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Structure and Dynamics of the Quiet Solar Chromosphere

The grant supported research on the structure of the quiet, nonmagnetic chromosphere and on wave excitation and propagation in both the nonmagnetic chromosphere and the magnetic network. The work on the structure of the chromosphere culminated in the recognition that between two competing views of the solar chromosphere, older models by Avrett and collaborators (referred to as VAL) and the newer, dynamical model by Carlsson & Stein (referred to as CS), the clear decision is in favor of the older models, and this in spite of the evident lack of physics, which does not include wave motion and oscillations. The contrast between the static VAL models and the dynamical CS model can be stated most succinctly by comparing the temperature variation implied by the VAL models and the temperature fluctuations of the CS model, which are, respectively, of the order of 10% for the VAL model (at heights where hydrogen is 50% ionized) and a factor of 10 (at the upper boundary of their chromospheric model). The huge fluctuations of the CS model have never been observed, whereas the smaller temperature variations of the VAL models are consistent with ground-based and space-based observations. While it should be obvious which model describes the Sun and which one fails, the case is far from settled in the minds of solar physicists. Thus, much educational work remains to be done and, of course, more research to develop arguments that make the case more convincing. The research on waves and oscillations has been based on a unified theory of excitation of acoustic waves in the field-free atmosphere and of transverse and longitudinal waves in magnetic flux tubes located in the magnetic network by noting, first, that impulsive excitation of all these waves in gravitationally stratified media leads to oscillations at the respective cutoff frequencies and, second, that the observed oscillation frequencies in the nonmagnetic and magnetic parts of the chromosphere match corresponding cutoff frequencies in the upper solar photosphere. The dynamical simulations by Carlsson and Stein have been most instructive and of fundamental importance for understanding wave propagation in a stratified medium by their "flaws", the most important of which is an intensity excess at the H2v emission peak in the H line of Ca II, which is surprising since the observed intensity should have been an upper limit to the simulated intensity. The only plausible explanation for a predicted intensity that is higher than observed is that energy is spread horizontally in upward propagation in the Sun, but not in the plane-wave modeling of CS (as well as by almost everyone else). Investigations of the horizontal size of the region disturbed by the upward-propagating shock in the acoustic-wave propagation implies that the waves in H2v bright-point oscillations emanate from a point source with a diameter corresponding to the width of an intergranular lane, about 100 km, and reach a size of about 4000 km in the upper layers of the chromosphere. Linear, analytic modeling of waves emanating from a point source in a stratified atmosphere shows that the upward-expanding propagation channel does not have sharp boundaries and that the shape of the wave front depends on the order of the wave behind the initial pulse. Otherwise, the behavior of the linear waves resembles that of the nonlinear shock waves observed in the Sun. Research that needs to be done to firm up the conclusions reached above concerns the numerical simulations of nonlinear waves and oscillations in a three-dimensional stratified atmosphere with impulsive excitation, and observations linking directly the horizontal size of the disturbed area in upward propagation to individual waves.

Kalkofen, Wolfgang↗

Impact of point spread function higher moments error on weak gravitational lensing

ABSTRACT Weak gravitational lensing is one of the most powerful tools for cosmology, while subject to challenges in quantifying subtle systematic biases. The point spread function (PSF) can cause biases in weak lensing shear inference when the PSF model does not match the true PSF that is convolved with the galaxy light profile. Although the effect of PSF size and shape errors – i.e. errors in second moments – is well studied, weak lensing systematics associated with errors in higher moments of the PSF model require further investigation. The goal of our study is to estimate their potential impact for LSST weak lensing analysis. We go beyond second moments of the PSF by using image simulations to relate multiplicative bias in shear to errors in the higher moments of the PSF model. We find that the current level of errors in higher moments of the PSF model in data from the Hyper Suprime-Cam survey can induce a ∼0.05 per cent shear bias, making this effect unimportant for ongoing surveys but relevant at the precision of upcoming surveys such as LSST.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaporation Submodel Development for Volume of Fluid (eVOF) Method Applicable to Spray-Wall Interaction Including Film Characteristics with Validation at High Pressure and Temperature Conditions

Internal combustion engines have seen a great evolution over the last several decades through application of high pressure direct injection, multiple injections, and other technologies to reduced fuel consumption, NOx, and PM. Although combustion systems with advanced injection strategies have been studied extensively, there exists a significant fundamental knowledge gap on the fuel-spray interactions with the piston surface and chamber walls. Advanced computational codes validated with experimental techniques have to be developed for accurate representation of the drop impingement, fuel film formation, and vaporization. Current engine CFD (Computational Fluid Dynamics) spray models utilize a Lagrangian framework for modeling which lacks critical considerations of the physics pertaining to these interactions and thus requiring extensive parameterization, tuning and validation. The team from Michigan Technological University, University of Massachusetts Dartmouth, and Argonne National Laboratory is composed of experts in sprays, combustion, engines and CFD with a wide spectrum of knowledge including specific expertise in the area under consideration. In the proposed work, a VOF (Volume of Fluid) modeling approach has been adopted for the spray-wall interaction, film formation and spreading, and vaporization. With the inclusion of a vaporization submodel, a more predictive and accurate simulation of the spray-film was performed without extensive need of parameterization and tuning. Extensive experimentation of the spray-wall interaction under the range of conditions matching the thermodynamic and surface temperatures that occur in diesel and gasoline engines were conducted to validate the SWI submodels and for development of the evaporation submodel, which has been implemented in the flow solver.

42 ENGINEERING↗

Scale-free models of galaxies. II - A complete survey of orbits

A complete set of orbits starting at over 400 distinct points spread out in the phase space of an oblate scale-free potential is investigated. Each orbit is followed for a time that corresponds to a Hubble time in a realistic galaxy potential suitable for an E5 or E6 galaxy. It is noted that none of the orbits in the survey is ergodic. All of the survey orbits are regular, visiting a region at least one dimension smaller than expected from the classical integrals of motion. Thus, for all practical purposes, they have an extra nonclassical isolating integral. Approximately 95% of the survey orbits are box orbits, the rest being pipes (formerly tubes). The survey exposes an ambiguity in the original classification scheme for orbits, which, it is noted, can be resolved on the basis of the topology of an orbit's surface of section. Nevertheless, the distinction between high order very convoluted pipes and boxes is probably artificial for practical purposes.

Richstone, D. O.↗

Solid-state combustion synthesis of ceramics and alloys in reduced gravity

Possible microgravity effects are explored in the combustion synthesis of ceramics and alloys from their constituent elements. Molten intermediates are typically present during the combustion process, thereby offering the chance for natural convection to take place. Numerical simulations suggest that the combustion front in concert with gravity may act as a partial zone-refinement mechanism which is attempting to sweep out porosity in the sample. Contrary to suggestions by dimensional analysis, no effects on the combustion rate are seen. An analytical model of the combustion velocity as a function of the gravitational field and the spreading rate of molten material gives the correct order of magnitude of the gravity effect as measured by centrifuge experiments.

Valone, S. M.↗

X-ray constraints on the intergalactic medium

We use ROSAT Position Sensitive Proportional Counter (PSPC) spectra of z approximately equal 3 quasars to constrain the density and temperature of the intergalactic medium (IGM). Strong low-energy cutoffs in PSPC spectra of high-redshift quasars are common. However, the absence of absorption toward some high-redshift quasars can be used to put limits on the possible cosmological density, Omega(sub G), of a hot diffuse intergalactic medium (IGM), via an X-ray Gunn-Peterson test using edge and line opacity in the soft X-rays. The K-edges of oxygen, neon, and carbon and the L-edge of iron produce most of the absorption which is spread out by the redshift of the source. We assume an isotropic, isothermal, nonevolving model of the IGM and calculate the optical depth of this absorption. We find that this test can constrain an enriched IGM at temperatures near 10(exp 5) - 10(exp 6) K, intermediate between the hot IGM ruled out by COBE, and the cold IGM ruled out by the traditional Ly alpha Gunn -Peterson test. Photoionization if the IGM by the ultraviolet and X-ray background has a large effect. We give results for three z approximately equal 3 quasars and discuss how the various trade-offs among temperature, abundance, and backgroud radiation strength affect the limits on Omega (sub G). In addition to the high-redshift case, we discuss techniques for constraining the IGM using X-ray spectra of low-redhift quasars (z approximately equal 0.1 - 0.3). Currently available X-ray spectral data have insufficient energy resolution to constrain the IGM umambiguously, and so expected detection limits for future high-resolution spectrometers are presented. We find that with a large effective area (approximately 2000 sq cm), it is possible to substantially constrain or detect the IGM at the densities which are typically predicted.

Aldcroft, Thomas↗

The Role of Gravity Waves in Modulating Atmospheric Tides

We discuss results for the diurnal and semidiurnal tides obtained from our 3-D, time dependent numerical spectral model (NMS), extending from the ground up into the thermosphere, which incorporates Hines' Doppler spread parameterization of small scale gravity waves (GW). In the DSP, GW momentum (and energy) are conserved as the waves modulate the background flow and are filtered by the flow.As a consequence, the GW interaction tightly couples the dynamic components of the middle atmosphere with strong non-linear interactions between mean zonal circulation, tides and planetary waves to produce complicated patterns of variability much like those observed. The major conclusions are: (1) Since GW momentum is deposited in the altitude regime of increasing winds, the amplitude of the diurnal tide is amplified and its vertical wavelength is reduced at altitudes between 80 and 120 km. Wave filtering by the mean zonal circulation (with peak velocities during solstice) causes the GW flux to peak during equinox, and this produces a large semi-annual variation in the tide that has been observed on UARS. (2) Without the diurnal tide, the semidiurnal tide would also be modulated in this way. But the diurnal tide filters out the GW preferentially during equinox, so that the semidiurnal tide, at higher altitudes, tends to peak during solstice. (3) Under the influence of GW, the tides are modulated also significantly by planetary waves, with periods between 2 and 30 days, which are generated preferentially during solstice in part due to baroclinic instability.

Mayr, H. G.↗

Two-Photon Fluorescence Microscope for Microgravity Research

A two-photon fluorescence microscope has been developed for the study of biophysical phenomena. Two-photon microscopy is a novel form of laser-based scanning microscopy that enables three-dimensional imaging without many of the problems inherent in confocal microscopy. Unlike one-photon optical microscopy, two-photon microscopy utilizes the simultaneous nonlinear absorption of two near-infrared photons. However, the efficiency of two-photon absorption is much lower than that of one-photon absorption, so an ultra-fast pulsed laser source is typically employed. On the other hand, the critical energy threshold for two-photon absorption leads to fluorophore excitation that is intrinsically localized to the focal volume. Consequently, two-photon microscopy enables optical sectioning and confocal performance without the need for a signal-limiting pinhole. In addition, there is a reduction (relative to one-photon optical microscopy) in photon-induced damage because of the longer excitation wavelength. This reduction is especially advantageous for in vivo studies. Relative to confocal microscopy, there is also a reduction in background fluorescence, and, because of a reduction in Rayleigh scattering, there is a 4 increase of penetration depth. The prohibitive cost of a commercial two-photon fluorescence-microscope system, as well as a need for modularity, has led to the construction of a custom-built system (see Figure 1). This system includes a coherent mode-locked titanium: sapphire laser emitting 120-fs-duration pulses at a repetition rate of 80 MHz. The pulsed laser has an average output power of 800 mW and a wavelength tuning range of 700 to 980 nm, enabling the excitation of a variety of targeted fluorophores. The output from the laser is attenuated, spatially filtered, and then directed into a confocal scanning head that has been modified to provide for side entry of the laser beam. The laser output coupler has been replaced with a dichroic filter that reflects the longer-wavelength excitation light and passes the shorter-wavelength fluorescence light. Also, the confocal pinhole has been removed to increase the signal strength. The laser beam is scanned by a twoperpendicular- axis pair of galvanometer mirrors through a pupil transfer lens into the side port of an inverted microscope. Finally, the beam is focused by a 63-magnification, 1.3-numerical- aperture oil-immersion objective lens onto a specimen. The pupil transfer lens serves to match the intermediate image planes of the scanning head and the microscope, and its location is critical. In order to maximize the quality of the image, (that is, the point spread function of the objective lens for all scan positions), the entire system was modeled in optical-design software, and the various free design parameters (the parameters of the spatial-filter components as well as the separations of all of the system components) were determined through an iterative optimization process. A modular design was chosen to facilitate access to the optical train for future fluorescence correlation spectroscopy and fluorescence-lifetime experiments.

Fischer, David G.↗

Burner Rig with an Unattached Duct for Evaluating the Erosion Resistance of Thermal Barrier Coatings

Extensive computational fluid dynamics (CFD) modeling backed by experimental observation has demonstrated the feasibility of using an unattached duct to increase the velocity and spatial spread of erodent particles exiting from a burner rig. It was shown that gas velocity and temperature are mostly retained if the inner diameter of the unattached duct equaled the exit diameter of the burner rig nozzle. For particles having a mean diameter of 550 millimeters, the modeled velocity attained at a distance 2.0 in. (50.8 millimeters) beyond the exit of a 12 in. (305 millimeters) long duct was approximately twice as large as the velocity the same distance from the nozzle when the duct was not present. For finer particles, the relative enhancement was somewhat less approximately 1.5 times greater. CFD modeling was also used to guide the construction of a device for slowing down the velocity of the particles being injected into the burner rig. This device used a simple 45 degree fitting to slow the particle velocity in the feed line from 20 meters per second, which is in the range needed to convey the particles, to about 3 meters per second just as they are injected into the burner. This lower injection velocity would lessen the severity of the collision of large particles with the wall of the burner liner opposite the injection port, thereby reducing potential damage to the burner liner by high-velocity particles.

Miller, Robert A.↗

A Unified Directional Spectrum for Long and Short Wind-Driven Waves

Review of several recent ocean surface wave models finds that while comprehensive in many regards, these spectral models do not satisfy certain additional, but fundamental, criteria. We propose that these criteria include the ability to properly describe diverse fetch conditions and to provide agreement with in situ observations of Cox and Munk [1954] and Jiihne and Riemer [1990] and Hara et al. [1994] data in the high-wavenumber regime. Moreover, we find numerous analytically undesirable aspects such as discontinuities across wavenumber limits, nonphysical tuning or adjustment parameters, and noncentrosymmetric directional spreading functions. This paper describes a two-dimensional wavenumber spectrum valid over all wavenumbers and analytically amenable to usage in electromagnetic models. The two regime model is formulated based on the Joint North Sea Wave Project (JONSWAP) in the long-wave regime and on the work of Phillips [1985] and Kitaigorodskii [1973] at the high wavenumbers. The omnidirectional and wind-dependent spectrum is constructed to agree with past and recent observations including the criteria mentioned above. The key feature of this model is the similarity of description for the high- and low-wavenumber regimes; both forms are posed to stress that the air-sea interaction process of friction between wind and waves (i.e., generalized wave age, u/c) is occurring at all wavelengths simultaneously. This wave age parameterization is the unifying feature of the spectrum. The spectrum's directional spreading function is symmetric about the wind direction and has both wavenumber and wind speed dependence. A ratio method is described that enables comparison of this spreading function with previous noncentrosymmetric forms. Radar data are purposefully excluded from this spectral development. Finally, a test of the spectrum is made by deriving roughness length using the boundary layer model of Kitaigorodskii. Our inference of drag coefficient versus wind speed and wave age shows encouraging agreement with Humidity Exchange Over the Sea (HEXOS) campaign results.

Elfouhaily, T.↗

Vinculin promotes cell spreading by mechanically coupling integrins to the cytoskeleton

Mouse F9 embryonic carcinoma 5.51 cells that lack the cytoskeletal protein vinculin spread poorly on extracellular matrix compared with wild-type F9 cells or two vinculin-transfected clones (5.51Vin3 and Vin4; Samuels et al., 1993, J. Cell Biol. 121, 909-921). In the present study, we used this model system to determine how the presence of vinculin promotes cytoskeletal alterations and associated changes in cell shape. Microscopic analysis of cell spreading at early times, revealed that 5.51 cells retained the ability to form filopodia; however, they could not form lamellipodia, assemble stress fibers, or efficiently spread over the culture substrate. Detergent (Triton X-100) studies revealed that these major differences in cell morphology and cytoskeletal organization did not result from differences in levels of total polymerized or cross-linked actin. Biochemical studies showed that 5.51 cells, in addition to lacking vinculin, exhibited slightly reduced levels of alpha-actinin and paxillin in their detergent-insoluble cytoskeleton. The absence of vinculin correlated with a decrease in the mechanical stiffness of the integrin-cytoskeleton linkage, as measured using cell magnetometry. Furthermore, when vinculin was replaced by transfection in 5.51Vin3 and 5.51Vin4 cells, the levels of cytoskeletal-associated alpha-actinin and paxillin, the efficiency of transmembrane mechanical coupling, and the formation of actin stress fibers were all restored to near wild-type levels. These findings suggest that vinculin may promote cell spreading by stabilizing focal adhesions and transferring mechanical stresses that drive cytoskeletal remodeling, rather than by altering the total level of actin polymerization or cross-linking.

NASA Program Space Biology↗

Effect of Recent Revisions to the Geomagnetic Reversal Time Scale on Estimates of Current Plate Motions

Recent revisions to the geomagnetic time scale indicate that global plate motion model NUVEL-1 should be modified for comparison with rates of motion estimated from space geodetic measurements. The optimal recalibration, which is a compromise among slightly different calibrations appropriate for slow, medium, and fast spreading rates is to multiply NUVEL-1 angular velocities by a multiplicative constant, alpha, of 0.9562. We refer to this simply recalibrated plate motion model as NUVEL-1A, and give correspondingly revised tables of angular velocities and uncertainties. Prior work has shown that space geodetic rates are slower on average than those calculated from NUVEL-1 by 6±1%. This average discrepancy is reduced to less that 2% when space geodetic rates are instead compared to NUVEL-1A.

geodetic↗

Sneezing and asymptomatic virus transmission

The novel coronavirus disease (COVID-19) spread pattern continues to show that geographical barriers alone cannot contain a virus. Asymptomatic carriers play a critical role in the nature of this virus quickly escalating into a global pandemic. Asymptomatic carriers may transmit the virus unintentionally through sporadic sneezing. A novel Computational Fluid Dynamics (CFD) approach has been proposed with a realistic modeling of a human sneeze achieved by the combination of state-of-the-art experimental and numerical methods. This modeling approach may be suitable for future engineering analyses aimed at reshaping public spaces and common areas, with the main objective to accurately predict the spread of aerosol and droplets that may contain pathogens. This study shows that the biomechanics of a human sneeze, including complex muscle contractions and relaxations, can be accurately modeled by the angular head motion and the dynamic pressure response during sneezing. These have been considered as the human factors and were implemented in the CFD simulation by imposing a momentum source term to the coupled Eulerian–Lagrangian momentum equations. The momentum source was modeled by the measured dynamic pressure response in conjunction with the angular head motion. This approach eliminated the need to create an ad hoc set of inlet boundary conditions. With this proposed technique, it is easier to add multiple fixed and/or moving sources of sneezes in complex computational domains. Additionally, extensive sensitivity analyses based on different environmental conditions were performed, and their impact was described in terms of potential virus spread.

42 ENGINEERING↗

Jet wake from linearized hydrodynamics

We explore how to improve the hybrid model description of the particles originating from the wake that a jet produced in a heavy ion collision leaves in the droplet of quark-gluon plasma (QGP) through which it propagates, using linearized hydrodynamics on a background Bjorken flow. Jet energy and momentum loss described by the hybrid model become currents sourcing linearized hydrodynamics. By solving the linearized hydrodynamic equations numerically, we investigate the development of the wake in the dynamically evolving droplet of QGP, study the effect of viscosity, scrutinize energy-momentum conservation, and check the validity of the linear approximation. We find that linearized hydrodynamics works better in the viscous case because diffusive modes damp the energy-momentum perturbation produced by the jet. We calculate the distribution of particles produced from the jet wake by using the Cooper-Frye prescription and find that both the transverse momentum spectrum and the distribution of particles in azimuthal angle are similar in shape in linearized hydrodynamics and in the hybrid model. Their normalizations are different because the momentum-rapidity distribution in the linearized hydrodynamics analysis is more spread out, due to sound modes. Since the Bjorken flow has no transverse expansion, we explore the effect of transverse flow by using local boosts to add it into the Cooper-Frye formula. After including the effects of transverse flow in this way, the transverse momentum spectrum becomes harder: more particles with transverse momenta bigger than 2 GeV are produced than in the hybrid model. Although we defer implementing this analysis in a jet Monte Carlo, as would be needed to make quantitative comparisons to data, we gain a qualitative sense of how the jet wake may modify jet observables by computing proxies for two example observables: the lost energy recovered in a cone of varying open angle, and the fragmentation function. We find that linearized hydrodynamics with transverse flow effects added improves the description of the jet wake in the hybrid model in just the way that comparison to data indicates is needed. Our study illuminates a path to improving the description of the wake in the hybrid model, highlighting the need to take into account the effects of both transverse flow and the broadening of the energy-momentum perturbation in spacetime rapidity on particle production.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The effect of the heliospheric current sheet on cosmic ray intensities at solar maximum - Two alternative hypotheses

The capabilities of two alternative models for accounting for the reversal of the solar magnetic field polarity at the point of solar maximum and for the associated modulation of cosmic ray intensities at 1 AU are assessed. One model posits a continuous increase in the inclination of the heliospheric current sheet to a point of verticality at maximum, when it overturns and the reversal occurs. The alternative view is that the sun sheds the magnetic field of the previous cycle and generates a new field of opposite polarity. Some data do exist for a tilted current sheet which increases its tilt with proximity to the solar maximum. However, coronal data also support the presence of isolated regions of anomalous polarity which spread over the surface of the sun as maximum approaches, a condition commensurate with flux shedding. Both models predict heliospheric current sheet configurations which would produce some cosmic ray modulations observed over the course of the solar cycle.

Thomas, B. T.↗

Bayesian image reconstruction - The pixon and optimal image modeling

In this paper we describe the optimal image model, maximum residual likelihood method (OptMRL) for image reconstruction. OptMRL is a Bayesian image reconstruction technique for removing point-spread function blurring. OptMRL uses both a goodness-of-fit criterion (GOF) and an 'image prior', i.e., a function which quantifies the a priori probability of the image. Unlike standard maximum entropy methods, which typically reconstruct the image on the data pixel grid, OptMRL varies the image model in order to find the optimal functional basis with which to represent the image. We show how an optimal basis for image representation can be selected and in doing so, develop the concept of the 'pixon' which is a generalized image cell from which this basis is constructed. By allowing both the image and the image representation to be variable, the OptMRL method greatly increases the volume of solution space over which the image is optimized. Hence the likelihood of the final reconstructed image is greatly increased. For the goodness-of-fit criterion, OptMRL uses the maximum residual likelihood probability distribution introduced previously by Pina and Puetter (1992). This GOF probability distribution, which is based on the spatial autocorrelation of the residuals, has the advantage that it ensures spatially uncorrelated image reconstruction residuals.

Pina, R. K.↗

First-principle and empirical modelling of the global-scale ionosphere

The SUNDIAL program offers a unique opportunity to study ionospheric behavior on a global scale. As part of this program, data pertaining to solar, interplanetary, magnetospheric, ionospheric, and thermospheric conditions are collected simultaneously from a large number of satellite and ground-based sites spread around the world. In the coming years, these data should lead to a major improvement in both empirical and first-principle ionospheric models. As a benchmark against which to compare future progress, the present state of empirical and numerical ionospheric modeling is discussed. The discussion covers the capabilities and limitations of the existing models as well as the direction of future modeling efforts.

Schunk, R. W.↗

Atomic step disorder on polycrystalline surfaces leads to spatially inhomogeneous work functions

Structural disorder causes materials’ surface electronic properties, e.g., work function (ϕ), to vary spatially, yet it is challenging to prove exact causal relationships to underlying ensemble disorder, e.g., roughness or granularity. For polycrystalline Pt, nanoscale resolution photoemission threshold mapping reveals a spatially varying ϕ=5.70±0.03 eV over a distribution of (111) vicinal grain surfaces prepared by sputter deposition and annealing. With regard to field emission and related phenomena, e.g., vacuum arc initiation, a salient feature of the ϕ distribution is that it is skewed with a long tail to values down to 5.4 eV, i.e., far below the mean, which is exponentially impactful to field emission via the Fowler–Nordheim relation. We show that the ϕ spatial variation and distribution can be explained by ensemble variations of granular tilts and surface slopes via a Smoluchowski smoothing model wherein local ϕ variations result from spatially varying densities of electric dipole moments, intrinsic to atomic steps, that locally modify ϕ. Atomic step-terrace structure is confirmed with scanning tunneling microscopy (STM) at several locations on our surfaces, and prior works showed STM evidence for atomic step dipoles at various metal surfaces. From our model, we find an atomic step edge dipole μ=0.12 D/edge atom, which is comparable to values reported in studies that utilized other methods and materials. Our results elucidate a connection between macroscopic ϕ and the nanostructure that may contribute to the spread of reported ϕ for Pt and other surfaces and may be useful toward more complete descriptions of polycrystalline metals in the models of field emission and other related vacuum electronics phenomena, e.g., arc initiation.

36 MATERIALS SCIENCE↗