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At least 847 records · Page 47

Diversion Path Analysis: A Proposed Methodology to Develop an MC&A Approach for Liquid-Fueled Molten Salt Reactors

Nuclear material control and accounting (MC&A) is a critical element of both the US Nuclear Regulatory Commission (NRC) and US Department of Energy (DOE)’s domestic safeguards and security requirements. NRC licensees are required, under Title 10 of the Code of Federal Regulations (10 CFR) Part 74 to establish and maintain an MC&A program that captures and records the quantities and locations of special nuclear material (SNM) at the facility. Along with physical protection, MC&A is a key element of domestic nuclear material safeguards that enables the NRC to ensure that SNM is controlled and accounted for. SNM, per 10 CFR Part 74, refers to plutonium, 233 U, and uranium enriched in the isotope 233 U or 235 U, but does not include source material. Periodic physical inventories, coupled with material balance evaluations, are effective and demonstrated tools to account for and detect theft or diversion of SNM in facilities containing SNM in bulk material form (i.e., not in discrete, countable items). Historically in the United States, these types of facilities have included fuel fabrication, conversion, and enrichment facilities. In comparison, reactors have relied on item counting of assemblies and control of SNM while in containment (e.g., a sealed reactor pressure vessel) because, to date, reactor fuel has been in item form. In liquid-fueled molten salt reactors (MSRs), unlike traditional light water reactors (LWRs) or bulk facilities, bulk SNM quantities can change significantly during operation as a result of depletion and transmutation. This introduces challenges to the use of traditional periodic physical inventories and material balance evaluations to detect theft or diversion of SNM in reactors that use SNM in bulk material form. Liquid-fueled (i.e., salt-fueled) MSR facilities are MSRs that use SNM within a salt eutectic as the fuel. The SNM is in a bulk material form any time it is outside of fresh or spent fuel storage containers. Some examples of when SNM will be in bulk form in the facility are during addition of fuel to the reactor system, while fuel is circulating in operation, and while fuel is in a drain tank. Periodic physical inventories and material balance evaluations can likely be effectively applied to many portions of an MSR facility, including all areas where depletion and transmutation are not significantly changing the quantities of SNM within the control area. Within an MSR facility, this would include fresh fuel receipt and loading, waste streams that may contain SNM, irradiated fuel storage outside of the reactor core, and any irradiated fuel processing that may happen after SNM has been removed from the reactor. All of these process steps could rely on measurements of SNM quantities compared with documented inventories. Any discrepancies from predicted (i.e., book) inventories and measured inventories could be quantified as inventory differences, consistent with traditional MC&A guidance from the NRC (e.g., in NUREG-1065 Revision 2, NUREG-2159 Revision 1, and RG 5.29 Revision 2). Within the reactor system, additions and removals to the book inventory include depletion of the SNM (e.g., fission of 235 U), which complicates the use of physical inventories. SNM control, however, can also likely be effectively applied to detect theft of SNM throughout a liquid-fueled MSR facility. To complement these approaches, prior technical reports have identified that a diversion path analysis may be a useful, risk-informed, and performance-based tool to determine suitable elements of an MC&A approach for the reactor system within a liquid-fueled MSR facility.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Control Boundary Analysis for Liquid-Fueled Molten Salt Reactors

The US Nuclear Regulatory Commission (NRC) will likely require license applicants for liquid-fueled molten salt reactors (MSRs) with circulating fuel to submit a nuclear material control and accounting (MC&A) plan or provide a detailed MC&A program description for the facility. In liquid-fueled MSRs with special nuclear material (SNM) in bulk form (i.e., not in discrete items) and with rapidly changing quantities due to fuel transmutation and depletion, a novel MC&A approach is needed because traditional nuclear material accounting methods with material balance evaluations will not be sufficient. This report details the continued efforts carried out at Oak Ridge National Laboratory (ORNL) during FY 2025 to develop a distinct MC&A approach suitable specifically for domestic safeguards of the first-of-a-kind MSRs. These efforts are built on previous ORNL efforts reported in ORNL/SPR-2023/3181 and ORNL/SPR-2024/3555.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Magnetic Bearing Pumps for Molten Salt Fusion Energy Devices

The Commonwealth Fusion Systems (CFS) ARC reactor will employ a novel liquid immersion blanket design that uses a molten lithium salt as both the tritium-breeding material and the vacuum vessel coolant. fluoride lithium beryllium (FLiBe) (a lithium fluoride–beryllium difluoride mixture) is currently the leading salt candidate. Its low-Z components provide good moderation, it has adequate heat transfer properties and low electrical conductivity, and it has good neutron multiplication properties, which further enhance tritium production.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Effect of moisture ingression on material performance and particle generation in molten salts

This report summarizes activities conducted to understand and mitigate the negative consequences that moisture ingressions have upon the operations of pyroprocessing equipment. The objectives of the work conducted in FY25 were to characterize (1) the physicochemical properties of particles generated as a result of moisture ingressions, and (2) the corrosion of relevant structural materials with the introduction of moisture. Compositional and morphological analyses of the generated particles were conducted through a suite of characterization technologies, including X-ray diffraction, microscopy, and particle size analysis. The results gathered this year were compared to those obtained in FY24 when studies with oxygen ingressions were conducted on CeCl 3 -LiCl-KCl and UCl 3 -LiCl-KCl systems. Investigations involving performance evaluations of industrially relevant structural alloys were also conducted under moisture ingress conditions. In-line electrochemical monitoring of the bulk salt was augmented with microscopy of alloy samples to quantify the concentration and accumulation of corrosion products in the bulk salt. The results reported in this work provide a more holistic understanding of the effects of atmospheric ingressions on molten chloride salt chemistry such that effective redox control strategies may be implemented.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Guidance Regarding Probable Approaches and Instrumentation to Liquid Fuel Molten Salt Reactor Material Control and Accounting (MC&A) Rev. 1

With the rapid development of advanced reactors and numerous companies requesting pre-application engagements with the Nuclear Regulatory Commission (NRC), there is need for the NRC to best prepare themselves for new challenges presented by advanced technologies. One specific reactor type of interest is the molten salt reactor (MSR) that uses liquid salt as the fuel for the reactor. Liquid salt fuel reactors have specific challenges with regards to performing material control and accounting (MC&A). The challenges result from the fuel form being a continuous fissile material form rather than discrete units like is found with fuel assemblies in traditional light water reactors (LWRs). The goal of this document is to provide the NRC with guidance on the different approaches and technologies that may be proposed by reactor designers to address these problems to prepare staff for regulatory reviews.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Molten Salt Targets for Future High-Power Accelerator Facilities

This talk will give an overview of will give an overview of recent work that began to examine the feasibility of molten salts as a target material for very high power beams as a potential solution for some of the present and future challenges of high power targetry at Fermilab, anchored by the F2D2 conceptual design study. This will include discussion of target and beam dump applications as well as likely challenges, potential for future R&D, projects, and synergy with existing high-power targetry research.

Williams, Jonathan K. [Fermilab]↗

Corrosion Testing of Refractory in Contact with Molten Glasses Designed for Waste Vitrification – APPS1 Matrix Glasses (Revision 3)

Preface or Acknowledgements This document serves to convey the refractory loss measurement results from corrosion testing of Monofrax® K-3 refractory by molten glass to support the enhanced waste glass program being led by Pacific Northwest National Laboratory (PNNL). Any discussion or conclusions to be drawn from the data are not presented in this report. The refractory corrosion data is intended to be used in the development, validation, and implementation of enhanced property/composition models for waste glass vitrification at Hanford. Funding for this work by the U.S. Department of Energy, Hanford Field Office, Waste Treatment & Immobilization Plant Project through Department of Energy Work Authorization M0SRV00101 managed by Albert A. Kruger is gratefully acknowledged.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Comparison of spatial dynamics and point kinetics approaches in multiphysics modeling of the molten salt reactor experiment

In this work, we present validation test results of fully coupled neutronics and thermal-hydraulics models of the Molten Salt Reactor Experiment (MSRE) against experimental data of the zero power pump transients and the natural circulation tests at low power. To capture the strong coupling between neutronics and thermal-hydraulics due to fuel circulation, and to account for the delayed neutron precursor (DNP) distribution, the porous media thermal-hydraulics solver Pronghorn was fully coupled to the spatial neutron dynamics code Griffin, which solves the neutron diffusion equation, and to the 0-D point kinetics solver Squirrel, using a 2-D homogenized representation of the MSRE. The validation test results show very good agreement with experimental data for both point kinetics and spatial dynamics simulations, capturing the strong feedback effect and DNP losses in the MSRE. The 0-D code Squirrel accurately predicted the time-dependent behavior in the MSRE given the steady-state spatial dynamics solution of Griffin.

42 - ENGINEERING↗

Molten Salt Reactor Sourdough Refueling and Waste Management Strategy

This paper presents a new approach to the spent nuclear fuel (SNF) problem, which is uniquely enabled by a liquid fuel form, specifically as in the case of molten salt reactor (MSR) systems. Managing the SNF problem is critical for public acceptance of nuclear power as a climate change solution. An MSR can be refueled while operating by adding more fresh fuel salt, which grows the in-core fuel salt volume. This growth will eventually double the size of the original fuel salt, allowing to start another core with this excess fuel so long as the daughter reactor is of the same design and there is sufficient excess fuel. This study explores how such a “sourdough” strategy would work in MSRs and provides an initial calculation methodology to find the correct refueling rates to match the desired growth curve of power generation. Higher uranium enrichment levels of the refuel salt result in lower refueling rates and thus a longer doubling time. As a result, the refuel salt uranium enrichment can be tailored to match a postulated clean power generation capacity expansion. This approach allows postponing the spent nuclear fuel disposal issue using the sourdough method. Along with the MSR fuel’s unique properties, it suggests a new path towards managing nuclear waste until long-term solutions become economically viable.

Wheeler, Alexander M.↗

Plutonium Signatures in Molten-Salt Reactor Off-Gas Tank and Safeguards Considerations

Fluid-fueled molten-salt reactors (MSRs) are actively being developed by several companies, with plans to deploy them internationally. The current IAEA inspection tools are largely incompatible with the unique design features of liquid fuel MSRs (e.g., the complex fuel chemistry, circulating fuel inventory, bulk accountancy, and high radiation environment). For these reasons, safeguards for MSRs are seen as challenging and require the development of new techniques. This paper proposes one such technique through the observation of the reactor’s off-gas. Any reactor design using low-enriched uranium will build up plutonium as the fuel undergoes burnup. Plutonium has different fission product yields than uranium. Therefore, a shift in fission product production is expected with fuel evolution. The passive removal of certain gaseous fission products to the off-gas tank of an MSR provides a valuable opportunity for analysis without significant modifications to the design of the system. Uniquely, due to the gaseous nature of the isotopes, beta particle emissions are available for observation. The ratios of these fission product isotopes can, thus, be traced back to the relative amount and types of fissile isotopes in the core. This proposed technique represents an effective safeguards tool for bulk accountancy which, while avoiding being onerous, could be used in concert with other techniques to meet the IAEA’s timeliness goals for the detection of a diversion.

Dunkle, Nicholas (ORCID:000000027323011X)↗

Nuclear Data Impact on Key Metrics for a Representative Molten Chloride Fast Reactor Model

Nuclear data are an essential component of the foundation on which all modeling and simulation methods and tools are relying upon, from the front end to the back end of the nuclear fuel cycle. In this study, the impact of uncertainties in nuclear data is investigated for a representative molten chloride fast reactor, for several important metrics, including eigenvalue, reactivity differences, and nuclide inventories in fuel at 5-yr irradiation. Uncertainty of keff for a full core model was found to be similar between the fresh fuel and the irradiated fuel states (1.7-1.8%), with its primary driver being the uncertainty in the 235U (n,γ) cross section. The results obtained for the reactivity differences show large uncertainties, of over 100%, in elastic scattering sensitivities of several nuclides, which led to large uncertainties of temperature reactivity differences for cladding and reflector. These results provide evidence that the currently applied methods may not be sufficiently adequate for ensuring the reliable determination of such metrics.

Procop, Germina [ORNL] (ORCID:0000000342226393)↗