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At least 847 records · Page 47

Erratum to: Impacts of rising air temperatures and emissions mitigation on electricity demand and supply in the United States: a multi-model comparison

The electric power sector both affects and is affected by climate change. Numerous studies highlight the potential of the power sector to reduce greenhouse gas emissions. Yet fewer studies have explored the physical impacts of climate change on the power sector. The present analysis examines how projected rising temperatures affect the demand for and supply of electricity. We apply a common set of temperature projections to three well-known electric sector models in the United States: the US version of the Global Change Assessment Model (GCAM-USA), the Regional Electricity Deployment System model (ReEDS), and the Integrated Planning Model (IPM®). Incorporating the effects of rising temperatures from a control scenario without emission mitigation into the models raises electricity demand by 1.6 to 6.5 % in 2050 with similar changes in emissions. The increase in system costs in the reference scenario to meet this additional demand is comparable to the change in system costs associated with decreasing power sector emissions by approximately 50 % in 2050. This result underscores the importance of adequately incorporating the effects of long-run temperature change in climate policy analysis.

McFarland, James↗

Negative emissions and international climate goals—learning from and about mitigation scenarios

For aiming to keep global warming well-below 2 °C and pursue efforts to limit it to 1.5 °C, as set out in the Paris Agreement, a full-fledged assessment of negative emission technologies (NETs) that remove carbon dioxide from the atmosphere is crucial to inform science-based policy making. With the Paris Agreement in mind, we re-analyse available scenario evidence to understand the roles of NETs in 1.5 °C and 2 °C scenarios and, for the first time, link this to a systematic review of findings in the underlying literature. In line with previous research, we find that keeping warming below 1.5 °C requires a rapid large-scale deployment of NETs, while for 2 °C, we can still limit NET deployment substantially by ratcheting up near-term mitigation ambition. Most recent evidence stresses the importance of future socio-economic conditions in determining the flexibility of NET deployment and suggests opportunities for hedging technology risks by adopting portfolios of NETs. Importantly, our thematic review highlights that there is a much richer set of findings on NETs than commonly reflected upon both in scientific assessments and available reviews. In particular, beyond the common findings on NETs underpinned by dozens of studies around early scale-up, the changing shape of net emission pathways or greater flexibility in the timing of climate policies, there is a suite of “niche and emerging findings”, e.g. around innovation needs and rapid technological change, termination of NETs at the end of the twenty-first century or the impacts of climate change on the effectiveness of NETs that have not been widely appreciated. Future research needs to explore the role of climate damages on NET uptake, better understand the geophysical constraints of NET deployment (e.g. water, geological storage, climate feedbacks), and provide a more systematic assessment of NET portfolios in the context of sustainable development goals.

54 ENVIRONMENTAL SCIENCES↗

Impact of methane and black carbon mitigation on forcing and temperature: a multi-model scenario analysis

The relatively short atmospheric lifetimes of methane (CH 4 ) and black carbon (BC) have focused attention on the potential for reducing anthropogenic climate change by reducing Short-Lived Climate Forcer (SLCF) emissions. This paper examines radiative forcing and global mean temperature results from the Energy Modeling Forum (EMF)-30 multi-model suite of scenarios addressing CH 4 and BC mitigation, the two major short-lived climate forcers. Central estimates of temperature reductions in 2040 from an idealized scenario focused on reductions in methane and black carbon emissions ranged from 0.18–0.26 °C across the nine participating models. Reductions in methane emissions drive 60% or more of these temperature reductions by 2040, although the methane impact also depends on auxiliary reductions that depend on the economic structure of the model. Climate model parameter uncertainty has a large impact on results, with SLCF reductions resulting in as much as 0.3–0.7 °C by 2040. We find that the substantial overlap between a SLCF-focused policy and a stringent and comprehensive climate policy that reduces greenhouse gas emissions means that additional SLCF emission reductions result in, at most, a small additional benefit of ~ 0.1 °C in the 2030–2040 time frame.

54 ENVIRONMENTAL SCIENCES↗

Radiation Damage and Mitigation by Minority Carrier Injection in InAsSb/AlAsSb Heterojunction Barrier Mid-Wave Infrared Detector

Here, the effects of gamma and proton irradiation, and of forward bias minority carrier injection, on photo-response were investigated for InAsSb/AlAsSb pBn mid-wave infrared (MWIR) detectors with an engineered majority-carrier barrier. Room-temperature gamma irradiation had an insignificant effect on 77 K photo-response. Gamma irradiation at 77 K detector temperature, however, decreased in situ photo-response by 19% after a cumulative dose of ~ 500 krad(Si). Subsequent forward bias minority carrier injection had no effect on photo-response. The 77 K detectors irradiated with 30 MeV protons up to 2 Mrad(Si) had photo-response degraded by up to 70%, but here forward bias minority carrier (hole) injection caused up to 12% recovery that persisted more than 30 min. These results suggest a mitigation strategy for maintaining the photo-response of similar detectors in radiation environments that cause displacement damage defects.

36 MATERIALS SCIENCE↗

Error-mitigated data-driven circuit learning on noisy quantum hardware

Application-level benchmarks measure how well a quantum device performs meaningful calculations. In the case of parameterized circuit training, the computational task is the preparation of a target quantum state via optimization over a loss landscape. This is complicated by various sources of noise, fixed hardware connectivity, and generative modeling, the choice of target distribution. Gradient-based training has become a useful benchmarking task for noisy intermediate-scale quantum computers because of the additional requirement that the optimization step uses the quantum device to estimate the loss function gradient. In this work, we use gradient-based data-driven circuit learning to qualitatively evaluate the performance of several superconducting platform devices and present results that show how error mitigation can improve the training of quantum circuit Born machines with 28 tunable parameters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Name that tune: Mitigation of driver fatigue via a song naming game

Fatigued driving contributes to a substantial number of motor vehicle accidents each year. Music listening is often employed as a countermeasure during driving in order to mitigate the effects of fatigue. And though music listening has been established as a distractor in the sense that it increases cognitive load during driving, it is possible that increased cognitive load is desirable under particular circumstances. For instance, during situations that typically result in cognitive underload, such as driving in a low-traffic monotonous stretch of highway, it may be beneficial for cognitive load to increase, thereby necessitating allocation of greater cognitive resources to the task of driving and attenuating fatigue. Here, we employed a song-naming game as a countermeasure to fatigued driving in a simulated monotonous environment. During the first driving session, we established that driving performance deteriorates in the absence of an intervention following 30 min of simulated driving. During the second session, we found that a song-naming game employed at the point of fatigue onset was an effective countermeasure, as reflected by simulated driving performance that met or exceeded fresh driving behavior and was significantly better relative to fatigued performance during the first driving session.

60 APPLIED LIFE SCIENCES↗

Control methods for mitigating flow oscillations in a supercritical CO 2 recompression closed Brayton cycle

A dynamic model of a 10 MWe supercritical CO 2 (sCO 2 ) recompression closed Brayton power generation cycle is used to investigate control methods for mitigating oscillations in flow conditions and power demand load, especially as the load ramp rate is increased and the load setpoint is more closely tracked. The focus is on control of the main compressor inlet temperature (MCIT) since oscillations are prompted by the strong nonlinearities in sCO 2 fluid properties near the critical point and by changes in system inventory for efficient load management. In this study, the oscillatory behavior during load ramping is first shown and then two potential control solutions for substantially reducing oscillations are given: 1) the use of the main compressor inlet guide vanes (IGV) and 2) bypassing a portion of the sCO 2 around the cooler to maintain the MCIT. These control methods reduce the effect of cycle feedback from interactions between the MCIT and load. When implementing either control method, a load setpoint ramp of 7.5%/min was maintainable while achieving closer load setpoint tracking with limited oscillations. Finally, the impact of sensor noise on the control was examined since derivative action was used in the IGV and cooler sCO 2 bypass control. Finally, while some effect was evident, signal noise was not problematic to the control.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Puerarin protects against heart failure induced by pressure overload through mitigation of ferroptosis

Highlights: • Ferroptosis is involved in the loss of myocytes during heart failure. • Puerarin exerted protective effects against heart failure through inhibition of ferroptosis. • Regulation of Nox4 signaling might be involved in puerarin inhibiting ferroptosis. Heart failure (HF) is the end stage of cardiovascular disease and is characterized by the loss of myocytes caused by cell death. Puerarin has been found to improve HF clinically, and animal study findings have confirmed its anti-cell-death properties. However, the underlying mechanisms remain unclear, especially with respect to the impact on ferroptosis, a newly defined mechanism of iron-dependent non-apoptotic cell death in HF. Here, ferroptosis-like cell death was observed in erastin- or isoprenaline (ISO)-treated H9c2 myocytes in vitro and in rats with aortic banding inducing HF, characterized by reduced cell viability with increased lipid peroxidation and labile iron pool. Interestingly, the increased iron overload and lipid peroxidation observed in either rats with HF or H9c2 cells incubated with ISO were significantly blocked by puerarin administration. These results provide compelling evidence that puerarin plays a role in inhibiting myocyte loss during HF, partly through ferroptosis mitigation, suggesting a new mechanism of puerarin as a potential therapy for HF.

60 APPLIED LIFE SCIENCES↗

Mitigation of chromosome loss in clinical CRISPR-Cas9-engineered T cells

CRISPR-Cas9 genome editing has enabled advanced T cell therapies, but occasional loss of the targeted chromosome remains a safety concern. To investigate whether Cas9-induced chromosome loss is a universal phenomenon and evaluate its clinical significance, we conducted a systematic analysis in primary human T cells. Arrayed and pooled CRISPR screens revealed that chromosome loss was generalizable across the genome and resulted in partial and entire loss of the targeted chromosome, including in preclinical chimeric antigen receptor T cells. T cells with chromosome loss persisted for weeks in culture, implying the potential to interfere with clinical use. A modified cell manufacturing process, employed in our first-in-human clinical trial of Cas9-engineered T cells (NCT03399448), reduced chromosome loss while largely preserving genome editing efficacy. Expression of p53 correlated with protection from chromosome loss observed in this protocol, suggesting both a mechanism and strategy for T cell engineering that mitigates this genotoxicity in the clinic.

59 BASIC BIOLOGICAL SCIENCES↗

Self-healing, re-adhering, and carbon-steel corrosion mitigating properties of fly ash-containing calcium aluminum phosphate cement composite at 300 °C hydrothermal temperature

This study assesses here the ability of calcium aluminate phosphate (CAP)/fly ash F (FAF) blend composite to self-heal at early age; to re-adhere to the casing surfaces after debonding and to protect carbon steel (CS) against brine-caused corrosion before and after the re-adherence. The composite was damaged after autoclaving for 24 h at 300 °C and then exposed to the same conditions for 5 more days for the self-healing and re-adhering processes. The ability of the blend to self-heal and re-adhere to CS was evaluated 1) by measurements of the recovery of compressive and bond strengths and Young's modulus; 2) by performing the 3-dimensional micro-image analysis of sealed cracks; 3) by phase identification in composite matrix and in the cracks after the healing; 4) by measurements of CS corrosion impediment by the re-adhered composite after 300°C-5-day restoration period. After the healing, the two factors, sealing effect of cracks by reaction products and change in phase composition of cement matrix, essentially governed the recovery of the original mechanical strength. For the former, analcime phase derived from pozzolanic FAF autogenous healing aid played the major role in sealing the cracks, while the well-formed hydroxyapatite phase contributed to the latter factor. The lap-shear bond with the strength of 1.11 MPa at CS plate/composite adhesive/CS plate joint failed cohesively, showing higher bond strength than strength of the composite matrix. The rebonded composite-CS plates developed a 0.37 MPa bond strength after the 5-day restoration period. The results of electrochemical polarization corrosion tests revealed that the re-adhered composite covering CS plate significantly inhibited the brine-caused corrosion of CS, leading to 0.011 mm/year corrosion rate, corresponding to 50% reduction compared with that of before re-adhering. There were two factors governing such corrosion mitigation: enhanced adhesive contact of composite with CS and increased coverage by the re-adhering composite.

36 MATERIALS SCIENCE↗

Modifying the pore size distribution in Fe-rich inorganic polymer mortars: An effective shrinkage mitigation strategy

Highlights: • Inorganic polymer mortar has mainly macropores and a drying shrinkage of 5.1 mm/m. • 2-methyl-2,4-pentanediol acts as air entrainer in inorganic polymer mortars. • Optimal dosage 2 wt% 2-methyl-2,4-pentanediol reduced drying shrinkage to 1.8 mm/m. • Heat curing inorganic polymer mortars reduced drying shrinkage more than 50%. • Blast Furnace slag addition increased drying shrinkage and reduced strength. Inorganic polymer (IP) binder is formed upon alkali-activation of Fe-rich (41 wt%) metallurgical slag leading to materials with mechanical properties comparable to ordinary Portland cement binders. Crack formation is reported in IPs, which can be related to volumetric stability, which is to date not thoroughly understood in IPs. This study determined the autogenous and drying shrinkage of IP mortars. Shrinkage mitigation strategies, such as the addition of 2-methyl-2,4-pentanediol (2MPL), blast furnace slag (GGBFS), and applying heat curing, were used separately or in combination. IP mortars exhibited autogenous expansion and high drying shrinkage. The addition of 2MPL led to a porosity increase, as air was entrained, decreasing the drying shrinkage with 64%. Additional heat curing had no effect on samples with 2MPL. Introducing GGBFS resulted in smaller pores, increasing drying shrinkage. Shrinkage in IP mortars is driven by its pore size distribution and higher shrinkage resulted in lower flexural strength.

36 MATERIALS SCIENCE↗

Efficiency of natural pozzolans, ground glasses and coal bottom ashes in mitigating sulfate attack and alkali-silica reaction

The use of pozzolans to partially replace Portland cement in concrete has generally demonstrated beneficial impacts on the durability characteristics of concrete for decades. In this paper a diverse range of pozzolans including natural pozzolans, ground glasses and industrial by-products such as coal ash (fly ash and bottom ash) and silica fume were investigated for their synergistic potential in binary or ternary blends with Portland cement in improving resistance to chemical sulfate attack and alkali-silica reaction (ASR). It is generally considered that pozzolans improve most of the durability issues encountered in concrete, including reducing the risk of sulfate attack or ASR. But this is not always the case. For example, it was found that ground glasses were very efficient in improving sulfate resistance, but their ability to mitigate expansion due to ASR was dictated by the equivalent alkalis content (Na{sub 2}O{sub e}) of the glass and high-alkali soda glass was generally not effective in this role. On the other hand, metakaolin, a highly reactive pozzolan, was highly effective in reducing ASR expansion, but may actually increase the damage due to sulfate attack when used at moderate replacement levels. Most pozzolans, such as low-CaO coal fly ash and ground coal bottom ash, silica fume, and pumice, were effective in controlling expansion due to both ASR and sulfate attack. The results demonstrated that the extent of the positive impact of using natural pozzolans on both properties was variable. The pozzolanic reactivity of materials alone was an unreliable indicator to assess the ability of the pozzolan to suppress expansion due to sulfate attack or ASR.

36 MATERIALS SCIENCE↗

Understanding and mitigating degradation in amine-based sorbents for CO 2 direct air capture

The success of direct air capture (DAC) of CO 2 depends on sorbents that combine high capacity, low energy requirements, and long-term durability. Amine-based sorbents-including solid-supported aminopolymers, grafted amines, and amine-functionalized resins-remain the leading candidates, but their limited lifetimes drive up costs and constrain deployment. In this review, we outline the current understanding of amine-based sorbent degradation with an emphasis on clearly identifying what is known about structure-property-performance relationships, as well as important knowledge gaps. More specifically, we discuss how polymer chemistry, sorbent design variables, and environmental and process conditions contribute to performance loss. In parallel, we outline how advances in spectroscopy, modeling, and accelerated testing are beginning to illuminate chemical and physical degradation mechanisms. Looking forward, we identify future research directions that will be critical for gaining a deeper understanding of degradation, as well as opportunities for developing innovative mitigation strategies for improving the lifetime of amine-based sorbents.

organic↗

Redox potential control in molten salt systems for corrosion mitigation

In a molten salt nuclear reactor system, the redox potential must be controlled for mitigating corrosion of structural materials. The paper presented a critical review on the available knowledge of redox potential control in molten fluoride salt systems. The major potential contaminants that affect the redox potential and material corrosion are TF, oxides, hydroxides, and various metal fluorides. Redox potential control methodologies include gas sparging, contacting the salt with a reducing metal, and adding soluble salt redox buffers to the salt. Redox potential measurement technologies include electrochemical sensors and optical spectroscopy. This work also analyzed the current technology issues and recommended near future studies.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Fractal coatings of Ni and NiYSZ for high-temperature corrosion mitigation in solar salt

This paper introduces a novel approach to corrosion mitigation using electrodeposited, fractal Ni and NiYSZ coatings. Highly adherent, durable multiscale coatings with fractal dimensions above 1.80 were fabricated. Corrosion characteristics of coated plain and etched surfaces of In800H, SS310, SS316 and SS347, in comparison to Ha230, were studied in molten 60% NaNO 3 + 40% KNO 3 at 600 °C. The corrosion rate of coated Fe-based alloys reduced by up to 68% compared to uncoated alloys and was on par with or lower than the corrosion rate of Ha230. Furthermore, the corrosion-resistant coatings provide for use of low-cost alloys in high temperature corrosive environments.

36 MATERIALS SCIENCE↗

Mitigation of polysulfide shuttle effect in Li-S batteries through catalytic disproportionation reaction

Polysulfides are poorly retained within porous cathodes and readily diffuse into the electrolyte over time, leading to the well-known shuttle effect that undermines the reversibility of Li-S batteries. Here, in this study, we demonstrate that catalytic disproportionation of polysulfides provides an effective pathway to suppress this process by rapidly converting dissolved species into solid sulfur and sulfides, thereby preventing their migration into the electrolyte. Fundamentally, the sluggish kinetics of sulfur redox reactions are responsible for the accumulation and redistribution of soluble polysulfides in the bulk electrolyte. By accelerating these kinetics, catalyzed disproportionation not only confines sulfur within the conductive cathode matrix but also promotes the homogeneous precipitation of Li₂S₂/Li₂S, which enhances electrochemical reversibility and cycling stability. Using nitrogen-doped carbon (NC800) as a model catalyst, we reveal its ability to drive a pseudo-16-electron reduction pathway, leading to a single dominant Li₂S product and uniform deposition within the porous framework. In contrast, a non-catalytic carbon (KB) yields multiple polysulfide intermediates and heterogeneous deposition. The mechanistic insights provided here highlight the pivotal role of catalytic disproportionation in reshaping sulfur redox pathways and offer a rational strategy for mitigating polysulfide shuttling in practical Li-S pouch cells.

25 ENERGY STORAGE↗

Climate Mitigation in Latin America: Implications for Energy and Land Use: Preface to the Special Section on the findings of the CLIMACAP-LAMP Project

The CLIMACAP-LAMP project, completed in December 2015, was an inter-model comparison exercise that focused on energy and climate change economics issues in Latin America. The project partners – co-financed by the EC / EuropeAid (CLIMACAP part) and EPA / USAID (LAMP part) and co-coordinated by respectively the Energy research Centre of the Netherlands (ECN) and the Pacific Northwest National Laboratory (PNNL) – report their main and detailed findings in this Special Issue of Energy Economics, exclusively dedicated to climate mitigation, low-carbon development and implications for energy and land use in Latin America. Our research endeavor included several of the most prominent regional energy modeling groups from Latin America, as well as a representative set of global integrated assessment modeling groups from a number of institutions from Europe and the US. About two dozen universities, research groups and environmental or consulting organizations took part in the CLIMACAP-LAMP cross-model comparison project, from both sides of the Atlantic. Over a handful of workshops were organized over the past four years in several countries in Latin America, attended by between 30 and 50 participants from, amongst others, Argentina, Brazil, Colombia, Mexico, the EU, and the US.

54 ENVIRONMENTAL SCIENCES↗

Mitigation of rapid capacity decay in silicon-LiNi 0.6 Mn 0.2 Co 0.2 O 2 full batteries

Silicon (Si)-based materials have been considered as the most promising anode materials for high-energy-density lithium-ion batteries because of their higher storage capacity and similar operating voltage, as compared to the commercial graphite (Gr) anode. But the use of Si anodes including silicon-graphite (Si-Gr) blended anodes often leads to rapid capacity decay in Si-Gr/LiNixMnyCo z O 2 (x+y+z=1) full cells, which has been attributed to surface instability of the Si component. In addition to stabilizing the surface, this work investigates the potential of the Si-Gr blended anodes in a full-cell configuration and its impact on the capacity contribution from active components. Using dQ/dV plots of the full cells, a powerful but simple-to-implement differential potential approach is developed to decouple the capacity contribution and degradation from the graphite and silicon components. Data collected from three-electrode cells confirm the results from the differential potential approach, which suggests a voltage slippage to a higher voltage at the blended anode side. Additionally, the voltage slippage causes a reduced utilization of the Gr component and exacerbates side reactions between the Si-Gr anode and carbonate electrolytes. Furthermore, based on these failure mechanisms, we adopted a mitigation strategy to tune the open circuit voltage of the prelithiated anode while stabilizing the surface. As a result, the full cells with the modified Si-Gr anodes (mass loading, 2.5 mAh/cm 2 ) offer a highly reversible full-cell energy density of 390 Wh/kg (based on the mass of both anode and cathode materials in a full cell) with a cycling CE of 99.9% over 200 cycles.

25 ENERGY STORAGE↗