Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Gas phase”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 847 records · Page 47
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

A kinetic study of the interaction between atomic oxygen and aerosols

This study was concerned with the effects of NH4Cl and (NH4)2SO4 aerosols on the kinetics of disappearance of atomic oxygen. Atomic oxygen was generated by a 2.45-GHz microwave discharge and the kinetics of disappearance measured in a fast flow system using NO2 titration. Values of the recombination coefficient for heterogeneous wall recombination were determined for clean, H2SO4-coated, and (NH4)2SO4-coated Pyrex to be 0.000050, 0.000020, and 0.000019, respectively. A rapid exothermic chemical reaction was found to occur between atomic oxygen and an NH4Cl wall coating; the products were NH3, NO, H2O, and HCl. The NH4Cl aerosol was generated by gas phase reaction of NH3 with HCl. The aerosol particles were approximately spherical and nearly monodisperse with a mean diameter of 1.6 plus or minus 0.2 micron. The rate constant for the disappearance of atomic oxygen in the presence of NH4Cl aerosol was measured. No significant decrease was observed in the rate of disappearance of atomic oxygen in the presence of an (NH4)2SO4 aerosol at a concentration of 285 mg per cu m.

Akers, F. I.↗
NASA NTRS1976

An analysis of the interstellar material in the line of sight toward Omicron Persei

Chemical abundances and physical conditions in the interstellar gas toward Omicron Per are analyzed using Copernicus UV spectrophotometric data on 69 lines due to ions and atoms as well as 19 lines of H2 and HD. The UV extinction toward the star is determined along with the column densities of atomic and molecular hydrogen, the atomic column densities and temperature in the H I region, and the nature of the ionized regions along the line of sight. It is concluded that: (1) Omicron Per is apparently embedded in the near edge of an extended dense molecular cloud, the outer parts of which give rise to the observed absorption lines; (2) the H I region may consist of more than one cloud; (3) the far-UV extinction rise is unusually steep, indicating a high proportion of small grains; (4) the element depletions are somewhat greater than in Zeta Oph, particularly for sulfur and argon; and (5) the molecular abundances are generally consistent with gas-phase formation models rather than with molecular formation on grain surfaces, unless a substantial amount of small grains is present to increase the available surface area.

Snow, T. P., Jr.↗
NASA NTRS1976

Abundances of simple oxygen-bearing molecules and ions in interstellar clouds

The abundances of simple oxygen-bearing interstellar molecules in warm (T at least 40 K), diffuse, and moderately thick clouds are calculated on the basis of binary gas-phase reactions. The most important reactions are ion-molecule, charge-exchange, and dissociative-recombination reactions, as suggested mainly by earlier workers. The progenitor of these molecules in diffuse clouds is the cosmic-ray-produced H(+) ion, working through the charge-exchange reaction with O. The ionization of H(+) and He(+) is also discussed. Dissociative charge exchange of He(+) with H2 is an important source of H(+) in regions of large fractional abundance of H2, as well as an important destruction mechanism for He(+) even for small f (at least 0.1). The calculated molecular abundances are consistent with some of the available observational information.

Glassgold, A. E.↗
NASA NTRS1976

Observations of heavy-element recombination lines in the Rho Ophiuchi dark cloud at 13 centimeters wavelength

High-sensitivity observations at the carbon 140-alpha and 141-alpha recombination-line frequencies in the direction of the Rho Oph dust cloud show the presence of recombination lines of carbon and sulfur, but not of other heavy elements. These results require that the elements Si, Fe, and Mg are depleted by factors greater than 15, 10, and 2, respectively, most likely into interstellar grains, whereas sulfur is undepleted. They also require that only approximately one-sixth of the carbon is present in the gas phase in the cloud. From the observed size of the C II region together with the observed carbon depletion, it is inferred that the density in the carbon-line-emitting region is 25,000 per cu cm and that the size of the S II region is significantly larger than that of the C II region. The agreement between the widths of the recombination lines (which arise in a small region of the cloud) and those of the more widely distributed molecular species suggests that the lines in this cloud are broadened by microturbulence on a scale of much less than 0.1 pc.

Knapp, G. R.↗
NASA NTRS1976

Time scales for molecule formation by ion-molecule reactions

Analytical solutions are obtained for nonlinear differential equations governing the time-dependence of molecular abundances in interstellar clouds. Three gas-phase reaction schemes are considered separately for the regions where each dominates. The particular case of CO, and closely related members of the Oh and CH families of molecules, is studied for given values of temperature, density, and the radiation field. Nonlinear effects and couplings with particular ions are found to be important. The time scales for CO formation range from 100,000 to a few million years, depending on the chemistry and regime. The time required for essentially complete conversion of C(+) to CO in the region where the H3(+) chemistry dominates is several million years. Because this time is longer than or comparable to dynamical time scales for dense interstellar clouds, steady-state abundances may not be observed in such clouds.

Langer, W. D.↗
NASA NTRS1976

Refinement of Promising Coating Compositions for Directionally Cast Eutectics

The successful application of high creep strength, directionally solidified gamma/gamma prime-delta (Ni-19.7Cb-6Cr-2.5Al) eutectic superalloy turbine blades requires the development of suitable coatings for airfoil, root and internal blade surfaces. In order to improve coatings for the gamma/gamma prime-delta alloy, the current investigation had the goals of (1) refining promising coating compositions for directionally solidified eutectics, (2) evaluating the effects of coating/ substrate interactions on the mechanical properties of the alloy, and (3) evaluating diffusion aluminide coatings for internal surfaces. Burner rig cyclic oxidation, furnace cyclic hot corrosion, ductility, and thermal fatigue tests indicated that NiCrAlY+Pt(63 to 127 micron Ni-18Cr-12Al-0.3Y + 6 micron Pt) and NiCrAlY(63 to 127 micron Ni-18Cr-12Al-0.3Y) coatings are capable of protecting high temperature gas path surfaces of eutectic alloy airfoils. Burner rig (Mach 0.37) testing indicated that the useful coating life of the 127 micron thick coatings exceeded 1000 hours at 1366 K (2000 deg F). Isothermal fatigue and furnance hot corrosion tests indicated that 63 micron NiCrAlY, NiCrAlY + Pt and platinum modified diffusion aluminide (Pt + Al) coating systems are capable of protecting the relatively cooler surfaces of the blade root. Finally, a gas phase coating process was evaluated for diffusion aluminizing internal surfaces and cooling holes of air-cooled gamma/gamma prime-delta turbine blades.

Strangman, T. E.↗
NASA NTRS1977

Apparatus for photon excited catalysis

An apparatus is described for increasing the yield of photonically excited gas phase reactions by extracting excess energy from unstable, excited species by contacting the species with the surface of a finely divided solid.

Saffren, M. M.↗
NASA NTRS1977

Burner rig alkali salt corrosion of several high temperature alloys

The hot corrosion of five alloys was studied in cyclic tests in a Mach 0.3 burner rig into whose combustion chamber various aqueous salt solutions were injected. Three nickel-based alloys, a cobalt-base alloy, and an iron-base alloy were studied at temperatures of 700, 800, 900, and 1000 C with various salt concentrations and compositions. The relative resistance of the alloys to hot corrosion attack was found to vary with temperature and both concentration and composition of the injected salt solution. Results indicate that the corrosion of these alloys is a function of both the presence of salt condensed as a liquid on the surface and of the composition of the gas phases present.

Deadmore, D. L.↗
NASA NTRS1977

Sputtering in interstellar shocks - A model for heavy element depletion

High-velocity (at least 100 km/s) shock fronts are found to provide an environment where grains can be destroyed by thermal sputtering. Application is made to supernova remnants. Sputtering of refractory grains in shocks associated with high-velocity clouds leads to cosmic abundances of heavy elements and if followed by deceleration of the high-velocity gas and dilution with ambient depleted matter. A correlation of depletion with systematic velocity is predicted. It is proposed that there is a residual underlying depletion associated with refractory grain formation and a subsequent trapping of gas-phase metallic species by adsorption. Sputtering of adsorbed monolayers in intermediate-velocity shocks (not exceeding 50 km/s) can account for a range of depletions in diffuse interstellar matter.

Barlow, M. J.↗
NASA NTRS1977

Isotopic abundance of CO in interstellar clouds

The fractional abundances of the isotopic species of carbon monoxide in interstellar clouds are calculated on a basis of gas-phase ion-molecule reactions. The (C-13)O/(C-12)O ratio varies significantly with extinction of the ultraviolet radiation field, and in the outer regions of dark dense clouds (C-13)O may be enhanced by a factor of 10. The observational interpretation of the CO to H2 or interstellar-reddening relation and the isotopic abundances of carbon are complicated by these effects.

Langer, W. D.↗
NASA NTRS1976

Equilibrium and disequilibrium chemistry of adiabatic, solar-composition planetary atmospheres

The impact of atmospheric and cloud-structure models on the nonequilibrium chemical behavior of the atmospheres of the Jovian planets is discussed. Quantitative constraints on photochemical, lightning, and charged-particle production of organic matter and chromophores are emphasized whenever available. These considerations imply that inorganic chromophore production is far more important than that of organic chromophores, and that lightning is probably a negligibly significant process relative to photochemistry on Jupiter. Production of complex molecules by gas-phase disequilibrium processes on Saturn, Uranus, and Neptune is severely limited by condensation of even simple intermediates.

Lewis, J. S.↗
NASA NTRS1976

Interagency comparison of iodometric methods for ozone determination

The California Air Resources Board appointed an Oxidant Calibration Committee for the purpose of evaluating the accuracy of the different agency calibration procedures. The committee chose UV absorption photometry as the reference method for ozone measurement. Interagency comparisons of the various iodometric methods were conducted relative to the ultraviolet standard. The tests included versions of the iodometric methods as employed by the Air Resources Board, the Los Angeles Air Pollution Control District, and the EPA. An alternative candidate reference method for ozone measurement, gas phase titration, was also included in the test series.

Demore, W. B.↗
NASA NTRS1977

Observations and interpretation of the infrared spectrum of HD 44179

Infrared spectra of HD 44179 have been obtained for the 3040-, 1150-, and 890-kayser emission features. The strengths of the features put constraints on the possible constituents of the materials responsible for each emission feature. The 3040-kayser feature can be due to emission either from a solid (if it arises from a different region than the 890-kayser feature) or from a gas-phase molecule. The 8-13-micron spectrum is fitted with a simple model employing carbonates plus a dielectric in emission and silicates in absorption. It is suggested that amorphous carbon is the dielectric responsible for the featureless underlying continuum.

Bregman, J. D.↗
NASA NTRS1977

Flash photolysis resonance fluorescence investigation of the reaction of Cl/2P/ atoms with ClONO2

Rate constants for the removal of Cl(2P) atoms by homogeneous gas phase reaction with ClONO2 were measured using the flash photolysis resonance fluorescence technique at 224, 250, and 273 K. The values obtained have been used to derive the above Arrhenius equation. The uncertainties expressed are 95% confidence limits obtained using the statistical standard deviation of the individual rate constants plus a 15% additional estimated uncertainty attributed to difficulties in chlorine nitrate concentration measurements. The results indicate that destruction of chlorine nitrate by reaction with chlorine atoms is perhaps the least important of the atmospheric reactive channels, and is at least three orders of magnitude slower than calculated photodissociation rates at all stratospheric altitudes.

Kurylo, M. J.↗
NASA NTRS1977

Laboratory studies of lean combustion

The fundamental processes controlling lean combustion were observed for better understanding, with particular emphasis on the formation and measurement of gas-phase pollutants, the stability of the combustion process (blowout limits), methods of improving stability, and the application of probe and optical diagnostics for flow field characterization, temperature mapping, and composition measurements. The following areas of investigation are described in detail: (1) axisymmetric, opposed-reacting-jet-stabilized combustor studies; (2) stabilization through heat recirculation; (3) two dimensional combustor studies; and (4) spectroscopic methods. A departure from conventional combustor design to a premixed/prevaporized, lean combustion configuration is attractive for the control of oxides of nitrogen and smoke emissions, the promotion of uniform turbine inlet temperatures, and, possibly, the reduction of carbon monoxide and hydrocarbons at idle.

Sawyer, R. F.↗
NASA NTRS1977

Effect of trichlorofluoromethane and molecular chlorine on ozone formation by simulated solar radiation

Mixtures of air with either Cl2 or CFCl3 were photolyzed in a reaction chamber by simulated solar radiation. Ozone formation was temporarily inhibited by Cl2 and permanently inhibited by CFCl3. A chemical mechanism including gas phase and wall reactions is proposed to explain these results. The CFCl3 is assumed to be adsorbed on the chamber walls and to poison the sites for Cl destruction.

Bittker, D. A.↗
NASA NTRS1976

Stability of water on the Galilean satellites

The selective loss of water from Io under currently prevailing physical conditions was studied to determine whether a large quantity of water can be lost from the satellite over the lifetime of the solar system. Loss processes considered include: thermal escape, photolysis, sputtering, and gas-phase charged particle interactions.

Pilcher, C. B.↗
NASA NTRS1978

Growth of single crystals by vapor transport in zero-gravity environment, ground-based experiments

Mass and heat transfer phenomena associated with the growth of single crystals by chemical vapor transport reactions were investigated. In this technique, a gaseous transport agent reacts with the solid source material to form exclusively gaseous products. The gas phase species migrate from the source to the condensation zone of the closed reaction ampoule where the reverse reaction occurs with formation of single crystals. The necessary concentration gradient is achieved by means of a temperature gradient.

Wiedemeier, H.↗