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NASA NTRS1998

The Effects of Ground and Space Processing on the Properties of Organic, Polymeric, and Colloidal Materials

In recent years, a great deal of interest has been directed toward the use of organic materials in the development of high-efficiency optoelectronic and phototonic devices. There is a myriad of possibilities among organic materials which allow flexibility in the design of unique structures with a variety of functional groups. The use of nonlinear optical (NLO) organic materials as thin film wave-guides allows full exploitation of their desirable qualifies by permitting long interaction lengths and large susceptibilities allowing modest power input. There are several methods in use to prepare thin films such as Langmuir-Blodgett (LB) and self-assembly techniques, vapor deposition, growth from sheared solution or melt, and melt growth between glass plates. Organic-based materials have many features that make them desirable for use in optical devices, such as high second-and third-order nonlinearity, flexibility of molecular design, and damage resistance to optical radiation. However, their use in devices has been hindered by processing difficulties for crystals and thin films. We discuss the potential role of microgravity processing of a few organic and polymeric materials. It is of interest to note how materials with second-and third-order NLO behavior may be improved in a diffusion-limited environment and ways in which convection may be detrimental to these materials. We focus our discussion on third-order materials for all-optical switching, and second-order materials for frequency conversion and electrooptics. The goal of minimizing optical loss obviously depends on processing methods. For solution-based processes, such as solution crystal growth and solution photopolymerization, it is well known that thermal and solutal density gradients can initiate buoyancy-driven convection. Resultant fluid flows can affect transport of material to and from growth interfaces and become manifest in the morphology and homogeneity of the growing film or crystal. Likewise, buoyancy-driven convection can hinder production of defect-free, high-quality crystals or films during crystal and film growth by vapor deposition.

Frazier, Donald O.↗

NASA NTRS1995

Polyimides Made From PDMDA

Thermally stable linear aromatic polyimides with improved optical, electrical, and processing characteristics made from 3,3'-bis(3,4-dicarboxyphenoxy)diphenylmethane dianhydride (PDMDA). Made in form of powders that can be dissolved to cast thin films. Potentially useful as coating and matrix materials. Films made vary from transparent to pale yellow. Greater degrees of transparency and lower dielectric constants make these polyimides more suitable for use in some electronic and optical applications; e.g., as insulating materials on wires and protective films on solar photovoltaic cells.

St. Clair, Anne K.↗

NASA NTRS2006

Microwave Oscillators Based on Nonlinear WGM Resonators

Optical oscillators that exploit resonantly enhanced four-wave mixing in nonlinear whispering-gallery-mode (WGM) resonators are under investigation for potential utility as low-power, ultra-miniature sources of stable, spectrally pure microwave signals. There are numerous potential uses for such oscillators in radar systems, communication systems, and scientific instrumentation. The resonator in an oscillator of this type is made of a crystalline material that exhibits cubic Kerr nonlinearity, which supports the four-photon parametric process also known as four-wave mixing. The oscillator can be characterized as all-optical in the sense that the entire process of generation of the microwave signal takes place within the WGM resonator. The resonantly enhanced four-wave mixing yields coherent, phase-modulated optical signals at frequencies governed by the resonator structure. The frequency of the phase-modulation signal, which is in the microwave range, equals the difference between the frequencies of the optical signals; hence, this frequency is also governed by the resonator structure. Hence, further, the microwave signal is stable and can be used as a reference signal. The figure schematically depicts the apparatus used in a proof-of-principle experiment. Linearly polarized pump light was generated by an yttrium aluminum garnet laser at a wavelength of 1.32 microns. By use of a 90:10 fiber-optic splitter and optical fibers, some of the laser light was sent into a delay line and some was transmitted to one face of glass coupling prism, that, in turn, coupled the laser light into a crystalline CaF2 WGM disk resonator that had a resonance quality factor (Q) of 6x10(exp 9). The output light of the resonator was collected via another face of the coupling prism and a single-mode optical fiber, which transmitted the light to a 50:50 fiber-optic splitter. One output of this splitter was sent to a slow photodiode to obtain a DC signal for locking the laser to a particular resonator mode. The other output of this splitter was combined with the delayed laser signal in another 50:50 fiber-optic splitter used as a combiner. The output.of the combiner was fed to a fast photodiode that demodulated light and generated microwave signal. In this optical configuration, the resonator was incorporated into one arm of a Mach-Zehnder interferometer, which was necessary for the following reasons: It was found that when the output of the resonator was sent directly to a fast photodiode, the output of the photodiode did not include a measurable microwave signal. However, when the resonator was placed in an arm of the interferometer and the delay in the other arm was set at the correct value, the microwave signal appeared. Such behavior is distinctly characteristic of phase-modulated light. The phase-modulation signal had a frequency of about 8 GHz, corresponding to the free spectral range of the resonator. The spectral width of this microwave signal was less than 200 Hz. The threshold pump power for generating the microwave signal was about 1 mW. It would be possible to reduce the threshold power by several orders of magnitude if resonators could be made from crystalline materials in dimensions comparable to those of micro-resonators heretofore made from fused silica.

Maleki, Lute↗

NASA NTRS1985

Polarization of light scattered by vegetation

The potential information in polarization data of both single leaves and plant canopies is investigated. Measurements demonstrate the relationship between polarization data and various optical and botanical properties of both pieces of foliage and plant canopies. The results provide a basis for gaining fundamental understanding of how light is scattered and polarized by a plant canopy. The results show the polarized and nonpolarized portions of the light scattered by a remotely sensed ground scene potentially are independent sources of information for discriminating species and assessing the condition of plant canopies.

Vanderbilt, V. C.↗

NASA NTRS2003

Measurement of Characteristics of Micron Size Individual Dust Particles of Astrophysical Interest

A laboratory facility for levitating single isolated dust particles in an electrodynamic balance has been developed at NASA's Marshall Space Flight Center for conducting studies of the physical and optical properties of the analogs of interstellar and interplanetary dust grains of 0.2-20 micron size under controlled pressures/temperatures simulating astrophysical environments. We plan three classes of experiments using this facility: (1) Charge characteristics of micron size single dust grains: The photoelectric efficiencies, yields, and equilibrium potentials when exposed to UV radiation found from these measurements will provide much-needed photoelectric emission data for individual dust particles; (2) Infrared optical properties of dust particles: Specifically, we will determines the complex refractive indices, the extinction coefficients, the scattering phase functions, and the polarization properties of single dust grains of interest in interstellar environments, in the 1- 25 micron spectral region; (3) Condensation experiments to investigate the deposition of volatile gases on colder nucleated particles in dense interstellar clouds and lower planetary atmospheres: The measured data will permit determination of the sticking efficiencies of volatile gases of astrophysical interest. Brief descriptions of the experimental setup for the last two classes of experiments will be given. We will present results of measurements of photoelectric emission using 0.2-6.6 micron size silica particles exposed to UV radiation at 120-200 nm and also results of radiation pressure measurements using the same size silica particles and laser light at 5320 Angstrom.

Craven, P. D.↗

NASA NTRS2008

Optical Communications from Planetary Distances

Future planetary campaigns, including human missions, will require data rates difficult to realize by microwave links. Optical channels not only provide an abundance of bandwidth, they also allow for significant size, weight, and power reduction. Moreover, optical-based tracking may enhance spacecraft navigation with respect to microwave-based tracking. With all its advantages, optical communications from deep space is not without its challenges. Due to the extreme distance between the two ends of the link, specialized technologies are needed to enable communications in the deep space environment. Although some of the relevant technologies have been developed in the last decade, they remain to be validated in an appropriate domain. The required assets include efficient pulsed laser sources, modulators, transmitters, receivers, detectors, channel encoders, precise beam pointing technologies for the flight transceiver and large apertures for the ground receiver. Clearly, space qualification is required for the systems that are installed on a deep space probe. Another challenge is atmospheric effects on the optical beam. Typical candidate locations on the ground have a cloud-free line of sight only on the order of 60-70% of the time. Furthermore, atmospheric losses and background light can be problematic even during cloud-free periods. Lastly, operational methodologies are needed for efficient and cost effective management of optical links. For more than a decade, the National Aeronautics and Space Administration (NASA) has invested in relevant technologies and procedures to enable deep space optical communications capable of providing robust links with rates in the order of 1 Gb/s from Mars distance. A recent publication indicates that potential exists for 30-dB improvement in performance through technology development with respect to the state-of-the-art in the early years of this decade. The goal is to fulfill the deep space community needs from about 2020 to the foreseeable future. It is envisioned that, at least initially, optical links will be complemented by microwave assets for added robustness, especially for human missions. However, it is expected that as optical techniques mature, laser communications may be operated without conventional radio frequency links. The purpose of this paper is to briefly review the state-of-the-art in deep space laser communications and its challenges and discuss NASA-supported technology development efforts and plans for deep space optical communications at JPL.

Laser Communications↗

NASA NTRSDate not supplied

A Photonic Clockwork for Deployed Timing and Radar

We present an environmentally robust photonic RF/microwave clockwork with low size, weight, and power (SWaP) for next-generation, field-deployable timing and radar applications. Compared to microwave references, optical local oscillators offer superior fractional frequency stability and phase-noise performance. When transferred with high fidelity into the RF/microwave domain, this “optical advantage” promises unparalleled performance across both private-industry and government (e.g., defense and space-agency) applications including very-long-baseline interferometry (VLBI), alternative positioning, navigation, and timing (PNT), multi-static synthetic aperture radar (MSAR), and geodetic sensing. However, this potential has yet to be fully realized outside the metrology lab primarily due to the high-SWaP and excessive environmental susceptibility of both the optical reference itself as well as the optical frequency comb (OFC) required to transfer the optical stability into the RF/microwave domain. Here, we present two demonstrations of a low-SWaP, environmentally robust photonic clockwork used to make a high-fidelity optical-microwave link with the stability and phase-noise performance relevant to the applications described above. Additionally, operational-testing results of the OFC subsystem under application-relevant environmental conditions will be presented to show pathway to field deployment of this critical subsystem.

Guangning Yang↗

NASA NTRS1980

Curves of growth for van der Waals broadened spectral lines

Curves of growth are evaluated for a spectral line broadened by the van der Waals interactions during collisions. The growth of the equivalent widths of such lines is shown to be dependent on the product of the perturber density and the 6/10 power of the van der Waals potential coefficient. When the parameter is small, the widths grow as the 1/2 power of the optical depth as they do for the Voigt profile: but when the parameter is large, they grow as 2/3 power and, hence, faster than the Voigt profile. An approximate analytical expression for the computed growth characteristics is given.

Park, C.↗

NASA NTRS1984

Determination of the mass of globular cluster X-ray sources

The precise positions of the luminous X-ray sources in eight globular clusters have been measured with the Einstein X-Ray Observatory. When combined with similarly precise measurements of the dynamical centers and core radii of the globular clusters, the distribution of the X-ray source mass is determined to be in the range 0.9-1.9 solar mass. The X-ray source positions and the detailed optical studies indicate that (1) the sources are probably all of similar mass, (2) the gravitational potentials in these high-central density clusters are relatively smooth and isothermal, and (3) the X-ray sources are compact binaries and are probably formed by tidal capture.

Grindlay, J. E.↗

NASA NTRS1990

Theoretical models of gas dynamics and star formation in interacting ring galaxies

A series of one and two dimensional hydrodynamic simulations of a ring wave in interstellar gas disks was completed. These calculations included nonlinear source terms to model the effects of interstellar interactions and star formation, as well as the spatial-temporal gas flow. Toomre's kinematical model was merged with the Arnold, Shandarin, and Zeldovich 'pancake' theory of caustics in galaxy formation. The resulting theory can describe almost all the structure in restricted three-body simulations of single-pass collisions, even with multi-component potentials. Off-center galactic collisions were studied to understand the dynamics involved. Multi-color optical and near-infrared observations of faint tidal features were performed in about two dozen interacting galaxies selected from the Arp atlas. This sample provided evidence for ongoing star formation in tidal structures, and even enhancements of star formation in some cases. The task of assembling the data for gas-rich, late-type galaxies, was undertaken to see if a more coherent picture of the gas distribution would emerge from the more complete data. Analytic solutions of the equations with subsonic flows to balance gas consumption for expulsion form a galactic fountain were also derived.

Struck-Marcell, Curtis↗

NASA NTRS1990

New screening methodology to select low outgassing materials for cold, spaceborne optical instruments

Standardized techniques for outgassing tests are developed and set forth for use in the screening of materials for aerospace instruments with cooled sensors, optics, and/or detectors. Materials for optical instruments are discussed in terms of molecular outgassing, and material-outgassing test results are presented which relate to several test conditions. The existing outgassing standard is found to be inadequate, and revised outgassing standards related to four application levels are given. The test protocols are designed for the development of materials for optical instruments that operate in environments with temperatures below 20 C. Consideration is also given to potential molecular contamination in the space environment and to outgas screening of instruments with a variety of sensor/optics/detector temperatures. The standards are designed for use with existing outgassing-test data as well as contamination analyses relating to the instrument being tested.

O'Donnell, T.↗

NASA NTRS1993

Three-Point Gear/Lead Screw Positioning

Triple-ganged-lead-screw positioning mechanism drives movable plate toward or away from fixed plate and keeps plates parallel to each other. Designed for use in tuning microwave resonant cavity. Other potential applications include adjustable bed plates and cantilever tail stocks in machine tools, adjustable platforms for optical equipment, and lifting platforms.

Calco, Frank S.↗

NASA NTRS1992

Advanced one-dimensional optical strain measurement system, phase 4

An improved version of the speckle-shift strain measurement system was developed. The system uses a two-dimensional sensor array to maintain speckle correlation in the presence of large off-axis rigid body motions. A digital signal processor (DSP) is used to calculate strains at a rate near the RS-170 camera frame rate. Strain measurements were demonstrated on small diameter wires and fibers used in composite materials research. Accurate values of Young's modulus were measured on tungsten wires, and silicon carbide and sapphire fibers. This optical technique has measured surface strains at specimen temperatures above 750 C and has shown the potential for measurements at much higher temperatures.

Lant, Christian T.↗

NASA NTRS1993

High-speed ultraviolet photometry of HD 60435

We present the first high-speed ultraviolet photometry of an oscillating Ap star, HD 60435. After removing known orbital effects related to the Hubble Space Telescope, we confirm the presence of a strong pulsation period at a frequency of 123.70 cycles per day. In addition, we find significant amplitude modulation of this frequency that we suggest could be the result of beating of multiple periodicities. In this context, we suggest evidence for the presence of four additional frequencies at nu = 120.56, 126.55, 149.49, and 221.03 cycles per day. Three of these frequencies correspond well to frequencies detected in optical observations of HD 60435. The fourth, at 149.49 cycles per day, if real, is a potentially new pulsation mode that has not been detected in ground-based observations of this star. The amplitude of the 123 cycles per day pulsation is significantly larger in the ultraviolet than it is in the blue.

Taylor, M.↗

NASA NTRS1998

Johnson Space Center Research and Technology 1997 Annual Report

This report highlights key projects and technologies at Johnson Space Center for 1997. The report focuses on the commercial potential of the projects and technologies and is arranged by CorpTech Major Products Groups. Emerging technologies in these major disciplines we summarized: solar system sciences, life sciences, technology transfer, computer sciences, space technology, and human support technology. Them NASA advances have a range of potential commercial applications, from a school internet manager for networks to a liquid metal mirror for optical measurements.

Source record↗

NASA NTRS1999

A Study of Flame Propagation on Water-Mist Laden Gas Mixtures in Microgravity

The use of water mists (very fine water sprays) for fire suppression is currently receiving increased attention as a replacement technology for halogen-based chemical agents-such as Halon 1301 (CF3Br)--the manufacturing of which has been banned by the Montreal Protocol due to their high ozone depletion potential. Water mist technology has been found effective for a wide range of applications such as Class B pool fires, shipboard machinery, aircraft cabins, computers, and electronic equipment. There are five distinct mechanisms by which water droplets may interact with a flame. First, the high enthalpy of vaporization of water (2450 kJ/kg) leads to heat removal from the flame front as the liquid droplets turn to steam. Second, as water vaporizes its volume increases approximately three orders of magnitude, which leads to the dilution of the oxygen and vaporized fuel required to maintain the flame. The third effect is the recombination of H-atoms and other radicals on the droplet surface. A fourth effect of water mists in fires is the retardation of surface propagation rates due to the wetting of walls and surfaces. The last potential impact of fine water mists affects the radiative propagation of the fire by forming an optically thick barrier to infrared radiation which prevents ignition of the unburned regions. Unfortunately, little fundamental information exists on the interaction of a flame with a water mist. To date, there is no widely accepted interpretation of the critical concentration of droplets required to suppress a flame or of the fundamental mechanisms involved in flame extinguishment by water mists. One of the main obstacles to obtaining such understanding is the difficulty of providing a simple, well-defined experimental setup for the flame front/water mist interaction. Some of the difficulty stems from the problem of generating, distributing and maintaining a homogeneous concentration of droplets throughout a chamber while gravity depletes the concentration and alters the droplet size by coalescence and agglomeration mechanisms. Experiments conducted in the absence of gravity provide an ideal environment to study the interaction of water mists and flames by eliminating these distorting effects. In addition, microgravity eliminates the complex flow patterns induced between the flame front and the water droplets. The long duration and quality of microgravity in space flights provide the required conditions to perform the setup and monitoring of flame suppression experiments. Consequently, a series of experiments have been identified to be performed on the Combustion Module (CM-2) in the Space Shuttle. These consist of measuring the extinguishing capability of a water mist on a premixed flame propagating along a tube. These experiments should provide the necessary data to obtain further understanding of the water mist suppression phenomena that can be later used to design and manufacture appropriate fire suppression systems. In preparation for the orbital flights, experiments have been conducted on low-gravity ground facilities to obtain the preliminary data necessary to define the scientific objectives and technical issues of the spacecraft experiments.

Abbud-Madrid, A.↗

NASA NTRS1999

The Effect of Magnetic Fields on Gamma-Ray Bursts Inferred from Multi-Wavelength Observations of the Bursts of 23 January 1999

Gamma-ray bursts (GRBs) are thought to arise when an extremely relativistic outflow of particles from a massive explosion (the nature at which is still unclear) interacts with material surrounding the site of the explosion. Observations of the evolving changes in emission at many wavelengths allow us to investigate the origin of the photons, and so potentially determine the nature of the explosion. Here we report the results of gamma-ray, optical, infrared, submillimeter, millimeter and radio observations of the burst ORB990123 and its afterglow. Our interpretation of the data indicates that the initial and afterglow emissions are associated with three distinct regions in the fireball. The peak flux of the afterglow, one day after the burst, has a lower frequency than observed for other bursts; this explains the short-lived radio emission. We suggest that the differences between bursts reflect variations in the magnetic-field strength in the afterglow-emitting regions.

Galama, T. J.↗

NASA NTRS2001

NASA Electronic Parts and Packaging (NEPP): Space Qualification Guidelines of Optoelectronic and Photonic Devices for Optical Communication Systems

Key elements of space qualification of opto-electric and photonic optical devices were overviewed. Efforts were concentrated on the reliability concerns of the devices needed for potential applications in space environments. The ultimate goal for this effort is to gradually establish enough data to develop a space qualification plan of newly developed specific photonic parts using empirical and numerical models to assess the life-time and degradation of the devices for potential long term space missions.

Kim, Quiesup↗