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At least 847 records · Page 47

A hybrid CoOOH-rGO/Fe 2 O 3 photoanode with spatial charge separation and charge transfer for efficient photoelectrochemical water oxidation

As a promising photoanode for photoelectrochemical (PEC) water oxidation, hematite (Fe 2 O 3 ) still suffers from poor charge mobility and serious charges recombination and sluggish surface oxygen evolution kinetics. Herein, a hybrid photoanode of cobalt (oxy)hydroxide coupled with reduced graphene oxide modified Fe 2 O 3 (CoOOH-rGO/Fe 2 O 3 ) is well crafted by a facile hydrothermal synthesis with a chelation-mediated in-situ growth method. Morphology characterizations indicate rGO forms the internal network among isolated Fe 2 O 3 and CoOOH nanosheets distribute on the terminal of Fe 2 O 3 , forming a spatial separated nanostructure. The resultant CoOOH-rGO/Fe 2 O 3 exhibits an obviously reduced onset potential of ca. 150 mV and a significantly enhanced photocurrent density of 2.56 mA cm -2 at 1.23 V, which is ca. 3.3 times higher than that of bare Fe 2 O 3 . Especially, the functions of rGO and CoOOH are studied by using electrochemical impedance spectroscopy, open circuit potentials and intensity modulated photocurrent spectroscopy. It is found rGO act as conductive network which facilitates the electron transfer from Fe 2 O 3 to the substrate, while CoOOH evidently passivate the surface states of Fe 2 O 3 , improve charge separation and provide catalytic active sites for water oxidation. Additionally, the spatial charge separation and charge transfer caused by CoOOH and rGO are responsible for the enhanced PEC performance of water oxidation. The rational design and the facile fabrication strategy exhibit great potential to be used for other PEC system with great efficiency.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cohesive phase-field chemo-mechanical simulations of inter- and trans- granular fractures in polycrystalline NMC cathodes via image-based 3D reconstruction

The optimal design and durable utilization of lithium-ion batteries necessitates an objective modeling approach to understand fracture and failure mechanisms. This paper presents a comprehensive chemo-mechanical modeling study focused on elucidating fracture-induced damage and degradation phenomena in the polycrystalline Li $\mathcal{x}$ Ni 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) cathode. An innovative approach that utilizes image-based reconstructed 3D geometry as finite element (FE) mesh input is employed to enhance the precision in capturing the convoluted architecture and morphological features. For accurately representing the intricate crack configurations within the polycrystalline system, we adopted the cohesive phase-field fracture (CPF) model. Through the integration of advanced image-based geometry reconstruction technique and the promising CPF modeling approach, lithium (de)intercalation induced crack evolution (e.g., nucleation, propagation, branching and diverse modes including inter-/trans-(intra-) granular patterns) and the resulting chemical degradation can be precisely captured, which is also compared and validated with numerical predictions using a continuum damage model. In particular, this model predicts fracture induced degradation under varying fracture properties of grain boundaries and charging rates; the conclusion that NMC particles comprised of larger grains are predicted to have less degradation than those with smaller grains can also be drawn. This comprehensive analysis provides valuable insights into the fracture and degradation within polycrystalline NMC cathodes.

25 ENERGY STORAGE↗

Synergistic Evolution of Segmental Motion and Cooperative Relaxation within the Amorphous Phase of Organic Mixed Ionic-Electronic Conductors

Organic mixed ionic-electronic conductors (OMIECs) facilitate a variety of electrochemical processes and feature a heterogeneous microstructure composed of both crystalline and amorphous phases. However, structural evolution in amorphous regions during electrochemical doping remains poorly understood, limiting our understanding of mixed conduction mechanisms. Here, in this work, we develop operando chip calorimetry to probe amorphous phase evolution in poly­(3,4-ethylenedioxythiophene):poly­(styrenesulfonate) (PEDOT:PSS) under swelling and electrochemical (de)­doping. Our results reveal that amorphous regions providing ionic transport pathways and those within electronic transport channels undergo heterogeneous, yet synergistic, evolution during electrochemical modulation. The cooperative interplay between segmental motion and relaxation maintains ionic conductivity and intergrain electronic transport upon electrowetting and doping, while facilitating efficient ion hopping and adaptable chain conformations during dedoping. Such synergies are more pronounced in loose structures featuring a fibrillar morphology, which exhibit lower glass transition temperatures (T g ) and higher fragility (m). High-throughput robotic screening further establishes a strong correlation between elevated m/T g ratios and enhanced mixed conduction. These findings elucidate the role of the amorphous phase in the synthesis of OMIECs and underscore the potential of operando chip calorimetry in uncovering structure–property relationships in electroactive polymers.

amorphous phase↗

Landsat Thematic Mapper observations of debris avalanche deposits in the Central Andes

Remote sensing with the Landsat Thematic Mapper of debris avalanche deposits in the Central Andes between 18 and 27 deg S revealed, for the first time, the presence of 28 breached volcanic cones and 11 major volcanic debris avalanche deposits, several of which cover areas in excess of 100 sq km. It is concluded that such avalanche deposits are normal products of the evolution of large composite volcanoes, comparable with lava and pyroclastic flow deposits. A statistical survey of 578 composite volcanoes in the same area indicated that a majority of cones which achieve edifice heights between 2000 and 3000 m may undergo sector collapse. The paper describes morphological criteria for identifying breached composite cones and volcanic debris avalanches using orbital images.

Francis, P. W.↗

Disentangling X-Ray Emission Processes in Vela-Like Pulsars

We present a deep observation with the X-Ray Multimirror Mission of PSR B1823-13, a young pulsar with similar properties to the Vela pulsar. We detect two components to the X-ray emission associated with PSR B1823-13: an elongated core of extent 30 min immediately surrounding the pulsar embedded in a fainter, diffuse component of emission 5 sec in extent, seen only on the southern side of the pulsar. The pulsar itself is not detected, either as a point source or through its pulsations. Both components of the X-ray emission are well fitted by a power-law spectrum, with photon index Gamma approx. 1.6 and X-ray luminosity (0.5-10 keV) L(sub X) approx. 9 x 10(exp 32) ergs/s for the core and Gamma approx. 2.3 and L(sub X) approx. 3 x 10(exp 33) ergs/s for the diffuse emission, for a distance of 4 kpc. We interpret both components of emission as corresponding to a pulsar wind nebula, which we designate G18.0-0.7. We argue that the core region represents the wind termination shock of this nebula, while the diffuse component indicates the shocked downstream wind. We propose that the asymmetric morphology of the diffuse emission with respect to the pulsar is the result of a reverse shock from an associated supernova remnant, which has compressed and distorted the pulsar-powered nebula. Such an interaction might be typical for pulsars at this stage in their evolution. The associated supernova remnant is not detected directly, most likely being too faint to be seen in existing X-ray and radio observations.

Gaensler, Bryan↗

Developmental evolutionary biology of the vertebrate ear: conserving mechanoelectric transduction and developmental pathways in diverging morphologies

This brief overview shows that a start has been made to molecularly dissect vertebrate ear development and its evolutionary conservation to the development of the insect hearing organ. However, neither the patterning process of the ear nor the patterning process of insect sensory organs is sufficiently known at the moment to provide more than a first glimpse. Moreover, hardly anything is known about otocyst development of the cephalopod molluscs, another triploblast lineage that evolved complex 'ears'. We hope that the apparent conserved functional and cellular components present in the ciliated sensory neurons/hair cells will also be found in the genes required for vertebrate ear and insect sensory organ morphogenesis (Fig. 3). Likewise, we expect that homologous pre-patterning genes will soon be identified for the non-sensory cell development, which is more than a blocking of neuronal development through the Delta/Notch signaling system. Generation of the apparently unique ear could thus represent a multiplication of non-sensory cells by asymmetric and symmetric divisions as well as modification of existing patterning process by implementing novel developmental modules. In the final analysis, the vertebrate ear may come about by increasing the level of gene interactions in an already existing and highly conserved interactive cascade of bHLH genes. Since this was apparently achieved in all three lineages of triploblasts independently (Fig. 3), we now need to understand how much of the morphogenetic cascades are equally conserved across phyla to generate complex ears. The existing mutations in humans and mice may be able to point the direction of future research to understand the development of specific cell types and morphologies in the formation of complex arthropod, cephalopod, and vertebrate 'ears'.

Non-NASA Center↗

Viscosity of the Mercurian Magma Ocean: Implications of Sulfur-Free and Sulfur-Bearing Magma Oceans for Differentiation and Crustal Petrogenesis

Mercury is believed to have had a magma ocean in its early evolution whose solidification dynamics contributed to the planet’s present day surface composition. The surface is characterized by two main geological provinces; the Northern Smooth Plains (NSP),and the Heavily Cratered Terrain (HCT) and Intercratered Terrian (IcT). These provinces are defined by the differences in morphology, composition, and age. The NSP are located in the northern hemisphere and have low Mg/Si, Ca/Si, and S/Si ratios and high Al/Si ratios, and are compositionally analogous to a magnesian alkali basalt. The HCT/IcT cover the majority of the planet and are older than the NSP, and are characterized by high Mg/Si, Ca/Si, and S/Si ratios and low Al/Si ratios. The dichotomy in surface composition motivates the study into the structure of the mantle as a product of magma ocean solidification. Two important and interrelated parameters that determine the efficiency of crystal fractionation during magma ocean solidification are convection vigor and viscosity of the magma ocean. Crystal suspension in a cooling magma ocean could be efficient or inefficient which suggests two end member possibilities for magma ocean solidification. The first is the formation of a compositionally stratified mantle reflecting a cumulate sequence produced along a fractional liquid line of descent. The second is the formation of a well-mixed, batch crystallized mantle by high viscosity and/or vigorously convecting magma ocean. Determining which of these end members, or where on the spectrum between them is most relevant to Mercury’s magma ocean can be experimentally constrained through high P-T falling-sphere viscometry experiments.

Mouser, M. D.↗

Correlations of multiscale structural evolution and homogeneous flows in metallic glass ribbons

Studying the flow behavior is critical to understand the deformation mechanism of amorphous solids. However, detecting the basic flow events in amorphous solids is challenging. Here, by simultaneous SAXS/WAXS, elementary flow carriers in wound metallic glasses are identified from flow-induced structural heterogeneities with a radius of gyration of 2.5~3.5 nm. Their size increases and morphology changes from sphere-like to rod-like under flow. Moreover, the atomic structure exhibits an unusual change to a more disordered state during winding/annealing at the temperature of ~0.8 T g . This work provides an atomic-to-nanoscale description of the flow carriers of amorphous solids during deformation. Impact Statement The elementary flow carriers in metallic glasses have a radius of gyration of 2.5~3.5 nm. During flow, their size increases and morphology changes from sphere-like to rod-like.

36 MATERIALS SCIENCE↗

Origin, Structure, and Evolution of Grooved Terrain on Ganymede and Comparison to Europa

'Ridge and trough terrain' (RTT) is a generic term for sets of subparallel ridges and troughs observed on several icy outer planet satellites. Ganymede's grooved terrain is the best studied example of ridge and trough terrain. However, the >500 a resolution of Voyager images limited the conclusions that could be drawn regarding its detailed morphology and deformational style, as well as the relationship of bright grooved terrain to dark terrain on Ganymede. The goal of this study was to utilize Galileo high resolution images to examine and categorize the detailed local-scale morphology of ridge and trough terrains on Ganymede, in order to determine the morphological variety and deformational styles of the terrain, and its evolutionary sequence. This included comparison of the ridges and troughs that occur within dark terrain to those within bright terrain. This study addressed implications for the satellite's local-scale stress history, its lithospheric character, and its broader-scale geological history. Conclusions from the Ganymede were applied to gain insight into the origin of ridge and trough terrains on Europa. Attached are the abstracts of the seven papers and list of one popular press article and 13 abstracts which resulted from this study. No subject inventions are associated with this work.

Pappalardo, Robert T.↗

Understanding the microstructural stability in a y’-strengthened Ni-Fe-Cr-Al-Ti alloy

Ni-Fe-Cr-Al-Ti alloys, with Ni levels near 50 wt.%, have the potential to develop a microstructure consisting of a face-centered cubic ? matrix with the homogeneous precipitation of fine ordered ?’ precipitates similar to traditional Ni-based superalloys with significantly greater Ni content. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), atom probe tomography (APT), and CALPHAD -based thermodynamic modeling were employed to understand the phase stabilities and microstructural evolution in an age-hardenable Ni-27Fe-18Cr-1Co-1.6Al-3.75Ti-1.2Mo-0.03C (wt%) alloy. The primary heat-treatment of solution annealing at 1121°C for 4h and age-hardening treatment at 760 °C for 16h resulted in a microstructure consisting of fine ?’ precipitates in an austenitic matrix along with grain boundary carbides, consistent with thermodynamic calculations. Long-term aging at 900 °C for 250h resulted in the coarsening of ?’ along with a change in the morphology of the precipitates from spherical to a more cuboidal shape. In addition, ? phase formation was observed concomitant with the partial dissolution of the ?’ phase. The ability of computational thermodynamic models to predict microstructural characteristics is discussed.

Gwalani, Bharat↗

NGC 6845 Revisited: Stellar Kinematics on the Early Type Member Galaxies

We observed the compact group of galaxies NGC 6845 with GMOS-S imaging and long-slit spectroscopy. The group itself is comprised of two spiral galaxies and two S0 galaxies, and shows signs of gravitational interaction among them. While the spiral galaxies have been already well studied, the two S0 galaxies have received little attention. We investigate the morphology and stellar kinematics of the two S0 galaxies in detail in order to derive the value for their mass and subsequently incorporate them into the mass model for the group. It was found that the internal kinematics of the largest S0 (NGC 6845 C) is mostly regular, while the smallest S0 (NGC 6845 D) shows some hint of interaction, most likely with NGC 6845 C and NGC 6845 A. The new determination of the dynamical mass of the group implies that the group mass has to be 10 times the combined mass of the individual members according to their internal kinematics. The results point to an early stage of the group interaction and also to the possibility that it has still not reached virial equilibrium. From the galaxy evolution viewpoint, this group represents an example of the case of the transformation of Spirals into S0 galaxies in dense environments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Formation and Evolution of Lakshmi Planum (V-7), Venus: Assessment of Models using Observations from Geological Mapping

Lakshmi Planum is a high-standing plateau (3.5-4.5 km above MPR) surrounded by the highest mountain ranges on Venus. Lakshmi represents a unique type of elevated region different from dome-shaped and rifted rises and tessera-bearing crustal plateaus. The unique characteristics of Lakshmi suggest that it formed by an unusual combination of processes and played an important role in Venus geologic history. Lakshmi was studied with Venera-15/16 and Magellan data, resulting in two classes of models, divergent and convergent, to explain its unusual topographic and morphologic characteristics. Divergent models explain Lakshmi as a site of mantle upwelling due to rising and subsequent collapse of a mantle diapir; such models explain emplacement of a lava plateau inside Lakshmi and, in some circumstances, formation of the mountain ranges. The convergent models consider Lakshmi as a locus of mantle downwelling, convergence, underthrusting, and possible subduction. Key features in these models are the mountain ranges, high topography of Lakshmi interior, and the large volcanic centers in the plateau center. These divergent and convergent models entail principally different mechanisms of formation and suggest different geodynamic regimes on Venus. Almost all models make either explicit or implicit predictions about the type and sequence of major events during formation and evolution of Lakshmi and thus detailed geological mapping can be used to test them. Here we present the results of such geological mapping (the V-7 quadrangle, 50-75degN, 300-360degE; scale 1:5M) that allows testing the proposed models for Lakshmi.

Ivanov, M. A.↗

Imaging Science Requirements for a Uranus Flagship Mission

Introduction: Our presentation will summarize the requirements for UV/Visible/Near-IR remote-sensing imaging science instruments (including mapping spectrometers) envisioned for the Uranus Orbiter and Probe (UOP) mission recommended by the recent planetary decadal survey. The Uranus system offers many targets for imaging investigations. Imaging science investigations are crucial to answering fundamental questions about various physical processes that shape the Uranian system and drive its evolution. Each science objective addressed through imaging has requirements for observation and illumination geometries as well as coverage and resolution in the spatial, spectral and temporal dimensions. By combining the requirements for the diverse science targets in the Uranian system, we present a set of overarching imaging science requirements for UOP. Atmospheric Science: The study of Uranus’ atmosphere is crucial in understanding the planet's energy balance and interior heat flux. Imaging observations map how the atmosphere scatters incident solar radiation. Imaging is key to characterizing planetary-scale energy/material transport though global atmospheric dynamics and local meteorology. Hyperspectral mapping combined with radiative transfer analysis reveals the vertical distribution of clouds and hazes. Chronicling temporal variabilities of atmospheric features is key to understanding the various processes that operate within the dynamic Uranian atmosphere. A comprehensive understanding of Uranus' atmosphere is essential in deciphering the planet's origins and evolution as well as providing insight into the broader field of planetary and exoplanetary science. Magnetospheric Interactions: Imaging science is critical to understand the elusive Uranian aurorae. Mapping the aurorae and their temporal dynamics will reveal the interaction of Uranus’ complex magnetosphere with the solar wind. The apparent decades-long cooling of Uranus’ upper atmosphere is thought to be due to changes in energy input from the overlying magnetosphere, and so mapping and quantifying the auroral evidence for this energy flux is particularly relevant for upper atmospheric science In addition, Uranus’ large moons may generate auroral footprints, which can be used to constrain the planet’s unusual magnetic field structure. Satellite Interiors: Imaging science can address the potential habitability of the larger moons of Uranus by measuring their shapes and rotational states (including librations), which combined with gravity data are crucial to understanding their internal density structure. Satellite Origins: Origin markers such as organics and volatiles may be preserved on the satellite surfaces, which may be sensed by UV/IR mapping. Imaging combined with the moons’ densities may reveal whether the moons formed in Uranus’ circumplanetary disk, rings, or from ejecta of a giant impact on Uranus. Satellite Geology: Imaging investigations, including stereo imaging to obtain topography, will enable constraining each satellite’s geologic history by investigating the distributions and morphologies of impact craters, tectonic and potential cryovolcanic features, and regolith and mass wasting deposits. These records will help unravel the past complex history of orbital resonances that occurred between Uranian satellites, which may have driven geologic activity. Analyses of these features will also point to resurfacing styles and modification processes important for understanding each moon’s thermal evolution, and any present-day geological activity, including potential subsurface deep oceans or possible current activity. Additionally, hyperspectral imaging will enable mapping the surface composition and identifying the potential presence of material that may point to a subsurface ocean, such as ammonia-bearing species. Rings and Small Moons: Imaging observations elucidate the physical processes that contribute to the complex ring-moon system’s inferred unstable state. Imaging surveys will seek smaller moons and other debris that could provide evidence of past collisions, while precise astrometric data of moons will determine the current dynamical state of the system. Many of Uranus' rings are exceptionally narrow, and images of the rings covering a broad range of longitudes, and high-resolution images of features within the rings will reveal how these rings are confined and maintained, as well as illustrating the rings' internal structure and dynamics. Images of the rings and moons obtained at a variety of wavelengths and lighting conditions are also needed to quantify the composition and the size distribution of the small satellites and ring particles.

K M Sayanagi↗

Catalytic materials for lithium-sulfur batteries: mechanisms, design strategies and future perspective

Lithium-sulfur batteries (LSBs) are attractive candidates for post-lithium-ion battery technologies because of their ultrahigh theoretical energy density and low cost of active cathode materials. However, the commercialization of LSBs remains extremely challenging primarily due to poor cycling performance and safety concerns, which are inherently caused by low conductivity of S 8 and Li 2 S, severe polysulfide shuttling, and high polarization by solid Li 2 S 2 /Li 2 S deposition. Catalytic materials could facilitate the large-scale practical application of LSBs by overcoming all these challenges. In this review, we investigate the sulfur species evolution in LSBs and explore the roles of catalytic materials in charge/discharge processes, highlighting the catalysis of solid S 8 to liquid polysulfides and solid Li 2 S 2 to Li 2 S. Furthermore, we offer systematic strategies from atomic to macro levels, including defect engineering, morphology engineering and catalyst compositing, to enhance catalysis efficiency in terms of sulfur supercooling, fast charge transfer, thiosulfate generation, disulfide bond cleavage, tuneable Li 2 S growth and Li 2 S decomposition enhancement. Finally, the design and availability of the proposed catalytic materials will further advance LSB technology from coin cells and pouch cells to the subsequent commercialization scale.

25 ENERGY STORAGE↗

In-situ TEM observation of shear induced microstructure evolution in Cu-Nb alloy

Phase boundaries in multiphase alloys govern defect interaction and chemical intermixing across different phases during plastic deformation. Dynamic interaction of defects with phase boundaries in multiphase alloys, especially for immiscible alloys, has been topic of significant research interest in recent years. In this work, we describe a novel approach for carrying out in-situ TEM shear deformation to directly observe interfacial microstructural evolution of a Cu-Nb alloy. A unique double shear specimen geometry is microfabricated by a focused ion beam technique to apply shear deformation upon push loading inside the TEM. From the real-time observation, we discover that the phase boundary with a zigzag morphology effectively blocks stacking faults nucleated in a Cu grain from slipping into a Nb grain. Meanwhile, the Cu phase bears the most plastic deformation through slip or twinning mechanisms. This work sheds light on understanding the shear deformation and the behavior of phase boundaries in multiphase alloys during shear deformation.

36 MATERIALS SCIENCE↗

Fast attenuation of high-frequency acoustic waves in bicontinuous nanoporous gold

We studied the formation and attenuation of GHz elastic waves in free-standing nanoporous gold films by MeV ultrafast electron diffraction and finite element simulations. By tracing the evolution of the high frequency acoustic waves in time domain, we found that the bicontinuous nanoporous structure in nanoporous gold films results in three-dimensionally acoustic response with low coherence, leading to fast attenuation of the elastic waves in comparison with solid gold films. The morphologically dominated dynamics indicates the nanoporosity plays an important role in the high-frequency acoustic energy relaxation, which shines a light on the applications of dealloyed nanoporous materials in nanodevices and sensors as GHz and THz acoustic filters and dampers.

36 MATERIALS SCIENCE↗

Particle size of several plutonium-238 oxide fuel samples from oxalate precipitation processes

Particle size of 238 PuO 2 powders is an important factor in determining the structural integrity of fuel pellets hot-pressed from the oxide powder. Understanding the evolution of particle size during aqueous processing is a first step in assuring control of particle size throughout the pellet formation process. Measured particle sizes are reported here, and discussed in terms of measured particle size changes occurring during calcining, observed aggregation of particulate, and particle morphology. Morphology and aggregation are related to surface energy, which governs granule formation and hot pressing behavior. Results are discussed in terms of reported dependence of oxide morphology on process temperatures and reagent concentrations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Gas flows in S-E binary systems of galaxies

Tidal interaction between the galaxies in binary systems leads to important consequences. Some peculiarities in galactic morphology as well as the transfer of matter from one galaxy to another may be due to this factor. In particular, gas flows in intergalactic space may be formed. Such flows enriching one component with gas from the other may play a substantial role in the evolution of mixed (S-E) pairs. One can mention several facts corroborating the possibility of the gas transfer from the spiral to the elliptical galaxy. High HI content (10(exp 7) to 10(exp 9) solar mass) is detected in nearly 40 E galaxies (Bottinelli and Gougenheim, 1979; Knapp et al., 1985). Such galaxies are often members of pairs or of multiple systems including an S galaxy, which may be the source of gas (Smirnov and Komberg, 1980). Moreover, the gas kinematics and its distribution also indicate an external origin for this gas (Knapp et al., 1985). In many cases there is an outer gaseous disk. The directions of the disk and of stellar rotation don't always coincide (van Gorkom et al., 1985; Varnas et al., 1987). The galaxy colors in S-E pairs are correlated (the Holmberg effect): bluer ellipticals have spiral components that are usually bluer (Demin et al., 1984). The fraction of E galaxies with emission lines (N sub em) in S-E pairs showing traces of tidal interaction is twice as large (N sub em approx. equals 0.24) as in pairs without interaction (N sub em approx. equals 0.12) (Sotnikova, 1988b). Since the presence of emission lines in a galaxy spectrum strongly depends on gas content, this fact also leads to the conclusion that ellipticals in interacting S-E pairs are enriched with gas. These facts may be considered as a serious indication of the existence of gas transfer. Hence, investigation of this process is of interest.

Sotnikova, N. YA.↗