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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Mapping of hydrothermal alternation zones and regional rock types using computer enhanced ERTS MSS images

A combination of digital computer processing and color compositing of ERTS MSS images has been used to map hydrothermal alternation zones and regional rock types in south-central Nevada. The technique is based on enhancement of subtle visible and near infrared reflectivity differences between mineralogically dissimilar rocks, especially unaltered and altered rocks. MSS spectral bands are ratioed, pixel by pixel, in the computer and subsequently stretched. These ratio values are used to produce a new black and white image which shows the subtle spectral reflectivity differences. Additional enhancement is achieved by preparing color composites of two or more stretched ratio images. The choice of MSS bands for rationing depends on the spectral reflectance properties of the rocks to be discriminated. Although this technique is in the initial stage of development and is untested in other areas, it already appears to have considerable potential for targeting mineral prospects and for regional geologic mapping.

Rowan, L. C.↗
NASA NTRS1975

Remote sensing techniques for prediction of watershed runoff

Hydrologic parameters of watersheds for use in mathematical models and as design criteria for flood detention structures are sometimes difficult to quantify using conventional measuring systems. The advent of remote sensing devices developed in the past decade offers the possibility that watershed characteristics such as vegetative cover, soils, soil moisture, etc., may be quantified rapidly and economically. Experiments with visible and near infrared data from the LANDSAT-1 multispectral scanner indicate a simple technique for calibration of runoff equation coefficients is feasible. The technique was tested on 10 watersheds in the Chickasha area and test results show more accurate runoff coefficients were obtained than with conventional methods. The technique worked equally as well using a dry fall scene. The runoff equation coefficients were then predicted for 22 subwatersheds with flood detention structures. Predicted values were again more accurate than coefficients produced by conventional methods.

Blanchard, B. J.↗
DOE OSTI2026

Adsorption of hydroxamic acid ligands for improved extraction of rare earth elements from monazite ores

Efficient separation of rare earth element (REE) ores via froth flotation requires the development of novel ligands with enhanced adsorption capacity and selectivity. To realize these advances, understanding the mechanisms underlying interactions between the ligand and mineral surfaces is essential. This study systematically evaluates the adsorption behavior of alkyl- and aromatic alkyl-substituted hydroxamic acid ligands on monazite surfaces using complementary spectroscopic techniques, including UV–visible (UV–vis) spectroscopy, Raman spectroscopy, infrared spectroscopy, and vibrational sum frequency generation (SFG) spectroscopy, together with the ab initio molecular dynamics (AIMD) simulations. Among the studied ligands, octanohydroxamic acid (OHA) and 4-ethoxy-N,2-dihydroxybenzamide (EDHBA) exhibit high adsorption capacity under basic pH (8–10) by forming multilayers on the surface. OHA has a higher equilibrium adsorption capacity compared to EDHBA, but it forms a less stable multilayer susceptible to disruption in the presence of interfering ions. AIMD results show that OHA adopts a single stable chelating geometry, while EDHBA exhibits multiple binding modes involving distinct interactions with La surface atoms and phosphate-bound oxygens, resulting in more complex adsorption kinetics. The variations in surface binding and intermolecular interactions observed between alkyl and aromatic molecules influence the differences in adsorption kinetics, equilibrium adsorption capacities on the mineral surface, and their flotation performance. This work provides valuable insight into the adsorption mechanism of ligands at mineral interfaces, which is crucial for guiding the design of new ligands with enhanced separation performance.

Zhou, Muchu [ORNL] (ORCID:0000000182650215)↗
DOE OSTI2025

Thermodynamic Profiling Through ASSIST Observations and TROPoe Retrievals

This report reviews the most relevant theoretical aspects of thermodynamic profiling techniques based on spectral observations from ASSIST-II infrared radiometers and TROPoe retrievals. The ASSIST+TROPoe system is a cutting-edge remote sensing technology deployed during the AWAKEN and WFIP3 field campaigns to estimate high-frequency profiles of temperature and humidity in the atmosphere. These profiles are highly valuable for characterizing atmospheric stratification, improving wind models, and understanding the impacts of wind plants on the climate. In this document, we discuss the operating principles of ASSIST, the physics of atmospheric infrared radiation, and the mathematical framework and capabilities of TROPoe. Sources of uncertainties in both the instrument and the retrieval method are also thoroughly addressed. This guide is designed to help users of ASSIST, TROPoe, and thermodynamic data in collecting, estimating, and applying thermodynamic profiles rigorously and scientifically.

17 WIND ENERGY↗
DOE OSTI2026

Superconducting qubits for particle detection and fundamental tests of quantum mechanics

Many fundamental questions at the interface of quantum mechanics, gravity, and measurement remain relatively unexplored in the laboratory. These include whether spatial superpositions experience gravitational redshift, how the quantum Zeno effect propagates through entangled systems, and whether quantum information is globally conserved or fundamentally lost during measurement-induced wavefunction collapse. In this colloquium, I will discuss how superconducting qubits—developed primarily for quantum computing—can be repurposed as ultra sensitive detectors to probe these questions and to search for low-energy particle interactions. I will describe my work at Fermilab on stabilizing these devices to the level required for next-generation qubit-based sensors. This includes mitigating decoherence from infrared radiation and cosmic rays, using machine-learning techniques to accelerate superconducting qubit design, and leveraging the quantum Zeno effect to improve coherence times and suppress qubit frequency fluctuations. Together, these advances point toward a new class of quantum sensors capable of testing fundamental physics.

Seidel, Olivia [Fermilab]↗
DOE OSTI2020

Accelerated Snowmelt Protocol to Simulate Climate Change Induced Impacts on Snowpack Dependent Ecosystems

Field studies that simulate the effects of climate change are important for a predictive understanding of ecosystem responses to a changing environment. Among many concerns, regional warming can result in advanced timing of spring snowmelt in snowpack dependent ecosystems, which could lead to longer snow-free periods and drier summer soils. Past studies investigating these impacts of climate change have manipulated snowmelt with a variety of techniques that include manual snowpack alteration with a shovel, infrared radiation, black sand and fabric covers. Within these studies however, sufficient documentation of methods is limited, which can make experimental reproduction difficult. Here, we outline a detailed plot-scale protocol that utilizes a permeable black geotextile fabric deployed on top of an isothermal spring snowpack to induce advanced snowmelt. The method offers a reliable and cost-effective approach to induce snowmelt by passively increasing solar radiation absorption at the snow surface. In addition, control configurations with no snowpack manipulation are paired adjacent to the induced snowmelt plot for experimental comparison. Past and ongoing deployments in Colorado subalpine ecosystems indicate that this approach can accelerate snowmelt by 14-23 days, effectively mimicking snowmelt timing at lower elevations. This protocol can be applied to a variety of studies to understand the hydrological, ecological, and geochemical impacts of regional warming in snowpack dependent ecosystems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Covalent integration of polymers and porous organic frameworks

Covalent integration of polymers and porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and hydrogen-bonded organic frameworks (HOFs), represent a promising strategy for overcoming the existing limitations of traditional porous materials. This integration allows for the combination of the advantages of polymers, i.e., flexibility, processability and chemical versatility etc., and the superiority of POFs, like the structural integrity, tunable porosity and the high surface area, creating a type of hybrid materials. These resulting polymer-POF hybrid materials exhibit enhanced mechanical strength, chemical stability and functional diversity, thus opening up new opportunities for applications across a large variety of fields, such as gas separation, catalysis, biomedical applications, environmental remediation and energy storage. In this review, an overview of synthetic routes and strategies on how to covalently integrate different polymers with various POFs is discussed, especially with a particular focus on methods like polymerization within, on and among POF structures. To investigate the unique properties and functions of these resultant hybrid materials, the characterization techniques, including nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), gas adsorption analysis (BET) and computational modeling and machine learning, are also presented. The ability of polymer-POFs to manipulate the pore environments at the molecular level affords these materials a wide range of applications, providing a versatile platform for future advancements in material science. Looking forward, to fully realize the potential of these hybrid materials, the authors highlight the scalability, green synthesis methods, and potential for stimuli-responsive polymer-POF materials as critical areas for future research.

Hossain, Md Amjad↗
NASA NTRS1972

Infrared spectra of group III A metal oxides

The measurement of infrared frequencies of metal-oxygen species which could be formed in the matrix and to investigate with an oxygen-18 enrichment study the controversy on the vibrational assignments for the suboxide. Several new molecules, Al3O2, Ga3O, In3O, In4O2, IntaO, IntaO2, and In2WO4, were found by mass spectrometric sampling to exist in extremely minor concentrations in the vapor phase. The latter three species were formed by reaction with the crucible materials and were unimportant for an infrared analysis. The infrared spectroscopic measurements were obtained by the matrix isolation technique of molecular beam sampling. The MO2 species were formed by direct reaction between metal and O2 in the matrix. A C2v structure and an O-M-O bond angle near 40 deg was favored for these molecules by analogy with a similar investigation of the alkali metals. The vibrational frequencies which were determined are given.

Lynch, D. A., Jr.↗
NASA NTRS1973

A multispectral study of an extratropical cyclone with Nimbus 3 medium resolution infrared radiometer data

Four registered channels (0.2 to 4, 6.5 to 7, 10 to 11, and 20 to 23 microns) of the Nimbus 3 Medium Resolution Infrared Radiometer (MRIR) were used to study 24-hr changes in the structure of an extratropical cyclone during a 6-day period in May 1969. Use of a stereographic-horizon map projection insured that the storm was mapped with a single perspective throughout the series and allowed the convenient preparation of 24-hr difference maps of the infrared radiation fields. Single-channel and multispectral analysis techniques were employed to establish the positions and vertical slopes of jetstreams, large cloud systems, and major features of middle and upper tropospheric circulation. Use of these techniques plus the difference maps and continuity of observation allowed the early detection of secondary cyclones developing within the circulation of the primary cyclone. An automated, multispectral cloud-type identification technique was developed, and comparisons that were made with conventional ship reports and with high-resolution visual data from the image dissector camera system showed good agreement.

Holub, R.↗
NASA NTRS1973

Opportunities for space surveys of moisture anomalies

Review of a combination of infrared scanning, unsupervised spectroscopic classification, change detection, and perturbation spectroscopy for monitoring anomalous moisture exchange from space. Infrared sensors have been developed which can monitor the solar reflectance from droplet distributions in vegetation and clouds, the absorption of thermal radiation by water vapor, and the microwave attenuation by atmospheric water. Unsupervised spectroscopic classification techniques are emerging which have the potential to subdivide strip maps from infrared scanners into different moisture targets. Intersecting and parallel spacecraft orbits provide opportunities to study the change of recognized targets between two scans and to recognize anomalous moisture exchange from those changes which significantly exceed the statistical uncertainty of the spectroscopic target signature. The new concept of perturbation spectroscopy shows a potential to quantitatively determine the change of integrated water vapor pressure with a minimum of 'atmospheric truth' and with low spectroscopic resolution that is typical of simple interference filters.

Krause, F. R.↗
NASA NTRS1975

Land use analysis of US urban areas using high-resolution imagery from Skylab

The author has identified the following significant results. The S-190B imagery from Skylab 3 permitted the detection of higher levels of land use detail than any satellite imagery previously evaluated using manual interpretation techniques. Resolution approaches that of 1:100,000 scale infrared aircraft photography, especially regarding urban areas. Nonurban areas are less distinct.

Gallagher, D. B.↗
NASA NTRS1981

Modern Observational Techniques for Comets

Techniques are discussed in the following areas: astrometry, photometry, infrared observations, radio observations, spectroscopy, imaging of coma and tail, image processing of observation. The determination of the chemical composition and physical structure of comets is highlighted.

Brandt, J. C.↗
NASA NTRS1983

Rain estimation from satellites: An examination of the Griffith-Woodley technique

The Griffith-Woodley Technique (GWT) is an approach to estimating precipitation using infrared observations of clouds from geosynchronous satellites. It is examined in three ways: an analysis of the terms in the GWT equations; a case study of infrared imagery portraying convective development over Florida; and the comparison of a simplified equation set and resultant rain map to results using the GWT. The objective is to determine the dominant factors in the calculation of GWT rain estimates. Analysis of a single day's convection over Florida produced a number of significant insights into various terms in the GWT rainfall equations. Due to the definition of clouds by a threshold isotherm the majority of clouds on this day did not go through an idealized life cycle before losing their identity through merger, splitting, etc. As a result, 85% of the clouds had a defined life of 0.5 or 1 h. For these clouds the terms in the GWT which are dependent on cloud life history become essentially constant. The empirically derived ratio of radar echo area to cloud area is given a singular value (0.02) for 43% of the sample, while the rainrate term is 20.7 mmh-1 for 61% of the sample. For 55% of the sampled clouds the temperature weighting term is identically 1.0. Cloud area itself is highly correlated (r=0.88) with GWT computed rain volume. An important, discriminating parameter in the GWT is the temperature defining the coldest 10% cloud area. The analysis further shows that the two dominant parameters in rainfall estimation are the existence of cold cloud and the duration of cloud over a point.

Negri, A. J.↗
NASA NTRS1984

Rain estimation from satellites - An examination of the Griffith-Woodley Technique

The Griffith-Woodley Technique (GWT) is an approach to estimating precipitation using infrared observations of clouds from geosynchronous satellites. It is examined in three ways: an analysis of the terms in the GWT equations; a case study of infrared imagery portraying convective development over Florida; and the comparison of a simplified equation set and resultant rain map to results using the GWT. The objective is to determine the dominant factors in the calculation of GWT rain estimates. Analysis of a single day's convection over Florida produced a number of significant insights into various terms in the GWT rainfall equations. Due to the definition of clouds by a threshold isotherm the majority of clouds on this day did not go through an idealized life cycle before losing their identity through merger, splitting, etc. As a result, 85 percent of the clouds had a defined life of 0.5 or 1 h. For these clouds, the terms in the GWT which are dependent on cloud life history become essentially constant. The empirically derived ratio of radar echo area to cloud area is given a singular value (0.02) for 43 percent of the sample, while the rainrate term is 20.7 mmh-1 for 61 percent of the sample. For 55 percent of the sampled clouds, the temperature weighting term is identically 1.0. Cloud area itself is highly correlated (r = 0.88) with GWT computed rain volume. An important, discriminating parameter in the GWT is the temperature defining the coldest 10 percent cloud area. The analysis further shows that the two dominant parameters in rainfall estimation are the existence of cold cloud and the duration of cloud over a point. Previously announced in STAR as N84-13735

Negri, A. J.↗
NASA NTRS1986

Radiometric responsivity determination for Feature Identification and Location Experiment (FILE) flown on space shuttle mission

A procedure was developed to obtain the radiometric (radiance) responsivity of the Feature Identification and Local Experiment (FILE) instrument in preparation for its flight on Space Shuttle Mission 41-G (November 1984). This instrument was designed to obtain Earth feature radiance data in spectral bands centered at 0.65 and 0.85 microns, along with corroborative color and color-infrared photographs, and to collect data to evaluate a technique for in-orbit autonomous classification of the Earth's primary features. The calibration process incorporated both solar radiance measurements and radiative transfer model predictions in estimating expected radiance inputs to the FILE on the Shuttle. The measured data are compared with the model predictions, and the differences observed are discussed. Application of the calibration procedure to the FILE over an 18-month period indicated a constant responsivity characteristic. This report documents the calibration procedure and the associated radiometric measurements and predictions that were part of the instrument preparation for flight.

Wilson, R. G.↗
NASA NTRS1987

Far-infrared detection of a circumstellar dust torus around Sharpless 106

High angular resolution scans at 42 and 95 microns have been obtained of the far-infrared source associated with S106. Using maximum entropy deconvolution techniques it is found that the far-IR-emitting dust appears to be distributed in a toroidal shape around the central star.This result is similar to the morphology implied to millimeter line and continuum mapping on a variety of size scales.

Harvey, Paul M.↗
NASA NTRS1987

Cellular solidification in a monotectic system

Succinonitrile-glycerol, SN-G, transparent organic monotectic alloy is studied with particular attention to cellular growth. The phase diagram is determined, near the monotectic composition, with greater accuracy than previous studies. A solidification interface stability diagram is determined for planar growth. The planar-to-cellular transition is compared to predictions from the Burton, Primm, Schlichter theory. A new technique to determine the solute segregation by Fourier transform infrared spectroscopy is developed. Proposed models that involve the cellular interface for alignment of monotectic second-phase spheres or rods are compared with observations.

Kaukler, W. F.↗
NASA NTRS1989

Solar sensor subsystems alignment check using solar scans for the Halogen Occultation Experiment

The alignment of a dual-axes sun sensor subsystem to a telescope having a multiple sensor subsystem is described. The sun sensor consists of two analog and one digital silicon detectors. The analog detectors are shadow mask type operating in the visible spectrum. The detectors are mounted for azimuth and elevation positioning of biaxial gimbals. The digital detector is a linear diode array that operates at a spectral position of 0.7 micron and is used for elevation positioning. The position signals correspond to relative angles between the sun sensor and the solar disk. These three detectors are aligned on an Invar structure which is mounted to a Cassegrain telescope. This telescope relays solar radiance to an eight channel detector subsystem operating in the infrared range from 2 to 10 microns. The test technique and results to check the boresight alignment of these two subsystems by scanning the solar disk will be reported. The boresight alignment for both the azimuth and elevation axes of the two detector subsystems is verified using this technique.

Jurczyk, S. G.↗