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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Effect of energetic oxygen atoms on neutral density models.

The dissociative recombination of O2(+) and NO(+) in the F region results in the production of atomic oxygen and atomic nitrogen with substantially greater kinetic energy than the ambient atoms. In the exosphere these energetic atoms have long free paths. They can ascend to altitudes of several thousand kilometers and can travel horizontally to distances of the order of the earth's radius. The distribution of energetic oxygen atoms is derived by means of models of the ion and neutral densities for quiet and disturbed solar conditions. A distribution technique is used to study the motion of the atoms in the collision-dominated region. Ballistic trajectories are calculated in the spherical gravitational field of the earth. The present calculations show that the number densities of energetic oxygen atoms predominate over the ambient atomic oxygen densities above 1000 km under quiet solar conditions and above 1600 km under disturbed solar conditions.

Rohrbaugh, R. P.↗
NASA NTRS1973

Photochemistry of planetary atmospheres

The atmospheric composition of Mars is presented, and the applicability of laboratory data on CO2 absorption cross sections and quantum yields of dissociation is discussed. A summary and critical evaluation are presented on the various mechanisms proposed for converting the photodissociation products CO and O2 back to CO2.

Stief, L. J.↗
NASA NTRS1973

Catalysis study for space shuttle vehicle thermal protection systems

Experimental results on the problem of reducing aerodynamic heating on space shuttle orbiter surfaces are presented. Data include: (1) development of a laboratory flow reactor technique for measuring gamma sub O and gamma sub N on candidate materials at surfaces, T sub w, in the nominal range 1000 to 2000, (2) measurements of gamma sub O and gamma sub N above 1000 K for both the glass coating of a reusable surface insulation material and the siliconized surface of a reinforced pyrolyzed plastic material, (3) measurement of the ablation behavior of the coated RPP material at T sub w is greater than or equal to 2150 K, (4) X-ray photoelectron spectral studies of the chemical constituents on these surfaces before and after dissociated gas exposure, (5) scanning electron micrograph examination of as-received and reacted specimens, and (6) development and exploitation of a method of predicting the aerodynamic heating consquences of these gamma sub O(T sub w) and gamma sub N(T sub w) measurements for critical locations on a radiation cooled orbiter vehicle.

Breen, J.↗
NASA NTRS1973

In situ transfer standard for ultrahigh vacuum gage calibration

A compact insitu calibration assembly, for ultrahigh vacuum gauges is described. The system depends on the repeatable generation of a specific gas pressure by the dissociation of a solid solution chemical compound when subjected to a given temperature. A precise temperature measurement is related to the pressure generated within the vacuum by the properties of the solid solution compound. this accurately establishes the gas pressure which in turn is used to calibrate a vacuum gauge. Also included is a metering orifice used in the calibration system and which is made movable to facilitate the degassing bakeout required in ultrahigh vacuum devices.

Outlaw, R. A.↗
NASA NTRS1973

Atmospheric composition

The earth's atmosphere is made up of a number of gases in different relative amounts. Near sea level and up to about 90 km, the amount of these atmospheric gases in clean, relatively dry air is practically constant. Four of these gases, nitrogen, oxygen, argon, and carbon dioxide, make up 99.99 percent by volume of the atmosphere. Two gases, ozone and water vapor, change in relative amounts, but the total amount of these two is very small compared to the amount of the other gases. The atmospheric composition shown in a table can be considered valid up to 90 km geometric altitude. Above 90 km, mainly because of molecular dissociation and diffusive separation, the composition changes.

Daniels, G. E.↗
NASA NTRS1973

Recombination in radar meteors

Recombinations in the ionized columns generated by faint radar meteors are observed as: (1) A rapid loss of returned signal in the first few milliseconds after formation of the column; (2) an apparent absence of bright, low meteors; and (3) anomalies in apparent diffusion rates. Recombination at rates characteristic of dissociative recombination of ionized atmospheric molecules N2(+) and O2(+) is completely consistent with the observations. It appears either that the molecules are ionized in the initial formation of the ionized column or that there is rapid charge exchange. Recombination is a sufficient cause for the differences between diffusion measures and other atmospheric studies.

Southworth, R. B.↗
NASA NTRS1973

Study of resonance light scattering for remote optical probing

Enhanced scattering and fluorescence processes in the visible and UV were investigated which will enable improved remote measurements of gas properties. The theoretical relationship between scattering and fluorescence from an isolated molecule in the approach to resonance is examined through analysis of the time dependence of re-emitted light following excitation of pulsed incident light. Quantitative estimates are developed for the relative and absolute intensities of fluorescence and resonance scattering. New results are obtained for depolarization of scattering excited by light at wavelengths within a dissociative continuum. The experimental work was performed in two separate facilities. One of these utilizes argon and krypton lasers, single moded by a tilted etalon, and a 3/4 meter double monochromator. This facility was used to determine properties of the re-emission from NO2, I2 and O3 excited by visible light. The second facility involves a narrow-line dye laser, and a 3/4 meter single monochromator. The dye laser produces pulsed light with 5 nsec pulse duration and 0.005 nm spectral width.

Penney, C. M.↗
NASA NTRS1974

Measurements of ion-molecule reactions of He plus, H plus, HeH plus with H sub 2 and D sub 2

A drift tube mass spectrometer apparatus has been used to determine the rate coefficient, energy dependence and product ions of the reaction He(+) +H2. The total rate coefficient at 300 K is 1.1 plus or minus 0.1) 10 to minus 13th power cu cm/sec. The reaction proceeds principally by dissociative charge transfer to produce H(+), with the small remainder going by charge transfer to produce H2(+) and by atom rearrangement to produce HeH(+). The rate coefficient increases slowly with increasing ion mean energy, reaching a value of 2.8 x ten to the minus 13th power cu cm sec at 0.18 eV. The corresponding reaction with deuterium, He(+) + D2, exhibits a value (5 plus or minus 1) x 10 to the minus 14th cu cm/sec at 300K. The reaction rates for conversion of H(+) and HeH(+) to H3(+) on collisions with H2 molecules are found to agree well with results of previous investigations.

Johnsen, R.↗
NASA NTRS1974

Electron and ion densities in interstellar clouds

A quantitative theory of ionization in diffuse clouds is developed which includes H(+) charge exchange with O. Dissociative charge exchange of He(+) with H2 plays an important role in the densities of H(+) and He(+). The abundance of HD is also discussed.

Glassgold, A. E.↗
NASA NTRS1974

Use of hexafluoroethane to simulate the inviscid real-gas effects on blunt entry vehicles

Results are presented of an experimental and theoretical investigation of the use of equilibrium hexafluoroethane C2F6 as an undissociated test gas in a wind tunnel to simulate the inviscid aerodynamic characteristics of blunt bodies in high-speed flight where dissociation occurs. The results indicate that the use of C2F6 as a test gas in wind tunnels is a practical and relatively simple and inexpensive method of obtaining test conditions with large normal-shock density ratios. Equations for the thermodynamic and transport properties of C2F6 are also included.

Hunt, J. L.↗
NASA NTRS1973

Double-discharge copper vapor laser with copper chloride as a lasant

A copper vapor laser utilizing copper chloride as a lasant in a heated discharge tube has been studied. The lasing action was observed only when two successive discharge current pulses at suitable time intervals were applied. The first pulse is considered to be a dissociation pulse to produce copper and chlorine atoms; the second to be a pumping pulse to produce population inversion. The maximum energy density measured to date was 17 microjoule/cu cm.

Chen, C. J.↗
NASA NTRS1973

Oxygen and sulfur interactions with a clean iron surface and the effect of rubbing contact on these interactions

An investigation was conducted to determine the nature of the chemical interactions of oxygen and sulfur with iron when surfaces are stationary and also during sliding in a vacuum environment. Various gases that contained sulfur, oxygen, or both were adsorbed to iron at 23 C. The gases included oxygen, hydrogen sulfide, methyl mercaptan, and sulfur dioxide. Friction experiments were conducted with a hemispherical rider sliding on a rotating disk. An Auger cylindrical mirror analyzer was used to monitor the iron surface chemistry. The results of this study indicate that oxygen will completely displace sulfide films from iron surfaces. Organic thiols containing sulfur, such as methyl mercaptan, adsorb to an iron surface dissociatively. Only sulfur is detected on the iron surface. Sliding inhibits the formation of sulfide films on iron with the adsorption of hydrogen sulfide and methyl mercaptan. With oxygen and sulfur dioxide, the sliding process does not affect adsorption behavior.

Buckley, D. H.↗
NASA NTRS1973

Electron excitation of a Jovian Aurora

Because Jupiter possesses a magnetic field, auroral activity is very likely. The auroral emissions due to electron precipitation are estimated for a model atmosphere with and without helium. The incident primary electrons, which are characterized by representative spectra, are degraded in energy by applying the continuous slow down approximation. All secondaries, tertiaries, and higher generation electrons are assumed to be absorbed locally. A compilation of excitation, dissociation, and ionization cross section data for H, H2, and He are used to model all aspects of the energy deposition process. Volume emission rates are calculated from the total direct excitation rates, and appropriate corrections for cascading are applied. Helium emissions are relatively small because the majority of electrons are absorbed above the region of maximum He concentration.

Heaps, M. G.↗
NASA NTRS1973

Classical trajectory study of the K + CH3I reaction

Potential surfaces for the system K+IR were considered, taking into account a covalent surface, an ionic surface, the overall potential, and a comparison of a modified Bunker-Blais and a hybrid covalent-ionic potential of the electron-jump type. The Lagrange equations were solved as a system of second-order differential equations. The impact parameter, angular, and energy dependences of the product distributions for the nonreactive, reactive, and dissociative scattering were studied.

Labudde, R. A.↗
NASA NTRS1974

Photodissociation of carbon dioxide in the Mars upper atmosphere

Calculation of the intensity of two of the emissions produced during the dissociative excitation of carbon dioxide in the upper atmosphere of Mars by solar ultraviolet radiation. The calculation tangential column emission rates of the atomic oxygen 2972-A line and the carbon monoxide Cameron bands produced by the photodissociative mechanism are found to be factors of 3 and 10, respectively, smaller than the emission rates observed by Mariner ultraviolet spectrometers.

Barth, C. A.↗
NASA NTRS1974

Extreme ultraviolet photodissociative excitation of molecular oxygen

Photodissociation processes in molecular oxygen occurring in the wavelength range from 500 to 900 A, investigated through observations of the resulting atomic fluorescence radiation, are reported. The dispersed radiation from a continuous light source was used to excite the gas, and the resulting fluorescence radiation was observed in the ultraviolet and infrared. The results obtained are compared with the dissociation cross sections derived by Matsunaga and Watanabe (1967).

Carlson, R. W.↗
NASA NTRS1974

Thermochemical water decomposition processes

Thermochemical processes which lead to the production of hydrogen and oxygen from water without the consumption of any other material have a number of advantages when compared to other processes such as water electrolysis. It is possible to operate a sequence of chemical steps with net work requirements equal to zero at temperatures well below the temperature required for water dissociation in a single step. Various types of procedures are discussed, giving attention to halide processes, reverse Deacon processes, iron oxide and carbon oxide processes, and metal and alkali metal processes. Economical questions are also considered.

Chao, R. E.↗