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A number of issues involving grain charging in the interstellar medium were discussed. Such effects include: (1) stark broadening of molecular spectral features, (2) electrostatic grain rupturing, (3) enhancements in particle-grain collision cross sections, and (4) excitation of molecular rotations and/or vibrations.
Noble gases and nitrogen were extracted from a 100 to 150 microns ilmenite separate from lunar soil 71501 by closed system stepped heating in approx. 10 torr O2 at 300 C, 400 C, 500 C, 600 C and 630 C, followed by stepped pyrolysis at ten temperatures between 680 C and approx. 1500 C. The five oxidation steps together liberated approx. 65% of the total He-4, 45% of the Ne-20, 23% of the N-14 and Ar-36, 12% of the Kr-84 and 8% of the Xe-132 in the sample; Ne-20/Ar-36 and Ne-20/Ne-22 ratios agree with the solar wind composition experiment, and Kr-84/Ar-36 and Xe-132/Ar-36 are within approx. 10% of Cameron's estimates for the sun and solar wind. The remaining gases, released above 630 C by pyrolysis, are strongly fractionated with respect to the SWC-Cameron solar wind elemental composition. Large concentrations of fractionated noble gases in grain interiors, their virtual absence in the relatively unfractionated surface gas reservoir, and the high N/noble gas ratio all imply that most of the solar wind noble gases initially implanted in grain surfaces are eventually lost by diffusion. Loss limits can be estimated by considering two given scenarios. It is concluded tat approx. 70 to 97% or more of the Ar implanted in 71501 ilmenite grains has diffusively escaped.
For the fist time, a time-dependent model is described which includes the role of grains in the production of molecules in dense clouds including ion-molecule gas phase chemistry. The approach provides information regarding the coupling between the two phases. Although the coupling between the two chemistries is extremely strong, the two domains maintain their own identities. While H2O, CH4, and NH3 are made efficiently, with a high production rate on grains and released back to the gas phase, the gas phase is essentially responsible for the formation of CO, a very stable molecule which may or may not react on grains with atomic oxygen and may or may not form CO2.
The presence of icy grains has important consequences for the physical and chemical processes which take place in the comae of comets. The search for the infrared signature of these icy grains is outlined. The absorption feature near 3 microns found in the coma grains of Comets Bowell and Cernis is interpreted as being due to water ice.
Interstellar grains of radius less than 003 microns are known to have a fluctuating temperature because their internal energy is comparable to the energy of UV and visible photons. The exact resultant grain temperature distribution is given by studying the multiphoton absorption processes. This distribution satisfies an homogeneous integral equation which can be solved by an iteration technique. These small grains generally emit at shorter wavelengths than big cold grians and therefore could help in the interpretation of the infrared spectra (1-1000 microns) of various astrophysical objects.
The magnetic-field alignment of interstellar silicate grains containing superparamagnetic (SPM) inclusions is investigated theoretically. It is shown that the observed dependence of polarization on wavelength can be fully explained in terms of the alignment mechanisms and the size distribution of the SPM grains, at least for interstellar polarizations peaking at wavelength 550 nm or higher. The implications of this finding for models of grain coagulation and shattering are considered.
A singular perturbation analysis valid for small grain-boundary slopes is used with the one-sided model for solidification to show that grain boundaries introduce imperfections into the symmetry of the developing cellular interfaces which rupture the junction between the family of planar shapes and the bifurcating cellular families. Undulating interfaces are shown to develop first near grain boundaries, and to evolve with decreasing temperature gradient either by a smooth transition from the almost planar family or by a sudden jump to moderate-amplitude cellular forms, depending on the growth rate.
This paper reviews mechanisms that have been proposed to account for alignment of dust grains in diffuse clouds and in dense clouds. The mechanisms that have proved inadequate are considered, including alignment by nonmagnetic and magnetic processes. The results thus far favor the Davis-Greenstein mechanism, in which paramagnetic relaxation of spinning grains removes components of rotation perpendicular to the magnetic field. Polarization measurements showing the alignment of grains in cool dense clouds are discussed.
The paper studies how infrared colors of dust emission from the interstellar medium vary with the energy density of the radiation field on the basis of IRAS observation of the California Nebula. The data suggest that color variations result from a combinatin of equilibrium emission from large grains, and nonequilibrium emission from small grains, with destruction of the small grains emitting at 12 microns at high energy density; it is estimated that 80 percent of these small particles are destroyed for an energy density in ultraviolet photons larger than 50 times that of the average interstellar radiation field in the solar neighborhood. In a color-color diagram, I(v)(60 microns)/I(v)(100 microns) versus I(v)(12 microns)/I(v)(25 microns), the California Nebula measurements at various distances to the ionizing star Zeta Per follow a sequence similar to that of galaxies. This result shows that the position of a galaxy along this sequence is a measure of the intensity of the radiation field in the regions responsible for the infrared emission.
Cometary dust is not spherical nor homogeneous, yet these are the assumptions used to model its thermal, optical, and dynamical properties. To better understand the effects of heterogeneity on the thermal and optical properties of dust grains, the effective dielectric constant for an admixture of magnetite and a silicate were calculated using two different effective medium theories: the Maxwell-Garnett theory and the Bruggeman theory. In concept, the MG theory describes the effective dielectric constant of a matrix material into which is embedded a large number of very small inclusions of a second material. The Bruggeman theory describes the dielectric constant of a well mixed aggregate of two or more types of materials. Both theories assume that the individual particles are much smaller than the wavelength of the incident radiation. The refractivity for a heterogeneous grain using the MG theory is very similar to the refractivity of the matrix material, even for large volume fractions of the inclusion. The equilibrium grain temperature for spherical particles sized from .001 to 100 microns in radius at 1 astronomical unit from the sun was calculated. Further explanation is given.
Giotto measured the in situ Halley dust grain mass distribution with 2 instruments, Particle Impact Analyzer and Dust Impact Detection System (DIDSY), as well as the total intercepted mass from the deceleration of the spacecraft (Giotto Radio-Science Experiment, GRE). Ground based observations made shortly before encounter have fluxes much higher than would be predicted from Giotto data. It is concluded that Giotto DIDSY and GRE data represent observations of dust originating from a narrow track along the nucleus. They are consistent with ground based data, if assumptions are made about the level of activity along this track. The actual size distribution that should be used for modeling of the whole coma should not include the large mass excess actually observed by Giotto. Extrapolation of the small grain data should be used, since for these grains the velocity dispersion is low and temporal changes at the nucleus would not affect the shape of the mass distribution.
An overview of the Gas-Grain Simulation Facility (GGSF) project and its current status is provided. The proceedings of the Gas-Grain Simulation Facility Experiments Workshop are recorded. The goal of the workshop was to define experiments for the GGSF--a small particle microgravity research facility. The workshop addressed the opportunity for performing, in Earth orbit, a wide variety of experiments that involve single small particles (grains) or clouds of particles. The first volume includes the executive summary, overview, scientific justification, history, and planned development of the Facility.
The significant interparticle forces observed between solar system dust grains upon desorption or sublimation of excess volatiles in simulated Martian or cometary environments are presently investigated, in order to more precisely define these mechanisms and to simulate the types of deposits thereby formed. Some classes of phyllosilicate mineral grains are noted to bond together to form a highly porous filamentary sublimate residue (FSR) exhibiting an exceptionally high tensile strength for its density; this may be important in its control of erosion and sublimation in Martian and cometary environments. It is concluded that FSR formation from clean mineral grains in water ice may be important in the formation of the Martian polar layered terrain.
The thermoelastic micromechanical stresses associated with a single large hexagonal alpha-SiC grain within a fine-grain-size cubic (3C) beta-SiC matrix were calculated. The naturally occurring residual stresses which are created during cooling from the processing temperatures and the effects of superimposed applied external stresses are both considered. A significant effect of the shape or geometry of the alpha-SiC grain is revealed, with the largest residual stresses associated with the naturally occurring tabular or platelet structure. The stresses are compared with the published strength results for these materials, which suggests that the residual stresses assume a significant role in the strength reduction that is observed.
Olivine-rich chondritic interplanetary dust particles (IDPs) are an important subset of fluffy chondritic IDPs collected in the earth's stratosphere. Particles in this subset are characterized by a matrix of nonporous, ultrafine-grained granular units. Euhedral single crystals, crystals fragments, and platey single crystals occur dispersed in the matrix. Analytical electron microscopy of granular units reveals predominant magnesium-rich olivines and FeNi-sulfides embedded in amorphous carbonaceous matrix material. The variable ratio of ultrafine-grained minerals vs. carbonaceous matrix material in granular units support variable C/Si ratios, and some fraction of sulfur is associated with carbonaceous matrix material. The high Mg/(Mg+Fe) ratios in granular units is similar to this distribution in P/Comet Halley dust. The chondritic composition of fine-grained, polycrystalline IDPs gradually breaks down into nonchondritic, and ultimately, single mineral compositions as a function of decreased particle mass. The relationship between particle mass and composition in the matrix of olivine-rich chondritic IDPs is comparable with the relationship inferred for P/Comet Halley dust.
In the gravitational field on earth, the large settling rate of micron-sized particles and the effects of gravity-induced convection prohibit many interesting studies of phenomena such as coagulation, collisions, and mutual interactions of droplets, dust grains and other particles. Examples of exobiology experiments involving these phenomena are the simulation of organic aerosol formation in Titan's atmosphere, studies of the role of comets in prebiotic chemical evolution, and simulations of carbon grain interactions in various astrophysical environments. The Gas-Grain Simulation Facility (GGSF) is a proposed earth-orbital laboratory that will allow present ground-based experimental programs which study processes involving small particles and weak interactions to be extended to a new domain. Physics issues that scientists wishing to propose GGSF experiments must consider are reviewed in this paper. Specifically, coagulation, motion in gases and vacua, and wall deposition of particles in a microgravity environment are discussed.
During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared (5000 to 500 cm(-1), 2 to 20 microns m), the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. By comparing these astronomical spectra with the spectra of laboratory ices one can determine the composition and abundance of the icy materials frozen on the cold (10K) dust grains present in the interior of molecular clouds. These grains and their ice mantles may well be the building blocks from which comets are made. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, researchers present the infrared spectra of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds. The last component was incorporated into this particular experiment as a tracer of the behavior of a non-aromatic hydrocarbon. The change in the composition that results from ultraviolet photolysis of this ice mixture using a UV lamp to simulate the interstellar radiation field is shown. Photolysis produces CO, CO2, CH4, HCO, H2CO, as well as a family of moderately volatile hydrocarbons. Less volatile carbonaceous materials are also produced. The evolution of the infrared spectrum of the ice as the sample is warmed up to room temperature is illustrated. Researchers believe that the changes are similar to those which occur as ice is ejected from a comet and warmed up by solar radiation. The warm-up sequence shows that the nitrile or iso-nitrile bearing compound produced during photolysis evaporates between 200 and 250K, suggesting that it is carried by a small molecular species. These molecules could be similar to the source material in Comet Halley that is ejected in grains into the coma, freed by sublimation, and photolyzed by solar radiation to produce the observed jets.
Experimental techniques for studying the processes which occur during the life cycle of a refractory grain are reviewed. Consideration is given to the construction of a differentially-pumped beam-mass spectrometer which is expected to determine the relative stability of small clusters in the Fe-Mg-Si-O and Ca-Ti-Al-O systems as a function of temperature and pressure. Also, a smoke generator has been constructed to produce gram quantities of amorphous grains for use in thermal annealing and hydrous alteration studies of smokes containing Fe-Mg-Al-Ti-Ca-Si-O and Cl. Topics of the studies include the properties of grains produced in a flow condensation apparatus, the sorption efficiency of Si2O3 smokes for AR gas, the processing of ices containing refractory precursors such as SiH4 or Fe(CO)5 plus water, and the residue from 1 MeV bombardment and warming of an amorphous Fe-SiO smoke.