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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48

Impacts of Fast Critical Assembly Fuel Discards on Liquid Waste Processes

The Savannah River Nuclear Solutions (SRNS) Fast Critical Assembly (FCA) mission is reestablishing the electrolytic dissolver for processing of Pu and Pu-U materials clad in stainless steel (SS). H-Canyon is planning to dissolve and neutralize FCA fuel without recovering the special nuclear material (i.e., Pu) prior to discarding to the Concentration, Storage, and Transfer Facilities (CSTF) operated by the Savannah River Mission Completion (SRMC) Liquid Waste (LW) Organization. The FCA discards will be combined with sludge in the CSTF after Low Temperature Aluminum Dissolution (LTAD) if needed. The combined waste will be washed, concentrated, and vitrified at the Defense Waste Processing Facility (DWPF). The high level waste canisters produced will be temporarily stored in the Glass Waste Storage Buildings prior to transfer to a future federal repository. Decants from LTAD and sludge washing will be combined with DWPF recycle and dissolved salt cake to prepare salt batches for processing in the Salt Waste Processing Facility. The resulting decontaminated salt solution will be processed in the Saltstone Production Facility.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Prefeasibility Assessment for Solar PV and Storage for Critical Community Facilities in Chernihiv, Ukraine [Slides]

A prefeasibility analysis is performed for integrating solar photovoltaics and battery energy storage at four critical facilities in Chernihiv, Ukraine. The facilities were identified by Chernihiv city officials and include Hospital No. 2, the Maternity Hospital, Secondary School No. 11, and Preschool No. 4. The analyses were performed using NREL's REopt decision-support software tool. The analysis identifies potential capacities for PV and battery energy storage to provide both economic and resilience benefits. The conceptual architecture and estimates of key summary financial and performance metrics are presented.

14 SOLAR ENERGY↗

Nuclear Energy Critical Material Waste Minimization Enabled by AM Techniques

This project provides evidence of the successful recycling of solid waste offcuts resulting from conventional manufacturing processes from three relevant alloys to next-generation nuclear reactor developers, providing a potentially upscalable circular process where no critical elements will be lost. Furthermore, iMOF-based adsorbents were successfully designed for CM extraction from aqueous solution, thereby providing a pathway for future upscaling for salvaging dissolved Ni ions. This research has achieved its goal of showing the impact of novel applications of recycling technologies for solid and liquid wastes that can be upscaled for application.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advanced Characterization to Inform Sustainable Recovery of Critical Minerals from Fossil Energy Waste Feedstocks

Rare earth elements (REE) and other critical minerals (CM, e.g., Co, Li) have important uses in green energy and modern technologies, yet are vulnerable to potential supply chain disruptions. One potential domestic source of CM is fossil energy wastes, such as acid mine drainage (AMD) and treatment solids (AMD solids), coal combustion ash, and Oil and Gas (O&G) drilling wastes (drill cuttings and produced waters). CM recovery from these waste feedstocks is promising due to their abundances and fast availability as waste products. On the other hand, the CM occurrence in these wastes is in small quantities compared to traditional ore bodies. Thus, novel and strategic separation and extraction processes are under exploration. Researchers at DOE’s National Energy Technology Laboratory (NETL) are collecting and analyzing CM data for aforementioned fossil energy wastes, and utilizing advanced geochemical characterization (e.g., synchrotron microprobe and sequential extraction) to understand the CM speciation and binding environments in these materials to better inform sustainable and effective recovery. Successful examples discussed in this talk include: (1) the discovery of easily mobile REE phases in Ca-rich coal combustion ash and developing a patented REE recovery process from Ca-rich Powder River Basin coal ash; (2) the successful identification of REE/Co/Ni/Zn hosting phases in acid mine drainage treatment solids (AMD solids) with diverse chemical composition (Al, Mn, or Fe-rich) informing the sequential recovery of different REE/CMs from AMD solids; (3) the recovery potential of Li and other CMs in O&G produced waters and drill cuttings. The innovations driven by characterization have the potential to offset the cost of waste management and wastewater treatments while reducing the cost and environmental footprint of CM extraction.

characterization and extraction↗

ZPR/ZPPR Critical Experiment Facilities and As-Built ZPR/ZPPR Models

Argonne National Laboratory (ANL) operated four split-table critical experiment facilities, ZPR 3, ZPR-6, ZPR-9 and ZPPR, between 1955 and 1990. ZPR is the abbreviation for Zero Power Reactor, and ZPPR was the abbreviation for Zero Power Plutonium Reactor which was changed to Zero Power Physics Reactor in the 1980s due to negative views on Plutonium breeding and proliferation concerns. ZPR-3, ZPR-6, ZPR-9 and ZPPR were four reactors in a series of zero power (or lower power reactors) designed at Argonne in the 1950s and 1960s.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Targeted Biomining and Machine Learning Approaches in Critical Minerals Revealed by a Biogeochemical Survey of a Coal Mine Drainage Remediation System

Abandoned coal mine drainage (AMD) remediation systems in Pennsylvania can concentrate critical minerals and materials (CMM) at levels comparable to mining-grade ores. Remediation systems have varying engineering features and are open to the environment, resulting in diverse microbial colonization and seasonal climate influences that may impact CMM speciation. The location of CMMs, the types of bacterial communities tolerant of these pollutant conditions, and the influence of localized climate on CMM rich remediation systems are not well characterized. Through a one-year spatiotemporal survey of biogeochemistry at a remediation system, we have initiated the process to address these questions. Rare Earth Elements (REE) ranged 180-1,200 ppm and greater than 1,500 bacterial ASVs were classified via 16S sequencing. Analyses indicate biogeochemical differences are heavily influenced by engineering features. Additionally, REE precipitants correlate strongly with the elements Al, Cu, Zn, Be, and U. Unearthing these trends has refined our line of inquiry to explore biological mining opportunities more closely with these metals. Furthermore, we created a Machine Learning Model for predicting AMD REE content, with 89% accuracy, using the data from this study and several others. Further training data is required to create a more reputable model. Recently, global research efforts have prioritized modeling work or the use of the few historical surveys to design experiments. Through our data, we challenge this approach, emphasizing the importance of expanding fundamental survey efforts prior to advanced product design and experimentation.

critical minerals↗

Microbial Reduction of Manganese Oxides From AMD Solids for the Biomining of Critical Minerals / Rare Earth Elements

Abandoned Coal-Mine Drainage (AMD) is a source of critical minerals (CMs) that can be biomined to increase domestic CM production for the growing tech industry while mitigating current AMD hazardous waste. Pennsylvania has ~11,000 abandoned mines, ~500 of which are currently being treated with passive remediation systems (PRS), designed to increase the pH and precipitate AMD waste onsite. Manganese (Mn) that precipitates from AMD waste can co-precipitate with CMs, and the Mn and CMs will accumulate on the PRS solids over the treatment period. This results in high Mn/CM solids that could produce a valuable leachate if resolubilized. Mn reduction and solubilization can occur through microbial driven geochemical changes such as the acidification of the environment, and it is expected that Mn resolubilization will lead to a co-resolubilization of the CMs. Investigation and stimulation of this microbial resolubilization could result in an affordable CM release process that does not require chemical additives into the environment. However the microbial mechanisms that contribute to Mn resolubilization are poorly understood. Here, we have isolated bacteria capable of resolubilizing Mn from AMD PRS. Five of the bacteria isolates have been identified as Bacillus spp. and two as Corynebacterium spp. that ferment glucose to reduce/solubilize Mn MnO2 by acidogenesis. The bacterial isolates are also capable of solubilizing Mn and CMs (Y, Zr, Sb, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) from AMD PRS precipitated solids through their production of organic acids. Determining the microbial metabolism and genes involved in the resolubilization of manganese is crucial to optimize the biomining of CMs from AMD solid precipitants. This work addresses the growing need to develop novel CM recovery methods from domestic sources.

critical minerals↗

Lilith: An Enduring Plutonium Critical Assembly [Slides]

A design of an enduring Pu critical assembly has been produced. This is very important to DOE/NNSA missions. This assembly would result in advances/improvements in nuclear data validation, analytical methods validation, dosimetry, reactor kinetics, materials, and more.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

MARVEL Dry Criticality Assembly [Slides]

This slideshow presents a high-level overview of the assembly sequence for the MARVEL dry criticality configuration.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗