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At least 847 records · Page 47

Analysis of opposed-jet hydrogen-air counter flow diffusion flame

An opposed-jet counterflow diffusion-flame configuration is considered for the analysis of a nitrogen-diluted hydrogen-air diffusion flame. A boundary-layer similarity solution is employed in order to reduce the governing equations to a set of equations in one independent variable. The equation set is written in the time-dependent form and solved by the finite-volume time-marching technique. This model uses detailed chemistry and accounts for the variations of Prandtl number and Lewis number as well as the effect of thermal diffusion on the flame. It is noted that a one-step model can predict several features of the flame, while the detailed-chemistry model can be used for fine-tuning the results. The present results indicate that thermal diffusion has negligible effect on the characteristics of the flame.

Ho, Y. H.↗

Geometry of premixed flames in three-dimensional turbulence

Constant density premixed flame propagation in three dimensional Navier-Stokes turbulence has been simulated. The zero-thickness flame model of Kerstein has been used. There are two aspects to this study: (1) adjustment of the large-scale strain rate in order to achieve a constant energy system; and (2) determination of flame curvature. The sampled distribution of curvature indicates that in most cases the flame has a cylindrical shape, with one curvature at least three times larger than the other. This implies that realistic chemical reactions in a flame-vortex interaction may be simulated in two dimensions.

Ashurst, William T.↗

Opposed-flow flame spread with implications for combustion at microgravity

Various regimes of the flame spread phenomenon in an opposing flow environment are classified here depending on the mechanism of flame spread. Simple analyses of energy balances at the tip of the flame are used to complement more sophisticated numerical analysis of the field problem associated with flame spreading in microgravity. The microgravity flames are shown to constitute a separate regime or class by themselves and are discussed in some detail.

Altenkirch, Robert A.↗

Saturated fluorescence measurements of the hydroxyl radical in laminar high-pressure C2H6/O2/N2 flames

Saturation of a transition of the OH molecule in high-pressure flames is demonstrated by obtaining saturation curves in C2H6/O2/N2 laminar flames at 1, 6.1, 9.2, and 12.3 atm. Quantitative fluorescence measurements of OH number density at pressures to 12.3 atm are presented. To assess the efficacy of the balanced cross-rate model for high-pressure flames, laser-saturated fluorescence measurements, which were calibrated in an atmospheric-pressure flame, are compared with absorption measurements at 3.1 and 6.1 atm. At 3.1 atm the absorption and fluorescence measurements compare well. At 6.1 atm, however, the concentrations given by lasre-saturated fluorescence are about 25 percent lower than the absorption values, indicating some depletion of the laser-coupled levels beyond that at atmospheric pressure. By using a reasonable estimate for the finite sensitivity to quenching, it is anticipated that fluorescence measurements that are calibrated at 1 atm can be applied to flames at about 10 atm with absolute errors within +/- 50 percent.

Carter, Campbell D.↗

Structure and Soot Properties of Non-Buoyant Laminar Round-Jet Diffusion Flames

The structure and soot properties of nonbuoyant laminar diffusion flames are being studied experimentally and theoretically in order to better understand the soot and thermal radiation emissions from luminous flames. The measurements involve weakly-buoyant flames at low pressure in normal gravity (ng) and nonbuoyant flames at normal pressures in microgravity (micro g). The objectives of the present investigation are to study the differences of soot properties between nonbuoyant and buoyant diffusion flames, and to evaluate predictions based on the laminar flamelet approach.

Mortazavi, Saeed↗

Analysis of Lewis Number Effects in Flame Spread

De Ris's formulation of the problem of flame spread over thin and thick solid fuel surfaces is extended to include the influence of nonunity Lewis numbers of oxidant and fuel vapors. A zeroth order formula for the flame spread velocity is deduced. To this order of approximation, the Lewis number of the oxidant affects the spread rate only through its effect on the flame temperature and the fuel Lewis number plays no role at all. Thin fuel predictions are compared with experiments on flame spread over thin paper samples in a variety of O2-diluent atmospheres. Good agreement between theory and experiment supports the theory and indicates that unity Lewis number assumptions can lead to rather inaccurate spread rate and flame temperature predictions.

Greenberg, J. B.↗

Experiments on stability of Bunsen-burner flames for turbulent flow

The results of a study of the stability of propane-air flames on Bunsen-burner tubes are presented. Fuel-air ratio, tube diameter, and Reynolds number were the primary variables. Regions of stability are outlined in plots of fuel-air ratio as a function of Reynolds number for flames seated on the burner lip and for flames suspended well above the burner. For fully developed flow, turbulent as well as laminar, the velocity gradient at the burner wall is a satisfactory variable for correlating the fuel-air ratio required for blow-off of seated flames for fuel-air ratios of less than 15 percent. For turbulent flames, wall velocity serves as a correlating variable in the same fuel-air ratio range.

Bollinger, Lowell M↗

Flame Speeds of Methane-Air, Propane-Air, and Ethylene-Air Mixtures at Low Initial Temperatures

Flame speeds were determined for methane-air, propane-air, and ethylene-air mixtures at -73 C and for methane-air mixtures at -132 C. The data extend the curves of maximum flame speed against initial mixture temperature previously established for the range from room temperature to 344 C. Empirical equations for maximum flame speed u(cm/ sec) as a function of initial mixture temperature T(sub O) were determined to be as follows: for methane, for T(sub O) from 141 to 615 K, u = 8 + 0.000160 T(sub O)(exp 2.11); for propane, for T(sub O) from 200 to 616 K, u = 10 + 0.000342 T(sub O)(exp 2.00); for ethylene, for T(sub O) from 200 to 617 K, u = 10 + 0.00259 T(sub O)(exp 1.74). Relative flame speeds at low initial temperatures were predicted within approximately 20 percent by either the thermal theory as presented by Semenov or by the diffusion theory of Tanford and Pease. The same order was found previously for high initial temperatures. The low-temperature data were also found to extend the linear correlations between maximum flame speed and calculated equilibrium active-radical concentrations, which were established by the previously reported high-temperature data.

Dugger, Gordon L↗

Some Effects of Small-scale Flow Disturbance on Nozzle-burner Flames

Laminar-like and brush-like propane-air flames were obtained when wire grids were used as turbulence generators in a 1/2-inch nozzle burner. The laminar-like flames for grid-disturbed flow had a slightly higher burning velocity than "true" laminar flames (no grid used). The brush-like flames were similar to those obtained with pipe turbulent flow. Their burning-velocity dependence on a "flow disturbance" Reynolds number compared favorably with that obtained for pipe turbulent flames. Hot-wire-anemometer equipment was used to measure the flow disturbance intensity in the cold flow with and without the grids in place.

COMBUSTION, TURBULENT-FLOW↗

Effect of water on carbon monoxide-oxygen flame velocity

The flame velocities were measured of 20 percent oxygen and 80 percent carbon monoxide mixtures containing either light water or heavy water. The flame velocity increased from 34.5 centimeters per second with no added water to about 104 centimeters per second for a 1.8 percent addition of light water and to 84 centimeters per second for an equal addition of heavy water. The addition of heavy water caused greater increases in flame velocity with equilibrium hydrogen-atom concentration than would be predicted by the Tanford and Pease square-root relation. The ratio of the flame velocity of a mixture containing light water to that of a mixture containing heavy water was found to be 1.4. This value is the same as the ratio of the reaction rate of hydrogen to that of deuterium and oxygen. A ratio of reaction rates of 1.4 would also be required for the square-root law to give the observed ratio of flame-velocity changes.

Mcdonald, Glen E↗

Experiments on Stability of Bunsen-Burner Flames for Turbulent Flow

The results of a study of the stability of propane-air flames on bunsen-burner tubes are presented. Fuel-air ratio, tube diameter, and Reynolds number were the primary variables. Regions of stability are outlined in plots of fuel-air ratio as a function of Reynolds number for flames seated on the burner lip and for flames suspended well above the burner. For fully developed flow, turbulent as well as laminar, the velocity gradient at the burner wall is a satisfactory variable for correlating the fuel-air ratio required for blow-off of seated flames for fuel-air ratios of less than 15 percent. For turbulent flames, wall velocity serves as a correlating variable in the same fuel-air-ratio range. (author)

Bollinger, Lowell M↗

Effect of Initial Mixture Temperature on Flame Speed of Methane-Air, Propane-Air, and Ethylene-Air Mixtures

Flame speeds based on the outer edge of the shadow cast by the laminar Bunsen cone were determined as functions of composition for methane-air mixtures at initial mixture temperatures ranging from -132 degrees to 342 degrees c and for propane-air and ethylene-air mixtures at initial mixture temperatures ranging from -73 degrees to 344 degrees c. The data showed that maximum flame speed increased with temperature at an increasing rate. The percentage change in flame speed with change in initial temperature for the three fuels followed the decreasing order, methane, propane, and ethylene. Empirical equations were determined for maximum flame speed as a function of initial temperature over the temperature range covered for each fuel. The observed effect of temperature on flame speed for each of the fuels was reasonably well predicted by either the thermal theory as presented by Semenov or the square-root law of Tanford and Pease.

Dugger, Gordon L↗

Study and modeling of finite rate chemistry effects in turbulent non-premixed flames

The development of numerical models that reflect some of the most important features of turbulent reacting flows requires information about the behavior of key quantities in well defined combustion regimes. In turbulent flames, the coupling between turbulent and chemical processes is so strong that it is extremely difficult to isolate the role played by one individual physical phenomenon. Direct numerical simulation (hereafter DNS) allows us to study in detail the turbulence-chemistry interaction in some restricted but completely defined situations. Globally, non-premixed flames are controlled by two limiting regimes: the fast chemistry case, where the turbulent flame can be pictured as a random distribution of local chemical equilibrium problems; and the slow chemistry case, where the chemistry integrates in time the turbulent fluctuations. The Damkoehler number, ratio of a mechanical time scale to chemical time scale, is used to distinguish between these regimes. Today most of the industrial computer codes are able to perform predictions in the hypothesis of local equilibrium chemistry using a presumed shape for the probability density function (pdt) of the conserved scalar. However, the finite rate chemistry situation is of great interest because industrial burners usually generate regimes in which, at some points, the flame is undergoing local extinction or at least non-equilibrium situations. Moreover, this variety of situations strongly influences the production of pollutants. To quantify finite rate chemistry effect, the interaction between a non-premixed flame and a free decaying turbulence is studied using DNS. The attention is focused on the dynamic of extinction, and an attempt is made to quantify the effect of the reaction on the small scale mixing process. The unequal diffusivity effect is also addressed. Finally, a simple turbulent combustion model based on the DNS observations and tractable in real flow configurations is proposed.

Vervisch, Luc↗

The Structure and Stability of Laminar Flames

This review paper on the structure and stability of laminar flames considers such phenomena as heterogeneous mixtures, acoustic instabilities, flame balls and related phenomena, radiation effects, the iodate oxidation of arsenous acid and 'liquid flame fronts', approximate kinetic mechanisms and asymptotic approximations, and tribrachial or triple flames. The topics examined here indicate three themes that may play an important role in laminar flame theory in the coming years: microgravity experiments, kinetic modeling, and turbulence modeling. In the discussion of microgravity experiments it is pointed out that access to drop towers, the Space Shuttle and, in due course, the Space Station Freedom will encourage the development of experiments well designed to isolate the fundamental physics of combustion.

Buckmaster, John↗

Flame-vortex interactions imaged in microgravity

The scientific objective is to obtain high quality color-enhanced digital images of a vortex exerting aerodynamic strain on premixed and nonpremixed flames with the complicating effects of buoyancy removed. The images will provide universal (buoyancy free) scaling relations that are required to improve several types of models of turbulent combustion, including KIVA-3, discrete vortex, and large-eddy simulations. The images will be used to help quantify several source terms in the models, including those due to flame stretch, flame-generated vorticity, flame curvature, and preferential diffusion, for a range of vortex sizes and flame conditions. The experiment is an ideal way to study turbulence-chemistry interactions and isolate the effect of vortices of different sizes and strengths in a repeatable manner. A parallel computational effort is being conducted which considers full chemistry and preferential diffusion.

Driscoll, James F.↗

Influence of a Simple Heat Loss Profile on a Pure Diffusion Flame

The presence of soot on the fuel side of a diffusion flame results in significant radiative heat losses. The influence of a fuel side heat loss zone on a pure diffusion flame established between a fuel and an oxidizer wall is investigated by assuming a hypothetical sech(sup 2) heat loss profile. The intensity and width of the loss zone are parametrically varied. The loss zone is placed at different distances from the Burke-Schumann flame location. The migration of the temperature and reactivity peaks are examined for a variety of situations. For certain cases the reaction zone breaks through the loss zone and relocates itself on the fuel side of the loss zone. In all cases the temperature and reactivity peaks move toward the fuel side with increased heat losses. The flame structure reveals that the primary balance for the energy equation is between the reaction term and the diffusion term. Extinction plots are generated for a variety of situations. The heat transfer from the flame to the walls and the radiative fraction is also investigated, and an analytical correlation formula, derived in a previous study, is shown to produce excellent predictions of our numerical results when an O(l) numerical multiplicative constant is employed.

Ray, Anjan↗

Effect of chemistry and turbulence on NO formation in oxygen-natural gas flames

The effects of chemistry and turbulence on NO formation in oxygen-natural turbulent diffusion flames gas flames have been investigated. The chemistry of nitric oxides has been studied numerically in the counterflow configuration. Systematic calculations with the GRI 2.11 mechanism for combustion of methane and NO chemistry were conducted to provide a base case. It was shown that the 'simple' Zeldovich mechanism accounts for more than 75% of N2 consumption in the flame in a range of strain-rates varying between 10 and 1000 s-l. The main shortcomings of this mechanism are: 1) overestimation (15%) of the NO production rate at low strain-rates because it does not capture the reburn due to the hydrocarbon chemistry, and 2) underestimation (25%) of the NO production rate at high strainrates because it ignores NO production through the prompt mechanism. Reburn through the Zeldovich mechanism alone proves to be significant at low strain-rates. A one-step model based on the Zeldovich mechanism and including reburn has been developed. It shows good agreement with the GRI mechanism at low strain-rates but underestimates significantly N2 consumption (about 50%) at high strain-rates. The role of turbulence has been assessed by using an existing 3-D DNS data base of a diffusion flame in decaying turbulence. Two PDF closure models used in practical industrial codes for turbulent NO formation have been tested. A simpler version of the global one-step chemical scheme for NO compared to that developed in this study was used to test the closure assumptions of the PDF models, because the data base could not provide all the necessary ingredients. Despite this simplification, it was possible to demonstrate that the current PDF models for NO overestimate significantly the NO production rate due to the fact that they neglect the correlations between the fluctuations in oxygen concentration and temperature. A single scalar PDF model for temperature that accounts for such correlations based on laminar flame considerations has been developed and showed excellent agreement with the values given by the DNS.

Samaniego, J. -M.↗

Turbulent Premixed Flame Propagation in Microgravity

A facility in which turbulent Couette flow could be generated in a microgravity environment was designed and built. To fit into the NASA Lewis drop tower the device had to be very compact. This means that edge effects and flow re-circulation were expected to affect the flow. The flow was thoroughly investigated using LDV and was found to be largely two dimensional away from the edges with constant turbulence intensities in the core. Slight flow asymmetries are introduced by the non symmetric re-circulation of the fluid outside the test region. Belt flutter problems were remedied by adding a pair of guide plates to the belt. In general, the flow field was found to be quite similar to previously investigated Couette flows. However, turbulence levels and associated shear stresses were higher. This is probably due to the confined re-circulation zone reintroducing turbulence into the test section. An estimate of the length scales in the flow showed that the measurements were able to resolve nearly all the length scales of interest. Using a new LES method for subgrid combustion it has been demonstrated that the new procedure is computational feasible even on workstation type environment. It is found that this model is capable of capturing the propagation of the premixed names by resolving the flame in the LES grid within 2-3 grid points. In contrast, conventional LES results in numerical smearing of the flame and completely inaccurate estimate of the turbulent propagation speed. Preliminary study suggests that there is observable effect of buoyancy in the 1g environment suggesting the need for microgravity experiments of the upcoming experimental combustion studies. With the cold flow properties characterized, an identical hot flow facility is under construction. It is assumed that the turbulence properties ahead of the flame in this new device will closely match the results obtained here. This is required since the hot facility will not enable LDV measurements. The reacting flow facility is also being constructed with planned drop tower experiments in mind. Therefore, issues related to safety and structural integrity are being take into account. Further development of the numerical model will also be carried out to include finite-rate kinetics for representative premixed cases. More detail analysis of the flame structure and propagation nature will be investigated. Simulations will also be compared to the flame properties observed in the experiments.

Menon, S.↗