodel size distribution with high concentrations of particle ranges at (1) 200-100 microns and (2) 20-0.1 microns. Close examination of individual particles shows that most larger ones are solidified magma particles of porous pumice with numerous gas bubbles in the interior and the smaller ones are all glassy fragments without any detectable gas bubbles. Elemental analysis demonstrates that the fine fragments all have a composition similar to that of the larger pumice particles. Laboratory experiments suggest that the formation of the fine fragments is by bursting of glassy bubbles from a partially solidified surface of a crystallizing molten magma particle. The production of gas bubbles is due to the release of absorbed gases in molten magma particles when solubility decreases during phase transition. Diffusion cloud chamber experiments strongly indicate that sub-micron volcanic fragments are highly hygroscopic and extremely active as cloud condensation nuclei. Ice crystals also are evidently formed on those fragments in a supercooled (-20 C) cloud chamber. It has been reported that charge generation from ocean volcanic eruptions is due to contact of molten lava with sea water. This seems to be insufficient to explain the observed rapid and intense lightning activities over Mount St. Helens eruptions. Therefore, a hypothesis is presented here that highly electrically charged fine solid fragments are ejected by bursting of gas bubbles from the surface of a crystallizing molten magma particles.

Cheng, R. J.↗

NASA NTRS1983

Experimental creep data for a built-up aluminum/titanium structure subjected to heating and loading

Experimental creep, temperature, and strain data resulting from a laboratory experiment on a built-up aluminum/titanium structure are presented. The structure and the experiment are described in detail. A heating and loading experiment lasting approximately six hours is conducted on a test structure. Considerable creep strain resulted from compressive stresses in the heated skin. Large residual stresses were found after the experiment was completed. The residual stresses in the substructure frames were large enough to preclude further cycles of creep experiments with this built-up structure because of concern that the frame webs would buckle.

Jenkins, J. M.↗

NASA NTRS1983

The water factor in harvest-sprouting of hard red spring wheat

Sprouting in unthreshed, ripe, hard red spring wheat (Triticum aestivum L.) is induced by rain, but sprouting does not necessarily occur because the crop is wetted. The spike and grain water conditions conducive to sprouting were determined in a series of laboratory experiments. Sprouting did not occur in field growing wheat wetted to 110% water concentration until the spike water concentration was reduced to 12% and maintained at this concentration for 2 days before wetting. When cut at growth stage 11.3, Feekes scale, Saratovskaya 20 (USSR) sprouted after 4 days drying, Olaf and Alex between 7 and 15 days drying and Columbus, recognized for its resistance to harvest time sprouting, after more than 15 days drying. Sprouting potential was enhanced after 4 wetting drying cycles in which any wetted interval was too brief to permit sufficient water imbibition to initiate sprouting. At harvest ripeness, grain water concentration exceeded spike water concentration by 0.7 percentage units. Following 6 months storage, 20% of the kernels in 300 spike bundles (simulating windrows) sprouted within 28 hrs after initiation of wetting to saturation (150% water concentration). Ninety percent sprouting occurred within 8 days in bundles maintained at 75% water concentration and higher, but less sprouting occurred in bundles dried to 50% water concentration before resaturation.

Bauer, A.↗

NASA NTRS1982

Uses of infrared thermography in the low-cost solar array program

The Jet Propulsion Laboratory has used infrared thermography extensively in the Low-Cost Solar Array (LSA) photovoltaics program. A two-dimensional scanning infrared radiometer has been used to make field inspections of large free-standing photovoltaic arrays and smaller demonstration sites consisting of integrally mounted rooftop systems. These field inspections have proven especially valuable in the research and early development phases of the program, since certain types of module design flaws and environmental degradation manifest themselves in unique thermal patterns. The infrared camera was also used extensively in a series of laboratory tests on photovoltaic cells to obtain peak cell temperatures and thermal patterns during off-design operating conditions. The infrared field inspections and the laboratory experiments are discussed, and sample results are presented.

Glazer, S. D.↗

NASA NTRS1983

On the dynamic response and collapse of slender guyed booms for space application

A procedure is developed for the analysis of the nonlinear transient response of an initially imperfect slender guyed boom having a concentrated mass at the tip. The analysis is compared with laboratory experiments, and the validated procedure is employed to study the transient response of a boom to suddenly applied step loads and prescribed initial velocities. Both cases approximate the transient conditions associated with commencing and terminating a slewing maneuver in space. Two nonlinear effects are examined, namely cable slackening and beam column behavior. It is shown that dynamic buckling of the boom may occur with excitations which result in slackening of a cable. It is also shown that transverse boom tip deflections are sensitive only to initial eccentricities when certain threshold values are exceeded. Design guidelines are established for combinations of pulse level and duration which meet performance requirements for allowable deflections.

Housner, J. M.↗

NASA NTRS1983

Exceedance statistics of accelerations resulting from thruster firings on the Apollo-Soyuz mission

Fichtl, G. H.↗

NASA NTRS1982

Theory of beam plasma discharge

The general theory of beam plasma discharge (BPD) is discussed in relation to space and laboratory beam injection situations. An important concept introduced is that even when beam plasma instabilities are excited, there are two regime of BPD with radically different observational properties. They are described here as BPD with either classical or anomalous energy depositions. For high pressures or low altitudes, the classical is expected to dominate. For high altitudes and laboratory experiments, where the axial system size is less than lambda sub en, no BPD will be triggered unless the unstable waves are near the ambient plasma frequency and their amplitudes at saturation are large enough to create suprathermal tails by collapsing.

Papadopoulos, K.↗