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At least 847 records · Page 47

Additively Printed Flexible Temperature Sensor for Wearable Applications

The flexible sensor has the capability to be mounted on any curved surfaces of applications and be used for portable devices. Additively printed sensors have received attention owing to their compact design and ability of application to non-planar surfaces. Wearable applications require capability of integration into a variety of surfaces with ability to flex, fold, twist and stretch under the stresses of daily motion. There is scarcity of data on the interaction of the process parameters with the realized performance. In addition, there is need for data focused on sensor accuracy, repeatability, and reliability. In this study, experimental analysis on function of the fabricated sensing board is conducted. The temperature sensors are made by direct write printing method with nScrypt printer. A calibration of the sensors has been conducted to confirm that resistance is well related to actual temperature and find TCR (temperature coefficient to resistance). The evolution of resistance has been correlated with the environmental temperature. The sensor hysteresis has been quantified using upswing and downswing of the environmental temperature. In addition, the effect of humidity on the temperature sensor accuracy and performance has been quantified. The effect of a polymide coat on the sensor to prevent humidity effects has also been quantified.

Pradeep Lall↗

Assimilation of SMAP Brightness Temperature Observations in the GEOS Land–Atmosphere Data Assimilation System

Errors in soil moisture adversely impact the modeling of land–atmosphere water and energy fluxes and, consequently, near-surface atmospheric conditions in atmospheric data assimilation systems (ADAS). To mitigate such errors, a land surface analysis is included in many such systems, although not yet in the currently operational NASA Goddard Earth Observing System (GEOS) ADAS. This article investigates the assimilation of L-band brightness temperature (Tb) observations from the Soil Moisture Active Passive (SMAP) mission in the GEOS weakly coupled land–atmosphere data assimilation system (LADAS) during boreal summer 2017. The SMAP Tb analysis improves the correlation of LADAS surface and root-zone soil moisture versus in situ measurements by ∼0.1–0.26 over that of ADAS estimates; the unbiased root-mean-square error of LADAS soil moisture is reduced by 0.002–0.008 m^3 /m^3 from that of ADAS. Furthermore, the global land average RMSE versus in situ measurements of screen-level air specific humidity (q2m) and daily maximum temperature (T2m_max ) is reduced by 0.05 g/kg and 0.04 K, respectively, for LADAS compared to ADAS estimates. Regionally, the RMSE of LADAS q2m and T2m_max is improved by up to 0.4 g/kg and 0.3 K, respectively. Improvement in LADAS specific humidity extends into the lower troposphere (below ∼700 mb), with relative improvements in bias of 15–25%, although LADAS air temperature bias slightly increases relative to that of ADAS. Finally, the root mean square of the LADAS Tb observation-minus-forecast residuals is smaller by up to ∼0.1 K than in a land-only assimilation system, corroborating the positive impact of the Tb analysis on the modeled land–atmosphere coupling.

microwave remote sensing↗

Exploring the Elevated Water Vapor Signal Associated With the Free Tropospheric Biomass Burning Plume Over the Southeast Atlantic Ocean

In southern Africa, widespread agricultural fires produce substantial biomass burning (BB) emissions over the region. The seasonal smoke plumes associated with these emissions are then advected westward over the persistent stratocumulus cloud deck in the southeast Atlantic (SEA) Ocean, resulting in aerosol effects which vary with time and location. Much work has focused on the effects of these aerosol plumes, but previous studies have also described an elevated free tropospheric water vapor signal over the SEA. Water vapor influences climate in its own right, and it is especially important to consider atmospheric water vapor when quantifying aerosol–cloud interactions and aerosol radiative effects. Here we present airborne observations made during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign over the SEA Ocean. In observations collected from multiple independent instruments on the NASA P-3 aircraft (from near-surface to 6–7 km), we observe a strongly linear correlation between pollution indicators (carbon monoxide (CO) and aerosol loading) and atmospheric water vapor content, seen at all altitudes above the boundary layer. The focus of the current study is on the especially strong correlation observed during the ORACLES-2016 deployment (out of Walvis Bay, Namibia), but a similar relationship is also observed in the August 2017 and October 2018 ORACLES deployments. Using reanalyses from the European Centre for Medium-Range Weather Forecasts (ECMWF) and Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), and specialized WRF-Chem simulations, we trace the plume–vapor relationship to an initial humid, smoky continental source region, where it mixes with clean, dry upper tropospheric air and then is subjected to conditions of strong westward advection, namely the southern African easterly jet (AEJ-S). Our analysis indicates that air masses likely left the continent with the same relationship between water vapor and carbon monoxide as was observed by aircraft. This linear relationship developed over the continent due to daytime convection within a deep continental boundary layer (up to ∼5–6 km) and mixing with higher-altitude air, which resulted in fairly consistent vertical gradients in CO and water vapor, decreasing with altitude and varying in time, but this water vapor does not originate as a product of the BB combustion itself. Due to a combination of conditions and mixing between the smoky, moist continental boundary layer and the dry and fairly clean upper-troposphere air above (∼6 km), the smoky, humid air is transported by strong zonal winds and then advected over the SEA (to the ORACLES flight region) following largely isentropic trajectories. Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT) back trajectories support this interpretation. This work thus gives insights into the conditions and processes which cause water vapor to covary with plume strength. Better understanding of this relationship, including how it varies spatially and temporally, is important to accurately quantify direct, semi-direct, and indirect aerosol effects over this region.

Kristina Pistone↗

Biomass Burning Smoke and Coincident Water Vapor Over the Southeast Atlantic Stratocumulus Region: Results from Observations and Models

In southern Africa, widespread agricultural fires produce substantial biomass burning (BB) emissions over the region. The seasonal smoke plumes associated with these emissions are then advected westward over the persistent stratocumulus cloud deck in the Southeast Atlantic (SEA) Ocean. We present airborne observations made during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign over the SEA. Using multiple airborne datasets, we observe a strongly linear correlation between biomass burning indicators (carbon monoxide (CO) and aerosol loading) and atmospheric water vapor content, seen at all altitudes above the boundary layer. This relationship was particularly strong in the 2016 observations, but was also present in the 2017 and 2018 deployments. Using ECMWF and MERRA-2 reanalyses and specialized WRF-Chem simulations, we trace the plume-vapor relationship to an initial humid, smoky continental source region, where it mixes with clean, dry upper-tropospheric air and then is subjected to conditions of strong westward advection, namely the South African Easterly Jet (AEJ-S). Our analysis indicates that airmasses likely left the continent with the same relationship between water vapor and carbon monoxide as was observed by aircraft. This linear relationship developed over the continent due to daytime convection within a deep continental boundary layer (up to ~5-6km) and mixing with higher-altitude air, which resulted in fairly consistent vertical gradients in CO and water vapor, decreasing with altitude and varying in time, but this water vapor does not originate as a product of the BB combustion itself. The smoky, humid mixed air is then subjected to strong zonal winds and advected over the SEA following largely isentropic trajectories. HYSPLIT back trajectories support this interpretation. With better understanding of this relationship, and its spatial and temporal variations, we are working towards accurately quantifying the radiative and dynamical effects of both aerosol and water vapor over this region.

Kristina Pistone↗

On the Relationship Between CYGNSS Surface Heat Fluxes and the Life Cycle of Low-Latitude Ocean Extratropical Cyclones

Surface latent and sensible heat fluxes are important for extratropical cyclone evolution and intensification. Because extratropical cyclone genesis often occurs at low-latitude, CYGNSS surface latent and sensible heat flux retrievals are composited to provide a mean picture of their spatial distribution in low-latitude oceanic extratropical cyclones. CYGNSSn heat fluxes are not affected by heavy precipitation and offer observations of storms with frequent revisit times. Consistent with prior results obtained for cyclones in the Gulf Stream region, the fluxes are strongest in the wake of the cold fronts, and weakest to negative in the warm sector in advance of the cold fronts. As cyclone strength increases, or mean precipitable water decreases, the maximum in surface heat fluxes increases while the minimum decreases. This impacts the changes in fluxes during cyclone intensification: the post-cold frontal surface heat flux maximum increases due to the increase in near surface winds. During cyclone dissipation, the fluxes in this sector decrease, due to the decrease in winds and in temperature and humidity contrast. The warm sector minimum decreases throughout the entire cyclone lifetime and is mostly driven by sea-air temperature and humidity contrast changes. However, during cyclone dissipation, the surface heat fluxes increase along the cold front in a narrow band to the east, independently from changes in the cyclone characteristics. This suggests that, during cyclone dissipation, energy transfers from the ocean to the atmosphere are linked to frontal in addition to synoptic-scale processes.

CYGNSS↗

Placing the East-West North American Aridity Gradient in a Multi-Century Context

Instrumental records indicate a century-long trend towards drying over western North America and wetting over eastern North America. A continuation of these trends into the future would have significant hydroclimatic and socioeconomic consequences in both the semi-arid Southwest and humid East. Using tree-ring reconstructions and hydrologic simulations of summer soil moisture, we evaluate and contextualize the modern summer aridity gradient within its natural range of variability established over the past 600 years and evaluate the effects of observed and anthropogenic precipitation, temperature, and humidity trends. The 2001–2020 positive (wet east-dry west) aridity gradient was larger than any 20-year period since 1400 CE, preceded by the most negative (wet west-dry east) aridity gradient during 1976-1995, leading to a strong multi-decade reversal in aridity gradient anomalies that was rivaled only by a similar event in the late-16th century. The 2001-2020 aridity gradient was dominated by long-term summer precipitation increases in the Midwest and Northeast, with smaller contributions from more warming in the West than the East and spring precipitation decreases in the Southwest. Multi-model mean climate simulations from CMIP6 experiments suggest anthropogenic climate trends should not have strongly affected the aridity gradient thus far. However, there is high uncertainty due to inter-model disagreement on anthropogenic precipitation trends. The recent strengthening of the observed aridity gradient, its increasing dependence on precipitation variability, and disagreement in modeled anthropogenic precipitation trends reveal significant uncertainties in how water resource availability will change across North America in the coming decades.

drought↗

A Path to Improving Simulated Properties of Low Clouds over the Beaufort Sea using Airborne In Situ Observations of Subgrid-Scale Variability

Arctic low clouds influence the evolution of the Arctic system through their effects on radiative fluxes, boundary layer mixing, stability, turbulence, humidity, and precipitation. Unfortunately, atmospheric models and retrospective analysis (reanalysis) products struggle to accurately simulate the occurrence and properties of low clouds in the Arctic. One of the main reasons for this problem are the possible unrealistic assumptions that models/reanalyses make about the subgrid-scale (SGS) variability of meteorological properties, as well as the relationship between SGS variability and grid-scale (GS) cloud properties. We utilize cloud and thermodynamic data of low level (primarily) liquid clouds collected from two aircraft campaigns conducted over the Beaufort Sea to better understand and characterize this problem. Examining data from the September 2014 Arctic Radiation-IceBridge Sea and Ice Experiment (ARISE) airborne campaign reveals that GS cloud water variability is closely related with SGS distribution of total water (i.e. water vapor + cloud water). Multiple models/reanalyses use SGS supersaturated total water (relative to GS saturation) as a threshold for partitioning available water for condensation, and indeed we find significant correlation between GS cloud water and SGS supersaturation. However, we also find that the assumption of a static threshold of 100% saturation to be unrealistic. Empirical calculations from the ARISE data show a large sensitivity of this threshold to GS relative humidity, and so a microphysical parameterization allowing the threshold to vary according to GS thermodynamic properties may result in more realistic GS cloud water values. Finally, to determine how sensitive the ARISE-derived results are to that particular campaign, we include additional data from the First International Satellite Cloud Climatology Project (ISCCP) Regional Experiment (FIRE)–Arctic Cloud Experiment (ACE) conducted in 1998. The inclusion of the second dataset will help with demonstrating the robustness of the results and their utility in improving the representation of Arctic clouds in models and reanalyses.

J Brant Dodson↗

Analytical Methods and Testbeds for Characterizing Adsorbents and Catalysts for Atmosphere Revitalization of Crewed Spacecraft

Spacecraft environmental control and life support systems (ECLSS) include a number of air revitalization (AR) technologies to provide breathable air and a comfortable living environment to the crew. Crew health and comfort is ensured by controlling human produced CO2 (1 kg person-1 day-1) and water vapor (~2 kg person-1 day-1), and by removing trace contaminants (TCs) from cabin air. These life support functions on-board the International Space Station (ISS) are carried out by the Carbon Dioxide Removal Assembly (CDRA), the Water Processor Assembly (WPA), and the trace contaminant control system (TCCS). During the development of the TCCS, new analytical and theoretical methods were developed in the 1970s for characterizing adsorption and desorption characteristics of activated carbons for the purpose of designing suitable AR technologies required for controlling airborne trace contaminants within spacecraft cabins during long exploration missions. The TCCS removes harmful volatile organic compounds and other trace contaminants from the circulating air. It consists of a granular activated carbon (GAC) bed for the removal of high molecular weight contaminants and ammonia followed by a heated catalytic bed for low molecular weight hydrocarbons. The high temperature catalytic oxidizer (HTCO) of the TCCS, which operates at 400°C and requires 120W average power, removes low molecular weight compounds such as carbon monoxide (CO), formaldehyde (CH2O), and methane (CH4), that pass through the GAC bed. The Air Revitalization Laboratory at the Kennedy Space Center (KSC) was established to develop new analytical methods for evaluating emerging ECLSS technologies for use in future AR architectures. General properties of adsorbents and catalysts are required for trace contaminant control system design calculations and vendor-supplied data are seldom available at relevant process conditions of interest to spacecraft cabin applications. To address this shortcoming, appropriate testbeds were developed to measure the desired properties of AR technologies being considered for use in ECLS architectures. Generally, the testbeds developed at KSC challenge the test media (activated carbon, impregnated activated carbon, catalysts, zeolites, solid amines, or pleated filters) with simulated spacecraft gas streams containing representative mixtures of trace contaminants (volatile organic compounds, ammonia, CO, CO2, or siloxanes) at the flow rates, temperatures, and relative humidity that will be encountered within manned spacecraft. Work performed at KSC funded by NASA’s Advanced Exploration (AES) Program has included: Identifying candidate sorbents to replace commercially obsolete impregnated carbons for NH3 control within the TCCS, characterizing their adsorptive capacities using simulated spacecraft gas streams, and ranking their appropriateness in various AR applications; evaluating novel low temperature catalysts for controlling CO and formaldehyde by traditional and photocatalytic methods for trace contaminant control; development of analytical methods to assess regenerable solid amine performance for CO2 control via pressure swing adsorption. The Air Revitalization lab was also funded to study trace contaminant control by other NASA programs. These include: screening of candidate sorbents for the design of new Charcoal HEPA Integrated Particle Scrubber (CHIPS) filters for removing siloxanes from cabin air; characterizing the performance of an impregnated activated carbon at low humidity for use in ORION ECLS; screening of sorbents for protecting the Sabatier 2.0 catalyst from DMSO2, siloxanes, NH3, and solid amine byproducts.

Monje, Oscar↗

Microbial Characterization of Heat Melt Compaction for Treatment of Space Generated Solid Wastes

One treatment process in development for solid waste management in space has been the Trash Compaction Processing System (TCPS). Human space mission wastes typically contain large percentages of contaminated wet solid waste. The Heat Melt Compactor (HMC) is being developed to be a multi-function means of water recovery, volume reduction, and the making safe of contaminant-rich trash with the potential for waste stabilization and/or sterilization. To determine the efficacy of the HMC treatment to kill microorganisms in solid waste and remain biologically stable, testing was conducted on three tiles produced by HMC-Gen 2 at Ames Research Center. Samples were shipped to Kennedy Space Center to test for microbial viability after compaction, determine the bio-stability of the HMC disks during storage (43 days), and assess potential airborne contaminate microbial growth on surfaces at low and high humidity conditions. In addition to the products of solid waste processing technologies, there is a concern that the crew might come into contact with hardware surfaces that have been contaminated by microorganisms during waste processing. The extent of microbial surface contamination of waste processing hardware was determined by surface sample swabbing and analysis for total bacterial and yeast counts and cultivable counts of aerobic and anaerobic bacteria, spore-forming bacteria, and fungi. Results indicate that trash processing increased bacterial counts on the surfaces of the compacter. All but one biological indicator spore strip imbedded in the HMC produced tiles were negative for growth after incubation for five days indicating effective sterilization through the heat melt compaction process. Analysis of core samples as well as surface growth of tiles inoculated with Aspergillus niger fungal spores incubated at three levels of humidity indicate that HMC created tiles did not support the proliferation of bacterial and fungal growth.

Mary E Hummerick↗

TLife-LSTM: Forecasting Future COVID-19 Progression with Topological Signatures of Atmospheric Conditions

Understanding the impact of atmospheric conditions on SARS-CoV2 is critical to model COVID-19 dynamics and sheds a light on the future spread around the world. Furthermore, geographic distri- butions of expected clinical severity of COVID-19 may be closely linked to prior history of respiratory diseases and changes in humidity, tem- perature, and air quality. In this context, we postulate that by tracking topological features of atmospheric conditions over time, we can provide a quanti?able structural distribution of atmospheric changes that are likely to be related to COVID-19 dynamics. As such, we apply the machinery of persistence homology on time series of graphs to extract topological signatures and to follow geographical changes in relative humidity and temperature. We develop an integrative machine learning framework named Topological Lifespan LSTM (TLife-LSTM) and test its predictive capabilities on forecasting the dynamics of SARS-CoV2 cases. We validate our framework using the number of con?rmed cases and hospitalization rates recorded in the states of Washington and California in the USA. Our results demonstrate the predictive potential of TLife-LSTM in forecasting the dynamics of COVID-19 and modeling its complex spatio-temporal spread dynamics.

Gel, Yulia R.↗

Variation and evolution of atmospheric structure over the SEA BB season as seen from aircraft and reanalysis

The presence of absorbing aerosols and atmospheric water vapor will impact clouds both radiatively and dynamically. The atmosphere over the southeast Atlantic Ocean (SEA) experiences consistent springtime biomass burning (BB) smoke from widespread agricultural fires on the African continent. This smoke layer is initially lofted high in a continental mixed layer (~5-6km) and is then transported westward into the free troposphere where it overlies and ultimately mixes into the underlying stratocumulus-topped oceanic boundary layer. Coincident with this smoke is an elevated humidity signal which is present from the time a given airmass is over the continental source region. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) was a NASA Earth Venture Suborbital mission with the goal of measuring aerosol, cloud, and atmospheric properties over this region over three deployments in September 2016, August 2017, and October 2018. Measurements included in situ profile measurements of aerosol physical and optical properties, trace gas concentrations, and cloud properties, as well as column measurements of aerosol optical depth and trace gas concentrations from an airborne sun photometer, allowing for calculation of radiative heating at different altitudes. Here we present results from the three ORACLES deployments over the southeast Atlantic Ocean. The airborne observations capture both seasonal patterns (August through October) and spatial patterns (north/south and east/west) in the vertical smoke distribution and its correlation to atmospheric specific humidity over the SEA basin. We describe the observed variations and show that the variability in both meteorological and emissions is largely captured in the European Centre for Medium-range Weather Forecasting Copernicus Atmosphere Monitoring Service (ECMWF CAMS) reanalysis, which allows for a more systematic examination of the relative frequency of observed conditions and their radiative impact over the region. Finally, we discuss the broader radiative and dynamical implications of these results for conditions of biomass burning aerosols overlying stratocumulus clouds.

Kristina Marie Myers Pistone↗

Validation of IMERG Oceanic Precipitation over Kwajalein

The integrated Multi-satellitE Retrievals for GPM (IMERG) Version V05B and V06B precipitation products from the Global Precipitation Measurement (GPM) mission are validated against ground-based observations from the Kwajalein Polarimetric S-band Weather Radar (KPOL) deployed at Kwajalein Atoll in the central Pacific Ocean. Such a validation is particularly important as comprehensive surface measurements over the oceans are practically infeasible, which hampers the identification of possible errors, and improvement of future versions of IMERG and other satellitebased retrieval algorithms. The V05B and V06B IMERG products are validated at their native 0.1°, 30 min resolution from 2014 to 2018 based on both volumetric and categorical metrics. This validation study indicates that precipitation rates from both IMERG V05B and V06B are underestimated with respect to radar surface estimates, but the underestimation is much reduced from V05B IMERG V06B outperforms V05B with reduced systematic bias and improved precipitation detectability. The IMERG performance is further traced back to its individual sensors and morphing-based algorithms. The overall underestimation in V05B is mainly driven by the negative relative biases from morphing-based algorithms which are largely corrected in V06B. Imagers perform generally better than sounders because of the usage of low-frequency channels in imagers which can better detect emission signals by the hydrometeors. Among imagers, the GPM Microwave Imager (GMI) and Advanced Microwave Scanning Radiometer Version 2 (AMSR2) are the best, followed by Special Sensor Microwave Imager/Sounder (SSMIS). Among sounders, the Microwave Humidity Sounder (MHS) is the best, followed by Advanced Technology Microwave Sounder (ATMS) and the Sounder for Atmospheric Profiling of Humidity in the Intertropics by Radiometry (SAPHIR) for V06B. Among all categories, morph-only and IR+morph only perform better than SAPHIR. SAPHIR shows the worst performance among all categories, likely due to its limited channel selection. It is envisaged that these results will improve our understanding of IMERG performance over oceans and aid in the improvement of future versions of IMERG.

KPOL↗

Long Term Performance Stability of TES Detectors

We are developing superconducting transition-edge sensor (TES) microcalorimeter arrays for a variety of applications such as ground-based laboratory astrophysics experiments and next generation space-based X-ray missions. These detectors can provide X-ray spectral information with an unprecedent resolution of ~2 eV at 6 keV and have been selected for the X-ray Integral Field Unit (X-IFU) instrument of ESA’s large flagship mission Athena. To maintain detector performance over the lifetime of the mission, it is important to understand whether environmental conditions that the detector may be exposed to will affect its properties over time. This “aging” begins right after the array leaves the fabrication environment, with potential exposure to humidity, oxygen, or elevated temperatures which may affect the detector performance. In a few prior arrays we have observed increased fall times in the pulse shape and/or the introduction of anomalous low energy tails on the X-ray spectrum. This is thought to be an indication of “aging” on chips exposed to such conditions, causing e.g. changes in the absorber properties. In this contribution, we report on a systematic characterization of TES properties, before and after exposing the chip to various controlled temperature and humidity levels and assess the changes in the measured transition and pulse shapes, energy resolution, and spectral redistribution.

S Beaumont↗

Detail Enhancement of AIRS/AMSU Temperature and Moisture Profiles Using a 3D Deep Neural Network

In recent decades, spaceborne microwave and hyperspectral infrared sounding instruments have significantly benefited weather forecasting and climate science. However, existing retrievals of lower troposphere temperature and humidity profiles have limitations in vertical resolution, and often cannot accurately represent key features such as the mixed layer thermodynamic structure and the inversion at the planetary boundary layer (PBL) top. Because of the existing limitations in PBL remote sensing from space, there is a compelling need to improve routine, global observations of the PBL and enable advances in scientific understanding and weather and climate prediction. To address this, we have developed a new 3D deep neural network (DNN) which enhances detail and reduces noise in Level 2 granules of temperature and humidity profiles from the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit (AMSU) sounder instruments aboard NASA’s Aqua spacecraft. We show that the enhancement improves accuracy and detail including key features such as capping inversions at the top of the PBL over land, resulting in improved accuracy in estimations of PBL height.

Adam B Milstein↗

Technology Assessment for Producing Propellant From Lunar Water

Introduction: The presence of water ice in permanently shadowed regions (PSRs) on the lunar surface may enable a sustained human presence on the Moon with minimal need for consumables. One of the most valuable uses of lunar water is to produce rocket propellant. A sustained human presence on the Moon will re-quire frequent launches from the lunar surface, and each launch will require tons of propellant. However, many other volatiles are likely to be present in the areas where lunar water is stable1. Producing propellant from lunar water in-situ will require the separation and purification of water before it can be electrolyzed into oxygen and hydrogen gas. The Resource Exploration and Science of OUR Cosmic Environment (RESOURCE) project, funded by the Solar System Exploration Research Virtual Institute (SSERVI) program, includes a task to demonstrate the end-to-end process of water extraction, capture, purification and electrolysis to produce pure/dry oxygen gas sourced from an icy regolith mixture. Water Purification: The requirements for water purity are driven by the type of water electrolyzer used. For example, the water electrolyzer currently used on the International Space Station is based on proton ex-change membrane (PEM) technology. PEM-based electrolyzers require water to be ultrapure and deionized (>10 MegaOhm-cm) so that electrical conductivity is limited to the membranes themselves, where electrical current is used to convert H2O into H2 and O2.. A practical first step toward purifying water that is sourced from a lunar PSR is to use freeze distillation to separate water from other volatiles2. A sub-micronic filter can also be used to ensure that a minimal amount of dust is present in any lunar water that is captured. The combination of freeze distillation and sub-micronic filtration will result in relatively pure water but would require a deionization step if being fed into a PEM electrolyzer. Water Electrolysis: An alternative to PEM electrolysis is to use a Solid Oxide Electrolyzer (SOE). This technology operates at a much higher operating temperature (~800oC) and has a limited pressure range but does not require water to be ultrapure and deionized. Another advantage of SOE technology is that it produces pure dry oxygen gas without the need of an additional drying step. PEM electrolyzers produce humid oxygen gas and the humidity must be removed prior to liquefaction. Assessment: In order to compare PEM and SOE technologies side-by-side, they must be compared at a system level that includes water purification and gas drying steps. Engineers at the Johnson Space Center up-dated and utilized a detailed In-Situ Resource Utilization (ISRU) system model to compare and select the best option for the RESOURCE project which will conclude with a laboratory demonstration of the process of producing pure/dry oxygen from an icy regolith mixture in 2025.

A.J. Paz↗

Technology Assessment for Producing Propellant From Lunar Water

Introduction: The presence of water ice in permanently shadowed regions (PSRs) on the lunar surface may enable a sustained human presence on the Moon with minimal need for consumables. One of the most valuable uses of lunar water is to produce rocket propellant. A sustained human presence on the Moon will re-quire frequent launches from the lunar surface, and each launch will require tons of propellant. However, many other volatiles are likely to be present in the areas where lunar water is stable1. Producing propellant from lunar water in-situ will require the separation and purification of water before it can be electrolyzed into oxygen and hydrogen gas. The Resource Exploration and Science of OUR Cosmic Environment (RESOURCE) project, funded by the Solar System Exploration Research Virtual Institute (SSERVI) program, includes a task to demonstrate the end-to-end process of water extraction, capture, purification and electrolysis to produce pure/dry oxygen gas sourced from an icy regolith mixture. Water Purification: The requirements for water purity are driven by the type of water electrolyzer used. For example, the water electrolyzer currently used on the International Space Station is based on proton ex-change membrane (PEM) technology. PEM-based electrolyzers require water to be ultrapure and deionized (>10 MegaOhm-cm) so that electrical conductivity is limited to the membranes themselves, where electrical current is used to convert H2O into H2 and O2.. A practical first step toward purifying water that is sourced from a lunar PSR is to use freeze distillation to separate water from other volatiles2. A sub-micronic filter can also be used to ensure that a minimal amount of dust is present in any lunar water that is captured. The combination of freeze distillation and sub-micronic filtration will result in relatively pure water but would require a deionization step if being fed into a PEM electrolyzer. Water Electrolysis: An alternative to PEM electrolysis is to use a Solid Oxide Electrolyzer (SOE). This technology operates at a much higher operating temperature (~800oC) and has a limited pressure range but does not require water to be ultrapure and deionized. Another advantage of SOE technology is that it produces pure dry oxygen gas without the need of an additional drying step. PEM electrolyzers produce humid oxygen gas and the humidity must be removed prior to liquefaction. Assessment: In order to compare PEM and SOE technologies side-by-side, they must be compared at a system level that includes water purification and gas drying steps. Engineers at the Johnson Space Center up-dated and utilized a detailed In-Situ Resource Utilization (ISRU) system model to compare and select the best option for the RESOURCE project which will conclude with a laboratory demonstration of the process of producing pure/dry oxygen from an icy regolith mixture in 2025.

ISRU↗

Synergy of Satellite Radiation, Precipitation, and Other Meteorological Variable Observations for Global Mean Sea Surface Turbulent Heat Flux Estimation

Sea surface turbulent heat flux is one of the key components in global freshwater and energy balances and plays an important role in atmospheric dynamics, thermodynamics and general circulation. This turbulent heat flux is dominantly decided by sea surface latent heat release with some contribution from sensible heat exchange. The flux and its anomaly could significantly affect ocean heat storage and ocean circulation. They are part of and have great impacts on climate variability. Though the turbulent heat flux is extremely important for the climate and weather systems, only very limited ship and buoy observations of the flux are available over open oceans. There are no global, operational, direct measurements of this crucial meteorological variable. Global estimates are, basically, indirectly calculated from bulk turbulent flux parameterization with a combination of satellite column water vapor, sea surface water temperature, and wind speed observations. Critical parameters such as sea surface air temperature and humidity are estimated from empirical relations of theses variables with the water vapor and sea surface water temperature, respectively. Lacking accurate knowledge on surface air temperature and humidity, uncertainties in the parameterization and potential changes in the non-linear turbulent processes with long-term climate variations could cause large errors in estimated long-term turbulent fluxes from the indirect method as shown in current global sea surface turbulent flux datasets. This study uses synergized data of satellite global radiation, precipitation, and other meteorological variable observations to estimate sea surface turbulent heat fluxes. The radiation observations are made by the satellite Clouds and the Earth’s Radiant Energy System (CERES) sensors, while the global precipitation data is from NASA’s satellite Global Precipitation Climatology Project (GPCP). Other data includes satellite sea surface water temperature and wind speed observations. These datasets are obtained from a wide range of space sensors from passive to active instruments and from visible and near infrared to thermal infrared and microwave spectral sounders. One significant feature of these datasets is that they have multi-decades long climate records. Top-of-atmosphere (TOA) radiation and its anomaly represents the net heat energy input to the climate system, and the oceanic precipitation and ocean-land moisture transport can be used to quantify sea surface latent heat release. Based on the synergized datasets and the principle of global water and energy balances, global mean turbulent heat fluxes are estimated. The turbulent heat anomalies for the first two decades of the 21st century are, then, obtained mainly from global CERES radiation and GPCP precipitation anomalies, along with CERES derived ocean-land heat transports. Analysis indicates that the uncertainties in the estimated turbulent flux anomalies may be reduced considerably. The results suggest a strong needs in synchronized and synergized observations of atmospheric radiation, precipitation, and oceanic meteorological variables for long-term climate studies.

Bing Lin↗

Stress Testing of Chip Aluminum Polymer Capacitors

Layered aluminum polymer capacitors (APC) may be viable replacements to current chip tantalum capacitors due to their lower ESR, weight, and smaller size. So far, there is a lack of information regarding the reliability of these parts. Available technical literature is mostly related to the effect on humidity. Although APCs have a limited moisture resistance, it may be contained to the level sufficient for space applications. In this work, seven types of commercial APCs manufactured by four vendors and rated to voltages from 6.3 to 35 V were used to evaluate reliability of the parts under environmental stresses and highly accelerated life tests. Characteristics of the parts, including breakdown voltages, the level of anomalous charging currents (ACC), capacitance, DF, ESR and leakage currents were measured in the process of storage at high-temperatures (from 100 to 150 °C) and high humidity at 85 °C. Monitored highly accelerated life tests have been carried out at temperatures of 85 °C and 125 °C and voltages varying from 1.2 to 1.9 times the rated voltage. Degradation processes and reliability of APCs have been analyzed and compared to polymer tantalum capacitors.

Alexander Teverovsky↗