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The inaugural flight of the Space Launch System (SLS) Block 1 launch vehicle, Artemis I, occurred on November 16, 2022, and featured a full suite of Developmental Flight Instrumentation (DFI) that provided aerothermodynamic measurements to assess thermal design and substantiate aerothermodynamic models. The Block 1 launch vehicle aerothermal instrumentation consisted of approximately 277 aerothermal gauges mounted throughout the Orion Multi-Purpose Crew Vehicle (MPCV), Integrated Spacecraft and Payload Element (ISPE), Core Stage (CS) and Solid Rocket Boosters (SRB) and an additional 179 thermal gauges on the Orion Crew Module (CM). Instrumentation included calorimeters, radiometers, pressure transducers, gas temperature probes, and thermocouples. Data was collected from lift-off through CS Main Engine Cut-Off (MECO). The flight data was invaluable for determining aerothermal model performance and developing flight-derived aerothermal environments for flight reconstruction thermal analysis and future SLS aerothermal models. The data offered critical insights into the aerothermodynamic conditions experienced during the launch and ascent of the SLS vehicle. This study compares the flight derived environments to pre-existing design models. The aerothermal models were constructed using MINIVER, the aerothermal engineering code which predicts aerodynamic heating and acts as an integration tool for incorporating databases from computational fluid dynamics (CFD) simulations and wind tunnel test data. The comparisons reveal the fidelity of the design models, highlighting areas where the design models accurately predicted flight conditions and instances where deviations were observed. Preliminary results suggest that while the design models largely aligned with the observed flight data, there were unique observations that reflected needed areas of model refinement. Aerothermal flight data from Artemis I for the SLS Block 1 vehicle will be further utilized to enhance the accuracy of Block 1B and Block 2 aerothermal models, ensuring improved safety and performance for subsequent Artemis missions.