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NASA NTRS2018

The Planetary Materials Database

NASA provides funds for a variety of research programs whose principal focus is to collect and analyze terrestrial analog materials. These data are used to (1) understand and interpret planetary geology; (2) identify and characterize habitable environments and pre-biotic/biotic processes; (3) interpret returned data from present and past missions; and (4) evaluate future mission and instrument concepts prior to selection for flight. Data management plans are now required for these programs, but the collected data are still not generally available to the community. There is also little possibility to re-analyze the collected materials by other techniques, since there is no requirement to archive collected samples. The Planetary Materials Database (PMD) is a central, high-quality, long-term data repository, which aims to promote the field of astrobiology and increase scientific returns from NASA funded research by enabling data sharing, collaboration and exposure of non-NASA scientists to NASA research initiatives and missions. The PMD is a linked collection of databases developed using the Open Data Repository (ODR) system. The PMD will include detailed descriptions of terrestrial analog planetary materials as well as data from the instruments used in their analysis. The goal is to provide example patterns/spectra/analyses, etc. and background information suitable for use by the Space Science community. An early example showing the utility of these databases (although not in the ODR format) is the RRUFF mineral database. RRUFF, comprising 4,000+ pure mineral standards, is the most popular and widely used dataset of minerals and receives more than 180,000 queries per week from geologists and mineralogists worldwide. The PMD will be patterned after the CheMin database [3], a resource that contains all of the data collected by the MSL CheMin XRD instrument on Mars. Raw and processed CheMin data can be viewed, downloaded, reprocessed and reanalyzed using cloud-based “applications” linked to the data.

Blake, David↗
NASA NTRS2016

Lunar Phase Function at 1064 Nm from Lunar Orbiter Laser Altimeter Passive and Active Radiometry

We present initial calibration and results of passive radiometry collected by the Lunar Orbiter Laser Al- timeter onboard the Lunar Reconnaissance Orbiter over the course of 12 months. After correcting for time- and temperature-dependent dark noise and detector responsivity variations, the LOLA passive radiometry measurements are brought onto the absolute radiance scale of the SELENE Spectral Profiler. The resulting photometric precision is estimated to be approximately 5%. We leverage the unique ability of LOLA to measure normal albedo to explore the 1064 nm phase function's dependence on various geologic parameters. On a global scale, we find that iron abundance and optical maturity (quantified by FeO and OMAT) are the dominant controlling parameters. Titanium abundance (TiO2 ), surface roughness on decimeter to decameter scales, and soil thermophysical properties have a smaller effect, but the latter two are correlated with OMAT, indicating that exposure age is the driving force behind their effects in a globally-averaged sense. The phase function also exhibits a dependence on surface slope at approximately 300 m baselines, possibly the result of mass wasting exposing immature material and/or less space weathering due to reduced sky visibility. Modeling the photometric function in the Hapke framework, we find that, relative to the highlands, the maria exhibit decreased backscattering, a smaller opposition effect (OE) width, and a smaller OE amplitude. Immature highlands regolith has a higher backscattering fraction and a larger OE width compared to mature highlands regolith. Within the maria, the backscattering fraction and OE width show little dependence on TiO2 and OMAT. Variations in the phase function shape at large phase angles are observed in and around the Copernican-aged Jackson crater, including its dark halo, a putative impact melt deposit. Finally, the phase function of the Reiner Gamma Formation behaves more optically immature than is typical for its composition and OMAT, suggesting the visible-to-near-infrared spectrum and phase function respond differently to the unusual regolith evolution and properties at this location.

LOLA↗
NASA NTRS1989

Characterization of Venera 15/16 Geologic Units from Pioneer Venus Reflectivity and Roughness Data

Geologic units have been defined for the surface of Venus from Venera 15/16 image data. A characterization of these geologic units is carried out using information on surface properties derived from Pioneer Venus (PV) reflectivity and rms slope data. The geologic context provided by Venera 15/16 units allows additional, more specific interpretations of surface radar properties to be made. Characterization of Venera units results in the definition of four groups of Venera units: (1) smooth rocky units, 2) rough rocky units, (3) rough high dielectric units, and (4) diffusely scattering units. On the basis of correlations of surface morphology to spatial and statistical distributions in rms slope and reflectivity data, we test models for the origin of the surface properties of some units. We conclude that plains and tectonic units can be contrasted in terms of the average roughness of the surface and that tectonic deformation appears to roughen the surface at 0.5- to 10-m and 5- to 50-cm scales. This tectonic weathering process appears to dominate the erosional regime of Venus. Unlike Earth or Mars, production and transport of soils dominates only a small portion (less than or equal to 5%) of the surface. Some of the Venera units display distinctive spatial and statistical distributions of PV radar data. In particular, apparent low reflectivity in the tesserae appears to be caused by small (5-50 cm) rock fragments on the surface which cause diffuse scattering at Pioneer Venus wavelengths. Analysis of models for the formation of these fragments suggests that they are due to the pervasive deformation undergone by the tesserae. Finally, aspects of this study have been used to extend results of Venera image data analysis southward of 30 deg. N lat, resulting in it prediction of the distribution of tessera. Such results can aid in Magellan investigations.

Bindschadler, D. L.↗
NASA NTRS1993

Shallow crustal discontinuities and graben and scarp formation in the Tharsis region of Mars

We recently obtained photoclinometric profiles across all simple grabens and erosional landforms (e.g., troughs, pits, wall-valley heads, and scarps that are bounded above and below by flat surfaces) that occur within Tempe Terra. These data, together with similar data that we obtained for Syria, Sinai, and Lunae Plana and the Alba Patera region, allow regional examination of shallow crust Al discontinuities between latitude 30 deg. S and 50 deg. N and longitude 50 deg. W and 112 deg. W. The profile for each simple graben was used with an appropriate structural model to estimate the depth to the base of the faulted layer. The depths of erosional wall scarps may also indicate the depths of mechanical discontinuities such as a local lithologic or cryospheric boundary. Examination of these data indicates a surprisingly consistent set of shallow crust Al discontinuities for the Tharsis region at depths of 0.4-0.6 km, 1.0-1.4 km, and 2 km; the maximum depth of the features in most study areas appears to be about 4 km. The concentration of values between 0.4 and 0.6 km in most scarp and some faulted-layer depth data is similar to the range in estimated thicknesses of individual exposed Noachian and Hesperian plains units in the Tharsis region. The regional depth data also show two modes near 1 and 2 km in some study areas and a maximum depth near 4 km in most study areas; the faulted-layer depths in excess of 4 km at Alba Patera occur near the summit of the caldera and could be attributed to volcanic loading. Our detailed examination of these depth data includes the following observations: (1) The mode at 1.0-1.4 km depth transcends age and geologic setting in this broad study area; (2) The 2-km mode is most obvious at Alba Patera and moderately well developed at Syria and Sinai Plana, but it is muted at Tempe Terra, which is in the same latitude range as Alba Patera but older; and (3) The 2-km-depth mode is not present in all areas that have features of Amazonian age. We suggest two possible explanations for our observations in the Tharsis region.

Davis, P. A.↗
NASA NTRS2017

Landsat at 45: How it Changed the Way We See the Earth

On October 24, 1946, more than 10 years before the launch of the first artificial satellite Sputnik, scientists at the White Sands Missile Range in New Mexico placed a camera on top of a captured German V-2 ballistic missile. As the rocket flew to an altitude of about 65 miles - just above the generally recognized border of outer space - the 35-millimeter motion picture camera snapped a frame every one and a half seconds. Minutes later, the missile came crashing back down and slammed into the ground at more than 340 mph, but the film survived and gave us our first glimpse of Earth from space. Earth Resources Technology Satellite aka Landsat It was images like those first grainy black and white pictures and later those taken by America's first astronauts in the 1960's that inspired the development of the Earth Resources Technology Satellite (ERTS). From the unique vantage point of space, we could now observe Earth using a variety of different instruments to monitor changes over time. The ERTS-1 satellite, wisely renamed Landsat-1, was launched aboard a Delta rocket on July 23, 1972, into a Sun-synchronous polar orbit at an altitude of about 560 miles. In this unique orbit, Landsat could observe the same point on the Earth every 18 days, always with the same solar illumination, allowing for precise monitoring of changes on the ground over time. Landsat-1, derived from the highly successful Nimbus weather satellites, carried two instruments that allowed it to take images not only in visible light but also in infrared, well-suited to track changes in vegetation over time. Designed to last only one year, Landsat-1 actually operated for nearly three years, by which time it had been joined in space by Landsat-2, a near identical copy of the original. Since then, ever more sophisticated instruments were flown aboard Landsat-3 through -8, with Landsat-9 planned for launch in 2020, acquiring millions of images of Earth over more than four decades. At first, images from Landsat were processed by NASA and hardcopies sold to users for a fee, a somewhat tedious process. Since 2008, images have been made available to all interested users by the US Geological Survey (USGS) at no cost via the Internet in near real time. So, how can Landsat help? In short, Landsat looks. And looks. And proves Yogi right. Space-based images from Landsat and other similar satellites offer a unique and critical capability to observe land use over time by providing repetitive observations of the Earth otherwise unavailable. The data provided by the images can be used by scientists and politicians to inform wise decisions in areas such as agriculture, climate, ecosystems and biodiversity, energy, forest management, human health, fire, natural disasters, urban growth and water management. This overview article doesn't allow for examples from each of these disciplines, but details can be found at the following website: https://landsat.gsfc.nasa.gov/how_landsat_helps/. One third of the US economy is influenced by climate, weather and natural hazards, providing strong economic incentives to sustain a healthy space-based Earth observation program. One example, however, may be illustrative of how Landsat and other space-based observations can be helpful in monitoring and documenting some effects of global climate change. It had been noted since the 1970's that permafrost in subarctic areas like Siberia was melting at an accelerating rate. It also became apparent that this led to the formation of hundreds of melt lakes and the liberation of large quantities of methane, a gas that in the short-term has more potent greenhouse effects than carbon dioxide. The methane turned the water in these lakes blue, making them easy to track over time by satellite. Additionally, the newly released methane has been carbon dated to tens of thousands of years ago, meaning that it had remained frozen since the last Ice Age and therefore hadn't been accounted for in models of the Earth's overall carbon balance. Release of sufficient methane by an increasingly warming climate could actually cause a positive feedback loop in global warming, melting more permafrost and releasing yet more methane. Further monitoring by Landsat and other platforms will reveal whether this process is reversible or whether we've passed the tipping point. In addition to the highly successful Landsat series of satellites, NASA and other agencies such as the National Oceanic and Atmospheric Administration (NOAA) operate a fleet of other Earth observing platforms, many with more specific research goals such as monitoring sea ice levels or atmospheric carbon content. Several instruments aboard the International Space Station also contribute to this overall effort to better understand short- and long-term changes to the Earth. Many of these missions are guided by the 2009 Decadal Survey published by the National Research Council of the National Academy of Sciences. Europe, Russia and China all see the value of space-based Earth observation by deploying their own fleet of satellites.

Uri, John↗
NASA NTRS1989

Geochemical and isotopic evidence for paleoredox conditions during deposition of the Devonian-Mississippian New Albany Shale, southern Indiana

The upper part of the New Albany Shale is divided into three members. In ascending order, these are (1) the Morgan Trail Member, a laminated brownish-black shale; (2) the Camp Run Member, an interbedded brownish-black and greenish-gray shale; and (3) the Clegg Creek Member, also a laminated brownish-black shale. The Morgan Trail and Camp Run Members contain 5% to 6% total organic carbon (TOC) and 2% sulfide sulfur. Isotopic composition of sulfide in these members ranges from -5.0% to -20.0%. C/S plots indicate linear relationships between abundances of these elements, with a zero intercept characteristic of sediments deposited in a non-euxinic marine environment. Formation of diagenetic pyrite was carbon limited in these members. The Clegg Creek Member contains 10% to 15% TOC and 2% to 6% sulfide sulfur. Isotopic compositions of sulfide range from -5.0% to -40%. The most negative values occur in the uppermost Clegg Creek Member and are characteristic of syngenetic pyrite, formed within an anoxic water column. Abundances of carbon and sulfur are greater and uncorrelated in this member, consistent with deposition in as euxinic environment. In addition, DOP (degree of pyritization) values suggest that formation of pyrite was generally iron limited throughout Clegg Creek deposition, but sulfur isotopes indicate that syngenetic (water-column) pyrite becomes an important component in the sediment only in the upper part of the member. At the top of the Clegg Creek Member, a zone of phosphate nodules and trace-metal enrichment coincides with maximal TOC values. During euxinic deposition, phosphate and trace metals accumulated below the chemocline because of limited vertical circulation in the water column. Increased productivity would have resulted in an increased flux of particulate organic matter to the sediment, providing an effective sink for trace metals in the water column. Phosphate and trace metals released from organic matter during early diagenesis resulted in precipitation of metal-rich phosphate nodules.

NASA Discipline Exobiology↗
NASA NTRS1998

Bacterial mineralization patterns in basaltic aquifers: implications for possible life in martian meteorite ALH84001

To explore the formation and preservation of biogenic features in igneous rocks, we have examined the organisms in experimental basaltic microcosms using scanning and transmission electron microscopy. Four types of microorganisms were recognized on the basis of size, morphology, and chemical composition. Some of the organisms mineralized rapidly, whereas others show no evidence of mineralization. Many mineralized cells are hollow and do not contain evidence of microstructure. Filaments, either attached or no longer attached to organisms, are common. Unattached filaments are mineralized and are most likely bacterial appendages (e.g., prosthecae). Features similar in size and morphology to unattached, mineralized filaments are recognized in martian meteorite ALH84001.

NASA Discipline Exobiology↗
NASA NTRS2015

Insights into the Martian Regolith from Martian Meteorite Northwest Africa 7034

Everything we know about sedimentary processes on Mars is gleaned from remote sensing observations. Here we report insights from meteorite Northwest Africa (NWA) 7034, which is a water-rich martian regolith breccia that hosts both igneous and sedimentary clasts. The sedimentary clasts in NWA 7034 are poorly-sorted clastic siltstones that we refer to as protobreccia clasts. These protobreccia clasts record aqueous alteration process that occurred prior to breccia formation. The aqueous alteration appears to have occurred at relatively low Eh, high pH conditions based on the co-precipitation of pyrite and magnetite, and the concomitant loss of SiO2 from the system. To determine the origin of the NWA 7034 breccia, we examined the textures and grain-shape characteristics of NWA 7034 clasts. The shapes of the clasts are consistent with rock fragmentation in the absence of transport. Coupled with the clast size distribution, we interpret the protolith of NWA 7034 to have been deposited by atmospheric rainout resulting from pyroclastic eruptions and/or asteroid impacts. Cross-cutting and inclusion relationships and U-Pb data from zircon, baddelleyite, and apatite indicate NWA 7034 lithification occurred at 1.4-1.5 Ga, during a short-lived hydrothermal event at 600-700 C that was texturally imprinted upon the submicron groundmass. The hydrothermal event caused Pb-loss from apatite and U-rich metamict zircons, and it caused partial transformation of pyrite to submicron mixtures of magnetite and maghemite, indicating the fluid had higher Eh than the fluid that caused pyrite-magnetite precipitation in the protobreccia clasts. NWA 7034 also hosts ancient 4.4 Ga crustal materials in the form of baddelleyites and zircons, providing up to a 2.9 Ga record of martian geologic history. This work demonstrates the incredible value of sedimentary basins as scientific targets for Mars sample return missions, but it also highlights the importance of targeting samples that have not been overprinted by metamorphic processes, which is the case for NWA 7034.

McCubbin, Francis M.↗
NASA NTRS1995

Evidence for gammacerane as an indicator of water column stratification

A new route for the formation of gammacerane from tetrahymanol is proposed; in addition to dehydration and hydrogenation, sulphurisation and early C-S cleavage are shown to be important in the pathway of formation, especially in marine sediments. Evidence is twofold. First, relatively large amounts of the gammacerane skeleton are sequestered in S-rich macromolecular aggregates formed by natural sulphurisation of functionalised lipids. Selective cleavage of polysulphide linkages with MeLi/MeI led to formation of 3-methylthiogammacerane, indicating that the gammacerane skeleton is primarily bound via sulphur at position 3, consistent with the idea that tetrahymanol (or the corresponding ketone) is the precursor for gammacerane. Second, upon mild artificial maturation of two sediments using hydrous pyrolysis, gammacerane is released from S-rich macromolecular aggregates by cleavage of the relatively weak C-S bonds. The stable carbon isotopic compositions of gammacerane and lipids derived from primary producers and green sulphur bacteria in both the Miocene Gessoso-solfifera and Upper Jurassic Allgau Formations indicate that gammacerane is derived from bacterivorous ciliates which were partially feeding on green sulphur bacteria. This demonstrates that anaerobic ciliates living at or below the chemocline are important sources for gammacerane, consistent with the fact that ciliates only biosynthesize tetrahymanol if their diet is deprived of sterols. This leads to the conclusion that gammacerane is an indicator for water column stratification, which solves two current enigmas in gammacerane geochemistry. Firstly, it explains why gammacerane is often found in sediments deposited under hypersaline conditions but is not necessarily restricted to this type of deposits. Secondly, it explains why lacustrine deposits may contain abundant gammacerane since most lakes in the temperate climatic zones are stratified during summer.

NASA Discipline Exobiology↗
NASA NTRSDate not supplied

The Global Water Monitor: Lake, Wetland, and River Reach Monitoring for Resource Management and Hazard Observation

The Global Water Monitor is a monitoring program offering surface water-related products for lakes, reservoirs, river reaches, and wetlands, https://blueice.gsfc.nasa.gov/gwm. These products are derived from multiple satellite-based altimetry and multispectral imaging platforms. The primary measurements are water level, slope, and extent, derived from a series of NASA and other agency instruments (Sentinel-3,-6, ICESat-2, SWOT, MODIS). The system serves stakeholders, the US Department of Agriculture Foreign Agricultural Service and the US Geological Survey, as well as various international, national, state, and intelligence agencies, engineers, ecologists, and hydrological researchers. Considering the sensitivity of ground-based data and the remote accessibility of many basins, the satellites offer global coverage, accuracy, and continuity of measurements. Observation of storage fluctuations in lakes and reservoirs provides users with knowledge of short and long-term drought conditions that can affect both water and energy resources. Emphasis is on changing climatic conditions, water sharing between nations, and regional stability. Measurements across a wetland complex can assist with efforts to assess hydrological dynamics with a focus on conservation efforts that aid both natural ecology and the sharing of precious water resources – the latter potentially being required in a basin across the municipal, crop irrigation, aquaculture, livestock, and power station spectrum. Observations of river reaches assists in the collection of basic hydraulic information, particularly in gauge-poor regions, for modelling efforts and the estimation of discharge, and at high-latitudes satellite-based river observations serve projects that warn of spring melts and flood hazards. We look at how recent improvements in instrument technology and mission operations are assisting with acquiring true global coverage and cross-validation efforts, and how stakeholders interact with the project in terms of setting requirements, product format, and accessibility methods. Examples show the application of the products across a range of programs, and in addition to meeting operational requirements, how the multi-decadal surface water levels are creating a high-quality timeline of Earth Data Records.

Lakes↗
NASA NTRS1985

Millimeter-scale variations of stable isotope abundances in carbonates from banded iron-formations in the Hamersley Group of Western Australia

Several diamond drill cores from formations within the Hamersley Group of Western Australia have been studied for evidence of short-range variations in the isotopic compositions of the carbonates. For a set of 32 adjacent microbands analyzed in a specimen from the Marra Mamba Iron Formation, carbon isotope compositions of individual microbands ranged from -2.8 to -19.8 per mil compared to PDB and oxygen isotope compositions ranged from 10.2 to 20.8 per mil compared to SMOW. A pattern of alternating abundances was present, with the average isotopic contrasts between adjacent microbands being 3.0 per mil for carbon and 3.1 per mil for oxygen. Similar results were obtained for a suite of 34 microbands (in four groups) from the Bruno's Band unit of the Mount Sylvia Formation. Difficulties were experienced in preparing samples of single microbands from the Dales Gorge Member of the Brockman Iron Formation, but overall isotopic compositions were in good agreement with values reported by previous authors. Chemical analyses showed that isotopically light carbon and oxygen were correlated with increased concentrations of iron. The preservation of these millimeter-scale variations in isotopic abundances is interpreted as inconsistent with a metamorphic origin for the isotopically light carbon in the BIF carbonates. A biological origin is favored for the correlated variations in 13C and Fe, and it is suggested that the 13C-depleted carbonates may derive either from fermentative metabolism or from anaerobic respiration. A model is presented in which these processes occur near the sediment-water interface and are coupled with an initial oxidative precipitation of the iron.

NASA Program Exobiology↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 6

Contents include the following: A Model for Multiple Populations of Presolar Diamonds. Characterization of Martian North Polar Geologic Units Using Mars Odyssey THEMIS Data. Effect of Flow on the Internal Structure of the Martian North Polar Layered Deposits. Elemental Abundance Distributions in Basalt Clays and Meteorites: Is It a Biosignature? Early Results on the Saturn System from the Composite Infrared Spectrometer. NanoSIMS D/H Imaging of Isotopically Primitive Interplanetary Dust Particles. Presolar (Circumstellar and Interstellar) Phases in Renazzo: The Effects of Parent Body Processing. Catastrophic Disruption of Hydrated Targets: Implications for the Hydrated Asteroids and for the Production of Interplanetary Dust Particles. Chemical and Mineralogical Analyses of Particles from the Stratospheric Collections Coinciding with the 2002 Leonid Storm and the 2003 Comet Grigg-Skjellerup Trail Passage. An Analysis of the Solvus in the CaS-MnS System. ESA s SMART-1 Mission at the Moon: First Results, Status and Next Steps. Europa Analog Ice-splitting Measurements and Experiments with Ice-Hunveyor on the Frozen Balaton-Lake, Hungary. Chromium on Eros: Further Evidence of Ordinary Chondrite Composition. Dust Devil Tracks on Mars: Observation and Analysis from Orbit and the Surface. Spatial Variation of Methane and Other Trace Gases Detected on Mars: Interpretation with a General Circulation Model. Mars Water Ice and Carbon Dioxide Seasonal Polar Caps: GCM Modeling and Comparison with Mars Express Omega Observations. Component Separation of OMEGA Spectra with ICA. Clathrate Formation in the Near-Surface Environment of Titan. Space Weathering: A Proposed Laboratory Approach to Explaining the Sulfur Depletion on Eros. Sample Collection from Small Airless Bodies: Examination of Temperature Constraints for the TGIP. Sample Collector for the Hera Near-Earth Asteroid Sample Return Mission. A Rugged Miniature Mass-Spectrometer for Measuring Aqueous Geochemistry on Mars. Martian and Lunar Pyroxene Microstructures Studied by Single-Crystal X-Ray Diffraction.

Source record↗
NASA NTRS1999

Origin and Reactivity of the Martian Soil: A 2003 Micromission

The role of water in the development of the martian surface remains a fundamental scientific question. Did Mars have one or more "warm and wet" climatic episodes where liquid water was stable at the surface? If so, the mineral phases present in the soils should be consistent with a history of aqueous weathering. More generally, the formation of hydrated mineral phases on Mars is a strong indicator of past habitable surface environments. The primary purpose of this investigation is to help resolve the question of whether such aqueous indicators are present on Mars by probing the upper meter for diagnostic mineral species. According to Burns [1993], the formation of the ferric oxides responsible for the visible color of Mars are the result of dissolution of Fe (+2) phases from basalts followed by aqueous oxidation and precipitation of Fe" mineral assemblages. These precipitates likely included iron oxyhydroxides such as goethite (a-FeOOH) and lepidocrocite (g-FeOOH), but convincing evidence for these phases at the surface is still absent. The stability of these minerals is enhanced beneath the surface, and thus we propose a subsurface search for hydroxylated iron species as a test for a large-scale chemical weathering process based on interactions with liquid water. It is also possible that the ferric minerals on Mars are not aqueous alteration products of the rocks. A chemical study of the Pathfinder landing site concluded that the soils are not directly derived from the surrounding rocks and are enhanced in Mg and Fe. The additional source of these elements might be from other regions of Mars and transported by winds, or alternatively, from exogenic sources. Gibson [1970] proposed that the spectral reflectivity of Mars is consistent with oxidized meteoritic material. Yen and Murray [1998] further extend Gibson's idea and show, in the laboratory, that metallic iron can be readily oxidized to maghemite and hematite under present-day martian surface conditions (in the absence of liquid water). A test for a meteoritic component of the soil can be conducted, as described below, by searching for the presence of Ni at the martian surface. The average abundance of nickel in an Fe-Ni meteorite is about 7% and, if present at measurable levels in the soil, would be indicative of an exogenic contribution. In addition, it may be possible to directly search for mineral phases common in meteorites. An understanding of the formation and evolution of the martian soil would not be complete without addressing the unusual reactivity discovered by the Viking Landers The presence of an inorganic oxidant, possibly one produced as a results of photochemical processes, is the most widely accepted explanation of the Viking results. Are these chemical species simply adsorbed on soil grains, or have they reacted with the metal oxide substrates and altered the mineral structures? Could a completely different (non-photochemical) process be responsible for the soil reactivity? The various ideas for the nature of this putative oxidant could be constrained by a measurement of the change in reactivity with depth. Different compositions will have different lifetimes and mobilities and thus will have different vertical profiles. Because the oxidizing compounds are believed to actively destroy organic molecules, determination of the reactivity gradient also has significant implications for the search for life on Mars. A DS2-based microprobe system can be instrumented for a 2003 micromission to investigate the origin and reactivity of the martian soil. These measurements would provide invaluable information regarding the climate history and exobiological potential of the planet. The NMR, X ray and chemiresistor measurement approach described embodies a highly synergistic and general set of soil interrogation methods for elements, compounds, and crystal structures and can also be applied to other geologic questions of interest. For example, if the capability for precise targeting of the probes is available, then in-situ investigations of suspected evaporite and hydrothermal deposits would be possible with the same set of instruments. Additional information is contained in the original.

Yen, Albert S.↗
NASA NTRSDate not supplied

On the Hunt for Detectable Biosignatures in Jezero Crater: What to Look for and Where

Introduction: The Perseverance rover, which is currently exploring Jezero crater on Mars, is equipped with seven instruments that allow for observation of textures, minerals, color, structure, and chemistry of rocks and sediments in order to search for signs of ancient life, understand the geologic history of the crater, and identify candidates for sample return (Farley et al. 2020). The first of these aims includes the direct detection of potential biosignatures, including textures, organic molecules, minerals, and elemental chemistries that are of biogenic origin (Mustard et al. 2013). The presence of these biosignatures will be constrained by the habitability of the local region, the preservation potential of the host rocks, and the sensitivity of the instrument suite, and their biogenicity will be investigated after return to Earth as part of the Mars Sample Return campaign. Here, we examine key targets on the three planned campaigns, potential biosignatures that may be present, and the capabilities of key rover instruments. High Potential Biosignature Sites in Jezero: To date, measurements have been made on multiple sites that both contain minerals known in terrestrial settings to preserve biosignatures and likely were habitable settings (Williford et al. 2021). Two examples include the fine-grained rocks at the base of the delta fan and the NW inner margin of the crater. Fine-grained Rocks at Base of Delta Fan. Fine-grained, clay-bearing rocks may have been deposited as muddy lake sediments that could have hosted life and preserved biosignatures settling out of the water column. The report of organic molecules by the Curiosity rover in the Sheepbed mudstone and Murray formation has highlighted this site in particular. Potential biosignatures in mudstones, especially those rich in silica (McMahon et al. 2018), microbialites and complex organics. NW Inner Margin of Crater. This unit, located along the inner margin of the crater, contains strong carbonate signatures and may have been the littoral zone of a lake (Horgan et al. 2020). The potential biosignatures here include microfossils, microbialites, biominerals, and complex organics. Detectability of Biosignatures by the Mars 2020 Instrument Suite: The Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) instrument comprises a Deep UV spectrometer, context imager, and color camera to generate spatially resolved chemical maps (Bhartia et al. 2020). It is sensitive to trace organics as well as a range of minerals and can detect native fluorescence from aromatic organics; the WATSON and ACI cameras can be used to observe morphologies such as stromatolitic laminations or filaments ranging from the tens of micron to millimeter scale. SHERLOC can detect organics that may be present in either of the high potential biosignature targets, as well as detect carbonates in the latter. However, the presence of high amounts of iron, such as in iron-rich clays, would cause attenuation of spectral response through UV absorption. The Planetary Instrument for X-ray Lithochemistry (PIXL) comprises an X-ray fluorescence spectrometer and camera that can scan rock surfaces to generate elemental maps (Allwood et al. 2020). PIXL can detect chemical biosignatures such as spatial variations of elemental abundances that may have resulted from biological activity. PIXL would be particularly useful in detecting fine textures and elemental chemistries in either high potential biosignature target, but cannot directly detect minerals such as carbonate. The SuperCam instrument performs three types of spectroscopy, color imaging, and acoustic recording to remotely examine elemental composition, minerals, organics, and textures (Maurice et al. 2021). Using laser induced breakdown spectroscopy and time resolved luminescence spectroscopy, SuperCam can detect major elemental building blocks of organics (i.e., C, H, N, O, P, S) and conjugated organic structures, respectively, which may be found in either site. While in other contexts, luminescence is a useful tool for biosignature identification, luminescence generated by the 532 nm laser may obscure the Raman signal. Conclusion: The three instruments discussed can be used collaboratively to establish the presence of potential biosignatures in samples. These high-priority samples may then be returned to Earth for detailed laboratory analysis.

S. Sharma↗
NASA NTRS2007

Aqueous Alteration of Basalts: Earth, Moon, and Mars

The geologic processes responsible for aqueous alteration of basaltic materials on Mars are modeled beginning with our knowledge of analog processes on Earth, i.e., characterization of elemental and mineralogical compositions of terrestrial environments where the alteration and weathering pathways related to aqueous activity are better understood. A key ingredient to successful modeling of aqueous processes on Mars is identification of phases that have formed by those processes. The purpose of this paper is to describe what is known about the elemental and mineralogical composition of aqueous alteration products of basaltic materials on Mars and their implications for specific aqueous environments based upon our knowledge of terrestrial systems. Although aqueous alteration has not occurred on the Moon, it is crucial to understand the behaviors of basaltic materials exposed to aqueous environments in support of human exploration to the Moon over the next two decades. Several methods or indices have been used to evaluate the extent of basalt alteration/weathering based upon measurements made at Mars by the Mars Exploration Rover (MER) Moessbauer and Alpha Particle X-Ray Spectrometers. The Mineralogical Alteration Index (MAI) is based upon the percentage of total Fe (Fe(sub T)) present as Fe(3+) in alteration products (Morris et al., 2006). A second method is the evaluation of compositional trends to determine the extent to which elements have been removed from the host rock and the likely formation of secondary phases (Nesbitt and Young, 1992; Ming et al., 2007). Most of the basalts that have been altered by aqueous processes at the two MER landing sites in Gusev crater and on Meridiani Planum have not undergone extensive leaching in an open hydrolytic system with the exception of an outcrop in the Columbia Hills. The extent of aqueous alteration however ranges from relatively unaltered to pervasively altered materials. Several experimental studies have focused upon the aqueous alteration of lunar materials and simulants (e.g., Keller and Huang, 1971; Eick et al., 1996). Lunar basalts are void of water and highly reduced, hence, these materials are initially very reactive when exposed to water under oxidizing conditions.

Ming, Douglas W.↗
NASA NTRS2011

Visible and Near-IR Reflectance Spectra of Smectite Acquired Under Dry Conditions for Interpretation of Martian Surface Mineralogy

Visible and near-IR (VNIR) spectra from the MEx OMEGA and the MRO CRISM hyper-spectral imaging instruments have spectral features associated with the H2O molecule and M OH functional groups (M = Mg, Fe, Al, and Si). Mineralogical assignments of martian spectral features are made on the basis of laboratory VNIR spectra, which were often acquired under ambient (humid) conditions. Smectites like nontronite, saponite, and montmorillionite have interlayer H2O that is exchangeable with their environment, and we have acquired smectite reflectance spectra under dry environmental conditions for interpretation of martian surface mineralogy. We also obtained chemical, Moessbauer (MB), powder X-ray diffraction (XRD), and thermogravimetric (TG) data to understand variations in spectral properties. VNIR spectra were recorded in humid lab air at 25-35C, in a dynamic dry N2 atmosphere (50-150 ppmv H2O) after exposing the smectite samples (5 nontronites, 3 montmorillionites, and 1 saponite) to that atmosphere for up to approximately l000 hr each at 25-35C, approximately 105C, and approximately 215C, and after re-exposure to humid lab air. Heating at 105C and 215C for approximately 1000 hr is taken as a surrogate for geologic time scales at lower temperatures. Upon exposure to dry N2, the position and intensity of spectral features associated with M-OH were relatively insensitive to the dry environment, and the spectral features associated with H2O (e.g., approximately 1.90 micrometers) decreased in intensity and are sometimes not detectable by the end of the 215C heating step. The position and intensity of H2O spectral features recovered upon re-exposure to lab air. XRD data show interlayer collapse for the nontronites and Namontmorillionites, with the interlayer remaining collapsed for the latter after re-exposure to lab air. The interlayer did not collapse for the saponite and Ca-montmorillionite. TG data show that the concentration of H2O derived from structural OH was invariant to the dry N2 treatment for saponite and the montmorillionites, but the nontronites had additional structural OH after treatment. Upon exposure to dry N2, the VNIR spectra also acquired a red slope with decreasing albedo between approximately 0.4 and approximately 2.0 micrometers. The magnitude of the effects covaries with exposure time to dry N2 and heating temperature. Upon re-exposure to lab air, the slope and albedo do not completely recover to pre-exposure values. MB data show that these effects do not result from partial reduction of ferric to ferrous iron, and TG data show they do not result from loss of structural OH. Possible explanations include formation of small clusters of (superparamagnetic) ferric oxide and reduced smectite crystallinity. The difference in spectral properties between spectra acquired in humid lab air and under dry conditions are consequential for interpretation of CRISM and OMEGA spectra. For example, nontronite by itself and not nontronite plus ferrihydrite can account for the red spectral slope in martian spectra where nontronite is indicated by the Fe-OH spectral features.

Morris, Richard V.↗
NASA NTRS2005

Experimental Studies of Phase Equilibria of Meteorites and Planetary Bodies

The primary theme of this project was the application of experimental petrology and geochemistry to a variety of problems in meteoritics and planetary geology. The studies were designed to help develop constraints on the histories of primitive meteorites and their components, the environments in which they formed and evolved, and to understand quantitatively the processes involved in the evolution of igneous rocks on the earth and other planetary bodies. We undertook several projects relating to the origin of CAIs and chondrules. Systematics in the thermodynamic properties of CAI-like liquids were investigated and used to elucidate speciation of multi-valent cations and sulfide capacity of silicate melts and to constrain redox conditions and the vapor pressures of volatile species over molten chondrules. We experimentally determined vanadium speciation in meteoritic pyroxenes and in pyroxenes crystallized from CAI-like melts under very reducing conditions. We also found that bulk oxygen isotope compositions of chondrules in the moderately unequilibrated LL chondrites are related to the relative timing of plagioclase crystallization. We completed an experimental study on the vaporization of beta-SiC and SiO2 (glass or cristobalite) in reducing gases and established the conditions under which these presolar grains could have survived in the solar nebula. We expanded our technique for determining the thermodynamic properties of minerals and liquids to iron-bearing systems. We determined activity-composition relationships in Pt-Fe, Pt-Cr and Pt-Fe-Cr alloys. Results were used to determine the thermodynamic properties of chromite-picrochromite spinels including the free energy of formation of end-member FeCr2O4. We also established a new approach for evaluating Pt-Fe saturation experiments. We calculated the T-fO2 relationships in equilibrated ordinary chondrites and thereby constrained the conditions of metamorphism in their parent bodies.

Stolper, Edward M.↗
NASA NTRS1993

Plains tectonism on Venus: The deformation belts of Lavinia Planitia

High-resolution radar images from the Magellan spacecraft have revealed the first details of the morphology of the Lavinia Planitia region of Venus. A number of geologic units can be distinguished, including volcanic plains units with a range of ages. Transecting these plains over much of the Lavinia region are two types of generally orthogonal features that we interpret to be compressional wrinkle ridges and extensional grooves. The dominant tectonic features of Lavinia are broad elevated belts of intense deformation that transect the plains with complex geometry. They are many tens to a few hundred kilometers wide, as much as 1000 km long, and elevated hundreds of meters above the surrounding plains. Two classes of deformation belts are seen in the Lavinia region. 'Ridge belts' are composed of parallel ridges, each a few hundred meters in elevation, that we interpret to be folds. Typical fold spacings are 5-10 km. 'Fracture belts' are dominated instead by intense faulting, with faults in some instances paired to form narrow grabens. There is also some evidence for modest amounts of horizontal shear distributed across both ridge and fracture belts. Crosscutting relationships among the belts show there to be a range in belt ages. In western Lavinia, in particular, many ridge and fracture belts appear to bear a relationship to the much smaller wrinkle ridges and grooves on the surrounding plains: ridge morphology tends to dominate belts that lie more nearly parallel to local plains wrinkle ridges, and fracture morphology tends to dominate belts that lie more nearly parallel to local plains grooves. We use simple models to explore the formation of ridge and fracture belts. We show that convective motions in the mantle can couple to the crust to cause horizontal stresses of a magnitude sufficient to induce the formation of deformation belts like those observed in Lavinia. We also use the small-scale wavelengths of deformation observed within individual ridge belts to place an approximate lower limit on the venusian thermal gradient in the Lavinia region at the time of deformation.

Squyres, Steven W.↗