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At least 847 records · Page 47

Supercritical Reforming of Wet Ethanol for High Efficiency Direct-injection Heavy-duty Compression-ignition Engines

The purpose of the research was to investigate the potential of using a mature bio-fuel in heavy-duty compression ignition engines. By co-optimizing both the fuel characteristics and engine system the potential for a superior outcome was demonstrated. The use of wet bio-ethanol eliminates the majority of the energy intensive distilling and dehydrating fuel production processes, which moves the fuel towards carbon neutral and also lowers the fuel costs. The relatively high water content of the resulting fuel is leveraged in the proposed novel combustion system by incorporating an integrated high efficiency exhaust waste heat recovery system. This results in significantly higher thermal efficiency. In addition the combustion system features low criteria pollutant emissions and the potential to reduce the initial cost of the engine system hardware. Substantial societal benefits are demonstrated through the co-optimization of the fuel and engine system. A computational proof-of-concept study has been performed to demonstrate the potential benefits of a novel wet ethanol heavy-duty compression ignition combustion system featuring integrated exhaust waste heat recovery. A combined in-cylinder closed cycle 3D computational fluid dynamics (CFD) - 1D engine system simulation approach was used. The models were validated to baseline engine data using diesel fuel and then applied to the wet ethanol study. The original concept was to maximize exhaust waste heat recovery through supercritical reforming of the wet ethanol fuel. Phase I simulation results indicated that the optimal solution for maximum engine efficiency gains were realized through maximizing thermo-mechanical recuperation with negligible fuel reformation. The results show the potential to achieve impressive gains in brake thermal efficiency (BTE) over the base diesel engine. The potential to increase BTE up to 20.9% over the base diesel engine was demonstrated, with even larger gains possible through reduced in-cylinder heat transfer losses. The majority of the efficiency gains were realized through integrated high efficiency exhaust waste heat recovery. The concept also has the potential to achieve future ultra-low NO x emissions standards and negligible engine-out soot emissions. The mixing controlled combustion of high temperature wet ethanol features relatively low engine-out NO x emissions without the need for exhaust gas recirculation (EGR). The soot free combustion enabled by the relatively high oxygen content of ethanol also allows for the use of stoichiometric mixing controlled combustion, which is not practical with diesel fuel. When stoichiometric combustion is used a simple passive 3-way catalyst can be used for exhaust emissions after-treatment and near zero tailpipe emissions. The Phase I simulations results have defined the system layout and requirements in preparation for the Phase II experimental proof-of-concept study. The potential applications of the research include most current applications of diesel engines. The Phase I study focused on heavy-duty on-highway class 8 trucks. However, virtually any application that requires highly efficient clean power generation would benefit from the novel engine system proposed. The results indicate substantial fuel cost savings and reduced greenhouse gas emissions with similar or reduced initial system hardware costs compared to modern diesel engine systems.

09 BIOMASS FUELS↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for Mn ions in low-density high-temperature plasmas

The analysis of optically-thin far-ultraviolet and X-ray emission lines of multiply-charged ions is one of the basic methods for determining the temperatures and densities of laboratory and astrophysical plasmas. In addition, the energy balance in these plasmas can be significantly influenced by the emission of radiation from relatively low concentrations of multiple-charged atomic ions. Because the populations of the excited levels are expected to depart substantially from their local thermodynamic equilibrium values a detailed treatment of the elementary collisional and radiative processes must be employed in order to predict the emission line intensities. In this investigation the authors present the results of calculations based on a corona equilibrium model in which a detailed evaluation is made of the dielectronic recombination rate coefficients. The ionization and autoionization following inner-shell electron excitation from each ground state are balanced by direct radiative and dielectronic recombination. The spectral line intensities emitted by the low-lying excited states, which are assumed to undergo spontaneous radiative decay in times that are short compared with the collision time, are evaluated in terms of the corona ionization equilibrium distributions of the ground states and their electron-impact excitation states.

Jacobs, V. L.↗

A search for chemical laser action in low pressure metal vapor flames

Optical emissions were studied from low pressure (approximately 1 torr) dilute diffusion flames of Ca and Mg vapor with O2, N2O and mixtures of CCl4 and O2. The Ca flames with O2 and N2O revealed high vibrational excitation of the product CaO molecule (up to v=30). The flames with CCl4 revealed extreme nonequilibrium metal atom electronic excitation, up to the metal atom ionization limit (6.1 eV for Ca, 7.6 eV for Mg). The metal atom excited electronic state populations did not follow a Boltzmann distribution, but the excitation rates ('pumping rate') were found to obey an Arrhenius-type expression, with the electronic excitation energy playing the role of activation energy and a temperature of about 5000 K for triplet excited states and 2500 K for singlets (vs. approximately 500 K translational temperature).

Zwillenberg, M. L.↗

Voyager spacecraft radio observations of Jupiter: Initial cruise results

Jupiter's low-frequency radio emission were detected by the planetary radio astronomy instruments onboard the two Voyager spacecraft. The emission is surprisingly similar in morphology but opposite in polarization to the high-frequency Jovian radio noise that were observed with ground-based telescopes for more than two decades. Several possible explanations for the behavior of the low-frequency emission are examined, but none of them is completely satisfactory.

Kaiser, M. L.↗

Morphology and spectral characteristics of the X-ray emission of M33

A previous analysis of the X-ray data on M33 has been extended to include a detailed study of the morpholgoy and spectral characteristics of the X-ray emission, and the results are reported. A low surface brightness, extended emission in the plane of the galaxy is detected. The X-ray luminosity of this component, about 10 to the 38th egs/s, is comparable to the total luminosity of the bright sources observed in the same region. Its radial distribution is similar to that of the blue light. The spectrum of the extended emission shows two distinct components: a hard one, with a temperature above 3 keV and a soft one with a temperature below 1 keV. The X-ray spectrum of the nuclear source, which is inconsistent with any of the known spectra of X-ray binary sources, can be fitted with either a low-temperature thermal emission or a steep power law model.

Trinchieri, G.↗

Planetary radio astronomy from Voyager

The technique of radio astronomy makes it possible for a remote observer to detect the presence of magnetic fields and plasmas in planetary environments. Prior to the flights of the Voyager spacecraft, radio astronomical studies of Jupiter from earth and from earth orbit had correctly predicted the strength and orientation of Jupiter's magnetic field and trapped radiation belts. The Voyager Planetary Radio Astronomy investigations have now provided measurements of the complete spectrum of low frequency radio emissions from both planets. Each Voyager instrument consists of a pair of orthogonal, 10-m, electric monopole antennas which are connected to a step-tuned, superheterodyne receiver operating over the frequency range from 1.2 kHz to 40.5 MHz. The Voyager trajectory provided observations from above both the sunlit and nightside hemispheres of Jupiter. Saturn's nonthermal radio emission has been observed at frequencies as low as 3 kHz and as high as 1.2 MHz.

Alexander, J. K.↗

Survey of emission-line galaxies: Universidad Complutense de Madrid list

A low-dispersion objective-prism survey for low-redshift emission-line galaxies (ELGs) is being carried out by the University Complutense de Madrid with the Schmidt telescope at the German-Spanish Observatory of Calar Alto (Almeria, Spain). A 4 deg full aperture prism, which provides a dispersion of 1950 A/mm, and IIIaF emulsion combination has been used to search for ELGs selected by the presence of H-alpha emission in their spectra. Our survey has proved to be able to recover objects already found by similar surveys with different techniques and, what is more important, to discover new objects not previously cataloged. A compilation of descriptions and positions, along with finding charts when necessary, is presented for 160 extragalactic emission-line objects. This is the first list, which contains objects located in a region of the sky covering 270 sq deg in 10 fields near alpha = 0(sup h) and delta = 20 deg.

Zamorano, J.↗

X-ray Emission from Magnetized Neutron Star Atmospheres at Low Mass Accretion Rates

Recent observations of X-ray pulsars at low luminosities allow, for the first time, to compare theoretical models for the emission from highly magnetized neutron star atmospheres at low mass accretion rates ( M ≲ 10(exp 15) g s(exp -1)) with the broadband X-ray data. The purpose of this paper is to investigate the spectral formation in the neutron star atmosphere at low M and to conduct a parameter study of physical properties of the emitting region. We obtain the structure of the static atmosphere, assuming that Coulomb collisions are the dominant deceleration process. The upper part of the atmosphere is strongly heated by the braking plasma, reaching temperatures of 30–40 keV, while its denser isothermal interior is much cooler (~2 keV). We numerically solve the polarized radiative transfer in the atmosphere with magnetic Compton scattering, free-free processes, and non-thermal cyclotron emission due to possible collisional excitations of electrons. The strongly polarized emitted spectrum has a double-hump shape that is observed in low-luminosity X-ray pulsars. A low-energy “thermal” component is dominated by extraordinary photons that can leave the atmosphere from deeper layers due to their long mean free path at soft energies. We find that a high-energy component is formed due to resonant Comptonization in the heated non-isothermal part of the atmosphere even in the absence of collisional excitations. The latter, however, affect the ratio of the two components. A strong cyclotron line originates from the optically thin, uppermost zone. A fit of the model to NuSTAR and Swift/XRT observations of GX304􀀀1 provides an accurate description of the data with reasonable parameters. The model can thus reproduce the characteristic double-hump spectrum observed in low-luminosity X-ray pulsars and provides insights into spectral formation.

X-Ray binaries↗

Refueling Infrastructure Deployment in Low-Income and Non-Urban Communities

The U.S. National Blueprint for Transportation Decarbonization identifies the need to invest in infrastructure supporting low- and zero-emission vehicles, especially in low-income and overburdened communities, to eliminate nearly all greenhouse gas emissions from the transportation sector by 2050. The alternative fuel vehicle refueling property tax credit (26 U.S. Code § 30C) includes eligibility criteria intended to encourage investment in underserved communities based on the economic characteristics or urban character of the census tract in which the fueling infrastructure is installed. Eligible census tracts are those that qualify for the New Markets Tax Credit or that are not located within urban areas as defined by the U.S. Census Bureau. This study quantifies how many fueling-related amenities are currently located in census tracts that qualify and do not qualify for the 30C tax credit based on IRS Notice 2024-20. For existing electric vehicle charging stations, 51% of Level 2 and 60% of Direct Current Fast Charging public stations are located in eligible census tracts. 73% of natural gas, propane, and hydrogen fueling stations are in qualifying census tracts and 75% of biodiesel and renewable fuel stations are in qualifying census tracts. This compares with 73% of existing gas stations in eligible census tracts. For deploying the refueling infrastructure to satisfy future demand, this study shows that truck stops (94%), commercial truck stops (92%), and Federal Highway alternative fuel corridors (89%) are predominantly located in eligible locations. Additionally, significant percentages of the population (62%), light-duty vehicle registrations (64%), and medium- and heavy-duty vehicle registrations (68%) fall within eligible areas.

33 ADVANCED PROPULSION SYSTEMS↗

Advanced Turbulence Modeling Concepts

The ZCET program developed at NASA Glenn Research Center is to study hydrogen/air injection concepts for aircraft gas turbine engines that meet conventional gas turbine performance levels and provide low levels of harmful NOx emissions. A CFD study for ZCET program has been successfully carried out. It uses the most recently enhanced National combustion code (NCC) to perform CFD simulations for two configurations of hydrogen fuel injectors (GRC- and Sandia-injector). The results can be used to assist experimental studies to provide quick mixing, low emission and high performance fuel injector designs. The work started with the configuration of the single-hole injector. The computational models were taken from the experimental designs. For example, the GRC single-hole injector consists of one air tube (0.78 inches long and 0.265 inches in diameter) and two hydrogen tubes (0.3 inches long and 0.0226 inches in diameter opposed at 180 degree). The hydrogen tubes are located 0.3 inches upstream from the exit of the air element (the inlet location for the combustor). To do the simulation, the single-hole injector is connected to a combustor model (8.16 inches long and 0.5 inches in diameter). The inlet conditions for air and hydrogen elements are defined according to actual experimental designs. Two crossing jets of hydrogen/air are simulated in detail in the injector. The cold flow, reacting flow, flame temperature, combustor pressure and possible flashback phenomena are studied. Two grid resolutions of the numerical model have been adopted. The first computational grid contains 0.52 million elements, the second one contains over 1.3 million elements. The CFD results have shown only about 5% difference between the two grid resolutions. Therefore, the CFD result obtained from the model of 1.3-million grid resolution can be considered as a grid independent numerical solution. Turbulence models built in NCC are consolidated and well tested. They can handle both coarse and fine grids near the wall. They can model the effect of anisotropy of turbulent stresses and the effect of swirling. The chemical reactions of Magnusson model and ILDM method were both used in this study.

Shih, Tsan-Hsing↗

Low-altitude ISIS 1 observations of auroral radio emissions and their significance to the cyclotron maser instability

Low-altitude ISIS 1 observations are presented which support the cyclotron maser instability as the generation mechanism of most, but not all, auroral radio emissions. The observations confirm the ability of the mechanism to generate different wave modes and harmonics as the ratio of the plasma frequency to gyrofrequency f(N)/f(H) increases depending on the form of the energetic electron distribution function. The present observations correspond to conditions where f(N)/F(H) is always larger than 0.2 and is typically about 1.0. The observations and instability growth rate calculations indicate that second harmonic radiation in the extraordinary and the Z modes is directly generated at low altitudes. By far the most common signals observed near ISIS 1 perigee, however, are in the fundamental Z and whistler modes. The observations and calculations in the case of the Z mode suggest that the pertinent process involves a maser that does not saturate, i.e., that group velocity effects are important. The whistler mode is the most intense signal observed at low altitudes. Since the cyclotron maser generated whistler mode waves have peak growth rates for downward field-aligned propagation, they should be able to penetrate the ionosphere. This process may provide the explanation of occasional reports, dating back to the International Geophysical Year time period, of ground level detection of radio noise associated with the aurora.

Benson, Robert F.↗

Mixing and NO(x) Emission Calculations of Confined Reacting Jet Flows in a Cylindrical Duct

Rapid mixing of cold lateral jets with hot cross-stream flows in confined configurations is of practical interest in gas turbine combustors as it strongly affects combustor exit temperature quality, and gaseous emissions in for example rich-lean combustion. It is therefore important to further improve our fundamental understanding of the important processes of dilution jet mixing especially when the injected jet mass flow rate exceeds that of the cross-stream. The results reported in this report describe some of the main flow characteristics which develop in the mixing process in a cylindrical duct. A 3-dimensional tool has been used to predict the mixing flow field characteristics and NOx emission in a quench section of an RQL combustor, Eighteen configurations have been analyzed in a circular geometry in a fully reacting environment simulating the operating condition of an actual RQL gas turbine combustion liner. The evaluation matrix was constructed by varying three parameters: 1) jet-to-mainstream momentum-flux ratio (J), 2) orifice shape or orifice aspect ratio, and 3) slot slant angle. The results indicate that the mixing flow field significantly varies with the value of the jet penetration and subsequently, slanting elongated slots generally improve the mixing uniformity at high J conditions. Round orifices produce more uniform mixing and low NO(x) emissions at low J due to the strong and adequate jet penetration. No significant correlation was found between the NO(x) production rates and the mixing deviation parameters, however, strong correlation was found between NO(x) formation and jet penetration. In the computational results, most of the NO(x) formation occurred behind the orifice starting at the orifice wake region. Additional NO(x) is formed upstream of the orifice in certain configurations with high J conditions due to the upstream recirculation.

Holdeman, James D.↗

Potential dependent spectroelectrochemistry of electrofluorogenic dyes on indium–tin oxide

Indium-tin oxide (ITO) is used in a variety of applications due to its electrical conductivity and optical transparency. Moreover, ITO-coated glass is a common working electrode for spectroelectrochemistry. Thus, the ITO substrates should exhibit well-understood spectroscopic characteristics. Here, we report anomalous potential-dependent luminescence emission from three structurally dissimilar electrofluorogenic probe on ITO-coated glass. The three probes, flavin mononucleotide, resorufin, and Nile blue, show the expected fluorescence modulation between their oxidized, emissive forms and their reduced, nonfluorescent forms at low laser irradiance and/or high concentrations. However, at high irradiance and/or low concentration, the emission intensity increases at reducing potentials, contrary to expectations. In addition, a strong interplay between probe molecule concentration and laser irradiance is observed. We attribute the anomalous behavior to a combination of (1) irradiance-dependent ITO carrier dynamics, and (2) interaction of the fluorescent probe with ITO at reducing potentials resulting in a charge transfer state with altered emission behavior. Thus, the potential- and irradiance-dependent behavior of ITO and the resulting charge transfer state may not only interfere with the observation of potential-dependent fluorescence from redox probes but can completely reverse the polarity of the potential-dependent luminescence, especially at high irradiance and low concentration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Synoptic observations of Jupiter's radio emissions: Average Statistical properties observed by Voyager

Observations of Jupiter's low frequency radio emissions collected over one month intervals before and after each Voyager encounter were analyzed. Compilations of occurrence probability, average power flux density and average sense of circular polarization are presented as a function of central meridian longitude, phase of Io, and frequency. The results are compared with ground based observations. The necessary geometrical conditions are preferred polarization sense for Io-related decametric emission observed by Voyager from above both the dayside and nightside hemispheres are found to be essentially the same as are observed in Earth based studies. On the other hand, there is a clear local time dependence in the Io-independent decametric emission. Io appears to have an influence on average flux density of the emission down to below 2 MHz. The average power flux density spectrum of Jupiter's emission has a broad peak near 9MHz. Integration of the average spectrum over all frequencies gives a total radiated power for an isotropic source of 4 x 10 to the 11th power W.

Alexander, J. K.↗

Fuel-Air Mixing Effect on Nox Emissions for a Lean Premixed-Prevaporized Combustion System

The lean premixed-prevaporized (LPP) concept effectively meets low nitrogen oxides (NOx) emission requirements for combustors with the high inlet temperature and pressure typical of the High-Speed Civil Transport (HSCT). For the LPP system fuel-air mixture uniformity is probably the most important factor for low NOx emissions. Previous studies have suggested that the fuel-air mixture uniformity can be severely affected by changing the number and configuration of fuel injection points. Therefore, an experimental study was performed to determine how the number of fuel injection points and their arrangement affect NOx emissions from an LPP system. The NOx emissions were measured by a gas-sampling probe in a flame-tube rig at the following conditions: inlet temperature of 810 K (1000 F), rig pressure of 10 atm, reference velocity of 150 ft/s, and residence time near 0.005 s. Additionally, a focused Schlieren diagnostic technique coupled with a high speed camera was used to provide a qualitative description of the spatial flow field.

Lee, Chi-Ming↗