Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Associated Storage”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 865 records · Page 48

Electric vehicle post-crash Recovery—Stranded energy issues and mitigation strategy

In post-crash situations, passengers, bystanders, and first responders are exposed to the immediate safety risks of stranded energy in electric vehicle (EV) batteries. Stranded energy is the energy remaining inside any undamaged or damaged battery following an accident. A potentially damaged battery with an unknown state of safety might go into thermal runaway in the absence of proper monitoring, diagnostics, controls, and handling—thereby leading to potential loss of life and property damage. Therefore, it is imperative to develop standard guidelines, diagnostic methods, and tools to handle stranded energy appropriately and minimize safety risks from immediately after an EV accident to final disposal or re-entry to the road. This perspective paper identifies the challenges associated with handling stranded energy and proposes some potential solution pathways. Further, we hope to draw attention of the research and development community, original equipment manufacturers, and policymakers for motivating new insights and research needs in mitigating safety implications associated with stranded energy.

25 ENERGY STORAGE↗

Assessing Suitable Geologic Carbon Storage Sites Across Utah

Utah has a wealth of potential geological reservoirs for carbon dioxide storage (CS) and a long history of geologic research resulting in an abundance of available subsurface data to evaluate CS potential. Reservoirs may include sandstone, carbonate, and basalt; these rock types are plentiful in Utah’s subsurface and the complex Phanerozoic history throughout the state requires evaluating each geologic region individually for promising reservoir-seal pairs for CO2 storage. Classifying Utah by geologic provinces (or “geo-regions”) allows for customized thinking about suitable CS reservoir and seal distribution, CO2 point sources, land use, and existing infrastructure. Preliminary results from this study highlight the geologic CS potential across 15 geo-regions. Four regions stand out as having high CS potential: the Uinta Basin, San Rafael Swell, Paradox Basin, and the southern Basin and Range Province. The Uinta Basin and San Rafael Swell geo-regions are well suited for CS and have several projects ongoing to evaluate Cretaceous Frontier and Naturita Formations, Jurassic Navajo Sandstone and Entrada Sandstone, and Permian Weber Sandstone reservoir units that lie beneath robust sealing units like the ~5000-ft-thick Mancos Shale and Carmel Formation. Reservoirs such as the Navajo and Weber Sandstones have been demonstrated to be suitable reservoirs through a long history of oil and gas exploration in Utah. New areas of interest include the southern Basin and Range in southwest Utah, where the Jurassic Navajo Sandstone is overlain by the sealing Carmel Formation at suitable depths (>3000 ft), and has good porosities based on outcrop analogue data. Just to the north (e.g., central Basin and Range), legacy wells and 2D seismic data show possible salt and subsurface basalt flows that may provide additional possible CS reservoirs and seals. This geo-region also has the advantage of being coupled with geothermal energy resources that may be used to power burgeoning direct air capture technologies. In the Paradox Basin of southeastern Utah, the Leadville Limestone is a potential storage reservoir beneath the thick (4000–5000 ft), salt-bearing Pennsylvanian Paradox Formation. Although the northern and western parts of Utah offer CS potential, these areas typically contain less infrastructure and subsurface penetrations, creating geologic uncertainty associated with subsurface seals and reservoirs due to a lack of data. Overall, this statewide assessment and ranking is the first step to aid in evaluating CS potential across Utah and provides a foundation for future research in the most favorable locations.

58 GEOSCIENCES↗

Smart Composite Pressure Vessels (SCPV) with Integrated Health Monitoring

The U.S. Department of Energy (DOE) is promoting and developing more energy efficient and environmentally friendly technologies that will enable America to use less petroleum. Hydrogen fuel cells – which directly convert the chemical energy in hydrogen to electricity with only water and heat as byproducts – are a very attractive solution that can enable this to happen. To date, DOE's efforts have culminated in commercial demonstration of on-board vehicular hydrogen storage systems that can allow for a driving range of greater than 300 miles. This requires storing 5 Kgs of hydrogen onboard a light vehicle. In order to store this quantity of hydrogen, the hydrogen gas needs to be stored in a composite overwrapped pressure vessel (COPV) at a very high internal pressure. The objective of the program was to demonstrate continuous and predictable health-monitoring of composite pressure vessels. A higher confidence in the operational safety of the vessels will lead to reduced burst factor of safety imposed by regulatory standards and hence will help reduce the structural wall thickness that drives the cost of the vessel. Highly optimized Type III (metal lined) and Type IV (polymer lined) COPVs that are manufactured using filament winding process have been designed and qualified for the above mentioned application. However, the main structural component of the COPVs is carbon fiber and the high cost of carbon fiber composite in a pressure vessel is a primary challenge in reducing the cost of gaseous hydrogen storage. Continuous and remote monitoring of structural health of the COPVs as well as optimization of the strength translation of carbon fibers have the potential to allow for reduced factor of safety, thereby reduced amount of carbon and associated cost of the vessel. In the current program, the project team including Steelhead Composites (SHC), University of Tennessee, Knoxville (UTK), Teijin Carbon America, Oak Ridge National Laboratory (ORNL) and LUNA designed, fabricated, and tested smart composite pressure vessels with integrated sensors. Iterative loops of design and testing using coupons, subscale STEB vessels and full size vessels proved that a new generation of high performance carbon fiber can be used for efficient design of Type 3 vessels for H2 storage. Novel analysis techniques were developed to predict the initiation and propagation of interlaminar damage inside the composite shell due to impact damage, a real threat in practical operation. Such an analysis scheme is typically not used in tank design but is an essential tool for health monitoring of composite vessels. Remote sensing of the key signatures of the tank’s operating parameters such as pressure, acceleration and humidity was demonstrated using a unique device that can wirelessly transmit and stream the data to a remote server. Fiber optic sensors were successfully integrated during fabrication of the tanks. These sensors provide a wealth of information regarding the structural health of the vessel when it is subsequently pressurized or subjected to impact damage. Excellent correlation was demonstrated between the fiber optic sensor and mechanical strain gage data, and between the measurements and analytical predictions.

08 HYDROGEN↗

A design for a new catalog manager and associated file management for the Land Analysis System (LAS)

Due to the larger number of different types of files used in an image processing system, a mechanism for file management beyond the bounds of typical operating systems is necessary. The Transportable Applications Executive (TAE) Catalog Manager was written to meet this need. Land Analysis System (LAS) users at the EROS Data Center (EDC) encountered some problems in using the TAE catalog manager, including catalog corruption, networking difficulties, and lack of a reliable tape storage and retrieval capability. These problems, coupled with the complexity of the TAE catalog manager, led to the decision to design a new file management system for LAS, tailored to the needs of the EDC user community. This design effort, which addressed catalog management, label services, associated data management, and enhancements to LAS applications, is described. The new file management design will provide many benefits including improved system integration, increased flexibility, enhanced reliability, enhanced portability, improved performance, and improved maintainability.

Greenhagen, Cheryl↗

Bio-Nanobattery Development and Characterization

A bio-nanobattery is an electrical energy storage device that utilizes organic materials and processes on an atomic, or nanometer-scale. The bio-nanobattery under development at NASA s Langley Research Center provides new capabilities for electrical power generation, storage, and distribution as compared to conventional power storage systems. Most currently available electronic systems and devices rely on a single, centralized power source to supply electrical power to a specified location in the circuit. As electronic devices and associated components continue to shrink in size towards the nanometer-scale, a single centralized power source becomes impractical. Small systems, such as these, will require distributed power elements to reduce Joule heating, to minimize wiring quantities, and to allow autonomous operation of the various functions performed by the circuit. Our research involves the development and characterization of a bio-nanobattery using ferritins reconstituted with both an iron core (Fe-ferritin) and a cobalt core (Co-ferritin). Synthesis and characterization of the Co-ferritin and Fe-ferritin electrodes were performed, including reducing capability and the half-cell electrical potentials. Electrical output of nearly 0.5 V for the battery cell was measured. Ferritin utilizing other metallic cores were also considered to increase the overall electrical output. Two dimensional ferritin arrays were produced on various substrates to demonstrate the feasibility of a thin-film nano-scaled power storage system for distributed power storage applications. The bio-nanobattery will be ideal for nanometerscaled electronic applications, due to the small size, high energy density, and flexible thin-film structure. A five-cell demonstration article was produced for concept verification and bio-nanobattery characterization. Challenges to be addressed include the development of a multi-layered thin-film, increasing the energy density, dry-cell bionanobattery development, and selection of ferritin core materials to allow the broadest range of applications. The potential applications for the distributed power system include autonomously-operating intelligent chips, flexible thin-film electronic circuits, nanoelectromechanical systems (NEMS), ultra-high density data storage devices, nanoelectromagnetics, quantum electronic devices, biochips, nanorobots for medical applications and mechanical nano-fabrication, etc.

King, Glen C.↗

State Charlton & MRCSP 1 Characterization Well Report

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. This report describes the efforts to drill and complete a well in the St. Peter sandstone for characterization and evaluation of storage potential in norther Michigan. However, as presented in this report, the well was not drilled and completed up to the intended target intervals due to drilling related difficulties. While the drilling issues were being resolved, the new Class VI injection well regulations were finalized by the US EPA. MRCSP efforts focused on evaluating CO 2 storage and containment using site characterization, modeling, and monitoring in conjunction with the ongoing CO 2 -EOR operations in the same area. This report describes work associated with the initial test well, the State Chester and MRCSP Well No. 1, drilled to a depth of about 7,968 feet TVD, and subsequently plugged and designated as temporarily abandoned. A high-level overview of data collected and analyzed is provided for shallower units.

01 COAL, LIGNITE, AND PEAT↗

Laser-Based Means for Accelerating Nuclear Decay Rate

This project aims to replicate and build upon a reported series of results whereby nuclear decay of unstable species has been accelerated under laser irradiation in the presence of resonantly excited plasmonic nanoparticles. Most theoretical investigations of this problem do not predict the enhancement to be significant. Further, alternate explanations for the observed decrease in signals associated with the supposedly destroyed species need to be examined. There are potentially substantial benefits from exploiting this effect to reduce the long-term radiological storage requirements of certain forms of nuclear waste. These benefits merit the confirmation or disproving of the effect.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Performance and Cost Potential for Exemplar Direct Supercritical Carbon Dioxide Natural Gas Plants

This report presents the techno-economic analysis (TEA) optimization results of natural gas-fired utility-scale power plants based on the direct supercritical carbon dioxide (sCO 2 ) power cycle. To identify optimum plant configuration, the study also considered three different cases (Case A, Case B, Case C) with varying levels of thermal integration with the plant air separation unit (ASU). A fourth case (Case D), which is based on a patent from 8 Rivers, was also considered and includes thermal integration with the ASU as well as compressed recycle carbon dioxide (CO 2 ) gas. The four direct sCO 2 power plants offered similar or slightly higher plant efficiencies than the reference NGCC plants based on an F-class gas turbine with carbon capture and storage (CCS). LCOE of the direct sCO 2 plants is 13.5–17.2 percent higher than the reference NGCC plants with CCS due to higher capital costs associated with the ASU and sCO 2 power block. Recuperators make up over 50 percent of the power cycle costs. Consequently, any research and development (R&D) efforts to reduce the recuperator capital costs will be beneficial for the technology commercialization. The study also investigated the impact of co-firing landfill gas (LFG) and natural gas on plant efficiency, LCOE, and CO 2 emissions. Increasing the LFG co-firing from 0 percent to 50 percent (mass basis), decreased the plant efficiency by 0.3 percentage points and increased the LCOE by 3 percent. Due to high inherent CO 2 capture rates, direct sCO 2 plants have strong potential to achieve net-zero CO 2 emissions with LFG and natural gas co-firing.

03 NATURAL GAS↗

Analysis of Solar-Heated Thermal Wadis to Support Extended-Duration Lunar Exploration

The realization of the renewed exploration of the Moon presents many technical challenges; among them is the survival of lunar surface assets during periods of darkness when the lunar environment is very cold. Thermal wadis are engineered sources of stored solar energy using modified lunar regolith as a thermal storage mass that can enable the operation of lightweight robotic rovers or other assets in cold, dark environments without incurring potential mass, cost, and risk penalties associated with various onboard sources of thermal energy. Thermal wadi-assisted lunar rovers can conduct a variety of long-duration missions including exploration site surveys; teleoperated, crew-directed, or autonomous scientific expeditions; and logistics support for crewed exploration. This paper describes a thermal analysis of thermal wadi performance based on the known solar illumination of the moon and estimates of producible thermal properties of modified lunar regolith. Analysis was performed for the lunar equatorial region and for a potential Outpost location near the lunar south pole. The results are presented in some detail in the paper and indicate that thermal wadis can provide the desired thermal energy reserve, with significant margin, for the survival of rovers or other equipment during periods of darkness.

Balasubramaniam, R.↗

Zero-Trust Architecture for Autonomous Edge Computing

We are at the apex of an aviation revolution where autonomy will play a central role in enabling complex, multi-agent systems to communicate, interact, and collaborate on a myriad of applications spanning autonomous swarms to wild-fire management. Autonomy is not an absolute but rather a spectrum ranging from a system requiring significant human intervention to one requiring little to none [1]. For example, the extreme, in the case of an autonomous aircraft, is one that operates independently in the airspace interacting with all other elements (air traffic controllers, other pilots) as if it were a human pilot. Critical to this vision is an architecture that enables autonomous agents to interact with minimal latency. Edge computing is an emerging architecture where compute and storage is pushed to the ‘edge’ of the network in order to minimize the round-trip time from agent to resource thereby mitigating the latency associated with cloud-only based approaches. Additionally, services can generate massive amounts of data (e.g., video feeds), which may require analysis in near real-time. Moving this data to the cloud for further processing may not be feasible due to latency, bandwidth, and cost. Privacy, security, and reliability can also be improved by edge computing architectures. However, this geo-distributed and dynamic* architecture complicates the establishment of unambiguous network security boundaries and can lead to vulnerabilities including man in the middle attacks, replay attacks, physical security breaches of edge nodes, signal interception, etc. This motivates the need for zero-trust architectures [2–4] which de-emphasize the notion of static network perimeters and, as the name implies, do not instill any innate trust in any particular agent. It is required that all agents must be authorized and approved in every transaction. In this paper, we present a zero-trust architecture suitable for edge-computing applications that demand significant low-latency, security, privacy, and reliability.

zero trust↗

Validation of a Two-Phase CFD Model for Autogenous Pressurization and Expulsion

This paper presents a two-phase CFD model for tank pressurization and expulsion in a liquid hydrogen cryogenic storage tank. The model uses a Volume-of-Fluid approach combined with the Kinetics-based Schrage equation to capture the phase boundary and the associated interfacial heat, mass, and momentum transfer between the liquid and vapor regions. The CFD model is validated against expulsion data from the NASA K-Site tank experiment. Predicted tank pressures, temperatures, and pressurant requirements are compared with the experimental data to demonstrate the model’s accuracy.

Autogenous Pressurization↗

A Preliminary Study on the Use of a NASA Developed Coatings Technology for Protecting Natural Science Collections from Molecular Contaminants

Many museum conservators and collection managers are faced with the challenge of molecular contaminants that can promote the degradation of specimens on display in exhibits or in cabinets at storage facilities. This has prompted the need to explore innovative techniques to alleviate the presence of chemical species that originate from atmospheric off-gassing of materials or cross-contamination among collection items. For example, the Smithsonian Institution's National Museum of Natural History (NMNH) has tackled this problem for many years, specifically targeting contaminants, such as mercury vapor, at its Museum Support Center (MSC) storage facility in Suitland, Maryland. Similarly, the presence of molecular contaminants poses a significant threat for NASA science and exploration missions. The deposition of chemical species on sensitive surfaces can degrade the performance and operational lifetime of satellites, telescopes, and instruments. As a result, a sprayable zeolite-based coatings technology was designed to passively capture molecular contaminants and reduce the risks associated with material outgassing in vacuum environments for aerospace applications. This technology, called the Molecular Adsorber Coating (MAC), was developed at NASA Goddard Space Flight Center (GSFC). MAC has been extensively used during thermal vacuum chamber testing of various spaceflight hardware and components, such as for the James Webb Space Telescope (JWST). The coating is also planned to fly aboard upcoming NASA missions to address on-orbit outgassing concerns within instrument and laser cavities. Recently, the MAC technology was evaluated as a possible solution for protecting the Smithsonian Institution's natural science specimens, specifically its mineral ore and botany collections at the MSC storage facility. The initial year-long study between NASA GSFC and NMNH involved investigating the effectiveness of the MAC technology in capturing molecular contaminants that are present within the collections and storage cabinets at ambient, non-vacuum conditions. The work included sample fabrication, installation and retrieval efforts, testing efforts and associated challenges, preliminary findings, and future plans for the multi-year project.

conservation↗

Kimberlina 1.2 Velocity Models and Seismic Data

Kimberlina 1.2 Velocity model and synthetic seismic data, produced in collaboration of teams at the National Energy Technology Laboratory, Los Alamos National Laboratory, and Lawrence Livermore National Laboratory through the National Risk Assessment Partnership. Data is associated with the following publication: Zheng Zhou, Youzuo Lin, Zhongping Zhang, Yue Wu, Zan Wang, Robert Dilmore, and George Guthrie, "A Data-Driven CO2 Leakage Detection Using Seismic Data and Spatial-Temporal Densely Connected Convolutional Neural Networks," International Journal of Greenhouse Gas Control, Vol 90, 2019. The Kimberlina 1.2 Velocity models were produced by Zan Wang, Robert Dilmore, William Harbert, and Lianjie Huang at NETL. The following citations are directly related to the creation of the velocity models: Wang, Z. Harbert, W., Dilmore, R., Huang, L. Modeling of time-lapse seismic monitoring using CO2 leakage simulations for a model CO2 storage site with realistic geology: Application in assessment of early leak-detection capabilities. International Journal of Greenhouse Gas Control. V. 76, September 2018, Pages 39-52. https://doi.org/10.1016/j.ijggc.2018.06.011 Wang, Z., Dilmore, R., Harbert, W. Inferring CO2 saturation from synthetic surface seismic and downhole monitoring data using machine learning for leakage detection at CO2 sequestration sites. International Journal of Greenhouse Gas Control, V. 100, September 2020. https://doi.org/10.1016/j.ijggc.2020.103115 The velocity models were built based on the Kimberlina 1.2 aquifer impact data which is associated with the following publications: Buscheck, T.A., Mansoor, K., Yang, X., Wainwright, H., and Carroll, S. (2019). Downhole pressure and chemical monitoring for CO2 and brine leak detection in aquifers above a CO2 storage reservoir. International Journal of Greenhouse Gas Control. 91. 102812. 10.1016/j.ijggc.2019.102812. Xianjin Yang, Thomas A. Buscheck, Kayyum Mansoor, Zan Wang, Kai Gao, Lianjie Huang, Delphine Appriou, Susan A. Carroll, Assessment of geophysical monitoring methods for detection of brine and CO2 leakage in drinking water aquifers, International Journal of Greenhouse Gas Control, Volume 90, 2019, 102803, ISSN 1750-5836, https://doi.org/10.1016/j.ijggc.2019.102803 The synthetic seismic data was produced by Youzuo Lin and team at LANL, and are associated with the following citations: Jordan, P. D., and J. L. Wagoner. Characterizing Construction of Existing Wells to a CO2 Storage Target: The Kimberlina Site, California. Zheng Zhou, Youzuo Lin, Zhongping Zhang, Yue Wu, Zan Wang, Robert Dilmore, and George Guthrie, "A Data-Driven CO2 Leakage Detection Using Seismic Data and Spatial-Temporal Densely Connected Convolutional Neural Networks," International Journal of Greenhouse Gas Control, Vol 90, 2019.

CO2 Leakage↗

Control of the Structural Charge Distribution and Hydration State upon Intercalation of CO 2 into Expansive Clay Interlayers

Numerous experimental investigations indicated that expansive clays such as montmorillonite can intercalate CO 2 preferentially into their interlayers and therefore potentially act as a material for CO 2 separation, capture, and storage. However, an understanding of the energy–structure relationship during the intercalation of CO 2 into clay interlayers remains elusive. Here, in this study, we use metadynamics molecular dynamics simulations to elucidate the energy landscape associated with CO 2 intercalation. Our free energy calculations indicate that CO 2 favorably partitions into nanoconfined water in clay interlayers from a gas phase, leading to an increase in the CO 2 /H 2 O ratio in clay interlayers as compared to that in bulk water. CO 2 molecules prefer to be located at the centers of charge-neutral hydrophobic siloxane rings, whereas interlayer spaces close to structural charges tend to avoid CO 2 intercalation. The structural charge distribution significantly affects the amount of CO 2 intercalated in the interlayers. These results provide a mechanistic understanding of CO 2 intercalation in clays for CO 2 separation, capture, and storage.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Potential for Transactive Energy to Improve the Provisioning of Grid Services from Batteries

This study assessed the degree to which transactive energy systems could help reduce or remove barriers to the deployment of battery energy storage, and realize the full potential of battery resources to supply needed services to the grid and fairly compensate various types of battery owners. To enable this assessment, typical battery deployments were characterized, along with energy markets, Federal Energy Regulatory Commission Order rulings and implementations, grid services, and current deployment barriers. Finally, this study analyzed the value that accrues to batteries supplying today’s grid services as a function of the participation models associated with three primary types of battery ownership: merchant-owned transmission-connected batteries; utility-owned distribution-connected batteries; and customer-owned behind-the-meter batteries. This provided both quantitative and qualitative assessments comparing opportunities for battery storage in business-as-usual and transactive energy scenarios.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Subcooling Cryogenic Propellants for Long Duration Space Exploration

The use of cryogenic propellants such as hydrogen and oxygen is crucial for exploration of the solar system because of their superior specific impulse capability. Future missions may require vehicles with the flexibility to remain in orbit or travel in space for months, necessitating long-term storage of these cryogens. One powerful technique for easing the challenge of cryogenic fluid storage is to remove energy from tlie cryogenic propellant by isobaricly subcooling them below their normal boiling point prior to launch. The isobaric subcooling of the cryogenic propellant will be performed by using a cold pressurant to maintain the tank pressure while the cryogen's temperature is simultaneously reduced. After launch, even with the use of the best insulation systems, heat will leak into the cold cryogenic propellant tank. However, the large heat capacity available in highly subcooled cryogenic propellants allows them to absorb the energy that leaks into the tank until the cryogen reaches its operational thermodynamic condition. During this period of heating of the subcooled cryogen there will be no loss of the propellant due to venting for pressure control. This simple technique can extend the operational life of a spacecraft or an orbital cryogenic depot many months with minimal mass penalty. Subcooling technologies for cryogenic propellants would thus provide the Exploration Systems Mission Directorate with an enhanced level of mission flexibility. However, there are a few challenges associated with subcooling cryogenic propellants since compact subcooling ground support equipment has not been demonstrated. This paper explores the beneficial impact of subcooling cryogenic propellants on the launch pad for long-term cryogenic propellant storage in space and proposes a novel method for implementing subcooling of cryogenic propellants for spacecraft such as the Ares V Earth Departure Stage (EDS). Analysis indicates that with a careful strategy to handle the subcooled cryogen it would be possible to store cryogenic propellants in space for many months without venting. A concept for subcooling the cryogenic propellant relatively quickly and inexpensively on the launch pad - the thermodynamic cryogen subcooler (TCS) - will be presented. Important components of the TCS and an associated subcooled cryogen tank (SCT) will be discussed in this paper. Results from a preliminary thermodynamic model of the performance of a TCS for an EDS sized hydrogen tank will also be presented.

Mustafi, Shuvo↗

Disposition of Newly Generated Transuranic Waste at ORNL - 20107

ORNL operates the High Flux Isotope Reactor, which provides a high neutron source for production of isotopes for medical, industrial, and nuclear research programs and is the US DoE's center for production, storage, and distribution for TRU isotopes (plutonium through californium). Operation of these facilities results in the generation of CH-TRU and RH-TRU waste for disposal at the WIPP. This paper describes the program ORNL is implementing in collaboration with the Carlsbad Field Office National TRU Program Difficult Waste Team to disposition newly generated TRU waste. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Zigzag flow reactor for weekly thermochemical energy storage

This paper describes theoretical models and experimental performance of a novel Zigzag Flow Reactor (ZFR) for weekly thermochemical energy storage. The ZFR reduces redox-active metal oxide (MO x ) particles at high temperature (up to ~1100 °C) under inert gas sweep. A physical model demonstrates the approach to process equilibrium by minimizing the associated exergy destruction in a finite number of reaction steps, establishing the thermodynamic requirements for a practical reactor. The model results show several cost-relevant parameter tradeoffs, and the tradeoff analysis implies a cost-optimized set of boundary conditions. Numerical models and prototypes show that the ZFR enables significant gas phase homogenization while simultaneously enabling a customizable MO x residence time in the reactor, both key requirements for approaching an equilibrium process. A scaling model demonstrates the simplicity and affordability of sizing the ZFR to grid-scale levels, with fabrication costs at least five times lower than previously proposed scalable reactor concepts. As a result, a laboratory ZFR prototype achieved an energy storage density of ~90 Wh/kg with CaAl 0.2 Mn 0.8 O 3-δ as the MO x , at temperatures of ~850 °C in >10 h of total runtime.

Thermochemical energy storage↗