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At least 865 records · Page 48

The reaction O((3)P) + HOBr: Temperature dependence of the rate constant and importance of the reaction as an HOBr stratospheric loss process

The absolute rate constant for the reaction O((3)P) + HOBr has been measured between T = 233K and 423K using the discharge-flow kinetic technique coupled to mass spectrometric detection. The value of the rate coefficient at room temperature is (2.5 +/- 0.6) x 10(exp -11)cu cm/molecule/s and the derived Arrhenius expression is (1.4 +/- 0.5) x 10(exp -10) exp((-430 +/- 260)/T)cu cm/molecule/s. From these rate data the atmospheric lifetime of HOBr with respect to reaction with O((3)P) is about 0.6h at z = 25 km which is comparable to the photolysis lifetime based on recent measurements of the UV cross section for HOBr. Implications for HOBr loss in the stratosphere have been tested using a 1D photochemical box model. With the inclusion of the rate parameters and products for the O + HOBr reaction, calculated concentration profiles of BrO increase by up to 33% around z = 35 km. This result indicates that the inclusion of the O + HOBr reaction in global atmospheric chemistry models may have an impact on bromine partitioning in the middle atmosphere.

Nesbitt, F. L.↗

Constant-Current Source For Measuring Low Resistances

Constant-current source constructed for measuring electrical resistances up to few ohms in power-supply equipment. By setting current at 1 A and measuring resulting voltage drop across item under test, one obtains voltage reading numerically equal to resistance in ohms.

Toomath, Robert L.↗

Sensing Position With Approximately Constant Contact Force

Computer-controlled electromechanical system uses number of linear variable-differential transformers (LVDTs) to measure axial positions of selected points on surface of lens, mirror, or other precise optical component with high finish. Pressures applied to pneumatically driven LVDTs adjusted to maintain small, approximately constant contact forces as positions of LVDT tips vary.

Sturdevant, Jay↗

Three-Wire Thermocouple: Frequency Response in Constant Flow

Theory and experimental measurements are compared with a novel three-wire thermocouple. Signals from three wires of unequal diameters are recorded from the thermocouple suspended in constant flow with a periodic temperature fluctuation. It is demonstrated that the reconstructed signal from the three-wire thermocouple requires no compensation for omega less than or equal to 5(omega(sub 1)), where omega(sub 1) is the natural frequency of the smaller wire. The latter result represents a significant improvement compared to previous work with two-wire thermocouples. A correction factor has also been derived to account for wires of arbitrary diameter.

Forney, L. J.↗

Three-wire Thermocouple: Frequency Response in Constant Flow

Theory and experimental measurements are compared with a novel three-wire thermocouple. Signals from three wires of unequal diameters arc recorded from the thermocouple suspended in constant flow with a periodic temperature fluctuation. It is demonstrated that the reconstructed signal from the three-wire thermocouple requires no compensation for omega less than or equal to 5(sub omega1), where omega, is the natural frequency of the smaller wire. The latter result represents a significant improvement compared to previous work with two-wire thermocouples. A correction factor has also been derived to account for wires of arbitrary diameter.

Forney, L. J.↗

Estimation of Slow Crack Growth Parameters for Constant Stress-Rate Test Data of Advanced Ceramics and Glass by the Individual Data and Arithmetic Mean Methods

The two estimation methods, individual data and arithmetic mean methods, were used to determine the slow crack growth (SCG) parameters (n and D) of advanced ceramics and glass from a large number of room- and elevated-temperature constant stress-rate ('dynamic fatigue') test data. For ceramic materials with Weibull modulus greater than 10, the difference in the SCG parameters between the two estimation methods was negligible; whereas, for glass specimens exhibiting Weibull modulus of about 3, the difference was amplified, resulting in a maximum difference of 16 and 13 %, respectively, in n and D. Of the two SCG parameters, the parameter n was more sensitive to the estimation method than the other. The coefficient of variation in n was found to be somewhat greater in the individual data method than in the arithmetic mean method.

Choi, Sung R.↗

Pulse Shaped Constant Envelope 8-PSK Modulation Study

This report provides simulation results for constant envelope pulse shaped 8 Level Phase Shift Keying (8 PSK) modulation for end to end system performance. In order to increase bandwidth utilization, pulse shaping is applied to signals before they are modulated. This report provides simulation results of power spectra and measurement of bit errors produced by pulse shaping in a non-linear channel with Additive White Gaussian Noise (AWGN). The pulse shaping filters can placed before (Type B) or after (Type A) signals are modulated. Three kinds of baseband filters, 5th order Butterworth, 3rd order Bessel and Square-Root Raised Cosine with different BTs or roll off factors, are utilized in the simulations. The simulations were performed on a Signal Processing Worksystem (SPW).

Tao, Jianping↗

Flight Demonstration of a Shock Location Sensor Using Constant Voltage Hot-Film Anemometry

Flight tests have demonstrated the effectiveness of an array of hot-film sensors using constant voltage anemometry to determine shock position on a wing or aircraft surface at transonic speeds. Flights were conducted at the NASA Dryden Flight Research Center using the F-15B aircraft and Flight Test Fixture (FTF). A modified NACA 0021 airfoil was attached to the side of the FTF, and its upper surface was instrumented to correlate shock position with pressure and hot-film sensors. In the vicinity of the shock-induced pressure rise, test results consistently showed the presence of a minimum voltage in the hot-film anemometer outputs. Comparing these results with previous investigations indicate that hot-film anemometry can identify the location of the shock-induced boundary layer separation. The flow separation occurred slightly forward of the shock- induced pressure rise for a laminar boundary layer and slightly aft of the start of the pressure rise when the boundary layer was tripped near the airfoil leading edge. Both minimum mean output and phase reversal analyses were used to identify the shock location.

Moes, Timothy R.↗

Galaxy Cluster Shapes and Systematic Errors in the Hubble Constant as Determined by the Sunyaev-Zel'dovich Effect

Imaging of the Sunyaev-Zei'dovich (S-Z) effect in galaxy clusters combined with the cluster plasma x-ray diagnostics can measure the cosmic distance scale to high accuracy. However, projecting the inverse-Compton scattering and x-ray emission along the cluster line-of-sight will introduce systematic errors in the Hubble constant, H$-O$, because the true shape of the cluster is not known. This effect remains present for clusters that are otherwise chosen to avoid complications for the S-Z and x-ray analysis, such as plasma temperature variations, cluster substructure, or cluster dynamical evolution. In this paper we present a study of the systematic errors in the value of H$-0$, as determined by the x-ray and S-Z properties of a theoretical sample of triaxial isothermal 'beta-model' clusters, caused by projection effects and observer orientation relative to the model clusters' principal axes. The model clusters are not generated as ellipsoids of rotation, but have three independent 'core radii', as well as a random orientation to the plane of the sky.

Sulkanen, Martin E.↗

Heat Transfer in the Turbulent Incompressible Boundary Layer: Constant Wall Temperature - Part 1

Heat-transfer rates, velocity profiles, and temperature profiles for the turbulent incompressible flow of air over a flat plate with a constant surface temperature have been measured at Reynolds numbers up to 3.5 x lO(exp 6). The turbulent heat-transfer measurements agree well with the von Karman analogy, and the velocity profiles agree with the data of previous investigators. The temperature profiles are similar to the velocity profiles, both being adequately described by power formulas.

Reynolds, W. C.↗

Atomic Clocks and Variations of the FIne Structure Constant

We describe a new test for possible variations of the fine structure constant alpha by comparisons of rates between clocks based on hyperfine transitions in alkali atoms with different atomic number Z. H-maser, Cs, and Hg(+) clocks have a different dependence on alpha via relativistic contributions of order (Z-alpha)(sup 2). Recent H-maser vs Hg(+) clock comparison data improve laboratory limits on a time variation by 100-fold to give dot-alpha less than or equal to 3.7 x 10(exp -14)/yr. Future laser cooled clocks (Be(+), Rb, Cs, Hg(+), etc.), when compared, will yield the most sensitive of all tests for dot-alpha/alpha.

Prestage, John D.↗

Constant-Pressure Specific Heat to Hemispherical Total Emissivity Ratio for Undercooled Liquid Nickel, Zirconium, and Silicon

Radiative cooling curves of nickel, zirconium, and silicon melts that were obtained using the high-temperature, high-vacuum electrostatic levitator (HTHVESL) have been analyzed to determine the ratio between the constant-pressure specific heat and the hemispherical total emissivity, c(sub p)(T)epsilon(sub T)(T). This ratio determined over a wide liquid temperature range for each material allows us to determine c(sub p)(T) if epsilon(sub T)(T) is known or vice versa. Following the recipe, the hemi-spherical total emissivities for each sample at its melting temperature, epsilon(sub T)(T(sub M)), have been determined using c(sub p)(T(sub m)) values available in the literature. They are 0.15, 0.29, and 0.17, for Ni, Zr, and Si, respectively.

Rulison, Aaron J.↗

Synthesis of Optimal Constant-Gain Positive-Real Controllers for Passive Systems

This paper presents synthesis methods for the design of constant-gain positive real controllers for passive systems. The results presented in this paper, in conjunction with the previous work by the authors on passification of non-passive systems, offer a useful synthesis tool for the design of passivity-based robust controllers for non-passive systems as well. Two synthesis approaches are given for minimizing an LQ-type performance index, resulting in optimal controller gains. Two separate algorithms, one for each of these approaches, are given. The synthesis techniques are demonstrated using two numerical examples: control of a flexible structure and longitudinal control of a fighter aircraft.

Mao, Y.↗

Acetylated Lysozyme as Impurity in Lysozyme Crystals: Constant Distribution Coefficient

Hen egg white lysozyme (HEWL) was acetylated to modify molecular charge keeping the molecular size and weight nearly constant. Two derivatives, A and B, more and less acetylated, respectively, were obtained, separated, purified and added to the solution from which crystals of tetragonal HEWL crystals were grown. Amounts of the A or B impurities added were 0.76, 0.38 and 0.1 milligram per millimeter while HEWL concentration were 20, 30 and 40 milligram per milliliter. The crystals grown in 18 experiments for each impurity were dissolved and quantities of A or B additives in these crystals were analyzed by cation exchange high performance liquid chromatography. All the data for each set of 18 samples with the different impurity and regular HEWL concentrations is well described by one distribution coefficient K = 2.15 plus or minus 0.13 for A and K = 3.42 plus or minus 0.25 for B. The observed independence of the distribution coefficient on both the impurity concentration and supersaturation is explained by the dilution model described in this paper. It shows that impurity adsorption and incorporation rate is proportional to the impurity concentration and that the growth rate is proportional to the crystallizing protein in solution. With the kinetic coefficient for crystallization, beta = 5.10(exp -7) centimeters per second, the frequency at which an impurity molecule near the growing interface irreversibly joins a molecular site on the crystal was found to be 3 1 per second, much higher than the average frequency for crystal molecules. For best quality protein crystals it is better to have low microheterogeneous protein impurity concentration and high supers aturation.

Thomas, B. R.↗

Mars Pathfinder Project: Planetary Constants and Models

This document provides a common set of astrodynamic constants and planetary models for use by the Mars Pathfinder Project. It attempts to collect in a single reference all the quantities and models in use across the project during development and for mission operations. These models are central to the navigation and mission design functions, but they are also used in other aspects of the project such as science observation planning and data reduction.

Vaughan, Robin↗

Mission Advantages of Constant Power, Variable Isp Electrostatic Thrusters

Electric propulsion has moved from station-keeping capability for spacecraft to primary propulsion with the advent of both the Deep Space One asteroid flyby and geosynchronous spacecraft orbit insertion. In both cases notably more payload was delivered than would have been possible with chemical propulsion. To provide even greater improvements electrostatic thruster performance could be varied in specific impulse, but kept at constant power to provide better payload or trip time performance for different mission phases. Such variable specific impulse mission applications include geosynchronous and low earth orbit spacecraft stationkeeping and orbit insertion, geosynchronous reusable tug missions, and interplanetary probes. The application of variable specific impulse devices is shown to add from 5 to 15% payload for these missions. The challenges to building such devices include variable voltage power supplies and extending fuel throughput capabilities across the specific impulse range.

Oleson, Steven R.↗

A Coupled Nonlinear Spacecraft Attitude Controller/Observer With an Unknown Constant Gyro Bias

A nonlinear control scheme for attitude control of a spacecraft is combined with a nonlinear gyro bias observer for the case of constant gyro bias. The closed loop system is proven to be globally stable, with zero tracking error, thus proving a separation principle for the given system. The nonlinear observer incorporates persistency of excitation, resulting in exponential convergence of the gyro bias error.

Deutschmann, Julie↗