Studies of energy-relevant materials by nuclear magnetic resonance
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Polysiloxane foams utilized for stockpile applications experience changes over time induced by exposure to thermal, radiative, and mechanical stresses. The interplay of these stresses can lead to chemical and/or physical changes in the polymer, such as alterations of compression set. Understanding these mechanisms require us to understand the in-situ stress states that these polymeric foams are exposed to in the service environment.
We have measured the DCIV EDMR response before and after high field gate stressing in Si/Si0 2 MOSFETs. The g-value and orientation dependence of the stress induced EDMR response indicate that it is dominated by some combination of Pbo and Pb1 interface defects.
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Two spectrometer systems have been developed at LANL for hazardous and/or toxic chemical agent detection and forensic analysis: SpEctroscopic Detection Of Nerve Agents (SEDONA) is a portable bottle scanner; and Earth’s field Resonance Detection and Evaluation (ERDE) Devices are fieldable J-coupled Earth’s Field - NMR (EF-NMR) spectrometers.
This report discuss aging mechanisms and cycling performance of Li batteries, and considers the influence of both the passive and active materials. To achieve this aim we developed in situ coin cell and pouch cell NMR probes as well as HR-MAS NMR protocols to study cells with as a little modification as possible.
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Electron spin resonance studies of Apollo 11 and 12 lunar soil samples, determining ferromagnetism due to Fe particles
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The Al-27 nuclear quadrupolar coupling constant and asymmetry parameter (eta) in topaz have been determined to be 1.67 (plus or minus 0.03) MHz and 0.38 plus or minus 0.05, respectively. These values and the orientations of the principal axes are consistent with the Fe(3+) paramagnetic resonance data and with the symmetry of the AlO4F2 octahedron.
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