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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47

The Volatile Composition of Comet C/2017 E4 (Lovejoy) Before Its Disruption, as Revealed by High-Resolution Infrared Spectroscopy with iSHELL at the NASA-IRTF

In April 2017, we acquired comprehensive high-resolution spectra of newly-discovered comet C/2017 E4 (Lovejoy) as it approached perihelion, and before its disintegration. We detected many cometary emission lines in the (2.8–5.3)μm range, in four customized instrument settings (L1-c, L3, Lp1-cand M1) of iSHELL -the new near-IR high resolution immersion echelle spectrograph at NASA/IRTF (Maunakea, Hawaii). We identified twelve molecular species; nine primary volatiles (H2O, HCN, NH3, CO, C2H2, C2H6, CH4, CH3OH, H2CO) and three product species (CN, NH2,OH). We detected 85H2O emission lines from 12 water vibrational bands across L1-c and M1 settings. The many detected water emission lines enabled retrieval of accurate measures for ortho-and para-H2O independently, thereby reducing systematic uncertainty in the derived ortho-para ratio and nuclear spin temperature. Excitation analyses and emission profile analyses were performed for all species, and molecular abundance ratios relative to water are compared with values found for other Oort Cloud comets in our infrared database. Abundance ratios are consistent for most species, with the exception of under-abundant methanol and over-abundant ammonia in E4.

S. Faggi↗

Fast DRR generation for 2D to 3D registration on GPUs

Purpose: The generation of digitally reconstructed radiographs (DRRs) is the most time consuming step on the CPU in intensity based two-dimensional x-ray to three-dimensional (CT or 3D rotational x-ray) medical image registration, which has application in several image guided interventions. This work presents optimized DRR rendering on graphical processor units (GPUs) and compares performance achievable on four commercially available devices. Methods: A ray-cast based DRR rendering was implemented for a 512 Multiplication-Sign 512 Multiplication-Sign 72 CT volume. The block size parameter was optimized for four different GPUs for a region of interest (ROI) of 400 Multiplication-Sign 225 pixels with different sampling ratios (1.1%-9.1% and 100%). Performance was statistically evaluated and compared for the four GPUs. The method and the block size dependence were validated on the latest GPU for several parameter settings with a public gold standard dataset (512 Multiplication-Sign 512 Multiplication-Sign 825 CT) for registration purposes. Results: Depending on the GPU, the full ROI is rendered in 2.7-5.2 ms. If sampling ratio of 1.1%-9.1% is applied, execution time is in the range of 0.3-7.3 ms. On all GPUs, the mean of the execution time increased linearly with respect to the number of pixels if sampling was used. Conclusions: The presented results outperform other results from the literature. This indicates that automatic 2D to 3D registration, which typically requires a couple of hundred DRR renderings to converge, can be performed quasi on-line, in less than a second or depending on the application and hardware in less than a couple of seconds. Accordingly, a whole new field of applications is opened for image guided interventions, where the registration is continuously performed to match the real-time x-ray.

07 ISOTOPE AND RADIATION SOURCES↗

Low Ohmic contact resistance and high on/off ratio in transition metal dichalcogenides field-effect transistors via residue-free transfer

Beyond-silicon technology demands ultrahigh performance field-effect transistors. Transition metal dichalcogenides provide an ideal material platform, but the device performances such as the contact resistance, on/off ratio and mobility are often limited by the presence of interfacial residues caused by transfer procedures. Here, we show an ideal residue-free transfer approach using polypropylene carbonate with a negligible residue coverage of ~0.08% for monolayer MoS 2 at the centimetre scale. By incorporating a bismuth semimetal contact with an atomically clean monolayer MoS 2 field-effect transistor on hexagonal boron nitride substrate, we obtain an ultralow Ohmic contact resistance of ~78 Ω µm, approaching the quantum limit, and a record-high on/off ratio of ~10 11 at 15 K. Further, such an ultra-clean fabrication approach could be the ideal platform for high-performance electrical devices using large-area semiconducting transition metal dichalcogenides.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Effects of Winglets on the Drag of a Low-Aspect-Ratio Configuration

A wind-tunnel investigation has been performed to determine the effect of winglets on the induced drag of a low-aspect-ratio wing configuration at Mach numbers between 0.30 and 0.85 and a nominal angle-of-attack range from -2 deg to 20 deg. Results of the tests at the cruise lift coefficient showed significant increases in lift-drag ratio for the winglet configuration relative to a wing-alone configuration designed for the same lift coefficient and Mach number. Further, even larger increases in lift-drag ratio were observed at lift coefficients above the design value at all Mach numbers tested. The addition of these winglets had a negligible effect on the static lateral-directional stability characteristics of the configuration. No tests were made to determine the effect of these winglets at supersonic Mach numbers, where increases in drag caused by winglets might be more significant. Computational analyses were also performed for the two configurations studied. Linear and small-disturbance formulations were used. The codes were found to give reasonable performance estimates sufficient for predicting changes of this magnitude.

Smith, Leigh Ann↗

JPSS-1 VIIRS Radiometric Characterization and Calibration Based on Pre-Launch Testing

The Visible Infrared Imaging Radiometer Suite (VIIRS) on-board the first Joint Polar Satellite System (JPSS) completed its sensor level testing on December 2014. The JPSS-1 (J1) mission is scheduled to launch in December 2016, and will be very similar to the Suomi-National Polar-orbiting Partnership (SNPP) mission. VIIRS instrument has 22 spectral bands covering the spectrum between 0.4 and 12.6 m. It is a cross-track scanning radiometer capable of providing global measurements twice daily, through observations at two spatial resolutions, 375 m and 750 m at nadir for the imaging and moderate bands, respectively. This paper will briefly describe J1 VIIRS characterization and calibration performance and methodologies executed during the pre-launch testing phases by the government independent team to generate the at-launch baseline radiometric performance and the metrics needed to populate the sensor data record (SDR) Look-Up-Tables (LUTs). This paper will also provide an assessment of the sensor pre-launch radiometric performance, such as the sensor signal to noise ratios (SNRs), radiance dynamic range, reflective and emissive bands calibration performance, polarization sensitivity, spectral performance, response-vs-scan (RVS), and scattered light response. A set of performance metrics generated during the pre-launch testing program will be compared to both the VIIRS sensor specification and the SNPP VIIRS pre-launch performance.

VIIRS↗

Large-Eddy Simulations of a Single-Injector Cooling Flow Using the High-Order Flux Reconstruction Method

A single-injector cooling flow into a heated crossflow was used as a validation case for large eddy simulations (LES) from two high-order CFD codes with comparisons to a state-of-the-art Reynolds averaged Navier-Stokes (RANS) turbulence model. The focus of this paper is on the validation of LES for one of the high-order CFD codes, namely the GFR (Glenn Flux Reconstruction) code that is being developed at NASA Glenn Research Center. Fourth-order LES were performed for the single-injector cooling flow configuration at blowing ratios of both 1.0 and 2.0, and a fifth-order LES was also performed with a blowing ratio of 1.0. The GFR simulations agree very well with the experiment mean quantities and reasonably well with the experiment turbulence quantities. The LES solutions from GFR and the other high-order CFD code, FDL3DI, agreed very closely for nearly every flow quantity examined, despite the fact that these two codes use completely different numerical methods, different grid geometries and domains, and different inflow boundary conditions. Finally, both LES show a significant accuracy improvement over RANS turbulence models for flows with large temperature gradients, where the standard gradient diffusion approximation is insufficient for temperature predictions.

Large Eddy Simulations↗

Large Eddy Simulations of a Single-Injector Cooling Flow Using the High-Order Flux Reconstruction Method

A single-injector cooling flow into a heated crossflow was used as a validation case for large eddy simulations (LES) from two high-order CFD codes with comparisons to a state-of-the-art Reynolds averaged Navier-Stokes (RANS) turbulence model. The focus of this paper is on the validation of LES for one of the high-order CFD codes, namely the GFR (Glenn Flux Reconstruction) code that is being developed at NASA Glenn Research Center. Fourth-order LES were performed for the single-injector cooling flow configuration at blowing ratios of both 1.0 and 2.0, and a fifth-order LES was also performed with a blowing ratio of 1.0. The GFR simulations agree very well with the experiment mean quantities and reasonably well with the experiment turbulence quantities. The LES solutions from GFR and the other high-order CFD code, FDL3DI, agreed very closely for nearly every flow quantity examined, despite the fact that these two codes use completely different numerical methods, different grid geometries and domains, and different inflow boundary conditions. Finally, both LES show a significant accuracy improvement over RANS turbulence models for flows with large temperature gradients, where the standard gradient diffusion approximation is insufficient for temperature predictions.

Large Eddy Simulation↗

Mean Field Games for Stochastic Growth with Relative Utility

This paper considers continuous time stochastic growth-consumption optimization in a mean field game setting. The individual capital stock evolution is determined by a Cobb–Douglas production function, consumption and stochastic depreciation. The individual utility functional combines an own utility and a relative utility with respect to the population. The use of the relative utility reflects human psychology, leading to a natural pattern of mean field interaction. The fixed point equation of the mean field game is derived with the aid of some ordinary differential equations. Due to the relative utility interaction, our performance analysis depends on some ratio based approximation error estimate.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

InP concentrator solar cells for space applications

The design, fabrication, and characterization of high-performance, n(+)/p InP shallow-homojunction (SHJ) concentrator solar cells is described. The InP device structures were grown by atmospheric-pressure metalorganic vapor phase epitaxy (APMOVPE). A preliminary assessment of the effects of grid collection distance and emitter sheet resistance on cell performance is presented. At concentration ratios of over 100, cells with AM0 efficiencies in excess of 21 percent at 25 C and 19 percent at 80 C are reported. These results indicate that high-efficiency InP concentrator cells can be fabricated using existing technologies. The performance of these cells as a function of temperature is discussed, and areas for future improvement are outlined.

Ward, J. S.↗

Isotope ratio characteristics and sensitivity for uranium determinations using a liquid sampling-atmospheric pressure glow discharge ion source coupled to an Orbitrap mass analyzer

Abstract The continued development of the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma as an ion source for diverse, elemental/isotopic analysis applications continues. To this end, characterization of the capabilities in performing precise and accurate isotope ratio (IR) determinations is essential. Based on past experience with the Thermo Exactive Orbitrap mass analyzer, the LS-APGD was interfaced with this instrument for these tests. While the Orbitrap platform has demonstrated excellent mass resolution and accuracy in “organic” mass spectrometry (MS) applications, work using an Orbitrap for IR analysis is very sparse. These efforts build off previous work in this coupling, where the importance of a few of the LS-APGD discharge parameters and Orbitrap data acquisition methods on IR precision and accuracy were probed. Presented here are the results of a study that evaluated the analytical precision for natural uranium sample (assumed 235U/238U = 0.0072) determinations. The instrumental parameters evaluated include the number of microscans and scans making up a data acquisition set, uranium concentration/signal level, sample make-up, and Fourier transform digitization window. Ultimately, a precision of 0.41% relative standard deviation (RSD) can be achieved for a single determination, with a reproducibility of 1.63 %RSD over 10 separate analytical measurements. A preliminary study of matrix effects on IR measurements of U is presented, highlighting the importance of pre-mass selection before injection into the Orbitrap. The analytical system sensitivity is suggested with the ability to produce a calibration function having an R2 value of >0.99 over a range of 4 orders of magnitude of concentration (~1 – 1000 ng mL-1). These efforts demonstrate the very promising pairing of the LS-APGD ionization source and the Orbitrap, pointing as well to definitive paths forward to better utilize both components in high quality isotope ratio mass spectrometry (IRMS).

Environmental Molecular Sciences Laboratory↗

Sidewall passivation layer thickness and composition profiles of etched silicon patterns from angle resolved x-ray photoelectron spectroscopy analysis

In this study, we present a technique to analyze side wall passivation layers formed on silicon sidewalls after plasma processing. The thickness and chemical composition are derived from angle resolved x-ray photoelectron spectroscopy analyses. It is a non-destructive, quasi in situ method to determine profiles of the thickness and the chemical composition of passivation layers in trenches up to an aspect ratio of about 3. The performance of this technique to quantify the passivation layer thickness is compared to a standard technique using secondary electron microscopy images with respect to two different samples and is found to be at least equivalent. The possible uncertainties and limitations of this technique are discussed as well.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

1025:1 Area Ratio Nozzle Evaluated at High Combustion Chamber Pressure

A recently completed experimental test program obtained performance data on an optimally contoured nozzle with an exit-to-throat area ratio of 1025:1 and on a truncated version of this nozzle with an area ratio of 440:1. The nozzles were tested with gaseous hydrogen and liquid oxygen propellants at combustion chamber pressures of 12.4 to 16.5 mPa (1800 to 2400 psia). Testing was conducted in the altitude test capsule at the NASA Lewis Research Center's Rocket Engine Test Facility (RETF), and results were compared with analytical performance predictions. This testing builds on previous work with this nozzle at Lewis, where testing was completed at nominal chamber pressure of 350 psia. High-area-ratio nozzles have long been sought as a means to increase the performance of spacebased rocket engines. However, as the area ratio increases, the physical size and weight of the nozzle also increase. As a result, engine and vehicle designers must make tradeoffs between nozzle size and performance enhancement. Until this test program, very little experimental data existed on the performance of the high-area-ratio nozzles used in rocket engine designs. The computer codes being used by rocket engine designers rely on data extrapolated from tests of low-area-ratio nozzles, and these extrapolations do not always provide the accuracy needed for a reliable design assessment. Therefore, we conducted this high-area-ratio nozzle testing program to provide performance data for use in rocket engine design and analysis computer codes. The nozzle had a nominal 2.54-cm- (1-in.-) diameter throat, an exit diameter of 81.3-cm (32.0-in.) at an exit-to-throat area ratio of 1025, and a length of 128.6 cm (50.6 in.). Testing was conducted in an altitude test capsule to simulate the static pressure at altitude by vacuum pumping. Data such as propellant mass flow, oxidizer-to-fuel mixture, and thrust were measured. These measurements were then used to calculate performance factors such as the thrust coefficient, the characteristic exhaust velocity efficiency, and the vacuum specific impulse. In addition, the nozzle temperature was measured to calculate the amount of heat transferred from the combustion gases to the nozzle.

Source record↗

Substitution of Co with Ni in Co/Al 2 O 3 Catalysts for Fischer–Tropsch Synthesis

The effect of cobalt substitution with nickel was investigated for the Fischer–Tropsch synthesis reaction. Catalysts having different Ni/Co ratios were prepared by aqueous incipient wetness co-impregnation, characterized, and tested using a continuously stirred tank reactor (CSTR) for more than 200 h. The addition of nickel did not significantly modify the morphological properties measured. XRD, STEM, and TPR-XANES results showed intimate contact between nickel and cobalt, strongly suggesting the formation of a Co-Ni solid oxide solution in each case. Moreover, TPR-XANES indicated that nickel addition improves the cobalt reducibility. This may be due to H 2 dissociation and spillover, but is more likely the results of a chemical effect of intimate contact between Co and Ni resulting in Co-Ni alloying after activation. FTS testing revealed a lower initial activity when nickel was added. However, CO conversion continuously increased with time on-stream until a steady-state value (34%–37% depending on Ni/Co ratio) was achieved, which was very close to the value observed for undoped Co/Al 2 O 3 . This trend suggests nickel can stabilize cobalt nanoparticles even at a lower weight percentage of Co. Currently, the cobalt price is 2.13 times the price of nickel. Thus, comparing the activity/price, the catalyst with a Ni/Co ratio of 25/75 has better performance than the unpromoted catalyst. Finally, nickel-promoted catalysts exhibited slightly higher initial selectivity for light hydrocarbons, but this difference typically diminished with time on-stream; once leveling off in conversion was achieved, the C 5+ selectivities were similar (≈ 80%) for Ni/Co ratios up to 10/90, and only slightly lower (≈ 77%) at Ni/Co of 25/75.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A comparative study on cubic and tetragonal Ce-ZrO 2 supported Rh catalysts for N 2 O decomposition

Zirconium oxide (ZrO 2 ) exhibits strong synergy with cerium oxide (CeO 2 ), acting as a structural and electronic promoter during catalytic redox reactions. As a result, Ce-ZrO 2 composite oxides are widely used as supports in various catalytic systems. In our previous work, we demonstrated that the incorporation of Zr 4+ into the CeO 2 lattice significantly enhanced Rh dispersion, improved redox ability, and stabilized surface Rh species, which collectively boosted the de-N 2 O activity of Rh/Ce-ZrO 2 catalysts. Building on these findings, the present study emphasizes that the crystallographic phase of Ce-ZrO 2 , governed by the Ce/Zr ratio, plays a decisive role in tuning the physicochemical environment of Rh active sites and thereby optimizing catalytic performance. In conclusion, tailoring the Ce/Zr ratio to favor the cubic fluorite structure emerges as a promising strategy for the rational design of highly active and stable catalysts for N 2 O decomposition and potentially other redox-sensitive environmental applications.

36 MATERIALS SCIENCE↗

Development of selected advanced aerodynamics and active control concepts for commercial transport aircraft

Work done under the Energy Efficient Transport project in the field of advanced aerodynamics and active controls is summarized. The project task selections focused on the following: the investigation of long-duct nacelle shape variation on interference drag; the investigation of the adequacy of a simple control law for the elastic modes of a wing; the development of the aerodynamic technology at cruise and low speed of high-aspect-ratio supercritical wings of high performance; and the development of winglets for a second-generation jet transport. All the tasks involved analysis and substantial wind tunnel testing. The winglet program also included flight evaluation. It is considered that the technology base has been built for the application of high-aspect-ratio supercritical wings and for the use of winglets on second-generation transports.

Taylor, A. B.↗

Supersonic airplane study and design

A supersonic airplane creates shocks which coalesce and form a classical N-wave on the ground, forming a double bang noise termed sonic boom. A recent supersonic commercial transport (the Concorde) has a loud sonic boom (over 100 PLdB) and low aerodynamic performance (cruise lift-drag ratio 7). To enhance the U.S. market share in supersonic transport, an airframer's market risk for a low-boom airplane has to be reduced. Computational fluid dynamics (CFD) is used to design airplanes to meet the dual constraints of low sonic boom and high aerodynamic performance. During the past year, a research effort was focused on three main topics. The first was to use the existing design tools, developed in past years, to design one of the low-boom wind-tunnel configurations (Ames Model 3) for testing at Ames Research Center in April 1993. The second was to use a Navier-Stokes code (Overflow) to support the Oblique-All-Wing (OAW) study at Ames. The third was to study an optimization technique applied on a Haack-Adams body to reduce aerodynamic drag.

Cheung, Samson↗

Current Source Inverter Based Large Constant Power Speed Ratio SPM Machine Drive for Traction Applications

A high-performance surface permanent magnet (SPM) machine drive with an extended constant power speed ratio is proposed using a current source inverter (CSI) for a traction application. The constant-power operation regions of an SPM machine can be extended in an appealing fashion by taking advantage of the output voltage boost capability of the CSI. The CSI is naturally a boost-type converter, in contrast to the voltage source inverter (VSI) which has buck-type characteristics. To investigate the value of the CSI voltage boost feature, a new traction motor with higher rated voltage and lower rated current has been designed and compared to the motor that would be used with a VSI. The lower CSI current makes it possible to reduce the mass of the inverter and output power cable, benefiting power density and cost reduction. The SPM machine is modeled in the synchronous reference frame including the effect of the ac filter capacitors at the CSI output terminals. The capability of extending the speed range of the proposed motor is verified via closed-form analysis and FEA simulation, and its performance characteristics are compared with those of a VSI-based SPM motor of the same type.

42 ENGINEERING↗