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At least 847 records · Page 47

Acid Sulfate Alteration on Mars

A variety of mineralogical and geochemical indicators for aqueous alteration on Mars have been identified by a combination of surface and orbital robotic missions, telescopic observations, characterization of Martian meteorites, and laboratory and terrestrial analog studies. Acid sulfate alteration has been identified at all three landing sites visited by NASA rover missions (Spirit, Opportunity, and Curiosity). Spirit landed in Gusev crater in 2004 and discovered Fe-sulfates and materials that have been extensively leached by acid sulfate solutions. Opportunity landing on the plains of Meridiani Planum also in 2004 where the rover encountered large abundances of jarosite and hematite in sedimentary rocks. Curiosity landed in Gale crater in 2012 and has characterized fluvial, deltaic, and lacustrine sediments. Jarosite and hematite were discovered in some of the lacustrine sediments. The high elemental abundance of sulfur in surface materials is obvious evidence that sulfate has played a major role in aqueous processes at all landing sites on Mars. The sulfate-rich outcrop at Meridiani Planum has an SO3 content of up to 25 wt.%. The interiors of rocks and outcrops on the Columbia Hills within Gusev crater have up to 8 wt.% SO3. Soils at both sites generally have between 5 to 14 wt.% SO3, and several soils in Gusev crater contain around 30 wt.% SO3. After normalization of major element compositions to a SO3-free basis, the bulk compositions of these materials are basaltic, with a few exceptions in Gusev crater and in lacustrine mudstones in Gale crater. These observations suggest that materials encountered by the rovers were derived from basaltic precursors by acid sulfate alteration under nearly isochemical conditions (i.e., minimal leaching). There are several cases, however, where acid sulfate alteration minerals (jarosite and hematite) formed in open hydrologic systems, e.g., in Gale crater lacustrine mudstones. Several hypotheses have been suggested for the aqueous formation of sulfate-bearing phases under acidic conditions on the surface of Mars including (1) sulfuric acid weathering of basaltic materials; (2) oxidative weathering of ultramafic igneous rocks containing sulfides; (3) acid fog weathering of basaltic materials, and (4) near-neutral pH subsurface solutions rich in Fe2(+) that were rapidly oxidized to Fe3(+), which produced excess acidity as iron was oxidized on exposure to O2 or photo-oxidized by ultraviolet radiation at the martian surface. Next, we briefly describe evidence for these hypothesis.

Ming, D. W.↗

Use of differential plasma rotation to prevent disruptive tearing mode onset from 3-wave coupling

Abstract Plasma differential rotation is found to be capable of preventing disruptive neoclassical tearing modes (NTMs) seeded by nonlinear three-wave coupling. As tearing modes degrade confinement and can lead to disruptions, stabilization strategies are crucial to the successful operation of future devices. In ITER-relevant scenarios on DIII-D, rotationally coupled m / n = 1/1 and 3/2 modes have been observed to drive 2/1 islands through three-wave coupling. The frequency of the driven 2/1 mode is set by matching conditions and the frequencies of the driving modes. When the driven mode frequency matches the local plasma rotation frequency, e.g. at low differential rotation, the driven 2/1 island can grow into a disruptive NTM. Using neutral beam torque as an actuator to scan the differential rotation, these experiments demonstrate that a sufficiently large frequency mismatch prevents destabilization of disruptive 2/1 NTMs by three-wave coupling. This work indicates that differential rotation can be used as an actuator to prevent NTMs seeded by three-wave coupling.

Richner, N. J. (ORCID:0000000155443915)↗

A flight investigation of static stability, control augmentation, and flight director influences on helicopter IFR handling qualities

A flight experiment was conducted using the NASA-Army V/STOLAND UH-1H variable-stability helicopter to investigate the influence of several longitudinal-static-stability, control-augmentation, and flight-director parameters on helicopter flying qualities during terminal area operations in instrument conditions. This experiment, which was part of a joint NASA/FAA program pertaining to helicopter IFR airworthiness, was designed to corroborate and extend previous ground simulation results obtained in this program. Variations examined included stable and neutral longitudinal control position gradients, rate-damping and attitude-command augmentation, and raw data versus flight-director displays. Pilot rating results agreed excellently with the ground simulation data, indicating an adequate instrument capability with rate-damping augmentation and neutral statics and the need for pitch-roll attitude augmentation to achieve a satisfactory system.

Lebacqz, J. V.↗

On the formation and expansion of H II regions

The evolution of H II regions in spherical clouds with small, constant-density cores and power-law density distributions r exp -w outside the core is described analytically. It is found that there is a critical exponent above which the cloud becomes completely ionized. Its value in the formation phase depends on the initial conditions, but it has a well-defined value w(crit) = 3/2 during the expansion phase. For w less than w(crit), the radius of the H II region grows at a given rate, while neutral mass accumulates in the interphase between the ionization and shock fronts. For w = w(crit), the fronts move together without mass accumulation. Cases with w greater than w(crit) lead to the champagne phase: once the cloud is fully ionized, the expansion becomes supersonic. For self-gravitating disks without magnetic fields, the main features include a new 'variable-size' stage. The initial shape of the H II region has a critical point beyond which the disk becomes completely ionized.

Franco, Jose↗

Ratio of Sodium to Potassium in the Mercurian Exosphere

Sodium (Na) and Potassium (K) atoms can be seen in the exosphere of Mercury and the Moon because they are extremely efficient at scattering sunlight. These species must be derived from surface materials, so that we might expect the ratio of sodium to potassium to reflect the ratio of these elements in the surface crust. This expectation is approximately born out for the Moon, where the ratio of sodium to potassium in the lunar exosphere averages to be about 6, not too far from the ratio in lunar rocks of 2 to 7. However, the ratio in the Mercury exosphere was found to be in the range 80 to 190, and at least once, as high as 400. The sodium and potassium atoms seen in the Mercury exosphere represent a balance between production from the surface and loss to space. Only if the production efficiencies and loss rates for Na and K were equal, would the ratio of Na to K in the exosphere reflect the ratio in the surface rocks. Since a value of 100 or more for the ratio of sodium to potassium in the surface rocks seems very unlikely, the high values of the observed ratios suggests that either production efficiencies or loss processes for the two elements are not equivalent. It does not seem likely that source processes should be different on the Moon and Mercury by an order of magnitude. This suggests that loss processes rather than source processes are the cause of the difference between the two. The major loss processes for sodium and potassium on Mercury are radiation pressure and trapping of photoions by the solar wind. Radiation pressure can reach 50-70% of surface gravity, and can sweep sodium and potassium atoms off the planet, provided they are sufficiently hot. Photoionization followed by trapping of the ions in the solar wind is the other major loss process. Photoions are accelerated to keV energies in the magnetosphere, and may either intercept the magnetopause, and be lost from the planet, or impact the planetary surface. Ions that impact the surface are neutralized, and are then available for resupply to the exosphere. The loss efficiency depends on characteristics of the magnetosphere that determine the fraction of the ions that are recycled by neutralization on the surface. Over the preceding decade, we have collected sodium and potassium data for Mercury at irregular intervals. We analyzed these data to extract values for the Na/K ratio at a variety of conditions on Mercury. Additional information is contained in the original extended abstract.

Potter, A. E.↗

A Method to Identify the Heat Flux From Photons and Neutrals at the Divertor Target

The Surface Eroding Thermocouple (SETC) is a diagnostic designed for fast surface heat flux measurement and has been successfully applied in DIII-D to investigate divertor detachment. A novel method has been developed of using a combination of surface-facing and recessed SETCs to distinguish between the heat flux from charged particles, and that from neutrals and radiative heating. Furthermore, this technique suggests that at least 20% of the total incident heat flux is attributable to the latter sources not trapped in the magnetic field in a fully detached open divertor condition. It not only indicates the non-charged particle heating significantly contributes to the total surface heat flux in detached divertor conditions, but also demonstrates the feasibility of using two operational modes of SETCs to distinguish between the two surface heating mechanisms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Achievement of Reactor-Relevant Performance in Negative Triangularity Shape in the DIII-D Tokamak

Plasma discharges with a negative triangularity (δ=−0.4) shape have been created in the DIII-D tokamak with a significant normalized beta (βN=2.7) and confinement characteristic of the high confinement mode (H98y2=1.2) despite the absence of an edge pressure pedestal and no edge localized modes (ELMs). These inner-wall-limited plasmas have a similar global performance as a positive triangularity (δ=+0.4) ELMing H-mode discharge with the same plasma current, elongation and cross sectional area. For cases both of dominant electron cyclotron heating with Te/Ti>1 and dominant neutral beam injection heating with Te/Ti=1, turbulent fluctuations over radii 0.5<ρ<0.9 were reduced by 10–50% in the negative triangularity shape compared to the matching positive triangularity shape, depending on the radius and conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A new solution to the accretion problem.

The Bondi-Hoyle theory of line-accretion is briefly reviewed, and it is shown that there are an infinity of steady-state solutions satisfying the requirements originally imposed as boundary conditions. Questions are raised as to the applicability of these solutions to physical reality. The existence of an entirely different type of steady-state solution that implies slow velocity in the accretion stream beyond the neutral point is demonstrated. Accurate numerical values of this solution are obtained for a number of cases. The braking action given by this solution, for any selected cut-off distance, is far stronger than in the Bondi-Hoyle solution. Consideration of the physical state in the accretion stream shows that for this slow solution the appropriate cutoff range would be only of the order of 100 AU rather than of interstellar-distance order.

Lyttleton, R. A.↗

The contribution of electron collisions to rotational excitations of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in comet Halley during the Giotto spacecraft encounter. In the case of the O(sub 00) yields 1(sub 11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral collisions, and the rotational temperature retrieved from high resolution infrared spectra of water in comet Halley may reflect electron temperatures rather than neutral gas temperature in the intermediate coma.

Xie, Xingfa↗

Nonlinear unstable auroral-arc driven thermospheric winds in an ionosphere-magnetosphere coupled model

The nonlinear evolution of thermospheric winds in an ionosphere-magnetosphere coupled model has been studied for the first time for a dynamic unstable auroral-arc environment. We treat the problem using a multi-layer, quasi-three-dimensional model which averages in altitude the thermospheric dynamics over each layer. For the upper thermosphere, we find that (1) the thermosphere can respond to the ionospheric Kelvin-Helmholtz (KH) instability on temporal scales on the order of an hour, depending on ambient conditions, and on spatial scales of tens to hundreds of kilometers, (2) strong thermospheric meridional and zonal vortical flows with embedded nonlinear jet-like structures can be generated by the ionospheric/magnetospheric KH instability and (3) neutral thermospheric winds, vortices, and associated power spectra develop in a distinctly different manner in the presence of magnetospheric coupling effects. Comparison with recent observations is made.

Keskinen, M. J.↗

NASA GRC and MSFC Space-Plasma Arc Testing Procedures

Tests of arcing and current collection in simulated space plasma conditions have been performed at the NASA Glenn Research Center (GRC) in Cleveland, Ohio, for over 30 years and at the Marshall Space flight Center (MSFC) for almost as long. During this period, proper test conditions for accurate and meaningful space simulation have been worked out, comparisons with actual space performance in spaceflight tests and with real operational satellites have been made, and NASA has achieved our own internal standards for test protocols. It is the purpose of this paper to communicate the test conditions, test procedures, and types of analysis used at NASA GRC and MSFC to the space environmental testing community at large, to help with international space-plasma arcing testing standardization. To be discussed are: 1. Neutral pressures, neutral gases, and vacuum chamber sizes. 2. Electron and ion densities, plasma uniformity, sample sizes, and Debye lengths. 3. Biasing samples versus self-generated voltages. Floating samples versus grounded. 4. Power supplies and current limits. Isolation of samples from power supplies during arcs. Arc circuits. Capacitance during biased arc-threshold tests. Capacitance during sustained arcing and damage tests. Arc detection. Preventing sustained discharges during testing. 5. Real array or structure samples versus idealized samples. 6. Validity of LEO tests for GEO samples. 7. Extracting arc threshold information from arc rate versus voltage tests. 8 . Snapover and current collection at positive sample bias. Glows at positive bias. Kapton pyrolization. 9. Trigger arc thresholds. Sustained arc thresholds. Paschen discharge during sustained arcing. 10. Testing for Paschen discharge thresholds. Testing for dielectric breakdown thresholds. Testing for tether arcing. 11. Testing in very dense plasmas (ie thruster plumes). 12. Arc mitigation strategies. Charging mitigation strategies. Models. 13. Analysis of test results. Finally, the necessity of testing will be emphasized, not to the exclusion of modeling, but as part of a complete strategy for determining when and if arcs will occur, and preventing them from occurring in space.

Ferguson, Dale C.a↗

Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof

Catalysts prepared from abundant, cost effective metals, such as cobalt, nickel, chromium, manganese, iron, and copper, and containing one or more neutrally charged ligands (e.g., monodentate, bidentate, and/or polydentate ligands) and methods of making and using thereof are described herein. Exemplary ligands include, but are not limited to, phosphine ligands, nitrogen-based ligands, sulfur-based ligands, and/or arsenic-based ligands. In some embodiments, the catalyst is a cobalt-based catalyst or a nickel-based catalyst. The catalysts described herein are stable and active at neutral pH and in a wide range of buffers that are both weak and strong proton acceptors. While its activity is slightly lower than state of the art cobalt-based water oxidation catalysts under some conditions, it is capable of sustaining electrolysis at high applied potentials without a significant degradation in catalytic current. This enhanced robustness gives it an advantage in industrial and large-scale water electrolysis schemes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Theory for the Balance between Warm Rain and Ice Crystal Processes of Precipitation in Mixed-Phase Clouds

Abstract Mixed-phase clouds contain both supercooled cloud liquid and ice crystals. In principle, precipitation may be initiated either by the liquid phase or by the ice phase. Ice crystals may grow by vapor diffusion to become snow (“ice crystal process”), forming “cold” precipitation. Equally, cloud droplets, when large enough, coalesce to form “warm” precipitation by the “warm rain process.” Warm rain could be supercooled and freeze as “warm” graupel. In the present paper, a new simplified theoretical analysis is provided to examine the microphysical system consisting of three species of hydrometeor, namely, cloud liquid, “cold ice” (crystals, snow), and “warm rain” (frozen or supercooled). This is obtained by nondimensionalizing and simplifying the evolution equations for the mass of each species. Analytical formulas are given for equilibria. Feedback analysis shows that the sign of the feedback is linked to the abundance of precipitation, with a neutral surface in the 3D phase space. The system’s precipitation amount explodes while in the initial unstable regime, crossing the neutral surface and approaching the equilibrium point that is a stable attractor. Positive and negative feedbacks are elucidated. In a standard case, the cold ice mass is about 1000 times larger than the warm rain mass. To illustrate the physical behavior of the theory, sensitivity tests are performed with respect to environmental conditions (e.g., aerosol, updraft speed) and microphysical parameters (e.g., riming and sedimentation rates for cold ice). Cold ice prevails, especially in fast ascent, due to its low bulk density, favoring slow sedimentation and a wide cross-sectional area for riming. Significance Statement The theory elucidates how the ice phase can prevail in the precipitation from any mixed-phase clouds with supercooled cloud liquid and crystals. The ice phase radically suppresses cloud liquid by riming when active and “wins” the competition against coalescence. This prevalence of ice is shown to arise from the low bulk density of snow. The cloud is viewed as a system of negative and positive feedbacks that prevail in realms of stability and instability in a 3D phase space.

Meteorology & Atmospheric Sciences↗

Argon: A thermometer of the upper atmosphere

The exospheric temperatures are derived from Ar, N2, O and He measurements obtained from the Aeros-1 NATE experiment. It is shown that the temperatures derived from Ar and N2 are very close to each other and show very similar seasonal, latitudinal and the day to night variations both under quiet and the geomagnetically disturbed conditions. The temperatures derived from O and He do not usually follow this pattern because of their large variabilities in the lower thermosphere. The differences in the inferred temperatures from these gases are particularly noticeable when the neutral composition data between 220-250 km are used. In this altitude region Ar appears to have some advantage over N2 for the purpose of deriving neutral temperature.

Chandra, S.↗

A piloted simulator investigation of static stability and stability/control augmentation effects on helicopter handling qualities for instrument approach

A ground simulator experiment was conducted on the Flight Simulator for Advanced Aircraft at Ames Research Center to investigate the influence of several static stability and stability/control augmentation design parameters on helicopter flying qualities during terminal area operations in instrument conditions. Effects of light turbulence were included. Two levels of static stability in each rotational axis (pitch, roll, yaw) were examined for a hingeless rotor configuration. The variations in pitch and roll were: (1) stable and (2) neutral static stability; in yaw there were two stable levels. Four types of stability/control augmentation were also examined for the lower level of static stability in each axis. This latter investigation covered three helicopter rotor types: hingeless, articulated, and teetering. Four pilots performed a total of 105 evaluations of these parameters for a representative VOR instrument approach task. Pilot rating results indicate the acceptability of neutral static stability longitudinally and laterally and the need for pitch-roll attitude augmentation to achieve a satisfactory system.

Lebacqz, J. V.↗

Infrared Line Emission from Molecular Gas Heated by X-Rays and Energetic Electrons

"I propose to carry out a detailed study using infrared observations (and in some cases, optical and ultraviolet observations) of dense interstellar gas exposed to intense fluxes of X-rays and/or energetic electrons. This is undoubtedly the dominant source of line emission for clouds exposed to X-rays from active galactic nuclei, supernova shocks, or embedded X-ray sources (e.g., X-ray binaries), or to high-temperature or relativistic electrons in galaxy clusters, near powerful radio sources, or supernova remnants. Detailed physical and chemical models of such clouds will be used to analyze infrared observations of the Great Annihilator X-ray source in the Galactic Center, cD galaxies in massive cooling flows, and the nuclei of Seyfert galaxies which will be obtained with the Infrared Space Observatory (ISO), UV and optical observations of the Crab Nebula obtained with the Hubble Space Telescope, and ground-based near-infrared observations of Seyfert nuclei. Results from this work will also be of great relevance to observations obtained with the Submillimeter Wave Astronomical Satellite (SWAS). In the first year of funding of this proposal, my chief collaborators (D.J. Hollenbach and A.G.G.M. Tielens, both of NASA Ames Research Center) and I concentrated on completing our models of the physical conditions in, and the resulting line emission from, dense gas irradiated by X-rays. As noted in the original proposal, some important physical processes were not yet thoroughly incorporated into our models at the time of submission. We completed our modeling of the physical conditions and line emission for essentially the entire range of parameter space (five orders of magnitude in X-ray flux to gas density ratio) occupied by typical dense interstellar clouds in which the gas is mostly neutral and X-rays are important for the ionization, chemistry, and thermal balance.

Maloney, Philip R.↗

Potentially Habitable Ancient Environments in Gusev Crater, Mars

Habitable environments must sustain liquid water at least intermittently and also provide both chemical building blocks and useful sources of energy for life. Observations by Spirit rover indicate that conditions have probably been too dry to sustain life, at least since the emplacement of the extensive basalts that underlie the plains around the Columbia Memorial Station landing site. Local evidence of relatively minor aqueous alteration [1] probably occurred under conditions where the activity of water was too low to sustain biological processes as we know them. In contrast, multiple bedrock units in West Spur and Husband Hill in the Columbia Hills have been extensively altered. Patterns of elemental abundances are consistent with aqueous processes involving migrating fluids [2]. Fe in several of these units has been extensively oxidized [3]. Conceivably any microbiota present during the aqueous alteration of these rocks might have obtained energy from Fe oxidation. Spirit discovered olivine-rich ultramafic rocks during her descent from Husband Hill southward into Inner Basin. Alteration of similar ultramafic rocks on Earth can yield H2 that can provide both energy and reducing power for microorganisms. Spirit's discovery of deposits rich in ferric sulfate is consistent with the aqueous dissolution and/or alteration of olivine under acidic conditions [2] such as those associated with hydrothermal activity. The oxidation of iron and sulfur that can accompany such activity can be an energy source for life. Hydrothermal systems on Earth that sustain either acidic [4] or neutral to alkaline fluids [5] have been shown to provide this energy. Collectively the observations by Spirit rover are consistent with the possibility that habitable environments existed in Gusev crater at least intermittently in the distant geologic past.

Fe oxidation↗