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At least 847 records · Page 47

Land Water Storage within the Congo Basin Inferred from GRACE Satellite Gravity Data

GRACE satellite gravity data is used to estimate terrestrial (surface plus ground) water storage within the Congo Basin in Africa for the period of April, 2002 - May, 2006. These estimates exhibit significant seasonal (30 +/- 6 mm of equivalent water thickness) and long-term trends, the latter yielding a total loss of approximately 280 km(exp 3) of water over the 50-month span of data. We also combine GRACE and precipitation data set (CMAP, TRMM) to explore the relative contributions of the source term to the seasonal hydrological balance within the Congo Basin. We find that the seasonal water storage tends to saturate for anomalies greater than 30-44 mm of equivalent water thickness. Furthermore, precipitation contributed roughly three times the peak water storage after anomalously rainy seasons, in early 2003 and 2005, implying an approximately 60-70% loss from runoff and evapotranspiration. Finally, a comparison of residual land water storage (monthly estimates minus best-fitting trends) in the Congo and Amazon Basins shows an anticorrelation, in agreement with the 'see-saw' variability inferred by others from runoff data.

Crowley, John W.↗

Open-Loop Control of Adjustable Tuned Mass Dampers for Floating Wind Turbine Platforms: Preprint

Floating offshore wind turbines have several advantages over their land-based counterparts, including access to stronger, more consistent winds and proximity to population centers. However, increased costs from the platform have been a challenge inhibiting their widespread adoption. New damping technologies with tunable target frequencies and damping ratios promise a greater degree of control over platform motions, allowing hulls to be designed smaller and reducing the overall cost of the turbines. In this work, a control strategy is proposed for these adjustable tuned mass dampers (TMDs). A frequency-domain model of the system is developed, from which response amplitude operators (RAOs) for the platform's rigid-body modes can be obtained for different natural frequencies and damping ratios of the dampers. Using these RAOs, and JONSWAP spectrums of operational and extreme sea states, the performance of the various damper settings are compared by evaluating the standard deviation of a rigid-body motion of interest (platform pitch or heave). By finding the optimal damper setting for a range of representative design load cases (DLCs), a lookup function is made to return the damper target frequency given the peak period of the sea state. To determine the current sea state, we propose a simple estimator that uses wave measurements (e.g., from a measurement buoy) to determine the peak period and significant wave height. The significant wave height is determined using the statistics of the past 100 seconds of wave elevation information and the peak period is computed using a frequency locked loop. Initial results show that we can use these estimated values to control the TMD natural frequency with an open loop controller. The controlled system is tested in a range of environmental conditions determined by the International Electrotechnical Commission design load cases (DLCs), which include normal and extreme wind and wave models. In these tests, we compare the performance of 4 cases: (1) no TMD, (2) a constant TMD based on the worst case DLC, (3) a controlled TMD based on known wind and wave environments, and (4) a real-time controlled TMD using estimated wind and wave environments. The effect of hull-based TMD control is also compared to changes in traditional wind turbine control via blade pitch.

control↗

Nonmodal Growth of TravelingWaves on Blunt Cones at Hypersonic Speeds

The existing database of transition measurements in hypersonic ground facilities has established that, as the nosetip bluntness is increased, the onset of boundary layer transition over a circular cone at zero angle of attack shifts downstream. However, this trend is reversed at sufficiently large values of the nose Reynolds number, so that the transition onset location eventually moves upstream with a further increase in nose-tip bluntness. Because modal amplification is too weak to initiate transition at moderate-to-large bluntness values, nonmodal growth has been investigated as the potential basis for a physics-based model for the frustum transition. The present analysis investigates the nonmodal growth of traveling disturbances initiated within the nose-tip vicinity that peak within the entropy layer. Results show that, with increasing nose bluntness, both planar and oblique traveling disturbances experience appreciable energy amplification up to successively higher frequencies. For moderately blunt cones, the initial nonmmodal growth is followed by a partial decay that is more than overcome by an eventual, modal growth as Mack-mode waves. For larger bluntness values, the Mack-mode waves are not amplified anywhere upstream of the experimentally measured transition location, but the traveling modes still undergo a significant amount of nonmodal growth. This finding does not provide a definitive link between optimal growth and the onset of transition, but it is qualitatively consistent with the experimental observations that frustum transition in the absence of sufficient Mack-mode amplification implies a double peak in disturbance amplification and the appearance of transitional events above the boundary-layer edge.

Hypersonic speed↗

Electrochemically in situ formed rocksalt phase in titanium dioxide determines pseudocapacitive sodium-ion storage

Earth-abundant TiO 2 is a promising negative electrode for low-cost sodium-ion batteries (SIBs) owing to its high capacity, rapid (dis)charging capability, safe operation potential and nonflammability. Crystalline anatase TiO 2 is not suitable for reversible Na + (de)intercalation, but it displays pseudocapacitive response after repeated cycles. Herein, we find and demonstrate that ordered rocksalt (RS) NaTiO 2 nanograins are in situ formed by electrochemically cycling with Na + ions in anatase and amorphous TiO 2 . The in situ formed RS-NaTiO 2 follows a solid-solution reaction with small volume changes of only 2.0%, that determines the pseudocapacitive “mirror-like” cyclic voltammetry curve with a couple of broad redox peaks at 0.75 V vs. Na + /Na, a high capacity of 253 mAh g −1 , high-rate capability and thousands of stable cycles. The multistep crystalline-to-amorphous-to-RS transformations are able to be electrochemically activated during the aging process of assembled full cells. Our finding provides a direction for developing unconventional Ti-based high-performance active materials for SIBs with both high energy and power densities.

Tang, Dafu [Xiamen University (China); Innovation ↗

Are Atmospheric Models Too Cold in the Mountains? The State of Science and Insights from the SAIL Field Campaign

Mountains play an outsized role in water resource availability, and the amount and timing of water they provide depend strongly on temperature. To that end, we ask the question: How well are atmospheric models capturing mountain temperatures? We synthesize results showing that high-resolution, regionally relevant climate models produce 2-m air temperature (T2m) measurements colder than what is observed (a “cold bias”), particularly in snow-covered midlatitude mountain ranges during winter. We find common cold biases in 44 studies across global mountain ranges, including single-model and multimodel ensembles. We explore the factors driving these biases and examine the physical mechanisms, data limitations, and observational uncertainties behind T2m. Our analysis suggests that the biases are genuine and not due to observation sparsity or resolution mismatches. Cold biases occur primarily on mountain peaks and ridges, whereas valleys are often warm biased. Our literature review suggests that increasing model resolution does not clearly mitigate the bias. By analyzing data from the Surface Atmosphere Integrated Field Laboratory (SAIL) field campaign in the Colorado Rocky Mountains, we test various hypotheses related to cold biases and find that local wind circulations, longwave (LW) radiation, and surface-layer parameterizations contribute to the T2m biases in this particular location. We conclude by emphasizing the value of coordinated model evaluation and development efforts in heavily instrumented mountain locations for addressing the root cause(s) of T2m biases and improving predictive understanding of mountain climates.

54 ENVIRONMENTAL SCIENCES↗

Are Atmospheric Models Too Cold in the Mountains? The State of Science and Insights from the SAIL Field Campaign

Mountains play an outsized role in water resource availability, and the amount and timing of water they provide depend strongly on temperature. To that end, we ask the question: How well are atmospheric models capturing mountain temperatures? We synthesize results showing that high-resolution, regionally relevant climate models produce 2-m air temperature (T2m) measurements colder than what is observed (a “cold bias”), particularly in snow-covered midlatitude mountain ranges during winter. We find common cold biases in 44 studies across global mountain ranges, including single-model and multimodel ensembles. We explore the factors driving these biases and examine the physical mechanisms, data limitations, and observational uncertainties behind T2m. Our analysis suggests that the biases are genuine and not due to observation sparsity or resolution mismatches. Cold biases occur primarily on mountain peaks and ridges, whereas valleys are often warm biased. Our literature review suggests that increasing model resolution does not clearly mitigate the bias. By analyzing data from the Surface Atmosphere Integrated Field Laboratory (SAIL) field campaign in the Colorado Rocky Mountains, we test various hypotheses related to cold biases and find that local wind circulations, longwave (LW) radiation, and surface-layer parameterizations contribute to the T2m biases in this particular location. We conclude by emphasizing the value of coordinated model evaluation and development efforts in heavily instrumented mountain locations for addressing the root cause(s) of T2m biases and improving predictive understanding of mountain climates.

54 ENVIRONMENTAL SCIENCES↗

The R-Process Alliance: Abundance Universality among Some Elements at and between the First and Second R-Process Peaks*

Abstract We present new observational benchmarks of rapid neutron-capture process ( r -process) nucleosynthesis for elements at and between the first ( A ∼ 80) and second ( A ∼ 130) peaks. Our analysis is based on archival ultraviolet and optical spectroscopy of eight metal-poor stars with Se ( Z = 34) or Te ( Z = 52) detections, whose r -process enhancement varies by more than a factor of 30 (−0.22 ≤ [Eu/Fe] ≤ +1.32). We calculate ratios among the abundances of Se, Sr through Mo (38 ≤ Z ≤ 42), and Te. These benchmarks may offer a new empirical alternative to the predicted solar system r -process residual pattern. The Te abundances in these stars correlate more closely with the lighter r -process elements than the heavier ones, contradicting and superseding previous findings. The small star-to-star dispersion among the abundances of Se, Sr, Y, Zr, Nb, Mo, and Te (≤0.13 dex, or 26%) matches that observed among the abundances of the lanthanides and third r -process-peak elements. The concept of r -process universality that is recognized among the lanthanide and third-peak elements in r -process-enhanced stars may also apply to Se, Sr, Y, Zr, Nb, Mo, and Te, provided the overall abundances of the lighter r -process elements are scaled independently of the heavier ones. The abundance behavior of the elements Ru through Sn (44 ≤ Z ≤ 50) requires further study. Our results suggest that at least one relatively common source in the early Universe produced a consistent abundance pattern among some elements spanning the first and second r -process peaks.

74 ATOMIC AND MOLECULAR PHYSICS↗

Excitation of solar p-modes

We investigate the rates at which energy is supplied to individual p-modes as a function of their frequencies nu and angular degrees l. The observationally determined rates are compared with those calculated on the hypothesis that the modes are stochastically excited by turbulent convection. The observationally determined excitation rate is assumed to be equal to the product of the mode's energy E and its (radian) line width Gamma. We obtain E from the mode's mean square surface velocity with the aid of its velocity eigenfuction. We assume that Gamma measures the mode's energy decay rate, even though quasi-elastic scattering may dominate true absorption. At fixed l, E(Gamma) arises as nu(exp 7) at low nu, reaches a peak at nu approximately equal 3.5 mHz, and then declines as nu(exp 4.4) at higher nu . At fixed nu, E(Gamma) exhibits a slow decline with increasing l. To calculate energy input rates, P(sub alpha), we rely on the mixing-length model of turbulent convection. We find entropy fluctuations to be about an order of magnitude more effective than the Reynolds stress in exciting p-modes . The calculated P(sub alpha) mimic the nu(exp 7) dependence of E(Gamma) at low nu and the nu(exp -4.4) dependence at high nu. The break of 11.4 powers in the nu-dependence of E(Gamma) across its peak is attributed to a combination of (1) the reflection of high-frequency acoustic waves just below the photosphere where the scale height drops precipitously and (2) the absence of energy-bearing eddies with short enough correlation times to excite high-frequency modes. Two parameters associated with the eddy correlation time are required to match the location and shape of the break. The appropriate values of these parameters, while not unnatural, are poorly constrained by theory. The calculated P(sub alpha) can also be made to fit the magnitude of E(Gamma) with a reasonable value for the eddy aspect ratio. Our resutls suggest a possible explanation for the decline of mode energy with increasing l at fixed nu. Entropy fluctuations couple to changes in volume associated with the oscillation mode. These decrease with decreasing n at fixed nu, becoming almost zero for the f-mode.

Goldreich, Peter↗

High-Latitude Thermosphere Neutral Density Response to Solar Wind Dynamic Pressure Enhancement

We examine the response of the thermosphere to the impact of solar wind dynamic pressure enhancements using observations and global magneto-hydrodynamics (MHD) simulations by the OpenGGCM model. Combining neutral density observations from the Challenging Minisatellite Payload (CHAMP) and the Gravity Recovery and Climate Experiment (GRACE) satellites with simultaneous Poynting flux measurements from the Defense Meteorological Satellite Program (DMSP) F16, we find that thermospheric density as well as downward Poynting flux intensified shortly after a sudden enhancement of the solar wind dynamic pressure. The intensification manifested mostly on the dayside high-latitude region with peak intensity in the vicinity of the noon and prenoon cusp. OpenGGCM modeling results show that the ionospheric Joule heating increased abruptly in response to the sudden enhancement of the dynamic pressure in the same region as the observed Poynting flux and neutral density enhancements. The modeling results show that the enhanced Joule heating coincides, both in time and location, with the appearance of a pair of high-latitude localized field-aligned currents (FACs) in the cusp region. The FACs intensified and extended azimuthally. Coincidental with the solar wind dynamic pressure enhancement, the y component of the interplanetary magnetic field (IMF) By became strongly positive and, in addition, had some large fluctuations. We explore the separate and combined effects of the dynamic pressure and IMF By perturbations, with specifically designed simulation experiments that isolate the effect of each solar wind parameter. We find that the dynamic pressure enhancement is the primary source for the Joule heating and neutral density enhancements, but the IMF By modulates the level of enhancement.

magneto-hydrodynamics↗

Gaining insight into lithium-ion battery degradation by a calorimetric approach

With the growing demand for lithium-ion batteries (LIBs) in transportation and renewable energy sectors, ensuring reliability and mitigating degradation are crucial challenges for their widespread deployment. Here this study investigates the relationship between thermal characteristics and degradation/reliability by developing an in-situ heat measurement methodology for LIBs operating under grid services. Using adiabatic mode-based calorimetry, we examine the thermal behavior of two commercial cells with different cathode chemistries (Ni-rich layered oxide and olivine) before and after two years of grid service (peak shaving) and demonstrate a strong correlation between thermal characteristics and electrochemical performance and its degradation. By further analyzing the heat sources separation (differentiating between irreversible and reversible heat), we disclose the underlying degradation mechanisms of LIBs. These findings emphasize the critical role of thermal characteristics in determining LIB reliability and deterioration, while the obtained heat data can aid in the development and calibration of LIB state-of-health models for grid applications.

25 ENERGY STORAGE↗

Horizon-scale variability of M87* from 2017–2021 EHT observations

Here, we report three epochs of polarized images of M87* at 230 GHz using data from the Event Horizon Telescope (EHT) taken in 2017, 2018, and 2021. The baseline coverage of the 2021 observations is significantly improved through the addition of two new EHT stations: the 12 m Kitt Peak Telescope and the Northern Extended Millimetre Array (NOEMA). All observations result in images dominated by a bright, asymmetric ring with a persistent diameter of 43.9 ± 0.6 µas, consistent with expectations for lensed synchrotron emission encircling the apparent shadow of a supermassive black hole. We find that the total intensity and linear polarization of M87* vary significantly across the three epochs. Specifically, the azimuthal brightness distribution of the total intensity images varies from year to year, as expected for a stochastic accretion flow. However, despite a gamma-ray flare erupting in M87 quasi-contemporaneously to the 2018 observations, the 2018 and 2021 images look remarkably similar. The resolved linear polarization fractions in 2018 and 2021 peak at ∼5%, compared to ∼15% in 2017. The spiral polarization pattern on the ring also varies from year to year, including a change in the electric vector position angle helicity in 2021 that could reflect changes in the magnetized accretion flow or an external Faraday screen. The improved 2021 coverage also provides the first EHT constraints on jet emission outside the ring, on scales of ≲ 1 mas. Overall, these observations provide strong proof of the reliability of the EHT images and probe the dynamic properties of the horizon-scale accretion flow surrounding M87*.

accretion, accretion disks↗

Influence of Pore Surface Structure and Contents on Shock-Induced Collapse and Energy Localization

The majority of computational efforts in the shockwave driven collapse of porosity focus on idealized pore geometries and structures. These give significant insight into the physical mechanisms in play, but omit some potentially important effects of real energetic materials. Here, to address this, we simulate pore collapse in 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) for four types of pore surfaces and fillings: an idealized cylindrical pore, a pore surface coated with polymer, a melted/amorphous pore surface, and a pore filled with gas molecules. We find that these perturbations to the pore structure result in only minor changes to the highly complex collapse mechanisms. However, significant differences in hotspot temperature are observed, with peak temperatures ranging over several hundred Kelvin. The polymer-coated system has the most effect, lowering the hotspot temperature by 300 K, and also limiting the manifestation of intramolecular strain energy that is known to induce mechanochemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Charge-transfer-enhanced d – d emission in antiferromagnetic NiPS3

The d electron plays a significant role in determining and controlling the properties of magnetic materials. However, the d electron transitions, especially d–d emission, have rarely been observed in magnetic materials due to the forbidden selection rules. Here, we report an observation of d–d emission in antiferromagnetic nickel phosphorus trisulfides (NiPS3) and its strong enhancement by stacking it with monolayer tungsten disulfide (WS2). We attribute the observation of the strong d–d emission enhancement to the charge transfer between NiPS3 and WS2 in the type-I heterostructure. The d–d emission peak splits into two peaks, D1 and D2, at low temperature below 150 K, from where an energy splitting due to the trigonal crystal field is measured as 105 meV. Moreover, we find that the d–d emissions in NiPS3 are nonpolarized lights, showing no dependence on the zigzag antiferromagnetic configuration. These results reveal rich fundamental information on the electronic and optical properties of emerging van der Waals antiferromagnetic NiPS3.

Physics↗

The primordial black holes that disappeared: connections to dark matter and MHz-GHz gravitational Waves

In the post-LIGO era, there has been a lot of focus on primordial black holes (PBHs) heavier than ~10 15 g as potential dark matter (DM) candidates. We point out that the branch of the PBH family that disappeared — PBHs lighter than ~10 9 g that ostensibly Hawking evaporated away in the early Universe — also constitute an interesting frontier for DM physics. Hawking evaporation itself serves as a portal through which such PBHs can illuminate new physics, for example by emitting dark sector particles. Here, taking a simple DM scalar singlet model as a template, we compute the abundance and mass of PBHs that could have provided, by Hawking evaporation, the correct DM relic density. We consider two classes of such PBHs: those originating from curvature perturbations generated by inflation, and those originating from false vacuum collapse during a first-order phase transition. For PBHs of both origins we compute the gravitational wave (GW) signals emanating from their formation stage: from second-order effects in the case of curvature perturbations, and from sound waves in the case of phase transitions. The GW signals have peak frequencies in the MHz-GHz range typical of such light PBHs. We compute the strength of such GWs compatible with the observed DM relic density, and find that the GW signal morphology can in principle allow one to distinguish between the two PBH formation histories.

79 ASTRONOMY AND ASTROPHYSICS↗

Excitons in strained and suspended monolayer WSe 2

Here, we study suspended membranes of atomically thin WSe 2 as hosts of excitons. We perform optical reflectance measurements to probe the exciton physics and obtain the peak energies for the 1$s$, 2$s$, and 3$s$ states of the $A$ exciton in suspended WSe 2 and consider supported membranes as a reference. We find that elimination of the influence of the dielectric environment enables a strong electron–hole interaction and a concomitant increase in the exciton binding energy in suspended monolayer (1L) WSe 2 . Based on the experimental results, we calculate the excitonic binding energies by employing the recently developed quantum electrostatic heterostructure model and the commonly employed Rytova–Keldysh potential model. We see that the binding energy of the ground state $A$ exciton increases from about 0.3 eV (on a substrate) to above 0.4 eV (suspended). We also exploit the tunability of the excitons in suspended samples via mechanical strain. By applying external gas pressure of 2.72 atm to a 1L suspended over a circular hole of 8 μm diameter, we strain the WSe 2 and obtain a reversible 0.15 eV redshift in the exciton resonance. The linewidth of the $A$ exciton decreases by more than half, from about 50 to 20 meV under 1.5% biaxial strain at room temperature. This line narrowing is due to the suppression of intervalley exciton–phonon scattering. By making use of the observed strain-dependent optical signatures, we infer the two-dimensional (2D) elastic moduli of 1L and 2L WSe 2 . Our results exemplify the use of suspended 2D materials as novel systems for fundamental studies, as well as for strong and dynamic tuning of their optical properties.

36 MATERIALS SCIENCE↗

Dynamical ejecta synchrotron emission as a possible contributor to the changing behaviour of GRB170817A afterglow

ABSTRACT Over the past 3 yr, the fading non-thermal emission from the GW170817 remained generally consistent with the afterglow powered by synchrotron radiation produced by the interaction of the structured jet with the ambient medium. Recent observations by Hajela et al. indicate the change in temporal and spectral behaviour in the X-ray band. We show that the new observations are compatible with the emergence of a new component due to non-thermal emission from the fast tail of the dynamical ejecta of ab-initio binary neutron star merger simulations. This provides a new avenue to constrain binary parameters. Specifically, we find that equal mass models with soft equations of state (EOSs) and high-mass ratio models with stiff EOSs are disfavoured as they typically predict afterglows that peak too early to explain the recent observations. Moderate stiffness and mass ratio models, instead, tend to be in good overall agreement with the data.

79 ASTRONOMY AND ASTROPHYSICS↗

Binary neutron star mergers as a probe of quark-hadron crossover equations of state

It is anticipated that the gravitational radiation detected in future gravitational wave (GW) detectors from binary neutron star (NS) mergers can probe the high-density equation of state (EOS). In this work, we perform the first simulations of binary NS mergers which adopt various parametrizations of the quark-hadron crossover (QHC) EOS. These are constructed from combinations of a hadronic EOS ($n_b$<2 $n_0$) and a quark-matter EOS ($n_b$>5 $n_0$), where $n_b$ and $n_0$ are the baryon number density and the nuclear saturation density, respectively. At the crossover densities (2 $n_0$ < $n_b$ < 5 $n_0$) the QHC EOSs continuously soften, while remaining stiffer than hadronic and first-order phase transition EOSs, achieving the stiffness of strongly correlated quark matter. This enhanced stiffness leads to significantly longer lifetimes of the postmerger NS than that for a pure hadronic EOS. We find a dual nature of these EOSs such that their maximum chirp GW frequencies $f_{\text{max}}$ fall into the category of a soft EOS while the dominant peak frequencies ($f_{\text{peak}}$) of the postmerger stage fall in between that of a soft and stiff hadronic EOS. An observation of this kind of dual nature in the characteristic GW frequencies will provide crucial evidence for the existence of strongly interacting quark matter at the crossover densities for QCD.

79 ASTRONOMY AND ASTROPHYSICS↗

Appendices for Geothermal Exploration Artificial Intelligence Report

The Geothermal Exploration Artificial Intelligence looks to use machine learning to spot geothermal identifiers from land maps. This is done to remotely detect geothermal sites for the purpose of energy uses. Such uses include enhanced geothermal system (EGS) applications, especially regarding finding locations for viable EGS sites. This submission includes the appendices and reports formerly attached to the Geothermal Exploration Artificial Intelligence Quarterly and Final Reports. The appendices below include methodologies, results, and some data regarding what was used to train the Geothermal Exploration AI. The methodology reports explain how specific anomaly detection modes were selected for use with the Geo Exploration AI. This also includes how the detection mode is useful for finding geothermal sites. Some methodology reports also include small amounts of code. Results from these reports explain the accuracy of methods used for the selected sites (Brady Desert Peak and Salton Sea). Data from these detection modes can be found in some of the reports, such as the Mineral Markers Maps, but most of the raw data is included the DOE Database which includes Brady, Desert Peak, and Salton Sea Geothermal Sites.

15 GEOTHERMAL ENERGY↗