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At least 847 records · Page 47

Reflectron Time-of-Flight Mass Spectrometer (REMAS) Instrumentation

The restricted mass and power budgets of landed science missions present a challenge to obtaining detailed analyses of planetary bodies. In situ studies, whether alone or as reconnaissance for sample return, must rely on highly miniaturized and autonomous instrumentation. Such devices must still produce useful data sets from a minimum of measurements. The great desire to understand the surfaces and interiors of planets, moons, and small bodies had driven the development of small, robotic techniques with ever-increasing capabilities. One of the most important goals on a surface mission is to study composition in many geological contexts. The mineralogical, molecular, elemental, and isotopic content of near-surface materials (regolith, rocks, soils, dust, etc.) at a variety of sites can complement broader imaging to describe the makeup and formative history of the body in question. Instruments that perform this site-to-site analysis must be highly transportable and work as a suite. For instance, a camera, microscope, spectrophotometer, and mass spectrometer can share several components and operate under a parallel command structure. Efficient use of multiple systems on a small rover has been demonstrated on the Mars Pathfinder mission.

Brinckerhoff, W. B.↗

Mapping Hesperia Planum, Mars

Hesperia Planum, characterized by a high concentration of mare-type wrinkle ridges and ridge rings [1-4], encompasses > 2 million km2 in the southern highlands of Mars (Fig. 1). The most common interpretation is that the plains were emplaced as flood lavas with total thicknesses of <3 km [4-10]. The wrinkle ridges on its surface make Hesperia Planum the type locale for Hesperian-aged ridged plains on Mars [e.g., 9], and recent investigations reveal that wrinkle-ridge formation occurred in more than one episode [4]. Hesperia Planum s stratigraphic position and crater-retention age [e.g., 9, 11-12] define the base of the Hesperian System. However, preliminary results of geologic mapping reveal that the whole of Hesperia Planum is unlikely to be composed of the same materials, emplaced at the same geologic time. To unravel these complexities, we are generating a 1:1.5M-scale geologic map of Hesperia Planum and its surroundings (Fig. 1). To date, we have identified 4 distinct plains units within Hesperia Planum and are attempting to determine the nature and relative ages of these materials (Fig. 2) [13-15].

Gregg, Tracy K. P.↗

Meteoritic Input of Amino Acids and Nucleobases: Methodology and Implications for the Origins of Life

The discoveries of amino acids of extraterrestrial origin in many meteorites over the last 40 years have revolutionized the Astrobiology field. A variety of non-terrestrial amino acids similar to those found in life on Earth have been detected in meteorites. A few amino acids have even been found with chiral excesses, suggesting that meteorites could have contributed to the origin of homochirality in life on Earth. In addition to amino acids, which have been productively studied for years, sugar-like molecules, activated phosphates, and nucleobases have also been determined to be indigenous to numerous meteorites. Because these molecules are essential for life as we know it, and meteorites have been delivering them to the Earth since accretion, it is plausible that the origin(s) of life on Earth were aided by extraterrestrially-synthesized molecules. Understanding the origins of life on Earth guides our search for life elsewhere, helping to answer the question of whether biology is unique to Earth. This tutorial review focuses on meteoritic amino acids and nucleobases, exploring modern analytical methods and possible formation mechanisms. We will also discuss the unique window that meteorites provide into the chemistry that preceded life on Earth, a chemical record we do not have access to on Earth due to geologic recycling of rocks and the pervasiveness of biology across the planet. Finally, we will address the future of meteorite research, including asteroid sample return mIssIons.

Burton, Aaron S.↗

Understanding Prebiotic Chemistry Through the Analysis of Extraterrestrial Amino Acids and Nucleobases in Meteorites

The discoveries of amino acids of extraterrestrial origin in many meteorites over the last 50 years have revolutionized the Astrobiology field. A variety of non-terrestrial amino acids similar to those found in life on Earth have been detected in meteorites. A few amino acids have even been found with chiral excesses, suggesting that meteorites could have contributed to the origin of homochirality in life on Earth. In addition to amino acids, which have been productively studied for years, sugar-like molecules, activated phosphates, and nucleobases have also been determined to be indigenous to numerous meteorites. Because these molecules are essential for life as we know it, and meteorites have been delivering them to the Earth since accretion, it is plausible that the origines) of life on Earth were aided by extrataterrestrially-synthesized molecules. Understanding the origins of life on Earth guides our search for life elsewhere, helping to answer the question of whether biology is unique to Earth. This tutorial focuses on meteoritic amino acids and nucleobases, exploring modern analytical methods and possible formation mechanisms. We will also discuss the unique window that meteorites provide into the chemistry that preceded life on Earth, a chemical record we do not have access to on Earth due to geologic recycling of rocks and the pervasiveness of biology across the planet. Finally. we will address the future of meteorite research, including asteroid sample return missions.

Burton, Aaron S.↗

Engineering a Solution to Jupiter Exploration

The Europa Jupiter System Mission (EJSM) would be an international mission with the overall theme of investigating the emergence of habitable worlds around gas giants. Its goals are to (1) explore Europa to investigate its habitability, (2) characterize Ganymede as a planetary object including its potential habitability and (3) explore the Jupiter system as an archetype for gas giants. NASA and ESA have concluded a detailed joint study of a mission to Europa, Ganymede, and the Jupiter system with conceptual orbiters developed by NASA and ESA. The baseline EJSM architecture consists of two primary elements operating simultaneously in the Jovian system: the NASA-led Jupiter Europa Orbiter (JEO), and the ESA-led Jupiter Ganymede Orbiter (JGO). JEO and JGO would execute an intricately choreographed exploration of the Jupiter System before settling into orbit around Europa and Ganymede, respectively. EJSM would directly address themes concerning the origin and evolution of satellite systems and water-rich environments in icy satellites. The potential habitability of the ocean-bearing moons Europa and Ganymede would be investigated, by characterizing the geophysical, compositional, geological, and external processes that affect these icy worlds. EJSM would also investigate Io and Callisto, Jupiter's atmosphere, and the Jovian magnetosphere. By understanding the Jupiter system and unraveling its history, the formation and evolution of gas giant planets and their satellites would be better known. Most importantly, EJSM would shed new light on the potential for the emergence of life in the celestial neighborhood and beyond. The EJSM baseline architecture would provide opportunities for coordinated synergistic observations by JEO and JGO of the Jupiter and Ganymede magnetospheres, the volcanoes and torus of Io, the atmosphere of Jupiter, and comparative planetology of icy satellites. Each spacecraft would conduct both synergistic dual-spacecraft investigations and stand-alone measurements toward the overall mission theme and goals.

Clark, Karla↗

Gully Formation at the Haughton Impact Structure (Arctic Canada) Through the Melting of Snow and Ground Ice, with Implications for Gully Formation on Mars

The formation of gullies on Mars has been the topic of active debate and scientific study since their first discovery by Malin and Edgett in 2000. Several mechanisms have been proposed to account for gully formation on Mars, from “dry” mass movement processes, release of water or brine from subsurface aquifers, and the melting of near-surface ground ice or snowpacks. In their global documentation of martian gullies, report that gullies are confined to ~27–83°S and ~28–72°N latitudes and span all longitudes. Gullies on Mars have been documented on impact crater walls and central uplifts, isolated massifs, and on canyon walls, with crater walls being the most common situation. In order to better understand gully formation on Mars, we have been conducting field studies in the Canadian High Arctic over the past several summers, most recently in summer 2018 and 2019 under the auspices of the Canadian Space Agency-funded Icy Mars Analogue Program. It is notable that the majority of previous studies in the Arctic and Antarctica, including our recent work on Devon Island, have focused on gullies formed on slopes generated by regular endogenic geological processes and in “regular” bedrock. How-ever, as noted above, meteorite impact craters are the most dominant setting for gullies on Mars. Impact craters provide an environment with diverse lithologies – including impact-generated and impact-modified rocks – and slope angle, and thus greatly variable hill slope processes could occur within a localized area. Here, we investigate the formation of gullies within the Haughton impact structure and compare them to gullies formed in unimpacted target rock in the nearby Thomas Lee Inlet

Osinski, G. R.↗

Geologic Settings of Martian Gullies: Implications for Their Origins

Martian gullies are found on steep slopes of all origins, on all sorts of terrains of all ages, scattered across nearly all of Mars. Gullies are observed on all manner of substrates (layered, massive, shattered, rubble), with or without nearby mantling deposits. Gullies are most common in the southern midlatitudes but also occur in the northern hemisphere, in near polar terrain, on equatorial volcanoes, and on northern plains. Most gullies in the southern hemisphere are on south-facing slopes, but they occur on slopes of all orientations. Gullies are among the youngest features on Mars but locally are overlain by eolian deposits and cut by faults. Old or eroded gullies are rare, and those found have been partially stripped from slopes, leaving no rock debris behind. Most gully deposits contain no detectable rocks. These data are inconsistent with published hypotheses of gully formation, including seeps and breakouts of water or brine, hydrothermal activity, cryovolcanism, and breakouts from liquid carbon dioxide. The data are consistent with gullies being dry flows of eolian material (dust and silt), comparable to climax snow avalanches on Earth. Eolian sedimentation should be correlated little with underlying geology: cause of slope, age of terrain, type of terrain, or the nature of the rocks. Eolian sedimentation should be correlated with wind deceleration (which will cause suspended sediment to drop), and areas with common gullies are those with strong wind deceleration (predicted by global circulation model). In such areas, sediment will be deposited preferentially in the lee of obstacles; for the gully-rich areas of the southern midlatitudes, winds blow from the NNW, so that sediment is deposited on SSE-facing slopes (i.e., poleward). These predictions are in accord with observations.

Treiman, Allan H.↗

Geologic Evolution of the Martian Dichotomy in the Ismenius Area of Mars and Implications for Plains Magnetization

The origin of the Martian dichotomy, which divides highlands from lowlands, is unknown. We examine a section of the dichotomy ( 50 - 90E) defined by steep scarps and normal faults. Stratigraphy and age relationships preclude the formation of the 2.5 km high boundary via erosion. The abrupt disappearance of topographic knobs similar to 300 - 500 km to the northeast is interpreted as a buried fault. Alignment of the buried fault with grabens, stratigraphy, and age determinations using crater counts indicate that the lowland bench is down faulted highlands crust. The estimated local strain (3.5%) and fault pattern are broadly consistent with gravitational relaxation of a plateau boundary. Magnetic and gravity anomalies occur on either side of the buried fault. Admittance analysis indicates isostatic compensation. Although nonunique, a model with a 10 km thick intracrustal block under the lowland bench, a 20 km thick block under the plains, and an excess density of 200 kg/m(3) provides a good fit to the isostatic anomaly. A good fit to a profile of the magnetic field perpendicular to the dichotomy is produced using uniformly polarized intracrustal blocks 10 - 20 km thick, an intensity of 6 Am/m, a field inclination of -30 degrees, and gaps aligned with the isostatic anomalies. One interpretation is that high-density intrusions demagnetized the crust after dynamo cessation and that low-lying magnetized areas could be down faulted highlands crust. Another model (inclination of 30 degrees) has magnetized crust beneath the isostatic anomalies, separated by gaps. The gaps could result from hydrothermal alteration of the crust along fault zones.

faulting↗

Petrologic and age relations of the Apollo 16 rocks - Implications for subsurface geology and the age of the Nectaris basin

In connection with its proximity to the Nectaris basin, the Apollo 16 site is the prime lunar sampling site for dating the Nectaris impact. It is found that the Ar-40/Ar-39 data set upper limits on the time of formation of the major types of breccia at the Apollo 16 site. These are 3.92 b.y. for the feldspathic fragmental breccias, and 3.92 b.y. for the dimict breccias. The data establish that the major subsurface units at the site were deposited no longer than 3.92 b.y. ago. Recent developments indicate that the bulk of the material at the site probably has Nectarian or pre-Nectarian ages. An age of 3.9 b.y. must be a rough upper limit to the age of the Nectaris impact. This limit must be verified by additional studies.

James, O. B.↗

Nanopore facilitated monohydrocalcitic amorphous calcium carbonate precipitation

Predicting the precipitation of solids is important in both natural systems and subsurface energy applications. The factors controlling reaction mechanisms, phase selection and conversion between phases are particularly important. In this contribution the precipitation and growth of an amorphous calcium carbonate species from flowing aqueous solution in a nanoporous controlled pore glass is followed in situ with differential X-ray pair distribution function analysis. It is discovered that the local atomic structure of this phase indicates monohydrocalcite-like pair–pair correlations, yet is functionally amorphous because it lacks long-range structure. The unexpected occurrence of synthetic proto-monohydrocalcite amorphous calcium carbonate, precipitated from a solution undersaturated with respect to published solubilities, suggests that nanopore confinement facilitates formation of an amorphous phase at the expense of more favorable crystalline ones. Finally, this result illustrates that confinement and interface effects are physical factors exerting control on mineral nucleation behavior in natural and geological systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Geology and Design of Major Spent Fuel Repositories

This report summarizes the geology and design concepts of four major spent fuel repositories from around the world. The crystalline rock with bentonite backfill is currently implemented in Finland with another repository being constructed in Sweden. The salt formation design focuses on the Waste Isolation Pilot Plant (WIPP) repository in the United States. The volcanic tuff open air design is based on the Yucca Mountain location. The volcanic tuff open air design at Yucca Mountain is only a concept as this repository has not been approved for operations. The last spent fuel repository design, clay/shale formation with backfill, focuses on the Cigeo Project in France, which is also pending.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Enhanced Recovery Opportunities in the Appalachian Basin

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO2) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. The Appalachian Basin Geoteam consists of geologists from the state geological surveys of Kentucky, Maryland, New York, Ohio, Pennsylvania, and West Virginia. Pennsylvania and West Virginia led the research related to enhanced recovery opportunities in oil and gas fields, while Kentucky led the work associated with enhanced gas recovery (EGR) opportunities in organic-rich shales. The Appalachian Basin Geoteam evaluated reservoirs amenable to CO2-EOR and EGR using a combination of data sources and technical approaches. The Geoteam characterized the subsurface geology of the area in stepwise fashion, starting with existing geologic maps and fields/pools data generated as part of previous MRCSP regional characterization research. With this data, the Geoteam correlated stratigraphy and generated cross sections to delineate the extent, depths and thicknesses of those formations that may serve as reservoirs for either miscible or immiscible enhanced recovery projects. In addition, the team prepared structure and isopach maps for prospective formations, as well as assessments of gross and net porosity of these units. Once prospective localities were identified, the Geoteam selected a short list of oil fields in each of the three states for assessment for case study preparation.

01 COAL, LIGNITE, AND PEAT↗

Occurrences of REE and CM in volcanic ash beds associated with coals in SW Wyoming & NW Colorado

Rare earth elements (REEs) and critical minerals (CMs) are vital components in the nation’s economy, national security, and the further strengthening of our renewable energy capabilities and infrastructure. Recent work has revealed more insight into previously unknown modes of occurrence for REEs, particularly in coal seams and adjacent noncoal sediments, but many data gaps persist. Temporal relationships between coal beds and adjacent tonstiens, ash beds, or other partings are widely recognized but not fully understood. Variations in REE concentration and their direct or indirect association with coal beds are not predictable. This study presents findings from examining lateral and potentially stratigraphic variation of REE and CM occurrences in coals of late Cretaceous and Paleocene age. In this study we collected and examined samples of differing ages both core and coal mine exposures for qualitative x-ray fluorescence (XRF), and multi-element geochemistry. Preliminary XRF data indicates variable levels of light REEs in a core from the Yampa coalfield of Moffat County in northwest Colorado. An absence of similar enrichments in slightly older coals in the Adaville Formation of the Fold and Thrust belt in southwest Wyoming is described from XRF and ICP-MS evaluation. Previous work has shown an association with the Yampa Bed and REE enrichment in coals of the Upper Cretaceous Williams Fork Formation. While not common and widespread, this association suggests that leaching or reworking of the ash bed could lead to elevated REEs in the adjacent coal. We investigate differences between the two data occurringas geologic compositions and post-depositional histories. In-depth petrography and precise geochemistry should reveal data that at the very least will help improve some aspects of the geologic models of coal basins and the effect of an influx of non-coal sediments.

REE, CM, ash, volcanic ash, coal↗

The evolution of the moon and the terrestrial planets

The thermal evolutions of the Moon, Mars, Venus and Mercury are calculated theoretically starting from cosmochemical condensation models. An assortment of geological, geochemical and geophysical data are used to constrain both the present day temperatures and the thermal histories of the planets' interiors. Such data imply that the planets were heated during or shortly after formation and that all the terrestrial planets started their differentiations early in their history. The moon, smallest in size, is characterized as a differentiated body with a crust, a thick solid mantle and an interior region which may be partially molten. Mars, intermediate in size, is assumed to have differentiated an Fe-FeS core. Venus is characterized as a planet not unlike the earth in many respects. Core formation has occurred probably during the first billion years after the formation. Mercury, which probably has a large core, may have a 500 km thick solid lithosphere and a partially molten core if it is assumed that some heat sources exist in the core.

Toksoez, M. N.↗

The evolution of the moon and the terrestrial planets

The thermal evolutions of the Moon, Mars, Venus, and Mercury were calculated theoretically starting from cosmochemical condensation models. An assortment of geological, geochemical, and geophysical data were used to constrain both the present day temperature and the thermal histories of the planets' interiors. Such data imply that the planets were heated during or shortly after formation and that all the terrestrial planets started their differentiations early in their history.

Toksoez, M. N.↗

Hadley Rille, lava tubes and mare volcanism at the Apollo 15 site

Hadley Rille appears to be a collapsed lava tube/channel, whose formation history may be more intimately related to the mare units sampled at 15 than was previously thought. More work is needed relating samples and observations from Apollo 15 to the rille and its geologic evolution. As the only sinuous rille visited during the Apollo missions, Hadley Rille represents a data source that is directly applicable to the deciphering of processes involved in lunar mare volcanism.

Greeley, R.↗