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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Evidence for a spinon Kondo effect in cobalt atoms on single-layer 1T-TaSe 2

Quantum spin liquids are highly entangled, disordered magnetic states that are expected to arise in frustrated Mott insulators and to exhibit exotic fractional excitations such as spinons and chargons. Despite being electrical insulators, some quantum spin liquids are predicted to exhibit gapless itinerant spinons that yield metallic behaviour in the charge-neutral spin channel. For this study, we deposited isolated magnetic atoms onto single-layer 1T-TaSe 2 , a candidate gapless spin liquid, to probe how itinerant spinons couple to impurity spin centres. Using scanning tunnelling spectroscopy, we observe the emergence of new, impurity-induced resonance peaks at the 1T-TaSe 2 Hubbard band edges when cobalt adatoms are positioned to have maximal spatial overlap with the local charge distribution. These resonance peaks disappear when the spatial overlap is reduced or when the magnetic impurities are replaced with nonmagnetic impurities. Theoretical simulations of a modified Anderson impurity model show that the observed peaks are consistent with a Kondo resonance induced by spinons combined with spin-charge binding effects that arise due to fluctuations of an emergent gauge field.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Nongassing nickel-cadmium battery electrodes and cells

The failure of nickel-cadmium storage batteries due to severe gassing during charging is discussed. In order to increase the life of such cells, nongassing positive and negative electrodes are used. The gassing characteristics of nickel electrodes were evaluated as a function of their loading, charge rate, and charge temperature.

Luksha, E.↗
NASA NTRS1992

The polarization electric field and its effects in an anisotropic rotating magnetospheric plasma

Spatial variations of density and temperature along a magnetic field line are evaluated for a plasma undergoing adiabatic motion in a rotating magnetosphere. The effects of centrifugal and gravitational forces are accounted for, as is anisotropy in the pitch angle distribution functions of individual species. A polarization electric field is invoked to eliminate the net electric charge density resulting from the aforementioned mass dependent forces and different anisotropies. The position of maximum density in a two-component, electron-ion plasma is determined both in the absence and in the presence of the polarization effect and compared. A scale height, generalized to include anisotropies, is derived for the density fall-off. The polarization electric field is also included in the parallel guiding center equation; equilibrium points are determined and compared in both individual and average senses with the position of density maximum. Finally a transverse (to magnetic field lines) electric component is deduced as a consequence of dissimilar charge neutralization on adjacent field lines. The E x B velocity resultant from such a 'fringing' electric field is calculated and compared with the magnitude of other drifts.

Huang, T. S.↗
DOE OSTI2021

A Comparative Study of Straight-Strip and Zigzag-Interleaved Anode Patterns for MPGD Readouts

Due to their simplicity and versatility of design, straight strip or rectangular pad anode structures are frequently employed with micro-pattern gas detectors to reconstruct high precision space points for various tracking applications. The particle impact point is typically determined by interpolating the charge collected by several neighboring strips. However, to effectively extract the inherent positional information, the lateral spacing of the straight strips must be comparable to or preferably smaller than the full extent of the incident charge cloud. In contrast, highly interleaved anode patterns, such as zigzags, can adequately sample the incident charge with a pitch appreciably larger than the charge cloud.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1973

An experimental investigation of mesospheric ionization

Mesospheric ionization and its variability are examined. Data were obtained primarily by the parachute-borne blunt probe technique conducted in coordinated rocket experiments at White Sands Missile Range, New Mexico and Wallops Island, Virginia. Electrical conductivity measurements and deduced charge density values from ten rocket launches are presented and discussed. Positive ion conductivity and electron density were found to be relatively invariant with height between 45 and 60 km. Variations in positive conductivity of a factor of two and enhancements in negative conductivity by as much as a factor of four were measured by the blunt probe. A simple lumped parameter ion chemistry model is shown to satisfactorily explain the charge density values for the undisturbed lower D-region. Implications of the data in terms of this model are considered. The principal loss mechanism for positive ions in the 45 to 60 km. region is concluded to be dissociative recombination. Electron densities deduced from the conductivity data are explained by detachment involving a minor neutral constituent which is mixed between 65 and 45 km. and then cuts off sharply below 45 km. A correlation study involving blunt probe measurements shows relatively good agreement between variations in positive conductivity and temperature.

Mitchell, J. D.↗
DOE OSTI2025

A formal Fe III/V redox couple in an intercalation electrode

Iron redox cycling between low-valent oxidation states of Fe II and Fe III drives crucial processes in nature. The Fe II/III redox couple charge compensates the cycling of lithium iron phosphate, a positive electrode (cathode) for lithium-ion batteries. High-valent iron redox couples, involving formal oxidation higher than Fe III , could deliver higher electrochemical potentials and energy densities. However, because of the instability of high-valent Fe electrodes, they have proven difficult to probe and exploit in intercalation systems. Here, in this study, we report and characterize a formal Fe III/V redox couple by revisiting the charge compensation mechanism of (de)lithiation in Li 4 FeSbO 6 . Valence-sensitive experimental and computational core-level spectroscopy reveal a direct transition from Fe III (3d 5 ) to a negative-charge-transfer FeV (3d 5 L 2 ) ground state on delithiation, without forming Fe IV , or oxygen dimers. We identify that the cation ordering in Li 4 FeSbO 6 drives a templated phase transition to stabilize the unique Fe V species and demonstrate that disrupting cation ordering suppresses the Fe III/V redox couple. Exhibiting resistance to calendar aging, high operating potential and low voltage hysteresis, the Fe III/V redox couple in Li 4 FeSbO 6 provides a framework for developing sustainable, Fe-based intercalation cathodes for high-voltage applications.

Ramachandran, Hari [Stanford Univ., CA (United Sta↗
NASA NTRS1979

Initial observations of low energy charged particles near the earth's bow shock on ISEE-1

Initial measurements from the ULECA sensor of the Max-Planck-Institut/University of Maryland experiment on ISEE 1 are reported. ULECA is an electrostatic deflection - total energy sensor consisting of a collimator, a deflection analyzer, and an array of solid-state detectors. The position of a given detector, which determines the energy per charge of an incident particle, together with the measured energy, determines the particle's charge state. It is found that a rich variety of phenomena are operative in the transthermal energy regime (about 10 keV/Q to 100 keV/Q) covered by ULECA. Specifically, observations are presented of locally accelerated protons, alpha particles, and heavier ions in the magnetosheath and upstream of earth's bow shock. Preliminary analysis indicates that the behavior of these locally accelerated particles is most similar at the same energy per charge.

Ipavich, F. M.↗
DOE OSTI2021

Influence of Surface and Structural Variations in Donor–Acceptor–Donor Sensitizers on Photoelectrocatalytic Water Splitting

Conjugated organic chromophores composed of linked donor (D) and acceptor (A) moieties have attracted considerable attention for photoelectrochemical applications. In this work, we compare the optoelectronic properties and photoelectrochemical performance of two D–A–D structural isomers with thiophene-X-carboxylic acid (X denotes 3 and 2 positions) derivatives and 2,1,3-benzothiadiazole as the D and A moieties, respectively. 5,5′-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)bis(thiophene-3-carboxylic acid), BTD1, and 5,5′-(benzo[c][1,2,5]thiadiazole-4,7-diyl)bis(thiophene-2-carboxylic acid), BTD2, were employed in the study to understand how structural isomers affect surface attachments within chromophore–catalyst assemblies and their influence on charge-transfer dynamics. Crystal structures revealed that varying the position of the −COOH anchoring group causes the molecules to either contort out of a plane (BTD1) or adopt a near-perfect planar conformation (BTD2). BTD1 and BTD2 were co-loaded with either a water oxidation catalyst, [Ru(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)-(4,4′-((HO) 2 OPCH 2 )2-2,2′-bipyridine)(OH 2 )] 2 , RuCt 2+ , or proton reduction catalyst [Ni(P 2 Ph N 2 C 6 H 4 CH 2 PO 3 H 2 ) 2 ] 2+ , NiCt 2+ , on oxide electrodes to facilitate photodriven water splitting reactions. Emission quenching measurements indicate that both BTD1 and BTD2 inject electrons into n-type SnO 2 |TiO 2 electrodes and holes into p-type NiO semiconductors from their respective excited states at high efficiencies >60%. Photocurrent densities of chromophore–catalyst assemblies obtained using linear sweep voltammetry (LSV) show that BTD2-sensitized photoanodes generate significantly more photocurrent than BTD1-sensitized electrodes; however, both exhibit similar performances at the photocathode. Photoelectrocatyltic measurements demonstrate that both BTD1 and BTD2 performed similarly, generating Faradaic efficiencies of 39 and 38% at the anode or 61 and 79% at the cathode. Transient absorption measurements suggest that the differences between the LSV and photoelectrocatalytic measurements result from the differences in quantum yields of the photogenerated redox equivalents, which is also a reflection of the varying metal oxide surface conformation. Our findings suggest that BTD2 should be investigated further in photocathodic studies since it has the structural advantage of being incorporated into diverse types of chromophore–catalyst assemblies.

Chromophores↗
DOE OSTI2023

Temperature Inhibition of Plasma-Driven Methane Conversion in DBD Systems

Low-temperature non-thermal plasmas produce highly reactive chemical environments made up of electrons, ions, radicals, and vibrationally excited molecules. These reactive species, when combined with catalysts, can help drive thermodynamically unfavorable chemical reactions at low temperatures and atmospheric pressure. The conversion of methane (CH 4 ) to produce other value-added chemicals is a good model system because of its applicability to a wide range of industries. To effectively create these plasma catalytic systems, a fundamental understanding of the plasma-phase chemistry alone is imperative. While there have been many studies on methane plasmas and how certain operating conditions (i.e., gas composition and power) affect the plasma, there is limited understanding on how changing bulk reaction temperature affects the plasma properties and ensuing plasma chemistry. Here, in this work, we use a dielectric barrier discharge to investigate the effects of temperature on the reaction chemistry and the plasma’s electrical properties in various methane-gas mixtures. Results show that increasing temperature leads to a reduction in methane conversion as well as changes to both the gas and dielectric material pre-breakdown, which manifests itself in temperature-dependent electrical properties of the plasma. Experiments at various temperatures and power show a positive correlation between key electrical plasma properties (average charge and lifetime per filament) and the measured methane conversion as a function of temperature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

First experimental measurements with the Segmented Inverted-coaxial GerMAnium (SIGMA) detector

The SIGMA project aims to develop a p-type segmented inverted coaxial point contact germanium detector for gamma-ray tracking and imaging. Here the performance of the first prototype of this type of detector is reported. The measurements performed verified the size and shape of the crystal and determined the location of the complex active volumes of the detector segments. The latter determines the charge collection times that are related to the position of interaction. Good agreement is found between the results and the specified crystal design. The energy resolution of the point contact has been measured to be 0.84 keV and 2.21 keV at 122 keV and 1332 keV, respectively.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Tunable artificial topological Hall effects in van der Waals heterointerfaces

The topological Hall effect (THE) originating from a real-space Berry phase is a significant transport signal for chiral spin textures and has been extensively investigated recently due to its potential applications in topological spintronics. Recently, chiral spin textures and THE were realized in heterointerfaces where spatial inversion symmetry is naturally broken. However, multichannel transport in heterointerfaces can mask the intrinsic THE associated with chiral spin textures. We systematically investigate multichannel transport in two different kinds of van der Waals (vdW) heterointerfaces. In ferromagnetic-ferromagnetic (FM-FM) heterointerfaces with two opposite anomalous Hall effects, multichannel transport has mimicked both positive and negative THE without involving any topological charges, which is dubbed as an artificial THE. Moreover, artificial THEs were also observed in FM-metal heterointerfaces consisting of a single FM layer stacked onto a nodal-line semimetal; this was attributed to the presence of multichannel transport as well. Our findings provide an alternative explanation for THE-like features in heterointerfaces. They also reveal exotic multichannel transport properties in vdW heterointerfaces which could facilitate the development of multifunctional nanodevices based on vdW heterointerfaces.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Pushing the limits of pulse shape discrimination in a large liquid xenon detector

Abstract The LUX-ZEPLIN (LZ) experiment is a direct-detection dark matter experiment, optimized to search for weakly interacting massive particles (WIMPs) through WIMP-nucleon interactions. The main challenge in dark matter detection is differentiating between WIMP signals and background events. In LZ, the ratio of ionization to scintillation signals (charge-to-light) is the primary method for rejecting electronic recoil (ER) background. Pulse shape discrimination (PSD) offers a method for additional ER backgrounds rejection in liquid xenon detectors. In this paper, the discrimination power of PSD with the LZ experiment is discussed. To precisely characterize the scintillation pulse shape, an analysis framework is developed to reconstruct the detection time of individual photons. Using LZ calibration data, the photon-timing tail fraction discriminator is optimized and achieves ER leakage as low as $$15\%$$ 15 % . For specific background processes such as $$^{124}$$ 124 Xe double electron capture, the leakage is reduced further to about $$5\%$$ 5 % . PSD is combined with charge-to-light to form two-factor discrimination (TFD). The optimized TFD performance is compared with the performance of the charge-to-light method, with the corresponding false positive rate reduced by up to a factor of two for large scintillation pulses. Finally, PSD and TFD are applied to data from LZ’s WS2024 run and their performance is summarized.

Akerib, D. S. [SLAC National Accelerator Laborator↗
DOE OSTI2022

Low Mass Straw Tube Tracker for the Mu2e Experiment

The Mu2e Tracker is a state of the art low mass straw tube detector that will look for charged lepton flavor violation (CLFV) by measuring the position and the momentum of the monochromatic 105 MeV/c electron from the $\mu^- N\rightarrow e^- N$ neutrinoless electron conversion in the presence of aluminum nucleus. To achieve this goal, the tracker needs to have momentum resolution of less than 180 keV/c \cite{TDR} for the conversion electron spectrum. The tracker is still under construction with the joint effort of several institutes. This paper will detail technical information about the Mu2e tracker and show early cosmics data taken with a production tracker plane.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1977

Plasma analyzer for the Pioneer Jupiter missions

A description is given of the NASA/Ames Research Center Plasma Probe on board the Jupiter Missions of the Pioneer 10 and 11 spacecraft. The instrument has two quadrispherical electrostatic analyzer units; one has high sensitivity and resolution and the other is capable of measuring large fluxes of solar wind particles. The two analyzer units measure particle energy-to-charge ratio, flux, and direction of flow for positive ions and electrons over the wide range of particle densities found in the solar wind during the Jupiter missions. Data formats in space and ground data processing, the NASA/Ames Research Center plasma probe calibration facility, and the instrument response functions are also described.

Mckibbin, D. D.↗
NASA NTRS1979

Plasma Interaction Experiment (PIX) flight results

An auxiliary payload package called PIX (plasma interaction experiment) was launched on March 5, 1978, on the LANDSAT 3 launch vehicle to study interactions between the space charged-particle environment and surfaces at high applied positive and negative voltages. Three experimental surfaces were used in this package: a plain disk to act as a control, a disk on a Kapton sheet to determine the effect of surrounding insulation on current collection, and a small solar-array segment to evaluate the effect of distributing biased surfaces among an array of insulators. Only half of the results from the 4 hours of PIX operations were recovered. The results did verify effects found in ground simulation testing. The results of this experiment are discussed in detail.

Grier, N. T.↗
NASA NTRS1982

Numerical simulation of the flow and fuel-air mixing in an axisymmetric piston-cylinder arrangement

The implicit factored method of Beam and Warming was employed to describe the flow and the fuel-air mixing in an axisymmetric piston-cylinder configuration during the intake and compression strokes. The governing equations were established on the basis of laminar flow. The increased mixing due to turbulence was simulated by appropriately chosen effective transport properties. Calculations were performed for single-component gases and for two-component gases and for two-component gas mixtures. The flow field was calculated as functions of time and position for different geometries, piston speeds, intake-charge-to-residual-gas-pressure ratios, and species mass fractions of the intake charge. Results are presented in graphical form which show the formation, growth, and break-up of those vortices which form during the intake stroke and the mixing of fuel and air throughout the intake and compression strokes. It is shown that at bore-to-stroke ratio of less than unity, the vortices may break-up during the intake stroke. It is also shown that vortices which do not break-up during the intake stroke coalesce during the compression stroke. The results generated were compared to existing numerical solutions and to available experimental data.

Shih, T. I. P.↗
NASA NTRS1985

Measuring Air-Ionizer Output

Test apparatus checks ion content of airstream from commercial air ionizer. Apparatus ensures ion output is sufficient to neutralize static charges in electronic assembly areas and concentrations of positive and negative ions are balanced.

Lonborg, J. O.↗
NASA NTRS1988

Generating Hyperthermal Atomic Oxygen

Atomic oxygen diffused through silver desorbed by low-energy electron impact. Oxygen atoms diffuse through silver foil and emerge on high-vacuum side, aided by electron-stimulated desorption. Atomic-oxygen flux levels range up to 10 to the 12th power cm to the negative 2 power S to the negative 1 power, and kinetic energies range from 1 to 10 eV. O positive and O negative ions swept aside by charged cylindrical grids.

Outlaw, Ronald A.↗