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At least 865 records · Page 48

A potpourri of pristine moon rocks, including a VHK mare basalt and a unique, augite-rich Apollo 17 anorthosite

The anorthosite fragment, 76504,18, the first of the Apollo 17's pristine anorthosites, was found to have: (1) a higher ratio of high-Ca pyroxine to low-Ca pyroxene, (2) higher Na in its plagioclase, (3) higher contents of incompatible elements, and (4) a higher Eu/Al ratio in comparison to ferroan anorthosites. With a parent melt having a negative Eu anomaly, 76504,18 closely resembles a typical mare basalt. This anorthosite was among the latest to be formed by plagioclase flotation above a primordial magmasphere; typical mare basalt regions accumulated at about the same time or even earlier. Another fragment 14181c, a very high potassium basalt, was studied and found to be similar to typical Apollo 14 mare basalt though it has a K/La ratio of 1050. It is suggested that this lithology formed after a normal Apollo 14 mare basaltic melt partially assimilated granite. New data for siderphile elements in Apollo 12 mare basalts indicate that only the lowest of earlier data are trustworthy as being free of laboratory contamination.

Warren, P. H.↗

Ragland - An LL3.4 chondrite find from New Mexico

The Ragland, New Mexico, chondrite was found in 1978. It consists of a single stone of 12.16 kg that broke into three pieces. The stone is moderately weathered and has a pronounced chondritic texture. Bulk composition favors an LL classification, and modal analysis and oxygen isotopic composition are consistent with this. The thermoluminescence sensitivity of 0.056 + or - 0.020 normalized to Dhajala, compositional variability of olivine (mean Fa 18.3, sigma = 10.1) and low-Ca pyroxene (mean Fs 14.6, sigma = 6.7), and Ca concentrations in olivine indicate metamorphic subtype 3.4 + or - 0.1. The isotopically heavy oxygen composition, which is characteristic of subtypes 3.0-3.1, may be a primary characteristic and not a result of weathering. Low concentrations of radiogenic Ar-40 and planetary Ar-36 suggest noble gas loss.

Recca, S. I.↗

Spectroscopic observations of cool degenerate star candidates

Spectroscopic observations are reported for 23 Luyten Half-Second degenerate star candidates and for 13 Luyten-Palomar common proper-motion pairs containing possible degenerate star components. Twenty-five degenerate stars are identified, 20 of which lack previous spectroscopy. Most of these stars are cool - Luyten color class g or later. One star, LP 77-57, shows broad continuum depressions similar to those in LHS 1126, which Liebert and Dahn attributed to pressure-shifted C2. A second degenerate star, LHS 290, exhibits apparent strong Swan bands which are blueshifted about 75 A. Further observations, including polarimetry and photometry, are required to appraise the spectroscopic peculiarities of these stars. Finally, five cool, sharp-lined DA white dwarfs have been observed to detect lines of metals and to determine line strengths. None of these DAs show signs of Mg b or the G band, and four show no evidence of Ca II K. The attempt to detect Ca MI in the fifth star, G199-71, was inconclusive.

Hintzen, P.↗

Calcium carbonate and calcium sulfate in Martian meteorite EETA79001

Chips of glassy Lithology C of EETA79001 were studied by scanning electron microscopy and energy dispersive X-ray spectroscopy to determine the mineralogy and petrogenesis of the glass that was shown by others to contain trapped Mars-like gases. Calcium carbonite was identified as massive to acicular crystals for which Ca, C, and O were the major elements. Calcium sulfate was identified as prismatic-acicular crystals with Ca and S as the major elements.

Gooding, J. L.↗

A sputtering derived atomic oxygen source for studying fast atom reactions

A technique for the generation of fast atomic oxygen was developed. These atoms are created by ion beam sputtering from metal oxide surfaces. Mass resolved ion beams at energies up to 60 KeV are produced for this purpose using a 150 cm isotope separator. Studies have shown that particles sputtered with 40 KeV Ar(+) on Ta2O5 were dominantly neutral and exclusively atomic. The atomic oxygen also resided exclusively in its 3P ground state. The translational energy distribution for these atoms peaked at ca 7 eV (the metal-oxygen bond energy). Additional measurements on V2O5 yielded a bimodal distribution with the lower energy peak at ca 5 eV coinciding reasonably well with the metal-oxygen bond energy. The 7 eV source was used to investigate fast oxygen atom reactions with the 2-butene stereoisomers. Relative excitation functions for H-abstraction and pi-bond reaction were measured with trans-2-butene. The abstraction channel, although of minor relative importance at thermal energy, becomes comparable to the addition channel at 0.9 eV and dominates the high-energy regime. Structural effects on the specific channels were also found to be important at high energy.

Ferrieri, Richard A.↗

Chromium isotopic anomalies in the Allende meteorite

Abundances of the chromium isotopes in terrestrial and bulk meteorite samples are identical to 0.01 percent. However, Ca-Al-rich inclusions from the Allende meteorite show endemic isotopic anomalies in chromium which require at least three nucleosynthetic components. Large anomalies at Cr-54 in a special class of inclusions are correlated with large anomalies at Ca-48 and Ti-50 and provide strong support for a component reflecting neutron-rich nucleosynthesis at nuclear statistical equilibrium. This correlation suggests that materials from very near the core of an exploding massive star may be injected into the interstellar medium.

Papanastassiou, D. A.↗

Observations of gaseous circumstellar disks. III

Echelle spectra obtained at the Ca II K line and the Na I D lines are reported for seven stars which show excess fluxes in at least one of the IRAS bands at 25, 60, and 100 microns. Detectable circumstellar absorption lines arising from the gaseous components of the presumed circumstellar dust disks are found in none of these cases, in contrast to the previously reported case of Beta Pic. Conversely, six A or F stars which were known before the launch of IRAS to show gaseous circumstellar disks do not show excess fluxes in any of the IRAS bands. Similar echelle spectra of these stars show Ca II circumstellar absorption lines comparable in four cases to that of Beta Pic.

Hobbs, L. M.↗

Identification of cosmogenic argon components in Allende by laser microprobe

New techniques are presented for using a laser microprobe to determine the spallation argon systematics of calcium-aluminum inclusions. The Ar-38(s) amounts determined for melilite and anorthite in a coarse-grained inclusion from Allende are 2.9 x 10 to the -8th and 1.3 x 10 to the -8th cc/g, respectively. The ratio of the amounts is consistent with the calcium contents of these two minerals. The Ar-38(s) amount determined for a fine-grained inclusion from Allende is 1.1 x 10 to the -8th cc/g. Calcium and potassium amounts were determined from irradiated samples of the same inclusions so that production of Ar-38 from calcium during the cosmic ray exposure of Allende could be determined for these samples. The production observed was 12.4 + or - 2.1 x 10 to the -8th cc STP Ar-38/g Ca for the coarse-grained inclusion and 9.9 + or - 2.4 cc STP Ar-38/g Ca for the fine-grained inclusion. No evidence of unusual exposure was observed in the two inclusions studied.

Kirschbaum, C.↗

The temperature of solar flares determined from X-ray spectral line ratios

The effect on derived solar flare plasma temperatures of (1) a power-law distribution of emission measure as a function of temperature, (2) a high-temperature isothermal source coupled to a low-temperature power-law distribution of emission measure, and (3) two isothermal sources is calculated for line ratios involving the ions S XV, Ca XIX, Ca XX, Fe XXV, Ni XXVII, and Fe XXVI. It is shown that if the Fe XXV temperature is less than about 25 million K, as is true for the majority of flares, then about 75 percent or more of the emission measure is produced by plasma at temperatures equal to or less than the Fe XXV temperature plus about 3 million K. If the Fe XXV temperature is 20 million K or higher, this percentage can be larger. This result is obtained even if a superhot component exists that extends up to several hundred million degrees. Temperatures determined from Fe XXVI demonstrate the presence of a superhot component.

Doschek, G. A.↗

Discovery of three new RS Canum Venaticorum-like counterparts to HEAO I X-ray sources

The identification of three high-latitude HEAO I Scanning Modulation Collimator X-ray sources with the chromospherically active RS CVn-like stars HD 113816, HD 146413, and HD 39576 is reported. Optical observations, including coude spectroscopy and broad-band and narrow band photoelectric photometry are presented. The Ca II emission strength of all three stars shows that they are chromospherically active. HD 146413 and HD 39576 exhibit variable X-ray emission in the 1-13 keV energy range, while HD 113816 is a softer and steadier source. The level of X-ray flux detected from these three stars is some one to two orders of magnitude higher than predicted empirically from the Ca II emission fluxes. It is proposed that this emission results from flarelike activity.

Buckley, D. A. H.↗

Mars regolith versus SNC meteorites - Possible evidence for abundant crustal carbonates

Viking XRF data of the Martian regolith are compared with data of typical igneous rocks of the earth, Moon, eucrite parent asteroid, and shergottite, nakhlite, and Chassigny (SNC) meteorites. It is suggested that regolith's low Ca/Si ratio, with respect to igneous rocks with similar (Mg + Fe)/Si ratios, is not a result of simple mixing of SNC-like rocks with other igneous rocks, but rather is due to the removal of Ca from the regolith as Ca-carbonate. Formation of a mass of carbonate equivalent to a 20-m-thick global shell could account for the removal of 1000 mbar of CO2 from the Martian atmosphere. This Ca/Si ratio is consistent with the hypothesis that the Martian climate was once far warmer and wetter than at present.

Warren, Paul H.↗

Studies of calcium emission stars. I - HD 158393 a giant star in a binary system

HD 158393 is a giant star of spectral type late G or early K which has moderately strong Ca II H and K emission cores. UBVRIJHK photometry and IUE spectra reveal a companion of type F0-F2, luminosity class IV or V. Radial velocity data yield an orbit with a period of 31 day. The K and F stars have nearly equal mass, with a minimum value of 1.7 solar masses if i of less than 72 deg is adopted, as required by the absence of eclipses. The strong Ca II emission indicates the enhanced chromospheric activity which is typical of giant stars in a binary system of this period, and the light is variable in a 31-day period, indicative of synchronous rotation as well as on a long time-scale. Analysis of the 31-day light period by fitting a spot model indicates the presence of two spots in 1975 and 1976; the major spot appears to have been present throughout the observing period (1973-1981). The potential confusion caused by the presence of the second spot for part of the observing period emphasizes the importance of fitting a model if the photometric period is to be understood in terms of the synchronous rotation. The two spots showed different periods and were at different latitudes, suggesting differential rotation of the giant star.

Evans, T. Lloyd↗

Correlated isotopic effects near the Fe abundance peak

A special class of refractory inclusions in carbonaceous meteorites show large isotopic anomalies in Ca, Ti, and Cr that are correlated by virtue of having been measured on the same samples. Large excesses in the neutron-rich isotopes Ca-48, Ti-50, and Cr-54 are comparable and consistent with theoretical calculations of the composition of materials produced during neutron-rich nuclear statistical equilibrium nucleosynthesis. This correlation suggests that materials from very near the core of an expoloding massive star may be injected into the interstellar medium.

Papanastassiou, D. A.↗

The delta upsilon = 1 fundamental bands of carbon monoxide in late-type stars

A program was begun to develop the fundamental vibration-rotation bands of CO near 4.7 micron, as a tool to investigate the properties of late type stellar atmospheres. The strong delta v = 1 lines are sensitive probes of the thermal structure of the outer layers, which can be strongly affected by the CO, itself: cooling in the fundamental lines can depress the surface temperature to low values that are in sharp contrast with those derived from chromospheric diagnostics like Ca II K and Mg II k. Cool atmospheric models are being constructed to reproduce observed high resolution CO spectra of several late-type stars. The sensitivity is illustrated of CO LTE spectra to variations in T sub eff, log g, (Fe/H), and isotopic abundances of C and O for a grid of such models. In parallel, the assumptions of LTE line formation are tested using newly available cross sections for translational-to-vibrational energy exchange in collisions of atomic H on CO. In addition, spectra of CO and Ca II K calculated from semi-empirical UV based hot chromospheric models are used to estimate geometrical filling factors for the CO dominated and chromospheric regions on the stellar surface, in the spirit of Ayres' thermal bifurcation scenario.

Wiedemann, G.↗

Carbonates and sulfates in CI chondrites - Formation by aqueous activity on the parent body

Compositions and morphologies of dolomites, breunnerites, Ca-carbonates, Ca-sulfates and Mg, Ni, Na-sulfates, and their petrologic interrelations, in four CI chondrites are consistent with their having been formed by aqueous activity on the CI parent body. Radiochronometric data indicate that this activity took place very early in solar-system history. No evidence for original ('primitive') condensates seems to be present. However, alteration apparently took place without change in bulk meteorite composition.

Fredriksson, Kurt↗

M dwarfs from the Einstein extended medium sensitivity survey

A complete sample of X-ray selected M dwarfs are presented which were serendipitously detected in the extended Einstein Observatory Medium Sensitivity Survey (MSS). The MSS detected only early M dwarfs (type MO through M5), 84 percent of which were emission stars (i.e., type Me V). It was calculated that the X-ray luminosity function for early M dwarfs with a log Lx greater than 27.6 and, by comparison to optical luminosity functions, find that about 25 percent of all early M dwarfs emit X-rays at a level greater than log Lx = 27.6. This result is compared to luminosity function estimates from optically selected samples and discussed in light of the sample's kinematic and mean age. Also presented is H alpha and Ca II K line fluxes for each member of the sample and it is shown that the surface H alpha and Ca II K luminosities do indeed correlate with Lx. The significance of this effect to theories of chromospheric and coronal heating is explained.

Fleming, Thomas A.↗

Soil developments in polar deserts: Implications for exobiology and future Mars missions

Chemical alterations, weathering, and diagenesis of soil profiles from the dry valleys of Antarctica were studied as analogs of regolith development for the Martian regolith. Chemical weathering processes play an important part in soil development within the dry valleys of Antarctica. A suite of core samples were studied which were taken within the valley floors in addition to samples taken in the vicinity of evaporite and brine ponds. Analysis of water soluable cations and anions from core samples were performed along with petrographic analysis of selected samples. It was shown that ionic transport processes operate primarily above the permafrost zone. Abundances of the water soluable ions reflect the nature of secondary minerals produced by evaporation and weathering. Chloride, calcium, and sodium abundances for soils from the cores within the North and South Forks of Wright Valley, reflect the secondary mineralogy of the soil columns. Calculations for Na, Ca, and Cl abundances reflect the appearance of halite and antarcticite. In areas where excess Ca is present, X-ray diffraction studies show the presence of gypsum. It is well known that the Martian surface conditions may be favorable for chemical weathering. Primary silicates would be expected to be reactive with any ground water. It seems likely that Martian subsurface water is available to assist in the weathering of the primary minerals. Such weathering could result in the formation of clays, sulfates, carbonates, hydrates, halides, and zeolites. The dry valley cores have shown that they maybe excellent analogs to weathering processes on the near-surface of Mars. Since movement of water within the near-surface region clearly results in chemical weathering, leaching, and salt formation in the dry valleys, similar processes are probably operating within the Martian regolith.

Gibson, Everett K., Jr.↗

A remote mineralogic perspective on gabbroic units in the lunar highlands

Three lunar highland regions containing abundant high-Ca pyroxene are investigated in order to constrain the chemistry of the pyroxene assemblage of gabbroic regions and determine the state of gabbroic materials in the highland crust. The compositional gap between orthopyroxenes and clinopyroxenes noted in remote sensing observations corresponds to that found in lunar rock samples. It is found that Mg-gabbronorite or KREEP basalt with abundant high-Ca pyroxene are the most likely rock types of those thus far identified that may be responsible for gabbroic areas in the highlands. The western lunar highlands are shown to be distinct from the east in minerology.

Lucey, Paul G.↗