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At least 847 records · Page 47

Plant versus local soil inorganic ionic composition: The relationship to biomass smoke

Here, we examine the relationship between soil and plant inorganic chemical composition as a precursor to biomass smoke aerosol particle (PM 2.5 ) properties in desert landscapes of the Southwestern United States. Past work underscored the importance of plant species and in particular the dependence of smoke PM 2.5 water uptake on the water-soluble inorganics important in select plant species (e.g., halophytes) versus absent in other species (e.g., conifers). This study extends this work by looking at a range of soil types and salinity in examining native and invasive species in the Desert Southwest US region. Eighteen plant samples and surrounding soils were taken from four ecosystems in New Mexico, USA. Results here support the conclusion that plant species are the primary controller over the inorganic plant composition that is relevant to biomass smoke and controls its hygroscopicity. The role of soil type is secondary to plant inorganic composition but is found to be important on the ecosystem level in determining what plant species are viable in a given ecosystem. This ultimately affects the smoke properties, including PM 2.5 hygroscopicity (water uptake), produced in landscape fires. Knowledge of ecosystem features including plant species distribution and soil salinity may be combined as a first-order predictor of PM 2.5 hygroscopicity of the primary smoke emissions. This can be particularly useful when combined with knowledge of burn characteristics such as flame temperature, which also plays a key role in determining PM 2.5 water uptake response.

54 ENVIRONMENTAL SCIENCES↗

Solar-plus-storage economics: What works where, and why?

This paper explores the economics of solar-plus-storage projects for commercial-scale, behind-the-meter applications. It provides insight into the near-term and future solar-plus-storage market opportunities across the U.S. We explore the impacts of location, building load profile, technology cost, utility rate structure, and policies on solar-plus-storage economic viability, and identify which factors are most significant to project economics. While savings from storage-only projects are largely derived from demand charge reductions, solar combined with storage also provides significant energy charge savings. A common assumption is that load profiles with peaks are likely candidates for savings from storage, due to the opportunity for demand charge reduction. Our results indicate that potential for savings from combining solar with storage is independent of building load variability, likely due to the energy cost reductions from the solar. Systems are more often economical under time of use and demand charge rates, particularly when demand charges are >$10 per kilowatt. Where systems were found to be economical, expected lifetime savings averaged between 7%-10%, with savings of 30% in numerous cases. Near term markets exist for solar-plus-storage in locations such as California and New York. As technology prices drop, the number of building types that can benefit increase, and additional markets appear in Colorado, New Mexico, and Alaska. All data from the study and interactive modeling results are available at: https://openei.org/wiki/Solar+Storage.

25 ENERGY STORAGE↗

Seasonality and Declining Intensity of Methane Emissions from the Permian and Nearby US Oil and Gas Basins

We quantify weekly methane emissions and trends from oil and gas production in the US Permian Basin for 2019-2023, and in nearby basins for 2022-2023, by analytical inversion of Tropospheric Monitoring Instrument (TROPOMI) satellite observations with the Integrated Methane Inversion (IMI) at 25 km resolution. Permian oil and gas emissions averaged 4.0 ± 1.1 Tg a-1 over 2019-2023, with large seasonal variation but little interannual variability. Methane intensity fell from 5.2 to 3.2% as production surged. Intensity in the New Mexico Permian fell from 4.5 to 2.1%, approaching the state's 2026 target of <2%. Emissions were on average 50 ± 10% higher in winter than summer, which we corroborate with Permian Basin Tower Network measurements, Insight M aircraft data, and GHGSat satellite observations. This seasonality may be driven in part by higher winter emissions from liquid storage tanks due to decreased separator efficiency in cold conditions. Similar but weaker seasonality along with decreasing emissions and intensities is found in weekly inversions for the Anadarko, Barnett, Eagle Ford, and Haynesville basins in 2022-2023. Our work suggests that better weatherization of oil and gas facilities could significantly reduce methane emissions.

Permian↗

Chemistry Science Investigation: Dognapping Workshop, An Outreach Program Designed To Introduce Students to Science through a Hands-On Mystery

The Chemistry Science Investigation: Dognapping Workshop was designed to (i) target and inspire fourth grade students to view themselves as Junior Scientists before their career decisions are solidified; (ii) enable hands-on experience in fundamental scientific concepts; (iii) increase public interaction with science, technology, engineering, and mathematical personnel by providing face-to-face opportunities; (iv) give teachers a pathway forward for scientific resources; (v) meet the New Mexico K–5 Science Benchmark Performance Standards; (vi) most importantly, ensure everyone has fun! For this workshop, the students are told they will be going to see a Chemistry Magic Show, but the performance is stopped when the Chemistry Dog is reportedly stolen. The students first clear their names using a series of interactive stations and then apply a number of science experiments to solve the mystery. This report describes the workshop in detail, which is suitable for large (~100 students per day) audiences but has flexibility to be modified for much smaller groups. An identical survey was given three times (before, immediately after, and 2 months after the workshop) to determine the impact on the students’ perception of science and scientists as well as determine the effectiveness in relaying scientific concepts through retention time. As a result, survey responses indicate that scientific information pertaining to the workshop is retained for up to 2 months.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantifying Disconnection of Groundwater From Managed‐Ephemeral Surface Water During Drought and Conjunctive Agricultural Use

Abstract The physics of disconnection between interrelated surface and groundwater has evolved considerably in recent years, especially since conjunctive use of water resources is increasingly dependent on groundwater resilience, but methods to measure disconnection on a river basin scale are lacking especially for managed‐ephemeral and irrigated‐agricultural systems. Multiyear drought limited surface water along Rincon Valley within the Elephant Butte Irrigation District (EBID) in the arid, Lower Rio Grande Basin of south‐central New Mexico, USA, and effects were compounded by continued extraction of groundwater to meet crop requirements. Average year‐end water table elevations in recent years have been below the average elevation of the riverbed, indicating potential disconnection between the river and the aquifer even when the river flows during the irrigation season. This study analyzed data from EBID groundwater monitoring wells adjacent to the river, infiltration determined from river flows, and riverbed measurements along the Rincon Valley reach to determine net annual seepage discharge to the aquifer and annual average pressure head below the river. Annual assessment from 2010 to 2017 confirmed that the drought shifted the system from connection to transition and then to disconnection. Nonlinear regression was used to quantify this shift to disconnection and back, enabled determination of several disconnection process metrics, and was also used to confirm that nonlinear disconnection behavior was reversible without significant hysteresis. The method developed herein confirms that the total head difference transition threshold can be determined from river/riparian monitoring sites over reach to basin scales.

Fuchs, Erek H.↗

Spatiotemporal Variability in Transport and Reactive Processes Across a First- to Fifth-Order Fluvial Network

Fluvial networks integrate and transport constituents from terrestrial and aquatic ecosystems. To date, most research on water quality dynamics has focused on process understanding at individual streams and, as a result, there is a lack of studies analyzing how small-scale, physical and biogeochemical drivers scale across fluvial networks. We performed tracer tests in five stream orders of the Jemez River continuum in New Mexico, USA, to quantify reach-scale hyporheic exchange during two different seasonal periods to address: how do hyporheic zone contributions to riverine processing change with space and time? And does the spatiotemporal variability of hyporheic exchange scale across fluvial networks? Combining conservative (i.e., bromide) and reactive (i.e., resazurin) tracer analyses with solute transport modeling, we found a dominance of reaction-limited transport conditions in space (for all stream orders) and time (two contrasting flow regimes). Moreover, we found a trend toward more reaction-limited conditions with increasing discharge across all stream orders. While our studied fluvial network did not consistently follow the expectations of decreasing hyporheic exchange contributions with increasing stream order, as it has been previously suggested from modeling studies, we found that processing rate coefficients and Damköhler numbers consistently decreased along the continuum with increasing discharge. Our findings suggest that knowledge transferability of hyporheic zone processing along fluvial networks may be possible if the scaling patterns that we found hold true in other catchments. Thus, more research on scaling patterns along fluvial networks is highly needed.

Gootman, Kaylyn S.↗

Human Mobility to Parks Under the COVID-19 Pandemic and Wildfire Seasons in the Western and Central United States

In 2020, people's health suffered a great crisis under the dual effects of the COVID-19 pandemic and the extensive, severe wildfires in the western and central United States. Parks, including city, national, and cultural parks, offer a unique opportunity for people to maintain their recreation behaviors following the social distancing protocols during the pandemic. However, massive forest wildfires in western and central US, producing harmful toxic gases and smoke, pose significant threats to human health and affect their recreation behaviors and mobility to parks. In this study, we employed the geographically and temporally weighted regression (GTWR) Models to investigate how COVID-19 and wildfires jointly shaped human mobility to parks, regarding the number of visits per capita, dwell time, and travel distance to parks, during June - September 2020. We detected strong correlations between visitations and COVID-19 incidence in southern Montana, western Wyoming, Colorado, and Utah before August. However, the pattern was weakened over time, indicating the decreasing trend of the degree of concern regarding the pandemic. Moreover, more park visits and lower dwell time were found in parks further away from wildfires and less air pollution in Washington, Oregon, California, Colorado, and New Mexico, during the wildfire season, suggesting the potential avoidance of wildfires when visiting parks. This study provides important insights on people's responses in recreation and social behaviors when facing multiple severe crises that impact their health and wellbeing, which could support the preparation and mitigation of the health impacts from future pandemics and natural hazards.

54 ENVIRONMENTAL SCIENCES↗

Pore Pressure Diffusion and Onset of Induced Seismicity

The Raton Basin of Southern Colorado and Northern New Mexico experienced a significant increase in seismicity over the last several decades, including two M5+ earthquakes. The increase in seismicity started soon after an increase in wastewater disposal associated with coal-bed methane production. Twenty-nine wastewater injection wells have operated in the Basin, with several high-rate injectors located within a kilometer of the most seismically active regions. We developed a pore pressure model to investigate the relationship between pore pressure diffusion and onset of induced seismicity, with an emphasis on the Trinidad fault zones. Our model indicates that sufficient pore pressure increase had accumulated on the northern extent of the Trinidad fault zone to induce seismicity at the time of early-stage seismic activity. The hydrogeologic architecture of the Basin played a key role in controlling pore pressure perturbation. The basal sedimentary interval with moderately low diffusivity restricted vertical pore pressure diffusion, creating a substantial lag time between wells becoming active and the expression of perturbation in the fault zones. The spatiotemporal relationship between early-stage seismicity and wastewater injection in conjunction with modeled pore pressures suggests that the early-stage seismicity in the Raton Basin was likely triggered by pore pressure diffusion.

58 GEOSCIENCES↗

Using Multiscale Ethane/Methane Observations to Attribute Coal Mine Vent Emissions in the San Juan Basin From 2013 to 2021

Abstract Source attribution of natural gas emissions from fossil fuels in New Mexico's San Juan Basin (SJB) is challenging due to source heterogeneity and emissions transience. We demonstrate that ethane (C 2 H 6 ) to methane (CH 4 ) mixing ratios can identify and separate sources over different scales using various measurement techniques. We report simultaneous CH 4 and C 2 H 6 observations near a coal mine vent and oil and gas (O&G) emission sources using ground‐based in situ measurements in 2020/2021. During these campaigns, we observed a stable coal vent C 2 H 6 :CH 4 ratio of 1.28% ± 0.11%, discernibly different than nearby O&G source ratios ranging from 0.9% to 16.8%. We analyze airborne observations of the SJB taken in 2014/2015 that exhibit similar coal vent ratios and further show the region's heterogeneity. We identify episodic O&G sources, including a gas plant source detected in 2014/2015 that is absent in our 2020/2021 data. We examine total column observations of C 2 H 6 and CH 4 made in 2013 with a solar spectrometer and find a C 2 H 6 :CH 4 ratio of 1.3% ± 0.4% for the coal vent. The stable and unique coal vent ratio relative to other O&G sources in the region is used to demonstrate that consistent attribution is possible using various measurement methods at multiple scales across many years. Finally, we demonstrate that using C 2 H 6 as a proxy for fossil CH 4 inversions can inform detailed basin‐scale inversions, provided we understand source specific changes in the C 2 H 6 :CH 4 ratio like we report in the SJB.

54 ENVIRONMENTAL SCIENCES↗

Spectral Hardness of X- and Gamma-Ray Emissions From Lightning Stepped and Dart Leaders

During the 2022 New Mexico monsoon season, we deployed two X-ray scintillation detectors, coupled with a 180 MHz data acquisition system to detect X-rays from natural lightning at the Langmuir Lab mountain-top facility, located at 3.3 km above mean sea level. Data acquisition was triggered by an electric field antenna calibrated to pick up lightning within a few km of the X-ray detectors. We report the energies of over 240 individual photons, ranging between 13 keV and 3.8 MeV, as registered by the LaBr3(Ce) scintillation detector. These detections were associated with four lightning flashes. Particularly, four-stepped leaders and seven dart leaders produced energetic radiation. Importantly, the reported photon energies allowed us to confirm that the X-ray energy distribution of natural stepped and dart leaders follows a power-law distribution with an exponent ranging between 1.09 and 1.96, with stepped leaders having a harder spectrum. Characterization of the associated leaders and return strokes was done with four different electric field sensing antennas, which can measure a wide range of time scales, from the static storm field to the fast change associated with dart leaders.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Terrestrial Gamma‐Ray Flash Following Intense Negative Return Stroke Observed With BIMAP‐3D

We report ground-based observations of a terrestrial gamma-ray flash (TGF) associated with a strong negative cloud-to-ground lightning strike (-CG) which occurred near Los Alamos National Laboratory (LANL) in New Mexico, USA. Gamma photons were detected by the Terrestrial High-energy Observations of Radiation (THOR) instrument, developed at the University of California, Santa Cruz, which has been hosted at LANL since 2022. Simultaneous measurements were also made with the 3-Dimensional Broadband Interferometric Mapping and Polarization (BIMAP-3D) system, which includes 3D lightning mapping, two fast antennas, and an additional plastic scintillator. Additional field change waveforms were obtained from the Earth Networks Total Lightning Network (ENTLN). The lightning initiated about 1 km above the ground, leading to a powerful -CG with an ENTLN peak current of −237 kA and bipolar field change matching the recently described “energetic compact stroke” (ECS) shape. The TGF was then observed ∼35 µs after the start of the return stroke. We also observe an electric field pulse likely produced by the TGF either in isolation or by coupling to the lightning channel. Based on modeling of the radiated electric field and photon propagation through the atmosphere we infer that the TGF source was on the order of 1⁢0 17 photons. This TGF and associated lightning are extremely similar to some recently reported ECS TGFs in coastal Japan in winter, but we report the first observation of this phenomenon outside of Japan in a different climate, terrain, and season.

58 GEOSCIENCES↗

Morphology and mixing state of individual freshly emitted wildfire carbonaceous particles

Biomass burning is one of the largest sources of carbonaceous aerosols in the atmosphere, significantly affecting earth’s radiation budget and climate. Tar balls, abundant in biomass burning smoke, absorb sunlight and have highly variable optical properties, typically not accounted for in climate models. Here we analyse single biomass burning particles from the Las Conchas fire (New Mexico, 2011) using electron microscopy. We show that the relative abundance of tar balls (80%) is 10 times greater than soot particles (8%). We also report two distinct types of tar balls; one less oxidized than the other. Furthermore, the mixing of soot particles with other material affects their optical, chemical and physical properties. We quantify the morphology of soot particles and classify them into four categories: B50% are embedded (heavily coated), B34% are partly coated, B12% have inclusions andB4% are bare. Inclusion of these observations should improve climate model performances.

09 BIOMASS FUELS↗

Duration of super-emitting oil and gas methane sources

The duration of super-emitting events (>100 kg h -1 ) in oil and gas basins remains insufficiently understood but is key for reporting programs and mitigation strategies. Carbon Mapper conducted aerial surveys from April 30 to May 17, 2024, over the New Mexico Permian Basin, covering 276,000 wells, 1100 compressor stations, 175 gas processing plants, and 27,000 km of pipeline. We find over 500 super-emitting sources with 300 of these sources observed repeatedly across multiple days. We quantify total super emissions by integrating individual events with observationally constrained event durations (5.98 −14.7 Gg CH 4 ) and compare to total emissions derived from basin average snapshots (12.7 ± 0.92 Gg CH 4 ). This gap between emission estimates is reconciled through assumptions on missed detections, characteristic event duration, detection frequency, and diurnal variability. Emission events generally lasted for at least 2 hours, and a small subset of sources (18 total), persistently emitted throughout the entire campaign, representing a near-term opportunity for mitigation. When compared to regional flux estimates derived from independent observations, we estimate super-emitters to contribute approximately 50% (37-73%) towards total emissions. Frequent wide-area monitoring is crucial for capturing rare super-emitter events that, together with other emission sources, drive basin-level variability and emission intensity.

Cusworth, Daniel H. [Carbon Mapper, Pasadena, CA (↗

Global Disease Outbreaks Associated with the 2015–2016 El Niño Event

Interannual climate variability patterns associated with the El Niño-Southern Oscillation phenomenon result in climate and environmental anomaly conditions in specific regions worldwide that directly favor outbreaks and/or amplification of variety of diseases of public health concern including chikungunya, hantavirus, Rift Valley fever, cholera, plague, and Zika. We analyzed patterns of some disease outbreaks during the strong 2015–2016 El Niño event in relation to climate anomalies derived from satellite measurements. Disease outbreaks in multiple El Niño-connected regions worldwide (including Southeast Asia, Tanzania, western US, and Brazil) followed shifts in rainfall, temperature, and vegetation in which both drought and fooding occurred in excess (14–81% precipitation departures from normal). These shifts favored ecological conditions appropriate for pathogens and their vectors to emerge and propagate clusters of diseases activity in these regions. Our analysis indicates that intensity of disease activity in some ENSO-teleconnected regions were approximately 2.5–28% higher during years with El Niño events than those without. Plague in Colorado and New Mexico as well as cholera in Tanzania were significantly associated with above normal rainfall (p<0.05); while dengue in Brazil and southeast Asia were significantly associated with above normal land surface temperature (p<0.05). Routine and ongoing global satellite monitoring of key climate variable anomalies calibrated to specific regions could identify regions at risk for emergence and propagation of disease vectors. Such information can provide sufficient lead-time for outbreak prevention and potentially reduce the burden and spread of ecologically coupled diseases.

54 ENVIRONMENTAL SCIENCES↗

Daily Satellite Observations of Methane from Oil and Gas Production Regions in the United States

Production of oil and natural gas in North America is at an all-time high due to the development and use of horizontal drilling and hydraulic fracturing. Methane emissions associated with this industrial activity are a concern because of the contribution to climate radiative forcing. We present new measurements from the space-based TROPOspheric Monitoring Instrument (TROPOMI) launched in 2017 that show methane enhancements over production regions in the United States. In the Uintah Basin in Utah, TROPOMI methane columns correlated with in-situ measurements, and the highest columns were observed over the deepest parts of the basin, consistent with the accumulation of emissions underneath inversions. In the Permian Basin in Texas and New Mexico, methane columns showed maxima over regions with the highest natural gas production and were correlated with nitrogen-dioxide columns at a ratio that is consistent with results from in-situ airborne measurements. The improved detail provided by TROPOMI will likely enable the timely monitoring from space of methane emissions associated with oil and natural gas production.

54 ENVIRONMENTAL SCIENCES↗

Estimation of the orientation of stress in the Earth’s crust without earthquake or borehole data

Abstract Mechanical stress acting in the Earth’s crust is a fundamental property that is important for a wide range of scientific and engineering applications. The orientation of maximum horizontal compressive stress can be estimated by inverting earthquake source mechanisms and measured directly from borehole-based measurements, but large regions of the continents have few or no observations. Here we present an approach to determine the orientation of maximum horizontal compressive stress by measuring stress-induced anisotropy of nonlinear susceptibility, which is the derivative of elastic modulus with respect to strain. Laboratory and Earth experiments show that nonlinear susceptibility is azimuthally dependent in an anisotropic stress field and is maximum in the orientation of maximum horizontal compressive stress. We observe this behavior in the Earth—in Oklahoma and New Mexico, U.S.A, where maximum nonlinear susceptibility coincides with the orientation of maximum horizontal compressive stress measured using traditional methods. Our measurements use empirical Green’s functions and solid-earth tides and can be applied at different temporal and spatial scales.

58 GEOSCIENCES↗

Experimental evidence for the impact of soil viruses on carbon cycling during surface plant litter decomposition

To date, the potential impact of viral communities on biogeochemical cycles in soil has largely been inferred from correlational evidence, such as virus-driven changes in microbial abundances, viral auxiliary metabolic genes, and links with soil physiochemical properties. To more directly test the impact of soil viruses on carbon cycling during plant litter decomposition, we added concentrated viral community suspensions to complex litter decomposer communities in 40-day microcosm experiments. Microbial communities from two New Mexico alpine soils, Pajarito (PJ) and Santa Fe (SF), were inoculated onto grass litter on sand, and three treatments were applied in triplicate to each set of microcosms: addition of buffer (no added virus), live virus (+virus), or killed-virus (+killed-virus) fractions extracted from the same soil. Significant differences in respiration were observed between the +virus and +killed-virus treatments in the PJ, but not the SF microcosms. Bacterial and fungal community composition differed significantly by treatment in both PJ and SF microcosms. Combining data across both soils, viral addition altered links between bacterial and fungal diversity, dissolved organic carbon and total nitrogen. Overall, we demonstrate that increasing viral pressure in complex microbial communities can impact terrestrial biogeochemical cycling but is context-dependent.

54 ENVIRONMENTAL SCIENCES↗