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Data was obtained from the UVI imager, ground based magnetometers, incoherent scatter radars, HF radars (SuperDarn), DMSP satellites, and NOAA TIROS satellites. The data from these sources have been integrated into a consistent description of the ionosphere, using the AMIE technique.
In January and March 1992, DC-8-measured stratospheric particle optical depth spectra, (tau)(sub p)(lambda), peaked broadly at midvisible or longer wavelengths. At mid-to-high northern latitudes outside the vortex, tau(sub p)(526 microns) above about 11 km was as large as 0.22 in both January and March, reflecting continued Pinatubo volcanic influence. In both months, in-vortex tau(sub p) above 11 km was smaller than outside-vortex values by a factor of two or more, and in January a strong anticorrelation was observed between tau(sub p)(lambda) and HF column content (an indicator of vortex penetration). In late January at 18-20S, near the edge of the southern subtropical jet, tau(sub p)(526 microns) above 12 km was only about 0.07- 0.09, with a flatter spectral shape than northern mid-to high-latitude measurements in both January and March. Occasional high-latitude vertical profiles indicate 6-1 km slab optical depths, delta(tau)(sub p)(526 micron), of 0.05 to 0.1, which should be added to the above-11-km values to yield values above 6 km.
The recent ban on the production of bromotrifluoromethane (CF3Br) because of its high stratospheric ozone depletion potential has led to interest in finding alternative agents for fire extinguishing applications. Some of the promising alternatives are fluorinated hydrocarbons. A clear understanding of the effects of CF3Br and alternative chemical suppressants on diffusion flames is therefore necessary in the selection of alternative suppressants for use in normal and microgravity. The flame inhibition effects of halogen compounds have been studied extensively in premixed systems. The effect of addition of halocarbons (carbon-halogen compounds) to diffusion flames has been studied experimentally in coflow configurations and in counterflow gaseous and liquid-pool flames. Halogenated compounds are believed to inhibit combustion by scavenging hydrogen radicals to form the relatively unreactive compound HF, or through a catalytic recombination cycle involving HBr to form H2. Comparisons between halogens show that bromine inhibition is significantly more effective than chlorine or fluorine. Although fluorinated compounds are only slightly more effective inhibitors on a mass basis than nitrogen, they are more effective on a volume basis and are easily stored in liquid form. The objectives of this study are (a) to determine the stability limits of laminar jet diffusion flames with respect to inhibitor concentration in both normal and microgravity, and (b) to investigate the structure of halocarbon-inhibited flames. In the initial phase of this project, visual diagnostics were used to observe the structure and behavior of normal and microgravity flames. The initial observations showed significant changes in the structure of the flames with the addition of halocarbons to the surrounding environment, as discussed below. Furthermore, the study established that the flames are more stable relative to the addition of halocarbons in microgravity than in normal gravity. Visual diagnostics of flames are, however, necessarily limited to detection of radiative emission in the visible range, and offer only qualitative information about the nature of the processes in the flame. In particular, the study sought to understand the structure of the inhibitor-perturbed flames with regard to temperature and species concentration in the outer region of the flame. Whereas thermocouple measurements can be used in ground based studies, their implementation in drop-tower rigs is limited. A possible approach to determine the temperature field around the flame is to use interferometric techniques. The implementation and testing of a shear-plate interferometry technique is described below.
The Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument is a high resolution Fourier transform spectrometer that measures atmospheric composition from low Earth orbit with infrared solar occultation sounding in the limb geometry. Following an initial flight in 1985, ATMOS participated in the Atmospheric Laboratory for Applications and Science (ATLAS) 1, 2, and 3 Space Shuttle missions in 1992, 1993, and 1994 yielding a total of 440 occultation measurements over a nine year period. The suite of more than thirty atmospheric trace gases profiled includes CO2, O3, N2O, CH4, H2O, NO, NO2, HNO3, HCl, HF, ClONO2, CCl3F, CCl2F2, CHF2Cl, and N2O5. The analysis method has been revised throughout the mission years culminating in the 'version 2' data set. The spectroscopic error analysis is described in the context of supporting the precision estimates reported with the profiles; in addition, systematic uncertainties assessed from the quality of the spectroscopic database are described and tabulated for comparisons with other experiments.
Measurements of the long-lived tracers CH4, N2O, and HF from the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument during the Atmospheric Laboratory for Science and Applications-2 (ATLAS-2) Space Shuttle mission in April 1993 are used to infer average winter descent rates ranging from 0.8 km/month at 20 km to 3.2 km/month at 40 km in the Arctic polar vortex during the 1992-93 winter. Descent rates in the mid-stratosphere are similar to those deduced for the Antarctic vortex using ATMOS/ATLAS-3 measurements in November 1994, but the shorter time period of descent in the Arctic leads to smaller total distances of descent. Strong horizontal gradients observed along the vortex edge indicate that the Arctic vortex remains a significant barrier to transport at least until mid-April in the lower to middle stratosphere.
Observations of the long-lived tracers N2O, CH4 and HF obtained by the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument in early November 1994 are used to estimate average descent rates during winter in the Antarctic polar vortex of 0.5 to 1.5 km/month in the lower stratosphere, and 2.5 to 3.5 km/month in the middle and upper stratosphere. Descent rates inferred from ATMOS tracer observations agree well with theoretical estimates obtained using radiative heating calculations. Air of mesospheric origin (N2O less than 5 ppbV) was observed at altitudes above about 25 km within the vortex. Strong horizontal gradients of tracer mixing ratios, the presence of mesospheric air in the vortex in early spring, and the variation with altitude of inferred descent rates indicate that the Antarctic vortex is highly isolated from midlatitudes throughout the winter from approximately 20 km to the stratopause. The 1994 Antarctic vortex remained well isolated between 20 and 30 km through at least mid-November.
Everyday, international broadcasters, ships, and aircraft use a naturally conducting atmospheric layer, the ionosphere, to reflect communications signals over the Earth's horizon. A better understanding of this layer, with its irregularities, instabilities, and dynamics, would improve communications transmission and reception. This atmospheric layer is also a lens that can distort signal transmissions from communications, navigation, and surveillance satellites. The ionosphere over Canada and other high latitude countries can carry large currents and is particularly dynamic, so that a scientific understanding of this layer is critical. The BOLAS (Bistatic Observations using Low Altitude Satellites) mission would characterize reflective and transmissive properties of the ionosphere by flying two satellites, each with identical HF receivers, dipole antennas, particle probes, and GPS receivers. The satellites would be connected by a non-conducting tether to maintain a 100 m separation, and would cartwheel in the orbit plane to spatially survey the ionosphere. The six-month mission would fly in a high inclination, 350 x 600 km orbit, and would be active during passes over the auroral region of Canada. This paper discusses the system requirements and architecture, spacecraft and operations concepts, and mission design, as well as team organization, international cooperation and the scientific and technological benefits that are expected.
In January and March 1992, DC-8-measured stratospheric particle optical depth spectra, tau(sub p)(lambda), peaked broadly at midvisible or longer wavelengths. At mid-to-high northern latitudes outside the vortex, tau(sub p)(526 nm) nm) above about 11 km was as large as 0.22 in both January and March, reflecting continued Pinatubo volcanic influence. In both months, in-vortex tau(sub p)(lambda) above 11 km was smaller than outside-vortex values by a factor of two or more, and in January a strong anticorrelation was observed between tau(sub p)(lambda) and HF column content (an indicator of vortex penetration). In late January at 18-20S, near the edge of the southern subtropical jet, tau(sub p)(526 nm) above 12 km was only about 0.07-0.09, with a flatter spectral shape than northern mid- to high-latitude measurements in both January and March. Occasional high-latitude vertical profiles indicate 6-11-km slab optical depths, Delta tau(sub p)(526 nm), of 0.05 to 0.1, which should be added to the above-11-km values to yield values above 6 km.
This work examines measurements of ozone, NO, NO2, and HCl made by the Halogen Occultation Experiment (HALOE) to track chemical change in the stratosphere. In addition, HALOE observations of two long-lived species, HF and CH4, are used as tracers to distinguish between change due to transport processes and change due to chemistry. The first study investigates the response of NO(x), (NO and NO2) and ozone to the presence of large amounts of sulfate aerosol in the stratosphere following the 1991 eruption of Mount Pinatubo. As the Pinatubo aerosol cleared the atmosphere at 17 mb (about 27-28 km), the partitioning of total reactive nitrogen shifted more toward NO(x), and ozone amounts declined. This trend is opposite that observed at lower altitudes. The second study examines the chemical aftermath of severe ozone depletion over Antarctica in spring. When ozone levels drop to a threshold amount (about 1 ppm near 20 km), the partitioning of the total chlorine family shifts rapidly from reactive species to the reservoir molecule HCl. This sudden repartitioning shuts down further ozone loss and may be significant as filaments of air peel off the polar vortex and mix with mid-latitude air.
We have determined major (Si, Zr, Hf), minor (Al, Y, Fe, P), and trace element (Ca, Sc, Ti, Ba, REE, Th, U) concentrations and Raman spectra of a zoned, 200 microns zircon grain in lunar sample 14161,7069, a quartz monzodiorite breccia collected at the Apollo 14 site. Analyses were obtained on a thin section in situ with an ion microprobe, an electron microprobe, and a laser Raman microprobe. The zircon grain is optically zoned in birefringence, a reflection of variable (incomplete) metamictization resulting from zo- nation in U and Th concentrations. Variations in the concentrations of U and Th correlate strongly with those of other high-field-strength trace elements and with changes in Raman spectral parameters. Concentrations of U and Th range from 21 to 55 ppm and 6 to 31 ppm, respectively, and correlate with lower Raman peak intensities, wider Raman peaks, and shifted Si-O peak positions. Concentrations of heavy rare earth elements range over a factor of three to four and correlate with intensities of fluorescence peaks. Correlated variations in trace element concentrations reflect the original magmatic differentiation of the parental melt approx. 4 b.y. ago. Degradation of the zircon structure, as reflected by the observed Raman spectral parameters, has occurred in this sample over a range of alpha-decay event dose from approx. 5.2 x 10(exp 14) to 1.4 x 10(exp 15) decay events per milligram of zircon, as calculated from the U and Th concentrations. This dose is well below the approx. 10(exp 16) events per milligram cumulative dose that causes complete metamictization and indicates that laser Raman microprobe spectroscopy is an analytical technique that is very sensitive to the radiation-induced damage in zircon.
Several single-crystal NiAl-X alloys (X=Hf, Ti, Cr, Ga) underwent hot corrosion testing in a Mach 0.3 burner rig at 900 deg. C for 300 1-hr cycles. The surface morphology after testing consisted of either mounds or an inward, uniform-type of attack which preserved surface features. It was observed that the surface morphology was affected by the surface preparation treatments. Microstructurally, the hot corrosion attack initiated as pits but evolved to a rampant attack consisting of the rapid inward growth of Al2O3. Electropolishing and chemical milling produced many pits and grooves on the surface. However, the presence of pits and grooves did not appear to strongly influence the hot corrosion response. Attack on many samples was strongly localized which was attributed to compositional inhomogeneity within the samples. It was found that increasing the Ti content from 1% to 5 % degraded the hot corrosion response of these alloys. In contrast, the addition of 1-2% Cr reduced the susceptibility of these alloys to hot corrosion attack and negated the deleterious effect of the 4-5% Ti addition.
We investigate the site substitution scheme of specific alloying elements in ordered compounds and the dependence of site occupancy on compound stoichiometry, alloy concentration. This basic knowledge, and the interactions with other alloying additions are necessary in order to predict and understand the effect of various alloying schemes on the physical properties of a material, its response to various temperature treatments, and the resulting mechanical properties. Many theoretical methods can provide useful but limited insight in this area, since most techniques suffer from constraints in the type of elements and the crystallographic structures that can be modeled. With this in mind, the Bozzolo-Ferrante-Smith (BFS) method for alloys was designed to overcome these limitations, with the intent of providing an useful tool for the theoretical prediction of fundamental properties and structure of complex systems. After a brief description of the BFS method, its use for the determination of site substitution schemes for individual as well as collective alloying additions to intermetallic systems is described, including results for the concentration dependence of the lattice parameter. Focusing on B2 NiAl, FeAl and CoAl alloys, the energetics of Si, Ti, V, Cr, Fe, Co, Ni, Cu, Zr, Nb, Mo, Ru, Hf, Ta and W alloying additions are surveyed. The effect of single additions as well as the result of two simultaneous additions, discussing the interaction between additions and their influence on site preference schemes is considered. Finally, the BFS analysis is extended to ternary L1(sub 2) (Heusler phase) alloys. A comparison between experimental and theoretical results for the limited number of cases for which experimental data is available is also included.
This report details the ongoing efforts by GATS, Inc., in conjunction with Hampton University and University of Wyoming, in NASA's Mission to Planet Earth UARS Science Investigator Program entitled "HALOE Algorithm Improvements for Upper Tropospheric Soundings." The goal of this effort is to develop and implement major inversion and processing improvements that will extend HALOE measurements further into the troposphere. In particular, O3, H2O, and CH4 retrievals may be extended into the middle troposphere, and NO, HCl and possibly HF into the upper troposphere. Key areas of research being carried out to accomplish this include: pointing/tracking analysis; cloud identification and modeling; simultaneous multichannel retrieval capability; forward model improvements; high vertical-resolution gas filter channel retrievals; a refined temperature retrieval; robust error analyses; long-term trend reliability studies; and data validation. The current (first-year) effort concentrates on the pointer/tracker correction algorithms, cloud filtering and validation, and multi-channel retrieval development. However, these areas are all highly coupled, so progress in one area benefits from and sometimes depends on work in others.
Measurements of the total solar irradiance (TSI) during the last 18 years from spacecraft are reviewed. Corrections are determined for the early measurements made by the HF radiometer within the ERB experiment on NIMBUS 7 and the factor to refer active cavity radiometer irradiation monitoring (ACRIM) 2 to the ACRIM 1 irradiance scale. With these corrections, a composite TSI is constructed with a model that combines a magnetic brightness proxy with observed sunspot darkening and explains nearly 90 percent of the observed short and long term variance. Possible, but still unverified degradation of the radiometers hampers conclusions about irradiance changes on decadal time scales and longer.
In order to investigate the complex electrodynamics and neutral-plasma coupling inherent to sporadic-E layers in the earth's mid-latitude ionosphere, a series of rocket/radar experiments were planned as part of the NASA El Coqui H Campaign from Tortuguero Launch Range, Puerto Rico, in March-April, 1998. The rocket experiments consisted of two pairs of "mother-daughter" payloads with limited apogees so that the payloads "hovered" in the sporadic-E region (95-125 km). Each payload pair included vector DC and AC electric field detectors, a highly accurate flux-gate DC magnetometer, an ion mass spectrometer, an ionization gauge, and spaced-electric field receivers to measure the wavelength and phase velocity of the unstable plasma waves. Separate rockets were included to simultaneously carry aloft TMA trails to measure the neutral wind and its velocity shear, believed responsible for the sporadic-E layer formation. In addition to the rocket experiments, incoherent scatter radar measurements of plasma density and drift velocity were gathered almost every night during the 3 week campaign. Continuous VHF backscatter radar operations were carried out from a site near Salinas, Puerto Rico, where 3-m backscatter echoes were observed associated with sporadic-E and other types of low altitude ionospheric layers. Other radars that operated during the campaign included an HF backscatter system near Ponce, Puerto Rico, and a second VHF backscatter radar set up near Aguadila Puerto Rico. On 24 March 1998, one of the instrumented rockets was launched, attaining an apogee of 129 km. The payloads successfully pierced an intense sporadic-E layer observed by both the Arecibo radar and the in-situ density and ion mass spectrometer probes. In-situ DC electric fields revealed very low (about 1-2 mV/m) ambient fields with small amplitude structures of the same order. No high frequency (short scale) waves were observed, consistent with the VHF backscatter observations at the time of the launch. An overview of the observations will be presented.
Recent results and ongoing studies of high resolution solar absorption spectra will be presented. The analysis of these spectra is aimed at the identification and quantification of trace constituents important in atmospheric chemistry of the stratosphere and upper troposphere. Analysis of balloon-borne and ground-based spectra obtained at 0.0025/ cm covering the 700-2200/ cm interval will be presented. Results from ground-based 0.02/ cm solar spectra, from several locations such as Denver, South Pole, M. Loa, and New Zealand will also be shown. The 0.0025/ cm spectra show many new spectroscopic features. The analysis of these spectra, along with corresponding laboratory spectra, improves the spectral line parameters, and thus the accuracy of trace constituents quantification. The combination of the recent balloon flights, with earlier flights data since 1978 at 0.02/ cm resolution, provides trends analysis of several stratospheric trace species. Results for COF2, F22, SF6, and other species will be presented. Analysis of several ground-based solar spectra provides trends for HCl, HF and other species. The retrieval methods used for total column density and altitude distribution for both ground-based and balloon-borne spectra will be presented. These are extended for the analysis of the ground-based spectra to be obtained by the high resolution interferometers of the Network for Detection of Stratospheric Change (NDSC). Progress or the University of Denver studies for the NDSC will be presented. This will include intercomparison of solar spectra and trace gases retrievals obtained from simultaneous scans by the high resolution (0.0025/ cm) interferometers of BRUKER and BOMEM.
Measured and calculated Nd and Hf isotopic compositions for geochemical reservoirs on the Moon and Mars are strikingly similar in some instances. Consequently, a magma ocean model is favored for Mars as well as the Moon.
Ultramicrotome sections of IDPs have been successfully etched with HF to isolate and reveal the microdistribution of carbonaceous material. The sections are evaluated for nanodiamonds, 3.4 micron feature, GEMS and the origin of low albedo in small interplanetary particles.