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At least 847 records · Page 47

Novel approaches to the construction of miniaturized analytical instrumentation

This paper focuses on the design, construction, preliminary testing, and potential applications of three forms of miniaturized analytical instrumentation. The first is an optical fiber instrument for monitoring pH and other cations in aqueous solutions. The instrument couples chemically selective indicators that were immobilized at porous polymeric films with a hardware package that provides the excitation light source, required optical components, and detection and data processing hardware. The second is a new form of a piezoelectric mass sensor. The sensor was fabricated by the deposition of a thin (5.5 micron) film of piezoelectric aluminum nitride (AIN). The completed deposition process yields a thin film resonator (TFR) that is shaped as a 400 micron square and supports a standing bulk acoustic wave in a longitudinal mode at frequencies of approx. 1 GHz. Various deposition and vapor sorption studies indicate that the mass sensitivity of the TFR's rival those of the most sensitive mass sensors currently available, though offering such performance in a markedly smaller device. The third couples a novel form of liquid chromatography with microlithographic miniaturization techniques. The status of the miniaturization effort, the goal of which is to achieve chip-scale separations, is briefly discussed.

Porter, Marc D.↗

Fibers and materials of medical application

Efferent sorption methods of organism detoxication (by medical trend) are presented. Recently, specialists have shown their keen interest in the problem of treating exogenous and endogenous intoxications. This was stipulated by the growing production and accumulation of chemical products for industrial, agricultural, and domestic needs. To solve this problem the industrial production of carbon fibrous adsorbents was developed and implemented at NII Chimvolokno in St. Petersburg. A description of the carbon fibers is given. Also, application of modern composite materials for manufacturing compression-distraction apparatus used for setting fractured bones is described.

Fridman, L. I.↗

Determination of Martian soil mineralogy and water content using the Thermal Analyzer for Planetary Soils (TAPS)

Physical and chemical interactions between the surface and atmosphere of Mars can be expected to embody a strong cause-and-effect relationship with the minerals comprising the martian regolith. Many of the minerals in soils and sediments are probably products of chemical weathering (involving surface/atmosphere or surface/hydrosphere reactions) that could be expected to subsequently influence the sorption of atmospheric gases and water vapor. Therefore, identification of the minerals in martian surface soils and sediments is essential for understanding both past and present interactions between the Mars surface and atmosphere. Clearly, the most definitive mineral analyses would be achieved with well-preserved samples returned to Earth-based laboratories. In advance of a Mars sample return mission, however, significant progress could be made with in situ experiments that fill current voids in knowledge about the presence or abundance of key soil minerals such as clays (layered-structured silicates), zeolites, and various salts, including carbonates. TAPS is intended to answer that challenge by providing first-order identification of soil and sediment minerals.

Gooding, James L.↗

Cryogenic probe station for use in automated microwave and noise figure measurements

A cryogenic measurement system capable of performing on-wafer RF testing of semiconductor devices and circuits has been developed. This 'CryoProbe Station' can wafer-probe devices and circuits at cryogenic temperatures, thus eliminating the need for wire bonds. The system operates under vacuum created by a sorption pump. It uses an open cycle cooling system that can be cooled with either liquid nitrogen or liquid helium. Presently, it can reach temperatures, as low as 80 K and 37 K for each of the coolants, respectively. The temperature can be raised using a heater and it is stabilized to within 0.2 K by use of a temperature controller. The CryoProbe Station features a 1 by 2 inch stage that can hold large circuits and calibration standards simultaneously. The system is used with a Hewlett Packard 8510C Automatic Network Analyzer (ANA) to obtain S-parameter data over the frequency range 0.045-26.5 GHz. S-parameter data on HEMT (high electron mobility transistors) devices has been obtained with this station. With the use of DEEMBED software from NIST, detailed transmission line studies have been performed. Although the CryoProbe Station is designed for frequencies up to 26.5 GHz, useful transmission line data has been obtained for frequencies as high as 40 GHz. The CryoProbe station has also been used with the ATN noise figure measurement system to perform automatic, temperature dependent noise figure measurements.

Taub, Susan R.↗

Catalytic methods using molecular oxygen for treatment of PMMS and ECLSS waste streams, volume 2

Catalytic oxidation has proven to be an effective addition to the baseline sorption, ion exchange water reclamation technology which will be used on Space Station Freedom (SSF). Low molecular weight, polar organics such as alcohols, aldehydes, ketones, amides, and thiocarbamides which are poorly removed by the baseline multifiltration (MF) technology can be oxidized to carbon dioxide at low temperature (121 C). The catalytic oxidation process by itself can reduce the Total Organic Carbon (TOC) to below 500 ppb for solutions designed to model these waste waters. Individual challenges by selected contaminants have shown only moderate selectivity towards particular organic species. The combined technology is applicable to the more complex waste water generated in the Process Materials Management System (PMMS) and Environmental Control and Life Support System (ECLSS) aboard SSF. During the phase 3 Core Module Integrated Facility (CMIF) water recovery tests at NASA MSFC, real hygiene waste water and humidity condensate were processed to meet potable specifications by the combined technology. A kinetic study of catalytic oxidation demonstrates that the Langmuir-Hinshelwood rate equation for heterogeneous catalysts accurately represent the kinetic behavior. From this relationship, activation energy and rate constants for acetone were determined.

Akse, James R.↗

High temperature sorbents for oxygen

A sorbent capable of removing trace amounts of oxygen (ppt) from a gas stream at a high temperature above 200 C comprising a porous alumina silicate support, such as zeolite, containing from 1 to 10 percent by weight of ion exchanged transition metal, such as copper or cobalt ions, and 0.05 to 1.0 percent by weight of an activator selected from a platinum group metal such as platinum is described. The activation temperature, oxygen sorption, and reducibility are all improved by the presence of the platinum activator.

Sharma, Pramod K.↗

Double layer hydroxide minerals as host structures for bioorganic molecules

A central problem in molecular evolution concerns the selective concentration from dilute, multicomponent solution of source molecules into a reactive environment, where formation of larger molecular assemblages can take place. Minerals consisting of positively charged, separable metal hydroxide sheets have proven capable of these functions. This common structural type is represented by minerals such as pyroaurite (Mg-Fe(3+) hydroxide), hydrotalcite (Mg-Al), green rust Fe(2+)-Fe(3+) and others. Effective interlayer sorption is demonstrated for orthophosphate and condensed phosphates, anionic alkyl compounds, polypeptides, nucleic acids, cyanide complexes and glycolaldehyde phosphate, the latter shown to readily oligomerize to form and selectively retain racemic hexose -2, 4, 6-phosphates, preferentially of altrose (Pitsch, et al, 1993). The selective aldomerization and retention effects correlate with the charge distribution in the host mineral structure and the stereochemistry of the substrate molecules. Interaction between nucleic acid bases, and between the cyanide groups of glycolaldehyde phosphate nitrile at the low water activity in the mineral interlayer is indicated by doubling of the monomeric separation of the hydroxide mineral sheets.

Lee, Ton↗

Mineral induced formation of sugar phosphates

Glycolaldehyde phosphate, sorbed from highly dilute, weakly alkaline solution into the interlayer of common expanding sheet structure metal hydroxide minerals, condenses extensively to racemic aldotetrose-2, 4-diphophates, and aldohexose-2, 4, 6-triphosphates. The reaction proceeds mainly through racemic erythrose-2, 4-phosphate, and terminates with a large fraction of racemic altrose-2, 4, 6-phosphate. In the absence of an inductive mineral phase, no detectable homogeneous reaction takes place in the concentration- and pH range used. The reactant glycolaldehyde phosphate is practically completely sorbed within an hour from solutions with concentrations as low as 50 micron; the half-time for conversion to hexose phosphates is of the order of two days at room temperature and pH 9.5. Total production of sugar phosphates in the mineral interlayer is largely independent of the glycolaldehyde phosphate concentration in the external solution, but is determined by the total amount of GAP offered for sorption up to the capacity of the mineral. In the presence of equimolar amounts of rac-glyceraldehyde-2-phosphate, but under otherwise similar conditions, aldopentose-2, 4, -diphosphates also form, but only as a small fraction of the hexose-2, 4, 6-phosphates.

Pitsch, S.↗

Sorbents Remove Oxygen At High Temperatures

Cobalt-exchanged, platinized zeolites 13X and L found conveniently reducible in hot gaseous mixture of hydrogen and nitrogen and thereafter useful as sorbents of trace amounts of oxygen at high temperatures. Aided by catalytic action of platinum, sorbents exhibit rapid oxygen-sorption kinetics and, according to thermodynamic properties of O2/CoO system, capable of lowering level of oxygen in otherwise inert gaseous atmosphere to less than 1 part per trillion in temperature range of 400 to 800 degrees C. Inert atmospheres with these oxygen levels required for processing of certain materials in semiconductor industry.

Sharma, Pramod K.↗

High Temperature Sorbents for Oxygen

A sorbent capable of removing trace amounts of oxygen (ppt) from a gas stream at a high temperature above 200 C is introduced. The sorbent comprises a porous alumina silicate support such as zeolite containing from 1 to 10 percent by weight of ion exchanged transition metal such as copper or cobalt ions and 0.05 to 1.0 percent by weight of an activator selected from a platinum group metal such as platinum. The activation temperature, oxygen sorption and reducibility are all improved by the presence of the platinum activator.

Sharma, Pramod K.↗

STS-77 Space Shuttle Mission Report

The STS-77 Space Shuttle Program Mission Report summarizes the Payload activities as well as the: Orbiter, External Tank (ET), Solid Rocket Booster (SRB), Reusable Solid Rocket Motor (RSRM), and the Space Shuttle Main Engine (SSME) systems performance during the seventy-seventh flight of the Space Shuttle Program, the fifty-second flight since the return-to-flight, and the eleventh flight of the Orbiter Endeavour (OV-105). STS-77 was also the last flight of OV-105 prior to the vehicle being placed in the Orbiter Maintenance Down Period (OMDP). In addition to the Orbiter, the flight vehicle consisted of an ET that was designated ET-78; three SSME's that were designated as serial numbers 2037, 2040, and 2038 in positions 1, 2, and 3, respectively; and two SRB's that were designated BI-080. The RSRM's, designated RSRM-47, were installed in each SRB and the individual RSRM's were designated as 360TO47A for the left SRB, and 360TO47B for the right SRB. The STS-77 Space Shuttle Program Mission Report fulfills the Space Shuttle Program requirement as documented in NSTS 07700, Volume VII, Appendix E. The requirement stated in that document is that each organizational element supporting the Program will report the results of their hardware (and software) evaluation and mission performance plus identify all related in-flight anomalies. The primary objectives of this flight were to successfully perform the operations necessary to fulfill the requirements of Spacehab-4, the SPARTAN 207/inflatable Antenna Experiment (IAE), and the Technology Experiments Advancing Missions in Space (TEAMS) payload. Secondary objectives of this flight were to perform the experiments of the Aquatic Research Facility (ARF), Brilliant Eyes Ten-Kelvin Sorption Cryocooler Experiment (BETSCE), Biological Research in Canisters (BRIC), Get-Away-Special (GAS), and GAS Bridge Assembly (GBA). The STS-77 mission was planned as a 9-day flight plus 1 day, plus 2 contingency days, which were available for weather avoidance or Orbiter contingency operations. The sequence of events for the STS-77 mission is shown in Table 1, and the Space Shuttle Vehicle Management Office Problem Tracking List is shown in Table 11. The Government Fumished Equipment/Flight Crew Equipment (GFE/FCE) Problem Tracking List is shown in Table II. Appendix A lists the sources of data, both formal and informal, that were used to prepare this report. Appendix B provides the definition of acronyms and abbreviations used throughout the report. All times during the flight are given in Greenwich mean time (G.m.t.) and mission elapsed time (MET). The six-person crew for STS-77 consisted of John H. Casper, Col., U. S. Air Force, Commander; Curtis L. Brown, Jr., Lt. Col., U. S. Air Force, Pilot; Andrew S. W. Thomas, Civilian, Ph.D., Mission Specialist 1; Daniel W. Bursch, CDR., U. S. Navy, Mission Specialist 2; Mario Runco, Jr., Civilian, Mission Specialist 3; and Marc Gameau, Civilian, PhD, Mission Specialist 4.

Fricke, Robert W., Jr.↗

Space-Borne Infrared Astronomy

The objective of this grant is to develop the Far IR Photometer (FIRP), one of four focal plane instruments on the IR Telescope in Space (IRTS). The IRTS was successfully launched in March 18, 1995 aboard the Japanese SFU platform. It surveyed the IR sky for approximately 40 days, and was eventually retrieved by NASA's STS. The FIRP succeeded in surveying approximately 5% of the sky in four bands centered at 150, 250, 400 and 700 microns. Several new technologies were developed using the funds from this grant, including: (1) a high performance gas-gap heat-switch, (2) a He-3 sorption refrigerator that is, to date, the only refrigerator to achieve sub-Kelvin temperatures in orbit, (3) high-sensitivity bolometric detectors with NEP less than 10-16 W(Hz(exp l/2)exp 1/2) when operated from a 300 mK heat sink, (4) readout electronics capable of providing DC stability for the bolometric detectors. Excess noise of unknown origin significantly reduced the sensitivity of the FIRP on orbit. Nevertheless, scientifically significant observations of the spectrum and temperature of the interstellar dust were made, and have been reported.

Lange, Andrew E.↗

Evaluation of Relative Sensitivity of SAW and Flexural Plate Wave Devices for Atmospheric Sensing

The objective of this project is to evaluate the suitability of the ultrasonic flexural plate wave (FPW) device as the detector in a gas chromatograph (GC). Of particular interest is the detection of nitrous oxide (N2O). From experimental results we conclude analyte detection is achieved through two mechanisms: changes in gas density, and mass loading of the device membrane due to the sorption of gas molecules. Reducing the dead volume of the FPW chamber increased the FPW response. A comparison of the FPW response to that of the surface acoustic wave (SAW) detector provided with the GC (made by MSI, Microsensor Technologies, Inc.), shows that for unseparated N2O in N2, the FPW exhibits a sensitivity that is at least 550 times greater than that of the SAW device. A Porapak Q column was found to separate N2O from its carrier gas, N2 or He. With the Porapak Q column, a coated FPW detected 1 ppm N2O in N2 or He, with a response magnitude of 7 Hz. A coated SAW exhibited a response of 25 Hz to pure N2O. The minimal detectable N2O concentrations of the sensors were not evaluated.

White, Richard M.↗

Absorption of Sunlight by Water Vapor in Cloudy Conditions: A Partial Explanation for the Cloud Absorption Anomaly

The atmospheric radiative transfer algorithms used in most global general circulation models underestimate the globally-averaged solar energy absorbed by cloudy atmospheres by up to 25 W/sq m. The origin of this anomalous absorption is not yet known, but it has been attributed to a variety of sources including oversimplified or missing physical processes in these models, uncertainties in the input data, and even measurement errors. Here, a sophisticated atmospheric radiative transfer model was used to provide a more comprehensive description of the physical processes that contribute to the absorption of solar radiation by the Earth's atmosphere. We found that the amount of sunlight absorbed by a cloudy atmosphere is inversely proportional to the solar zenith angle and the cloud top height, and directly proportional to the cloud optical depth and the water vapor concentration within the clouds. Atmospheres with saturated, optically-thick, low clouds absorbed about 12 W/sq m more than clear atmospheres. This accounts for about 1/2 to 1/3 of the anomalous ab- sorption. Atmospheres with optically thick middle and high clouds usually absorb less than clear atmospheres. Because water vapor is concentrated within and below the cloud tops, this absorber is most effective at small solar zenith angles. An additional absorber that is distributed at or above the cloud tops is needed to produce the amplitude and zenith angle dependence of the observed anomalous absorption.

Crisp, D.↗

Development Unit Configuration and Current Status of the MIP/MTERC Experiment

The Mars In-Situ Propellant Production (ISPP) Precursor (MIP) experiment package is planned for inclusion on the Mars 2001 Lander. This experiment package consists of five experiments whose purpose is to demonstrate the performance of various ISPP processes in-situ on Mars. The demonstrated ability to produce propellant for Mars Return Vehicles (MRV) is considered to be a necessary precursor to any future manned mission to Mars. The Mars Thermal Environment/Radiator Characterization (MTERC) experiment is part of the MIP package and is intended to determine the Mars night sky temperature as well as to characterize the performance degradation of radiators caused by environmental exposure on Mars over time. Radiators are needed as part of the ISPP process to remove heat from the Mars Atmosphere Acquisition and Compression (MAAC) CO2 sorption compressor. MTERC will provide the data needed to optimize the design of radiators for ISPP and other processes. A MTERC Development Unit (DU) has been fabricated and tested at JPL. The MTERC DU consists of 1) a radiator subassembly, 2) a motor/cover subassembly, 3) a differential temperature control circuit and motor control electronics circuit board, and 4) a command and data handling electronics circuit board. This paper will describe the operational theory and the configuration of the MTERC DU and will discuss the current status of the MTERC experiment development including some selected results of performance testing that has been completed prior to the ISRU III meeting.

Juanero, K. J.↗

Development Unit Configuration and Current Status of the MIP/MTERC Experiment

The Mars In-Situ Propellant Production (ISPP) Precursor (MIP) experiment package is planned for inclusion on the Mars 2001 Lander. This experiment package consists of five experiments whose purpose is to demonstrate the performance of various ISPP processes in-situ on Mars. The demonstrated ability to produce propellant for Mars Return Vehicles (MRV) is considered to be a necessary precursor to any future manned mission to Mars. The Mars Thermal Environment/Radiator Characterization (MTERC) experiment is part of the MIP package and is intended to determine the Mars night sky temperature as well as to characterize the performance degradation of radiators caused by environmental exposure on Mars over time. Radiators are needed as part of the ISPP process to remove heat from the Mars Atmosphere Acquisition and Compression (MAAC) C02 sorption compressor. MTERC will provide the data needed to optimize the design of radiators for ISPP and other processes. A MTERC Development Unit (DU) has been fabricated and tested at JPL. The MTERC DU consists of: (1) a radiator subassembly, (2) a motor/cover subassembly, (3) a differential temperature control circuit and motor control electronics circuit board, and (4) a command and data handling electronics circuit board. This paper will describe the operational theory and the configuration of the MTERC DU and will discuss the current status of the MTERC experiment development including some selected results of performance testing that has been completed prior to the ISRU III meeting.

Juanero, K. J.↗

Cryocoolers for Space

This paper presents Cryocoolers for Space in viewgraph form. The topics include: 1) U.S. Cryocoolers for 4 to 6 Kelvin; 2) Turbo Brayton Cryocooler-Features; 3) HST/NICMOS (Hubble Space Telescope/Near Infrared Camera and Multiobject Spectrometer) 75 Kelvin Cryocooler; 4) Turbo-Brayton Cryocooler-NGST Design; and 5) Two-stage Sorption J-T Cryocooler.

Castles, Stephen↗

Buffer Gas Acquisition and Storage

The acquisition and storage of buffer gases (primarily argon and nitrogen) from the Mars atmosphere provides a valuable resource for blanketing and pressurizing fuel tanks and as a buffer gas for breathing air for manned missions. During the acquisition of carbon dioxide (CO2), whether by sorption bed or cryo-freezer, the accompanying buffer gases build up in the carbon dioxide acquisition system, reduce the flow of CO2 to the bed, and lower system efficiency. It is this build up of buffer gases that provide a convenient source, which must be removed, for efficient capture Of CO2 Removal of this buffer gas barrier greatly improves the charging rate of the CO2 acquisition bed and, thereby, maintains the fuel production rates required for a successful mission. Consequently, the acquisition, purification, and storage of these buffer gases are important goals of ISRU plans. Purity of the buffer gases is a concern e.g., if the CO, freezer operates at 140 K, the composition of the inert gas would be approximately 21 percent CO2, 50 percent nitrogen, and 29 percent argon. Although there are several approaches that could be used, this effort focused on a hollow-fiber membrane (HFM) separation method. This study measured the permeation rates of CO2, nitrogen (ND, and argon (Ar) through a multiple-membrane system and the individual membranes from room temperature to 193K and 10 kpa to 300 kPa. Concentrations were measured with a gas chromatograph that used a thermoconductivity (TCD) detector with helium (He) as the carrier gas. The general trend as the temperature was lowered was for the membranes to become more selective, In addition, the relative permeation rates between the three gases changed with temperature. The end result was to provide design parameters that could be used to separate CO2 from N2 and Ar.

Parrish, Clyde F.↗