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At least 847 records · Page 47

Electrophoretic deposited TiO 2 pigment-based back reflectors for thin film solar cells

Highly reflective coatings with strong light scattering effect have many applications in optical components and optoelectronic devices. This paper reports titanium dioxide (TiO 2 ) pigment-based reflectors that have 2.5 times higher broadband diffuse reflection than commercially produced aluminum or silver based reflectors and result in efficiency enhancements of a single-junction amorphous Si solar cell. Electrophoretic deposition is used to produce pigment-based back reflectors with high pigment density, controllable film thickness and site-specific deposition. Electrical conductivity of the pigment-based back reflectors is improved by creating electrical vias throughout the pigment-based back reflector by making holes using an electrical discharge / dielectric breakdown approach followed by a second electrophoretic deposition of conductive nanoparticles into the holes. While previous studies have demonstrated the use of pigment-based back reflectors, for example white paint, on glass superstrate configured thin film Si solar cells, this work presents a scheme for producing pigment-based reflectors on complex shape and flexible substrates. Finally, mechanical durability and scalability are demonstrated on a continuous electrophoretic deposition roll-to-roll system which has flexible metal substrate capability of 4 inch wide and 300 feet long.

14 SOLAR ENERGY↗

Exposing hidden alternative backbone conformations in X-ray crystallography using qFit

Proteins must move between different conformations of their native ensemble to perform their functions. Crystal structures obtained from high-resolution X-ray diffraction data reflect this heterogeneity as a spatial and temporal conformational average. Although movement between natively populated alternative conformations can be critical for characterizing molecular mechanisms, it is challenging to identify these conformations within electron density maps. Alternative side chain conformations are generally well separated into distinct rotameric conformations, but alternative backbone conformations can overlap at several atomic positions. Our model building program qFit uses mixed integer quadratic programming (MIQP) to evaluate an extremely large number of combinations of sidechain conformers and backbone fragments to locally explain the electron density. Here, we describe two major modeling enhancements to qFit: peptide flips and alternative glycine conformations. We find that peptide flips fall into four stereotypical clusters and are enriched in glycine residues at the n+1 position. The potential for insights uncovered by new peptide flips and glycine conformations is exemplified by HIV protease, where different inhibitors are associated with peptide flips in the “flap” regions adjacent to the inhibitor binding site. Our results paint a picture of peptide flips as conformational switches, often enabled by glycine flexibility, that result in dramatic local rearrangements. Our results furthermore demonstrate the power of large-scale computational analysis to provide new insights into conformational heterogeneity. Furthermore, improved modeling of backbone heterogeneity with high-resolution X-ray data will connect dynamics to the structure-function relationship and help drive new design strategies for inhibitors of biomedically important systems.

59 BASIC BIOLOGICAL SCIENCES↗

Specific Energy Analysis for the Manufacturing of Light-Weight Automobile Body

This manuscript analyses the specific energy requirements to produce two hybridised vehicle structures on current automotive assembly lines. It provides quantitative and specific electric (kWhr/vehicle) and fossil-fuel (MMBtu/vehicle) energy predictions of the body-in-white (BIW) manufacturing processes including body panel forming, welding, painting, and final assembly, in addition to the facility heating ventilation and air conditioning or HVAC consumption. Two hybridised BIW design criteria are analysed; the first is based on minimising the added cost per unit weight saved (+$/-kg), while the second is based on maximising the percentage of weight saved (% -kg). Also a new criterion; that is the added specific-energy per unit weight-saved or (+kWhr/vehicle/-kg) is proposed. The light-weight structures comprise body parts made of aluminium and steel. To compute energy consumptions, the study utilises the energy performance index (EPI) stochastic model in addition to complementing it with a panel-forming energy model. Cost analysis is also provided for all the major vehicle body-panels using an in-house Excel macro. The study reverse engineers a passenger vehicle BIW using a full-size coordinate measuring machine (CMM). The presented work further highlights the monetary value of the associated emissions when increasing the specific energy.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Dendrometer data at The Morton Arboretum Forestry Plots 2019-2023

We are collecting long-term dendrometer data at The Morton Arboretum to determine seasonal growth patterns in trees. This data on stem growth patterns will eventually be integrated with other ongoing data streams to paint a broader picture of plant phenology. This data package contains the outputs from three types of dendrometer devices: ICT band dendrometer data is in the "ICT_data2020_2023.csv" file, TreeHugger band dendrometer data is in the "TreeHugger_data2019_2020.csv" file, and TOMST point dendrometer data is in the "TOMST_data2021_2023.csv" file. The TreeHugger and TOMST files contain corrected and raw uncorrected values, whereas the ICT data file contains only raw data. Initial tree size data at device installation is located in the "Initial_Tree_Size.csv" file. Additional information on units are contained within each data file's respective data dictionary, and the location metadata file contains the geographic locations of the 23 forestry plots at The Morton Arboretum as well as the measured tree species at each location.

54 ENVIRONMENTAL SCIENCES↗

Herbert Fröhlich: A Physicist Ahead of His Time, by G.J. Hyland [Book Review]

This authoritative biography of Herbert Fröhlich (1905-1991), a well-known theoretical physicist, paints an intimate portrait of a pioneering scientist who made seminal contributions to condensed matter physics and left his mark on other domains such as biology over a 60-year career. From his vantage point as the last graduate student of this eminent physicist, Gerard Hyland has produced an account that weaves the personal experiences and travails of Fröhlich with detailed discussion of the theory of dielectrics. The political upheavals in Europe during the 20th century provide a dramatic backdrop for the narrative.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Irradiation at Different Fetal Stages Results in Different Translocation Frequencies in Adult Mouse Thyroid Cells

While it is generally believed that fetuses are at high risk of developing cancers, including leukemia, after low doses of radiation, it has been reported that atomic bomb survivors exposed in utero did not show a dose response for translocations in blood T lymphocytes when they were examined at approximately 40 years of age. Subsequent mouse studies confirmed that animals irradiated during the fetal stage did not show evidence of radiation effects in lymphocytes and bone marrow cells when they were examined after reaching adulthood. However, in a study of rat mammary epithelial cells, radiation effects were clearly observed after fetal irradiation. These results indicate that the fate of chromosome aberrations induced in a fetus could vary among different tissues. Here we report on translocation frequencies in mouse thyroid cells, which were irradiated at different stages of fetal development. Cytogenetic examination was then conducted using fluorescence in situ hybridization (FISH) painting of chromosomes 1 and 3. Adult mice, 2 Gy X-ray irradiated at 15.5-day-old fetuses (E15.5), showed a higher translocation frequency (30/1,155 or 25.3 x 10 -3 ) than nonirradiated adult controls (0/1,007 or 0.1 x 10 -3 ), and was near that experienced by irradiated mothers and non-pregnant adult females (43/1,244 or 33.7 x 10 -3 ). These results are consistent with those seen in rat mammary cells. However, when fetuses were irradiated at an earlier stage of development (E6.5) before thyroid organogenesis, the resulting observed translocation frequency was much lower (3/502 or 5.8 x 10 -3 ) than that in E15.5 mice. These results suggest that after fetal irradiation, tissue stem cells record radiation effects primarily when the exposure occurs in cells that have been integrated into tissue. Embryonic stem cells that have been damaged prior to integration into the niche may undergo negative selection due to apoptosis, mitotic death or stem cell-niche cell interactions. The implications of these results in interpreting cancer risks after fetal irradiation are also discussed.

59 BASIC BIOLOGICAL SCIENCES↗

Design of imaginary transition gamma booster synchrotron for the Jefferson Lab EIC (JLEIC)

Baseline design of the JLEIC booster synchrotron is presented. Its aim is to inject and accumulate heavy ions and protons at 285 MeV, to accelerate them to about 7 GeV, and finally to extract the beam into the ion collider ring. The Figure-8 ring features two 2600 achromatic arcs configured with negative momentum compaction optics, designed to avoid transition crossing for all ion species during the course of acceleration. The lattice also features a specialized high dispersion injection insert optimized to facilitate the transverse phase-space painting in both planes for multi-turn ion injection. Furthermore, the lattice has been optimized to ease chromaticity correction with two families of sextupoles in each plane. The booster ring is configured with super-ferric, 3 Tesla bends. We are presently launching optimization of the booster synchrotron design to operate in the extreme space-charge dominated regime.

Bogacz, Alex↗

BEAM COLLIMATION IN THE PIP-II LINAC TO BOOSTER TRANSFER LINE

The new PIP-II superconducting linac will deliver a 2 mA average H⁻ beam to the existing Booster synchrotron. The injected beam is accumulated by charge exchange over approximately 300 turns; phase space painting is used to mitigate space charge effects. To limit the power load on the internal waste beam absorber from the transverse tails of the H⁻ distribution missing the foil, the beam will be collimated in both planes in the linac to Booster transfer line using compact collimators of a novel design. Both the number of parasitic hits and the fraction of the beam missing the foil are sensitive functions of the H⁻ beam centroid position with respect to the edge of the foil. The positioning of the collimation is constrained by the availability of suitable space in the transfer line lattice, by specifics of the collimator design, by the phase space orientation at the collimator, and by the betatron phase advance to the foil needed to achieve proper orientation of the spatial distribution at the injection point. In this contribution, we describe the procedure by which collimator positions were optimized. We then discuss the expected performance of the overall system.

Johnson, David E.↗

6D Simulations of PIP-II Booster Injection

The PIP-II superconducting linac will deliver 2 mA average H⁻ beam current at 800 MeV to the existing Booster synchrotron over a period of 0.55 ms (285 turns). As a result, the injected beam power will quadruple to 17 kW. Safe operation at the increased beam power implies careful attention to the origin, magnitude, and distribution of both controlled and uncontrolled losses. Uncontrolled losses are due to neutral ions in excited states stripped in downstream magnets and large angle scattered protons from parasitic foil hits. The relative magnitudes of these loss mechanisms is used to determine the optimal foil thickness. A transverse painting scheme involving closed orbit motion will be used to mitigate space charge effects and minimize parasitic foil hits. Using a detailed full 6D simulation of the injection process, we compute large angle scattering losses and compare results to back of the envelope estimates. We investigate possible impact of space charge on the emittance and beam distribution both during and at the conclusion of the injection period.

43 PARTICLE ACCELERATORS↗

Morphological and molecular characterization of Paratylenchus beltsvillensis n. sp. (Tylenchida: Paratylenchidae) from the rhizosphere of pine tree ( Pinus virginiana Mill) in Maryland, USA

The pin nematode, Paratylechus beltsvillensis sp. collected from rhizosphere soil of a Virginia pine tree (Pinus virginiana Mill) growing in Little Paint Branch Park, Beltsville, Prince George’s County, Maryland, USA, is described and illustrated along with light and scanning electron photomicrographs. Females, males, and juveniles of this new species were recovered from soil samples using the sugar centrifugal flotation and Baermann funnel extraction methods. Morphologically, females are short, body length ranging from 245 to 267 μm, stylet from 70 to 75 μm long with anchor shaped knobs, vulva located at 70–73% and small vulval flap, spermatheca large, and ovoid filled with sperms. Lateral field with three incisures, of which the outer two are prominent. Tail slender, having a rounded tail terminus. Males without stylet and have a degenerated pharynx, spicules = 17–20 µm and gubernaculum = 5.0–5.5 µm. Both morphological observations and molecular analysis of ITS and partial 28S ribosomal RNA gene sequences indicated that the specimens collected from the soil at Beltsville Park from rhizosphere soil samples from Virginia pine represents a new pin nematode species.

59 BASIC BIOLOGICAL SCIENCES↗

Heritable Genetic Changes in Cells Recovered from Irradiated 3D Tissue Contracts (Final report)

Combining contemporary cytogenetic methods with DNA CGH microarray technology and chromosome flow-sorting increases substantially the ability to resolve exchange breakpoints associated with interstitial deletions and translocations, allowing the consequences of radiation damage to be directly measured at low doses, while also providing valuable insights into molecular mechanisms of misrepair processes that, in turn, identify appropriate biophysical models of risk at low doses. The aims of this work apply to cells recovered from 3D tissue constructs of human skin and, for the purpose of comparison, the same cells irradiated in traditional 2D cultures. These aims are: to analyze by multi-flour fluorescence in situ hybridization (mFISH) the chromosomes in clonal descendents of individual human fibroblasts that were previously irradiated; to examine irradiated clones from Aim 1 for submicroscopic deletions by subjecting their DNA to comparative genomic hybridization (CGH) microarray analysis; and to flow-sort aberrant chromosomes from clones containing stable radiation-induced translocations and map the breakpoints to within an average resolution of 100 kb using the technique of 'array painting'.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Development of spray coated cathodes for RITS-6.

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean↗

The Commercial Development of Water Repellent Coatings for High Voltage Transmission Lines

The purpose of the Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Southwire Company was to jointly develop a low cost, commercially viable, water-repellant anti-icing coating system for high voltage transmission lines. Icing of power lines and other structures caused by freezing rain events occurs annually in the United States, and leads to severe and prolonged power outages. These outages cause untold economic and personal distress for many American families and businesses. Researchers at the Department of Energy's Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee have previously developed a set of superhydrophobic coatings with remarkable anti-icing properties that could potentially be sprayed or painted onto high-tension power lines and pylons. These coatings drastically reduce ice accumulation on these structures during freezing rain events. The project involved obtaining technical input, supplies and test high voltage cables from Southwire, along with the joint development of anti-icing coating techniques, which would result in a commercial license agreement between Southwire and ORNL, and potentially other companies requiring water repellent anti-icing coatings.

Hunter, Scott Robert↗

The commercial development of water repellent coatings for high voltage transmission lines

The purpose of the Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Southwire Company was to jointly develop a low cost, commercially viable, water-repellant anti-icing coating system for high voltage transmission lines. Icing of power lines and other structures caused by freezing rain events occurs annually in the United States, and leads to severe and prolonged power outages. These outages cause untold economic and personal distress for many American families and businesses. Researchers at the Department of Energy's Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee have previously developed a set of superhydrophobic coatings with remarkable anti-icing properties that could potentially be sprayed or painted onto high-tension power lines and pylons. These coatings drastically reduce ice accumulation on these structures during freezing rain events. The project involved obtaining technical input, supplies and test high voltage cables from Southwire, along with the joint development of anti-icing coating techniques, which would result in a commercial license agreement between Southwire and ORNL, and potentially other companies requiring water repellent anti-icing coatings.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Spray Foam Exterior Insulation with Stand-Off Furring

IBACOS, in collaboration with GreenHomes America, was contracted by the New York State Energy Research and Development Authority to research exterior wall insulation solutions. This research investigated cost-effective deep energy retrofit (DER) solutions for improving the building shell exterior while achieving a cost-reduction goal, including reduced labor costs to reach a 50/50 split between material and labor. The strategies included exterior wall insulation plus energy upgrades as needed in the attic, mechanical and ventilation systems, and basement band joist, walls, and floors. The work can be integrated with other home improvements such as siding or window replacement. This strategy minimizes physical connections to existing wall studs, encapsulates existing siding materials (including lead paint) with spray foam, and creates a vented rain screen assembly to promote drying. GreenHomes America applied construction details created by IBACOS to a test home. 2x4 framing members were attached to the wall at band joists and top plates using 'L' clips, with spray foam insulating the wall after framing was installed. Windows were installed simultaneously with the framing, including extension jambs. The use of clips in specific areas provided the best strength potential, and 'picture framing' the spray foam held the 2x4s in place. Short-term testing was performed at this house, with monitoring equipment installed for long-term testing. Testing measurements will be provided in a later report, as well as utility impact (before and after), costs (labor and materials), construction time, standard specifications, and analysis for the exterior wall insulation strategy.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Stand-Off Furring in Deep Energy Retrofits: Syracuse, New York (Fact Sheet)

IBACOS, in collaboration with GreenHomes America, was contracted by the New York State Energy Research and Development Authority to research exterior wall insulation solutions. This research investigated cost-effective deep energy retrofit (DER) solutions for improving the building shell exterior while achieving a cost-reduction goal, including reduced labor costs to reach a 50/50 split between material and labor. The strategies included exterior wall insulation plus energy upgrades as needed in the attic, mechanical and ventilation systems, and basement band joist, walls, and floors. The work can be integrated with other home improvements such as siding or window replacement. This strategy minimizes physical connections to existing wall studs, encapsulates existing siding materials (including lead paint) with spray foam, and creates a vented rain screen assembly to promote drying. GreenHomes America applied construction details created by IBACOS to a test home. 2x4 framing members were attached to the wall at band joists and top plates using 'L' clips, with spray foam insulating the wall after framing was installed. Windows were installed simultaneously with the framing, including extension jambs. The use of clips in specific areas provided the best strength potential, and 'picture framing' the spray foam held the 2x4s in place. Short-term testing was performed at this house, with monitoring equipment installed for long-term testing. Testing measurements will be provided in a later report, as well as utility impact (before and after), costs (labor and materials), construction time, standard specifications, and analysis for the exterior wall insulation strategy.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Pilot Implementation of a Field Study Design to Evaluate the Impact of Source Control Measures on Indoor Air Quality in High Performance Homes

To improve the indoor air quality in new, high performance homes, a variety of standards and rating programs have been introduced to identify building materials that are designed to have lower emission rates of key contaminants of concern and a number of building materials are being introduced that are certified to these standards. For example, the U.S. Department of Energy (DOE) Zero Energy Ready Home program requires certification under the U.S. Environmental Protection Agency (EPA) Indoor airPLUS (IaP) label, which requires the use of PS1 or PS2 certified plywood and OSB; low-formaldehyde emitting wood products; low- or no-VOC paints and coatings as certified by Green Seal Standard GS-11, GreenGuard, SCS Indoor Advantage Gold Standard, MPI Green Performance Standard, or another third party rating program; and Green Label-certified carpet and carpet cushions. However, little is known regarding the efficacy of the IAP requirements in measurably reducing contaminant exposures in homes. The goal of this project is to develop a robust experimental approach and collect preliminary data to support the evaluation of indoor air quality (IAQ) measures linked to IAP-approved low-emitting materials and finishes in new residential homes. To this end, the research team of Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) developed a detailed experimental plan to measure IAQ constituents and other parameters, over time, in new homes constructed with materials compliant with IAP’s low-emitting material and ventilation requirements (i.e., section 6.1, 6.2, 6.3, and 7.2) and similar homes constructed to the state building code with conventional materials. The IAQ in IAP and conventional homes of similar age, location, and construction style is quantified as the differences in the speciated VOC and aldehyde concentrations, normalized to dilution rates. The experimental plan consists of methods to evaluate the difference between low-emitting and “conventional” materials as installed in newly constructed residential homes using both (1) highly controlled, short-term active samples to precisely characterize the building-related chemical emissions and building contents and (2) a week-long passive sample designed to capture the impact of occupant behavior and related activities on measured IAQ contaminant levels indoors. The combination of detailed short-term measurements with the home under controlled/consistent conditions during pre- and post-occupancy and the week-long passive sampling data provide the opportunity to begin to separate the different emission sources and help isolate and quantify variability in the monitored homes. Between April and August 2014, the research team performed pre-occupancy and post-occupancy sampling in one conventional home and two homes built with low-emitting materials that were generally consistent with EPA’s Indoor airPLUS guidelines. However, for a number of reasons, the full experimental plan was not implemented. The project was intended to continue for up to three years to asses long-term changes in IAQ but the project was limited to one calendar year. As a result, several of the primary research questions related to seasonal impacts and the long-term trends in IAQ could not be addressed. In addition, there were several unexpected issues related to recruiting, availability of home types, and difficulty coordinating with builders/realtors/homeowners. Several field monitoring issues also came up that provide “lessons learned” that led to improvements to the original monitoring plan. The project produced a good experimental plan that is expected to be be useful for future efforts collecting data to support answering these same or similar research questions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

2012 Update to the Site Discharge Pollution Prevention Plan, Rev. 1: Sandia/Mortandad Watershed Receiving Waters: Sandia Canyon, Cañada del Buey, Mortandad Canyon, and Ten-Site Canyon (Vol. 2)

Two historical industrial activity areas are associated with S001, S-SMA-0.25: Sites 03-013(a) and 03-052(f). Solid Waste Management Unit (SWMU) 03-013(a) is a 1500-ft-long corrugated metal pipe (CMP) storm drain that served building 03-0038. The storm drain ran underground around building 03-0038, east along the south side of the Otowi Building (building 03-0261) and connected to four other storm drains before daylighting 100 ft east of the Otowi Building where it became an open concrete- and rock-lined ditch. The open drain continued past transportable office buildings (buildings 03-1616 and 03-1617) and passed beneath streets and sidewalks to a point northeast of the Oppenheimer Study Center (building 03-0207) where it discharged to the SWMU 03-052(f) outfall before draining into Sandia Canyon. Most of the CMP associated with SWMU 03-013(a) was removed in 2004 to accommodate the construction of the National Security Science Building (03-1400) and a new parking structure (03-1402) east of the Otowi Building. The CMP was managed as nonhazardous/nonradioactive industrial waste. Inspection of the drainline trench showed no evidence of a release from the drainpipe. A new storm drainline was installed west of SWMU 03-052(f) to manage storm water runoff from the new parking structure. The new storm drain discharges to SWMU 03-052(f). Potential contaminants associated with industrial materials historically managed at this Site are metals and petroleum products. SWMU 03-052(f) is a formerly permitted outfall (U.S. Environmental Protection Agency [EPA] 03A023) that received wastewater from floor drains [Area of Concern (AOC) 03-013(b)], sinks, water fountains, and a storm drain [SWMU 03-013(a)], which served building 03-0038 until 1987 when the drains in building 03-0038 were rerouted to the Technical Area 03 (TA-03) sanitary sewer system. Stoddard solvents, dry acid, and caustic materials from the maintenance shop were discarded through sinks and floor drains to this outfall. Spent paint solvents and cutting oils contaminated with machined beryllium particles may also have been released to the floor drains during the 1960s and 1970s. In addition, cooling water for welding torches was discharged directly to the drains. The first spill was approximately 200 gal. of a water-waste oil mixture that was discharged when an automatic compressor blowdown mechanism failed. A second spill from a ruptured air-compressor oil line resulted in the release of approximately 1 qt of compressor oil to the drain. This spill produced an oily sheen on the surface of the water at the SWMU 03-052(f) outfall. A third spill occurred when approximately 15 gal. of diesel fuel was released from a ruptured truck fuel line into the utilities construction trench between buildings 03-1793 and 03-1794. On the same day, a clay sewer pipe in the utility trench broke, releasing approximately 2000 gal. of wastewater into the excavation. A sump was used to remove the wastewater from the excavation, and the wastewater was discharged to SWMU 03-052(f). The diesel-contaminated asphalt and soil were removed and disposed of. Runoff from parking lots and the surrounding areas also discharges to the outfall. Outfall 03A023 was removed from the National Pollutant Discharge Elimination System (NPDES) permit on July 11, 1997. Potential contaminants associated with industrial materials historically managed at this Site are volatile organic solvents, petroleum products, and metals included in discharges from the maintenance contractor’s shop in building 03-38 and three reported petroleum hydrocarbon spills.

54 ENVIRONMENTAL SCIENCES↗