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A Mercury Orbiter mission has been assigned high priority in the Roadmaps of two of NASA's four space science themes: Solar System Exploration (SSE)and Sun Earth Connection (SEC).
The Hermes Global Orbiter is a proposed Discovery-class mission. Hermes will be launched aboard a Delta II rocket in 1999 and will be placed in an elliptical polar orbit about Mercury. Remote sensing measurements of the planet's surface, atmosphere, and magnetosphere will be performed. Key mission goals include mapping the entire surface at 1 km resolution, characterizing the surface composition, texture and topography, searching for water ice at the poles, characterizing the atmosphere, and constraining the interior structure.
This a brief report on radar ranging data to the subradar point on Mercury. This report makes available ten years of such data, from 1987 to 1997.
We demonstrate the functionality of a mercury capillary lamp with a diameter in the sub-mm range and deep ultraviolet (DUV)/ vacuum ultraviolet (VUV) radiation delivery via an optical fiber integrated with the capillary. DUV spectrum control is observed by varying the fabrication parameters such as buffer gas type and pressure, capillary diameter, electrical resonator design, and temperature. We also show spectroscopic data of the 199Hg+ hyper-fine transition at 40.5GHz when applying the above fiber optical design. We present efforts toward micro-plasma generation in hollow-core photonic crystal fiber with related optical design and theoretical estimations. This new approach towards a more practical DUV optical interface could benefit trapped ion clock developments for future ultra-stable frequency reference and time-keeping applications.
Measurements of surface reflectance of permanently shadowed areas near Mercury's north pole reveal regions of anomalously dark and bright deposits at 1064-nanometer wavelength. These reflectance anomalies are concentrated on poleward-facing slopes and are spatially collocated with areas of high radar backscatter postulated to be the result of near-surface water ice. Correlation of observed reflectance with modeled temperatures indicates that the optically bright regions are consistent with surface water ice, whereas dark regions are consistent with a surface layer of complex organic material that likely overlies buried ice and provides thermal insulation. Impacts of comets or volatile-rich asteroids could have provided both dark and bright deposits.
Caloris basin, Mercury's youngest large impact basin, is filled by volcanic plains that are spectrally distinct from surrounding material. Post-plains impact craters of a variety of sizes populate the basin interior, and the spectra of the material they have excavated enable the thickness of the volcanic fill to be estimated and reveal the nature of the subsurface. The thickness of the interior volcanic plains is consistently at least 2.5 km, reaching 3.5 km in places, with thinner fill toward the edge of the basin. No systematic variations in fill thickness are observed with long-wavelength topography or azimuth. The lack of correlation between plains thickness and variations in elevation at large horizontal scales within the basin indicates that plains emplacement must have predated most, if not all, of the changes in long-wavelength topography that affected the basin. There are no embayed or unambiguously buried (ghost) craters with diameters greater than 10 km in the Caloris interior plains. The absence of such ghost craters indicates that one or more of the following scenarios must hold: the plains are sufficiently thick to have buried all evidence of craters that formed between the Caloris impact event and the emplacement of the plains; the plains were emplaced soon after basin formation; or the complex tectonic deformation of the basin interior has disguised wrinkle-ridge rings localized by buried craters. That low-reflectance material (LRM) was exposed by every impact that penetrated through the surface volcanic plains provides a means to explore near-surface stratigraphy. If all occurrences of LRM are derived from a single layer, the subsurface LRM deposit is at least 7.5-8.5 km thick and its top likely once made up the Caloris basin floor. The Caloris-forming impact would have generated a layer of impact melt 3-15 km thick; such a layer could account for the entire thickness of LRM. This material would have been derived from a combination of lower crust and upper mantle.
Seasonal variation of mercury (Hg) is not well studied in free-ranging wildlife. Atmospheric deposition patterns of Hg have been studied in detail and have been modeled for both global and specific locations with great accuracy and correlates to environment impact. However, monitoring these trends in wildlife is complicated due to local environmental parameters (e.g., rainfall, humidity, pH, bacterial composition) that can affect the transformation of atmospheric Hg to the biologically available forms. Here, we utilized an abundant and healthy population of American alligators (Alligator mississippiensis) at Merritt Island National Wildlife Refuge (MINWR), FL, and assessed Hg burden in whole blood samples over a span of 7 years (2007 2014; n 174) in an effort to assess seasonal variation of total [Hg]. While the majority of this population is assumed healthy, 18 individuals with low body mass indices (BMI, defined in this study) were captured throughout the 7 year sampling period. These individual alligators exhibited [Hg] that were not consistent with the observed overall seasonal [Hg] variation, and were statistically different from the healthy population of alligators. The alligators with low BMI had elevated concentrations of Hg compared to their age/sex/season matched counterparts with normal BMI. Statistically significant differences were found between the winter and spring seasons for animals with normal BMI. The data in this report supports the conclusion that organismal total [Hg] do fluctuate directly with seasonal deposition rates as well as other seasonal environmental parameters, such as average rainfall and prevailing wind direction. This study highlights the unique environment of MINWR to permit annual assessment of apex predators, such as the American alligator, to determine detailed environmental impact of contaminants of concern.
This paper reports on recent advances made in obtaining low delta V trajectories to conduct Mercury orbiter missions.
Mercury (Hg) and radiocesium ( 137 Cs) are well-known environmental contaminants with the potential to impact the health of humans and wildlife. Snakes have several characteristics conducive to studying environmental contamination but have rarely been included in the monitoring of polluted sites. We investigated the bioaccumulation of Hg and 137 Cs and associations with sublethal effects (standard metabolic rate [SMR] and hemoparasite infections) in Florida green watersnakes (Nerodia floridana). We captured 78 snakes from three former nuclear cooling reservoirs on the US Department of Energy's Savannah River Site in South Carolina (USA). For captured snakes, we (1) determined whole-body 137 Cs, (2) quantified total Hg (THg) using snake tail clips, (3) conducted hemoparasite counts, and (4) measured the SMR. We used multiple regression models to determine associations among snake body size, capture location, sex, tail THg, whole-body 137 Cs, Hepatozoon spp. prevalence and parasitemia, and SMR. Average whole-body 137 Cs (0.23 ± 0.08 Becquerels [Bq]/g; range: 0.00–1.02 Bq/g) was correlated with snake body size and differed significantly by capture site (Pond B: 0.67 ± 0.05 Bq/g; Par Pond: 0.10 ± 0.02 Bq/g; Pond 2: 0.03 ± 0.02 Bq/g). Tail THg (0.33 ± 0.03 mg/kg dry wt; range: 0.16–2.10 mg/kg) was significantly correlated with snake body size but did not differ by capture site. We found no clear relationship between SMR and contaminant burdens. However, models indicated that the prevalence of Hepatozoon spp. in snakes was inversely related to increasing whole-body 137 Cs burdens. Our results indicate the bioaccumulation of Hg and 137 Cs in N. floridana and further demonstrate the utility of aquatic snakes as bioindicators. Furthermore, our results also suggest a decrease in Hepatozoon spp. prevalence related to increased burdens of 137 Cs. Although the results are intriguing, further research is needed to understand the dynamics between 137 Cs and Hepatozoon spp. infections in semiaquatic snakes.
East Fork Poplar Creek (EFPC) is a mercury (Hg) contaminated creek in east Tennessee, USA. Stream restoration activities included the initiation of a flow management programme in 1996 in which water from a nearby lake was pumped to the head of the creek. We conducted regular water sampling for 2 years along the length of EFPC during active flow management and for 5 years after flow management stopped. Total Hg and total monomethylmercury (MMHg) concentration and flux decreased in the uppermost reaches of EFPC that were closest to the point of water addition. Most water quality parameters, including DOC concentration, remained unchanged after flow management termination. Nevertheless, SUVA 254 , a measure of dissolved organic matter (DOM) composition, increased and coincided with increased dissolved Hg (Hg D ) concentration and flux and decreased Hg solid-water partitioning coefficients throughout EFPC. Higher SUVA 254 and Hg D concentration have potential implications for bioavailability and MMHg production. Total and dissolved MMHg concentrations increased in lower reaches of EFPC after the end of flow management and these increases were most pronounced during spring and early summer when biota are more susceptible to exposure and uptake. A general warming trend in the creek after active flow management ended likely acted in concert with higher Hg D concentration to promote higher MMHg concentration. Total and dissolved MMHg concentrations were positively correlated with water temperature above a threshold value of 10°C. Concentration changes for Hg and MMHg could not be accounted for by changes in creek discharge that accompanied the cessation of flow management. In addition to the changing DOM composition in-stream, other watershed-scale factors likely contributed to the observed patterns, as these changes occurred over months rather than instantaneously after flow management stopped. Nevertheless, similar changes in MMHg have not been observed in a tributary to EFPC.
Mercury extraction has been studied in nitric and hydrochloric acids with hexathia-18-crown-6 dissolved in carbon tetrachloride. Batch study experiments have been performed to determine the best conditions for maximum extraction. In both acids, Hg(II) was best extracted at low molarity while almost no extraction was observed above 2 M. Furthermore, speciation studies were carried out in an attempt to describe the extraction mechanism, but the exact composition of the extracted species was not determined. The extraction kinetics were studied to assess the feasibility of this crown ether for extracting Cn and/or Fl in a future online experiment.
Past industrial activities have generated many contaminated lands from which Mercury (Hg) escapes, primarily by volatilization. Current phytomanagement techniques aim to limit Hg dispersion by increasing its stabilization in soil. Although soil fungi represent a source of Hg emission associated with biovolatilization mechanisms, there is limited knowledge about how dead fungal residues (i.e., fungal necromass) interact with soil Hg. This study determined the Hg biosorption potential of fungal necromass and the chemical drivers of passive Hg binding with dead mycelia. Fungal necromass was incubated under field conditions with contrasting chemical properties at a well-characterized Hg phytomanagement experimental site in France. After four months of incubation in soil, fungal residues passively accumulated substantial quantities of Hg in their recalcitrant fractions ranging from 400 to 4500 μg Hg/kg. In addition, infrared spectroscopy revealed that lipid compounds explained the amount of Hg biosorption to fungal necromass. In conclusion, based on these findings, we propose that fungal necromass is likely an important factor in Hg immobilization in soil.
We report some thiols, such as cysteine (CYS) at moderate concentrations (10–500 µM), can enhance methylmercury (MeHg) formation by Geobacter sulfurreducens PCA, whereas others such as dithiol 2,3-dimercaptopropanesulfonate (DMPS) and 2,3-dimercaptosuccinic acid (DMSA) abolish mercury [Hg(II)] methylation. Little is known, however, about whether Hg(II) methylation could be enhanced or inhibited by the presence of mixed thiol ligands at low concentrations observed in the environment. Surprisingly we found that mixing CYS (1 µM) with DMPS (0.025–0.5 µM) or DMSA (0.025–1 µM) substantially increased MeHg production by 1.5–3.5-fold, compared to the no-thiol control, whereas complexation with a single DMPS, or DMSA, or CYS (1 µM) strongly inhibited Hg(II) methylation. Pre-equilibration between Hg(II) and thiols before the addition of cells was necessary to observe enhanced methylation. Spectroscopic analyses indicated the formation of mixed or heteroleptic coordinated Hg(II)-S 3 /S 4 complexes, which likely facilitated exchange of Hg(II) with cells and its uptake and internal transfer to the HgcAB proteins required for methylation. These results suggest that the effects of thiols on Hg(II) methylation were more complex than previously thought (using a single thiol) and thus underscore the importance of understanding how mixed thiols and their interactions with Hg(II) may ultimately influence MeHg production in the natural environment.
Mercury (Hg) is a pervasive environmental pollutant and poses serious health concerns as inorganic Hg(II) can be converted to the neurotoxin methylmercury (MeHg), which bioaccumulates and biomagnifies in food webs. Phytoplankton, representing the base of aquatic food webs, can take up Hg(II) and influence MeHg production, but currently little is known about how and to what extent phytoplankton may impact Hg(II) methylation by itself or by methylating bacteria it harbors. This study investigated whether some species of phytoplankton could produce MeHg and how the live or dead phytoplankton cells and excreted algal organic matter (AOM) impact Hg(II) methylation by several known methylators, including iron-reducing bacteria (FeRB), Geobacter anodireducens SD-1 and Geobacter sulfurreducens PCA, and the sulfate-reducing bacterium (SRB) Desulfovibrio desulfuricans ND132 (or Pseudodesulfovibrio mercurii). Here our results indicate that, among the 4 phytoplankton species studied, none were capable of methylating Hg(II). However, the presence of phytoplankton cells (either live or dead) from Chlorella vulgaris (CV) generally inhibited Hg(II) methylation by FeRB but substantially enhanced methylation by SRB D. desulfuricans ND132. Enhanced methylation was attributed in part to CV-excreted AOM, which increased Hg(II) complexation and methylation by ND132 cells. In contrast, inhibition of methylation by FeRB was attributed to these bacteria incapable of competing with phytoplankton for Hg(II) binding and uptake. These observations suggest that phytoplankton could play different roles in affecting Hg(II) methylation by the two groups of anaerobic bacteria, FeRB and SRB, and thus shed additional light on how phytoplankton blooms may modulate MeHg production and bioaccumulation in the aquatic environment.
Environmental mercury (Hg) contamination threatens ecosystems due to its bioaccumulation and toxicity. Effective and sustainable remediation strategies are essential, with carbon-based sorbents like biochar (BC) and activated carbon (AC) gaining attention for their high adsorption capacity and cost-effectiveness. However, their ecological impacts remain poorly understood. This study evaluates the Hg removal efficacy and ecological effects of three sorbents—BC, granular AC (GAC), and AC fiber (ACF)—in a flow-through column system with and without Hg additions. We tested Hg removal at two concentrations (1 and 4 µg/L Hg) and assessed chronic exposure effects on a sentinel and sensitive freshwater organism, Daphnia magna, over 30 days of exposure to the columns’ effluent. GAC removed 100 % of Hg, while BC and ACF achieved 99 % removal. The ACF + 4 µg/L Hg effluent induced 70 % lethality in D. magna after nearly three weeks of exposure, while the GAC effluent significantly reduced fecundity, even in the absence of Hg exposure. In contrast, the BC effluent enhanced reproductive output, likely due to inputs of carbon and nitrogen in the effluent. These findings highlight the need to balance Hg removal efficacy with ecological safety, emphasizing the importance of considering both remediation effectiveness and potential environmental impacts.
Herein, mercury (Hg) is a contaminant that enters the environment through natural or anthropogenic means. Ecological risk assessments have examined Hg bioaccumulation and effects in many taxa, but little is known about Hg dynamics in reptiles, or their potential use as bioindicator species for monitoring Hg in aquatic systems. Numerous snake species, like North American watersnakes (Nerodia spp.), are piscivorous and are exposed to Hg through their diet. The purpose of this study was to identify factors associated with Hg accumulation in a common watersnake species and compare Hg concentrations of the snakes to those in fish occupying the same habitats. To this end, we sampled brown watersnakes (Nerodia taxispilota) from the Savannah River, a major river system in the southeastern U.S., and compared N. taxispilota Hg accumulation trends to those of bass (Micropterus salmoides), catfish (Ictalurus and Ameiurus spp.), and panfish (Lepomis and Pomoxis spp.) collected from the same reach. Total Hg (THg) in N. taxispilota tail tips ranged from 0.020 to 0.431 mg/kg (wet weight; mean: 0.104 ± 0.008). Snake tail THg was significantly correlated with blood THg, which ranged from 0.003 to 1.140 mg/kg (0.154 ± 0.019). Snake size and site of capture were significantly associated with tail THg. Snake tail THg increased at sites along and downstream of the area of historic Hg pollution, consistent with fish THg. Snake muscle THg was predicted based on tail THg and ranged from 0.095 to 1.160 (0.352 ± 0.022). To gauge Hg biomagnification in N. taxispilota, we compared predicted snake muscle THg concentrations to THg in fish of consumable size. Average biomagnification factors for THg in N. taxispilota were 3.1 (panfish) and 5.4 (catfish), demonstrating N. taxispilota likely biomagnify Hg through their diet. These results reveal N. taxispilota to be an effective bioindicator species for monitoring Hg in aquatic environments.
Here, a model developed to represent the progress of erosion damage in liquid-metal spallation target vessels was modified to incorporate the effect of gas injection on the erosion rate. The liquid mercury target system for the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory now operates with helium gas injection to reduce target vessel fatigue stress and cavitation-induced erosion damage. Erosion damage is a primary degradation phenomenon affecting the service life of SNS target vessels, and cavitation mitigation techniques, such as small-bubble gas injection, have been implemented to reduce damage and extend target lifetimes. Erosion depths in samples removed from SNS targets after operation were measured using laser line scanning. These measurements confirmed that gas injection reduced erosion damage. However, quantifying the damage reduction due to gas injection was complicated by variations in lifetime, power, and gas injection rates between different targets. In this study, the operating power and gas injection rate of targets were incorporated into an erosion damage prediction model to quantify their effects on erosion damage reduction. Values of a power scaling factor, β, were calculated by comparing modeled with measured erosion damage. These values indicate that the use of gas injection at the SNS reduced damage to a level equivalent to operating targets without gas injection at 35–47% of the actual beam power. To account for the gas injection effect on the cavitation damage, a simple exponential form based on analysis of the scaling factor β was developed to incorporate the gas rate history with a scaling factor γ in the erosion damage modeling.
Biochars can remove potentially toxic elements, such as inorganic mercury [Hg(II)] from contaminated waters. However, their performance in complex water matrices is rarely investigated, and the combined roles of natural organic matter (NOM) and ionic composition in the removal of Hg(II) by biochar remain unclear. Here, we investigate the influence of NOM and major ions such as chloride (Cl – ), nitrate (NO 3 – ), calcium (Ca 2+ ), and sodium (Na + ) on Hg(II) removal by a wood-based biochar (SWP700). Multiple sorption sites containing sulfur (S) were located within the porous SWP700. In the absence of NOM, Hg(II) removal was driven by these sites. Ca 2+ bridging was important in enhancing removal of negatively charged Hg(II)-chloro complexes. In the presence of NOM, formation of soluble Hg-NOM complexes (as seen from speciation calculations), which have limited access to biochar pores, suppressed Hg(II) removal, but Cl – and Ca 2+ could still facilitate it. The ability of Ca 2+ to aggregate NOM, including Hg-NOM complexes, promoted Hg(II) removal from the dissolved fraction (<0.45 μm). Hg(II) removal in the presence of Cl – followed a stepwise mechanism. Weakly bound oxygen functional groups in NOM were outcompeted by Cl – , forming smaller-sized Hg(II)-chloro complexes, which could access additional intraparticle sorption sites. Therein, Cl – was outcompeted by S, which finally immobilized Hg(II) in SWP700 as confirmed by extended X-ray absorption fine structure spectroscopy. We conclude that in NOM containing oxic waters, with relatively high molar ratios of Cl – : NOM and Ca 2+ : NOM, Hg(II) removal can still be effective with SWP700.