Fracture mechanics and the time dependent strength of adhesive joints
Fracture mechanics and time dependent strength of elastic or viscoelastic solids adhesively jointed by soft polymeric bonding layer
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Fracture mechanics and time dependent strength of elastic or viscoelastic solids adhesively jointed by soft polymeric bonding layer
Elastic adhesive interlayer effect on bond fracture strength, considering propellant-liner- steel combination in solid rocket motors
Bulk and surface diffusion roles in clean and contaminated Cu-Ni surfaces adhesion
Vacuum pumped Apollo 12 lunar soil sample 12001,118 gas exposure effects, interface microanalysis and adhesion measurements in ultrahigh vacuum system
Surface segregation, adhesion and friction of monocrystalline Cu-Al, Cu-Sn and Fe-Al alloys from Auger emission spectroscopy and low energy electron diffraction experiments
Formulation of polymers has been devised that, when vibrated, adhesive becomes more fluid (thixotropic) to better absorb shock and, when warmed, will actually hold its shape better (thermosetting) rather than deform.
Polyurethane adhesive mixed to various proportions with milled glass fibers match the thermal characteristics of 2014-T6 aluminum at cryogenic temperatures.
The adhesion and transfer of polytetrafluoroethylene (PTFE) to metals in ultrahigh vacuum has been studied using Auger emission spectroscopy. The transfer was effected both by compressive static contact and by sliding contact. The transfer observed after static contact was independent of the chemical constitution of the substrate. Electron induced desorption of the fluorine in the transferred PTFE showed that the fluorine had no chemical interaction with the metal substrate. The coefficient of friction on metals was independent of the chemical constitution of the substrate. However, sliding PTFE on soft metals such as aluminum, generated wear fragments that lodged in the PTFE and machined the substrate.
The adhesion and transfer of polytetrafluoroethylene (PTFE) to metals in ultrahigh vacuum were studied. The transfer was effected both by compressive static contact and by sliding contact. The transfer observed after static contact was independent of the chemical constitution of the substrate. Electron-induced desorption of the fluorine in the transferred PTFE showed that the fluorine had no chemical interaction with the metal substrate. The coefficient of friction on metals was independent of the chemical constitution of the substrate. However, sliding PTFE on soft metals, such as aluminum, generated wear fragments that lodged in the PTFE and machined the substrate.
Structural adhesive consists of titanium chelate polymer, reactive plasticizer, and cure accelerator (phenylsilanetriol). Mixture polymerizes in situ in 65 hours at 170 C.
Technical information on chemical formulations for improving and/or producing adhesives is presented. Data are also reported on polymeric plastics with special characteristics or those plastics that were produced by innovative means.
A theoretical model is developed to establish an adhesion criterion for the interaction of a gas atom or molecule with a nonmetallic surface. As a first approximation a linear lattice mass points of the solid surface is considered and the classical lattice dynamical model is used.
A commercially used cast cobalt base alloy was investigated as a turbine shroud material which revealed a surface enriched with tungsten and carbon suggesting a surface layer of tungsten carbide. Adhesion and friction of this segregated surface layer are higher than for the bulk cobalt base alloy composition. Auger spectroscopy analysis of the segregation of tungsten in the alloy indicates that it occurs between 850 and 1000 C.
The adhesion, friction, and wear behavior of the solid polymers PTFE and polyimide in contact with various metals were studied using field ion microscopy, Auger emission spectroscopy, and scanning electron microscopy. Results indicate that the polymers will transfer to a clean tungsten surface on simple tough contact, forming a chemical bond. With PTFE, it is hypothesized that the bonding is of the carbon to the metal surface, while with the polyimide, both oxygen and carbon bonding to the tungsten surface are possible. In sliding contact, the friction process itself can initiate polymer film formation. The formation of such films has been suggested as a form of extreme pressure lubrication.
High bonding strengths are obtained for metals and fiber-reinforced organic resin composites with no significant loss in thermo-oxidative stability of the adhesive resin.
Numerical or analytical analyses were performed on seven different test specimens including blister test, 90-degree peel test, torsion test, and various cone tests. These specimens are in general subjected to complex stress fields having various amounts of Mode I, Mode II, and Mode III loads. The specimens were then constructed using polymethyl methacrylate for the adherends and a transparent polyurethane elastomer (Solithane 113) for the adhesive. This combination permitted direct observation of the bondline as load was applied. Although initial debonds as well as bond end termination singularities were present in all specimens, in some cases the debond did not initiate at the singularity points as would normally have been expected. An explanation for this behavior is presented, as well as a comparison of loading mode effect on those specimens for which the debond did propagate from a bond terminus singular point.
Report discusses number of tests used in comparing polymer adhesives with metal bonding processes and includes charts and photographs to illustrate test results. Findings suggest reduced quality control costs when epoxies are used in fabrication of microcircuits.
An experimental program was conducted to identify the outgassing rate for a shuttle baseline thermal protective surface (TPS) which utilizes room temperature volcanizing (RTV) 560 adhesive. Results are discussed.