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NASA NTRS1985

Glass formation and properties in the system calcia-gallia-germania

The critical cooling rate for glass formation, R sub c was measured for four compositions in the system calcia-gallia-germania. The activation energy, E, and frequency factor, nu, for the crystallization process were determined by reheating the glasses at varied constant heating rates and measuring the temperature of crystallization. Both E and nu increased, with increasing germania content of the glass, whereas R sub c decreased. The density, refractive index, and Abbe number were also measured; all decreased with increasing GeO2 content. These results are compared with those for calcia-gallia-silica glasses of comparable compositions.

Angel, P. W.↗

NASA NTRS1993

Lava crusts and flow dynamics

Lava flows can be considered as hot viscous cores within thinner, solidified crusts. Interaction between crust and core determines a flow's morphological and dynamical evolution. When the lava core dominates, flow advance approaches a steady state. When crusts are the limiting factor, advance is more irregular. These two conditions can be distinguished by a timescale ratio comparing rates of core deformation and crustal formation. Aa and budding pahoehoe lavas are used as examples of core- and crustal-dominated flows, respectively. A simple model describes the transition between pahoehoe and aa flow in terms of lava discharge rate, underlying slope, and either the thickness or velocity of the flow front. The model shows that aa morphologies are characterized by higher discharge rates and frontal velocities and yields good quantitative agreement with empirical relations distinguishing pahoehoe and aa emplacement on Hawaii.

Kilburn, C. R. J.↗

NASA NTRS1994

Pondermotive versus mirror force in creation of the filamentary cavities in auroral plasma

Recently rocket observations on spikelets of lower-hybrid waves along with strong density cavities and transversely heated ions were reported. The observed thin filamentary cavities oriented along the magnetic field in the auroral plasma have density depletions up to several tens of percent. These observations have been interpreted in terms of a theory for lower-hybrid wave condensation and collapse. The modulational instability leading to the wave consensation of the lower-hybrid waves yields only weak density perturbations, which cannot explain the above strong density depletions. The wave collapse theory is based on the nonlinear pondermotive force in a homogeneous ambient plasma and the density depletion is determined by the balance between the wave pressure (pondermotive force) and the plasma pressure. In the auroral plasma, the balance is achieved in a time tau(sub wc) equal to or less than 1 ms. It is shown here that the mirror force, acting on the transversely heated ions at a relatively long time scale, is an effective mechanism for creating the strong plasma cavities. We suggest that the process of wave condensation, through the pondermotive force causing generation of short wavelength waves from relatively long wavelength waves, is a dominant process until the former waves evolve and become effective in the transverse heating of ions. As soon as this happens, mirror force on ions becomes an important factor in the creation of the density cavities, which may further trap and enhance the waves. Results from a model of cavity formation by transverse ion heating show that the observed depletions in the density cavities can be produced by the heating rates determined by the observed wave amplitudes near the lower-hybrid frequency. It is found that the creation of a strong density cavity takes a few minutes.

Singh, Nagendra↗

NASA NTRS1995

The detection of molecular gas in the ring galaxy Arp 143

We have used the NRAO 12 m telescope to map the inner 10 kpc of NGC 2445, the ring galaxy in Arp 143, in CO-12(J = 1-0). Emission is peaked near the ring galaxy nucleus, but we find evidence for an additional asymmetric and extended CO component. This extended CO distribution is consistent with an approximately 8 kpc diameter crescent-shaped ring of molecular gas, similar to the one seen in H I, accounting for approximately half of the total CO flux. Assuming this distribution, we derive a total H2 mass for NGC 2445 of 0.4-2.4 x 10(exp 10) solar mass, depending on whether a Galactic or low-metallicity Large Magellanic Cloud (LMC) conversion factor is used, and an H2/H I mass ratio between 0.9 and 5. The ring is experiencing low rates of massive star formation despite very high gas column densities. We find that the gas surface density exceeds the critical threshold for star formation throughout the ring, even without a possible contribution from a significant molecular component. The absence of vigorous star formation is most simply understood in terms of its youth (approximately 30 Myr): massive stars have not had time to form in large numbers. Our results support the interpretation that NGC 2445 is a nascent ring galaxy, seen prior to its ring starburst phase.

Higdon, James L.↗

NASA NTRS2004

The Science Goals of the Constellation-X Mission

The Constellation-X mission will address the questions: "What happens to matter close to a black hole?" and "What is Dark Energy?" These questions are central to the NASA Beyond Einstein Program, where Constellation-X plays a central role. The mission will address these questions by using high throughput X-ray spectroscopy to observe the effects of strong gravity close to the event horizon of black holes, and to observe the formation and evolution of clusters of galaxies in order to precisely determine Cosmological parameters. To achieve these primary science goals requires a factor of 25-100 increase in sensitivity for high resolution spectroscopy. The mission will also perform routine high- resolution X-ray spectroscopy of faint and extended X-ray source populations. This will provide diagnostic information such as density, elemental abundances, velocity, and ionization state for a wide range of astrophysical problems. This has enormous potential for the discovery of new unexpected phenomena. The Constellation-X mission is a high priority in the National Academy of Sciences McKee-Taylor Astronomy and Astrophysics Survey of new Astrophysics Facilities for the first decade of the 21st century.

White, Nicholas E.↗

NASA NTRS2006

The Constellation-X Mission: The next giant step in X-ray Astronomy

Constellation-X is the x-ray astronomy equivalent of large ground-based optical telescopes such as the Keck and the VLT, complementing the high spatial resolution capabilities of Chandra. By increasing the telescope aperture and utilizing efficient spectrometers the mission will achieve a factor of 100 increased sensitivity. with its increased capabilities, Constellation-X will address many fundamental astrophysics questions such as observing the formation and evolution of clusters of galaxies, constraining the Baryon content of the Universe, observing the effects of strong gravity close to the event horizon of black holes in AGN and using these effects to determine the black hole rotation. The Constellation-X mission has been under study for eight years and in the Presidents FY04 budget has been given approval to proceed with a launches in 2013 and 2014. In this talk I will review the science goals of the mission, and the implementation approach.

White, Nicholas E.↗

NASA NTRS2007

Going Beyond Einstein with the Constellation-X Mission

The Constellation-X mission will address the questions: "What happens to matter close to a black hole?" and "What is Dark Energy?" These questions are central to the NASA Beyond Einstein Program, where Constellation-X plays a central role. The mission will address these questions by using high throughput X-ray spectroscopy to observe the effects of strong gravity close to the event horizon of black holes, and to observe the formation and evolution of clusters of galaxies in order to precisely determine Cosmological parameters. To achieve these primary science goals requires a factor of 25-100 increase in sensitivity for high resolution X-ray spectroscopy.'The mission will also perform routine high-resolution X-ray spectroscopy of faint 2nd extended X-ray source populations. This will provide diagnostic information such as density, elemental abundances, velocity; and ionization state for a wide range of astrophysical problems, including new constraints on the Neutron Star equation of state.

White, Nicholas↗

NASA NTRS2009

Multiplexed Colorimetric Solid-Phase Extraction

Multiplexed colorimetric solid-phase extraction (MC-SPE) is an extension of colorimetric solid-phase extraction (C-SPE) an analytical platform that combines colorimetric reagents, solid phase extraction, and diffuse reflectance spectroscopy to quantify trace analytes in water. In CSPE, analytes are extracted and complexed on the surface of an extraction membrane impregnated with a colorimetric reagent. The analytes are then quantified directly on the membrane surface using a handheld diffuse reflectance spectrophotometer. Importantly, the use of solid-phase extraction membranes as the matrix for impregnation of the colorimetric reagents creates a concentration factor that enables the detection of low concentrations of analytes in small sample volumes. In extending C-SPE to a multiplexed format, a filter holder that incorporates discrete analysis channels and a jig that facilitates the concurrent operation of multiple sample syringes have been designed, enabling the simultaneous determination of multiple analytes. Separate, single analyte membranes, placed in a readout cartridge create unique, analyte-specific addresses at the exit of each channel. Following sample exposure, the diffuse reflectance spectrum of each address is collected serially and the Kubelka-Munk function is used to quantify each water quality parameter via calibration curves. In a demonstration, MC-SPE was used to measure the pH of a sample and quantitate Ag(I) and Ni(II).

Gazda, Daniel B.↗

NASA NTRS2010

Multifunctional and biologically active matrices from multicomponent polymeric solutions

The present invention relates to a biologically active functionalized electrospun matrix to permit immobilization and long-term delivery of biologically active agents. In particular the invention relates to a functionalized polymer matrix comprising a matrix polymer, a compatibilizing polymer and a biomolecule or other small functioning molecule. In certain aspects the electrospun polymer fibers comprise at least one biologically active molecule functionalized with low molecular weight heparin. Examples of active molecules that may be used with the multicomponent polymer of the invention include, for example, a drug, a biopolymer, for example a growth factor, a protein, a peptide, a nucleotide, a polysaccharide, a biological macromolecule or the like. The invention is further directed to the formation of functionalized crosslinked matrices, such as hydrogels, that include at least one functionalized compatibilizing polymer capable of assembly.

Kiick, Kristi L.↗

NASA NTRS2010

Lunar Topographic Mapping Using a New High Resolution Mode for the GSSR Radar

Mapping the Moon's topography using Earth based radar interferometric measurements by the Goldstone Solar System Radar (GSSR) has been done several times since the mid 1990s. In 2008 we reported at this conference the generation of lunar topographic maps having approximately 4 m height accuracy at a horizontal posting of 40 m. Since then GSSR radar has been improved to allow 40 MHz bandwidth imaging and consequently obtained images and interferograms with a resolution of about 4 m in range by 5 m in azimuth. The long synthetic aperture times of approximately 90 minutes in duration necessitated a migration from range/Doppler image formation techniques to spotlight mode processing and autofocusing methods. The improved resolution imagery should permit the generation of topographic maps with a factor of two better spatial resolution with about same height accuracy. Coupled the with the recent availability of new lidar topography maps of the lunar surface made by orbiting satellites of Japan and the United States the geodetic control of the radar generated maps products can be improved dramatically. This paper will discuss the hardware and software improvements made to the GSSR and present some of the new high resolution products.

interferometry↗

NASA NTRS2014

The Host Galaxies of Fast-Ejecta Core-Collapse Supernovae

Spectra of broad-lined Type Ic supernovae (SN Ic-BL), the only kind of SN observed at the locations of long-duration gamma-ray bursts (LGRBs), exhibit wide features indicative of high ejecta velocities ((is) approximately 0.1c). We study the host galaxies of a sample of 245 low-redshift (z (is) less than 0.2) core-collapse SN, including 17 SN Ic-BL, discovered by galaxy-untargeted searches, and 15 optically luminous and dust-obscured z (is) less than 1.2 LGRBs. We show that, in comparison with SDSS galaxies having similar stellar masses, the hosts of low-redshift SN Ic- BL and z (is) is less than 1.2 LGRBs have high stellar-mass and star-formation-rate densities. Core-collapse SN having typical ejecta velocities, in contrast, show no preference for such galaxies. Moreover, we find that the hosts of SN Ic-BL, unlike those of SN Ib/Ic and SN II, exhibit high gas velocity dispersions for their stellar masses. The patterns likely reflect variations among star-forming environments, and suggest that LGRBs can be used as probes of conditions in high-redshift galaxies. They may be caused by efficient formation of massive binary progenitors systems in densely star-forming regions, or, less probably, a higher fraction of stars created with the initial masses required for a SN Ic-BL or LGRB. Finally, we show that the preference of SN Ic-BL and LGRBs for galaxies with high stellar-mass and star-formation-rate densities cannot be attributed to a preference for low metal abundances but must reflect the influence of a separate environmental factor.

collapse↗

NASA NTRS1973

Use of Polarization Lidar for Investigation of Meteorological Formations

This paper presents the results of theoretical and experimental, investigations of depolarization characteristics of different meteorological formations. Experimental investigations are carried out with a monostatic lidar. The ruby laser radiation is polarized in a vertical plane. The radiation reflected is accepted by a lens system of 150 rom in diameter and a viewing angle of 12' and further it is divided by Wollaston prism into the components polarized orthogonally. In this case the principal plane of the prism is exposed parallel with the laser polarization plane. Investigations show the degree of radiation polarization, reflected from water clouds, to be changed within 1/0.7 (seldom up to 0.6) depending on their density. In most cases a signal reflected from the cloud leading edge is polarized completely. The time shift is observed between polarized and crosspolarized components of a Fignal, reflected from a cloud, depending on the density of a meteorological object. While penetrating into the cloud depth a degree of polarization decreases up to 0.8-0.7, and the character of this decrease is different for various types of clouds. For crystal clouds the shift between the components of the reflected signal is not observed and the magnitude of polarization degree amounts to 0.1/0.3 in comparison with water clouds. The polarization degree of radiation reflected by fog is not less than 0.6, and that in the rains of average intensity (about 5 mm/h) is always about 1. The authors have suggested an algorithm of numerical solution of nonstationary transfer equation in the vector form to forecast the influence of multiple scattering effects on polarization characteristics of the lidar light signal. The method of statistical simulation (Monte-Carlo technique) forms the basis of the algorithm. Numerical estimates obtained for a model of stratocumulus at lambda = 0.6943 microns under boundary conditions close to the conditions of natural experiment being discussed proved to be in a good agreement with the results of observation. Specifically, Fig. 1 shows the profiles of polarization (p) versus depth (L) of the following drop formations: fog (curve 1) with horizontal meteorological visibility of 4 km two stratocumulus at a height of 1100 m with the attenuation factors delta = 0.01m(exp -1) (curve 2) and delta = 0.05m(exp -1) (curve 3). Curve 3 shows the results of numerical estimates and the value of their statistical error.

Balin, Yu. S.↗

NASA NTRS1987

Effect of high temperature annealing on the thermoelectric properties of GaP doped SiGe

Silicon-germanium alloys doped with GaP are used for thermoelectric energy conversion in the temperature range 300-1000 C. The conversion efficiency depends on Z = S-squared/rho lambda, a material's parameter (the figure of merit), where S is the Seebeck coefficient, rho is the electrical resistivity and lambda is the thermal conductivity. The annealing of several samples in the temperature range of 1100-1300 C resulted in the power factor P (= S-squared/rho) increasing with increased annealing temperature. This increase in P was due to a decrease in rho which was not completely offset by a drop in S-squared suggesting that other changes besides that in the carrier concentration took place. SEM and EDX analysis of the samples indicated the formation of a Ga-P-Ge rich phase as a result of the annealing. It is speculated that this phase is associated with the improved properties. Several reasons which could account for the improvement in the power factor of annealed GaP doped SiGe are given.

Vandersande, Jan W.↗

DOE OSTI2026

Neutrinos as Dark Matter

Active neutrinos in standard cosmology were ruled out as a dark matter candidate in the 1980's. The reason is twofold: they are too light to account for the observed energy density of dark matter in the Universe, and their relativistic nature would spoil structure formation. In this note we suggest that an enhanced density of cold Standard Model active neutrinos today could behave effectively as dark matter, avoiding constraints from recombination and structure formation. Such an enhancement could be produced, for instance, by late-time decays of a light scalar field that is not in thermal equilibrium with the plasma. This mechanism is testable through the detection of the Cosmic Neutrino Background (C$\nu$B), which could have an average cosmological energy density a factor of $\sim 100-200$ times larger than expected in $\Lambda$CDM. The postulated light neutrinophilic scalar field may be observable, with Yukawa couplings in the range $y \sim 5 \times 10^{-16}-10^{-12}$. A scenario preferred by structure formation constraints is that the scalar is a Majoron, and the neutrinos have an inverted mass hierarchy.

Cline, James M. [McGill U.] (ORCID:000000017437419↗

NASA NTRS1994

Computational Simulation of the Formation and Material Behavior of Ice

Computational methods are described for simulating the formation and the material behavior of ice in prevailing transient environments. The methodology developed at the NASA Lewis Research Center was adopted. A three dimensional finite-element heat transfer analyzer was used to predict the thickness of ice formed under prevailing environmental conditions. A multi-factor interaction model for simulating the material behavior of time-variant ice layers is presented. The model, used in conjunction with laminated composite mechanics, updates the material properties of an ice block as its thickness increases with time. A sample case of ice formation in a body of water was used to demonstrate the methodology. The results showed that the formation and the material behavior of ice can be computationally simulated using the available composites technology.

Tong, Michael T.↗

DOE OSTI2025

Underground Hydrogen Storage: Transforming Subsurface Science into Sustainable Energy Solutions

As the global economy moves toward net-zero carbon emissions, large-scale energy storage becomes essential to tackle the seasonal nature of renewable sources. Underground hydrogen storage (UHS) offers a feasible solution by allowing surplus renewable energy to be transformed into hydrogen and stored in deep geological formations such as aquifers, salt caverns, or depleted reservoirs, making it available for use on demand. This study thoroughly evaluates UHS concepts, procedures, and challenges. This paper analyzes the most recent breakthroughs in UHS technology and identifies special conditions needed for its successful application, including site selection guidelines, technical and geological factors, and the significance of storage characteristics. The integrity of wells and caprock, which is important for safe and efficient storage, can be affected by the operating dynamics of the hydrogen cycle, notably the fluctuations in pressure and stress within storage formations. To evaluate its potential for broader adoption, we also examined economic elements such as cost-effectiveness and the technical practicality of large-scale storage. We also reviewed current UHS efforts and identified key knowledge gaps, primarily in the areas of hydrogen–rock interactions, geochemistry, gas migration control, microbial activities, and geomechanical stability. Resolving these technological challenges, regulatory frameworks, and environmental sustainability are essential to UHS’s long-term and extensive integration into the energy industry. This article provides a roadmap for UHS research and development, emphasizing the need for further research to fully realize the technology’s promise as a pillar of the hydrogen economy.

25 ENERGY STORAGE↗

DOE OSTI2026

Low-Temperature Gold Deposition Improves CdTe Back Contacts

Improved back contacts can benefit CdTe photovoltaics (PV). In this work, Cd(Se,Te) PV absorbers are cooled during Au evaporation to thermally quench a chemical reaction occurring between gold and CdTe and the generation of a reaction product that lowers device efficiency. Reducing substrate temperature enhances PV power conversion efficiency via open-circuit voltage and fill factor increases. X-ray photoelectron spectroscopy (XPS) reveals that lower temperature also reduces chemical perturbations of the CdTe, potentially linking back contact formation to a CdTe degradation product that hinders PV performance. Comparing reaction enthalpy and substrate heating energy shows that back contact formation by sputtering elemental metals onto ZnTe may exhibit a degradation pathway analogous to that of CdTe/Au reported here. Degradation-diminishing contact formation processes are therefore of general interest for optoelectronic devices, and the reduced substrate temperature in this study is one example.

14 SOLAR ENERGY↗

DOE OSTI2024

Operando visualization of porous metal additive manufacturing with foaming agents through high-speed x-ray imaging

Porous metals find extensive applications in soundproofing, filtration, catalysis, and energy-absorbing structures, thanks to their unique internal pore structure and high specific strength. In recent years, there has been an increasing interest in fabricating porous metals using additive manufacturing (AM), leveraging its unique advantages, including improved design freedom, spatial material control, and cost-effective small-batch production. In this study, we conducted pioneering operando visualization of AM porous metal using a laser powder bed fusion (L-PBF) setup combined with a high-speed synchrotron x-ray imaging system. Single track printing experiments using Ti6Al4V (Ti64) combined with titanium hydride (TiH 2 ) and sodium carbonate (Na 2 CO 3 ) as foaming agents, with varying mixing ratios were performed under different processing conditions. Here. the results elucidate the dynamic development of porosity formation. The average pore size is significantly influenced by the particle size of foaming agents when pore coalescence is absent. For all foaming agent content tested in the current study, the number of pores is found to be more sensitive to changes in laser power than in laser scanning speed. Increasing linear energy density (increasing laser power or reducing laser scanning speed) promotes the foaming agent activation thereby porosity formation. However, high linear energy density skews pore distribution towards the surface despite forming deeper melt pools. In addition, the impact of additional factors including foaming agent's laser absorptivity and decomposition kinetics with respect to AM time scales should be carefully considered to avoid ineffective activation of foaming agents during the AM of porous metals.

36 MATERIALS SCIENCE↗