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At least 847 records · Page 47

WCATS: Waste Documentation, Course No. 8504

This course was developed for individuals at Los Alamos National Laboratory (LANL) who characterize and document waste streams in the Waste Compliance and Tracking System (WCATS) according to Environmental Protection Agency (EPA) Department of Transportation (DOT) regulations, Department of Energy Orders, and other applicable criteria. When you have completed this course, you will be able to recognize how waste documentation enables LANL to characterize and classify hazardous waste for compliant treatment, storage, and disposal, identify the purpose of the waste stream profile (WSP), identify the agencies that provide guidance for waste management, and more.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Biogas Opportunities Roadmap Progress Report

In support of the Obama Administration's Climate Action Plan, the U.S. Department of Energy, the U.S. Environmental Protection Agency, and U.S. Department of Agriculture jointly released the Biogas Opportunities Roadmap Progress Report, updating the federal government's progress to reduce methane emissions through biogas systems since the Biogas Opportunities Roadmap was completed by the three agencies in July 2014. The report highlights actions taken, outlines challenges and opportunities, and identifies next steps to the growth of a robust biogas industry.

09 BIOMASS FUELS↗

KIVA-hpFE. Predictive turbulent reactive and multiphase flow in engines - An Overview

Research and development of KIVA-hpFE for turbulent reactive and multiphase flow particularly as related to engine modeling program has relevance to National energy security and climate change. Climate change is a source problem, and energy national security is consumption of petroleum products problem. Accurately predicting engine processes leads to, lower greenhouse gas (GHG) emission, where engines in the transportation sector currently account for 26% of the U.S. GHG emissions. Less dependence on petroleum products leads to greater energy security. By Environmental Protection Agency standards, some vehicles are now reaching 42 to the 50 mpg mark. These are conventional gasoline engines. Continued investment and research into new technical innovations, the potential exists to save more than 4 million barrels of oil per day or approximately $200 to $400 million per day. This would be a significant decrease in emission and use of petroleum and a very large economic stimulus too! It is estimated with further advancements in combustion, the current emissions can be reduced up to 40%. Enabling better understanding of fuel injection and fuel-air mixing, thermodynamic combustion losses, and combustion/emission formation processes enhances our ability to help solve both problems. To provide adequate capability for accurately simulating these processes, minimize time and labor for development of engine technology, are the goals of our KIVA development program.

33 ADVANCED PROPULSION SYSTEMS↗

Annual Energy Outlook 2016 With Projections to 2040

The Annual Energy Outlook 2016 (AEO2016), prepared by the U.S. Energy Information Administration (EIA), presents long-term projections of energy supply, demand, and prices through 2040. The projections, focused on U.S. energy markets, are based on results from EIA’s National Energy Modeling System (NEMS). NEMS enables EIA to make projections under alternative, internally consistent sets of assumptions. The analysis in AEO2016 focuses on the Reference case and 17 alternative cases. EIA published an Early Release version of the AEO2016 Reference case (including U.S. Environmental Protection Agency’s (EPA) Clean Power Plan (CPP)) and a No CPP case (excluding the CPP) in May 2016.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Idling Reduction for Long-Haul Trucks: An Economic Comparison of On-Board and Wayside Technologies

Reducing the idling of long-haul heavy-duty trucks has long been recognized as a particularly low-hanging fruit of fuel efficiency and emissions reduction. The displacement of about 10 hours of diesel idling every day, for most days of the year, for as many as a million long-haul trucks has very clear benefits. This report considers the costs and return on investment (ROI) for idling reduction (IR) equipment for both truck owners and electrified parking space (EPS) equipment owners. For the truck owners, the key variables examined are idling hours to be displaced (generally 1,000 to 2,000 hours per year) and the price of fuel ($0 to $5/gal). The ideal IR option would provide complete services in varied climates in any location and offer the best ROI on trucks that log many idling hours. For trucks that have fewer idling hours, options with a fixed cost per hour (i.e., EPS) might be most attractive if they were available to all, or even most, truck drivers. EPS, however, is particularly cost effective for trucks on prescribed routes with a need for regular, extended stops at terminals. (EPS is also called truck stop electrification, or TSE.) The analysis shows that all IR options save money when fuel costs more than $2/gal. For trucks requiring bunk heat, a simple heater (plug-in or diesel) is almost always the most costeffective way to provide heat, even if the truck is equipped with an auxiliary power unit (APU) or is parked at a single-system EPS location. For trucks requiring bunk air-conditioning, the use of single-system EPS is most cost effective for those logging fewer idling hours. Even for trucks with higher idling hours, the cost of EPS may be about the same as that for on-board air-conditioning. Clearly, trucks’ locations and seasonal factors—and the availability of EPS— are significant in the choice of “best fit” IR equipment for truck owners. This report also considers costs and payback for owners of EPS infrastructure. An industry that 5 years ago had at least five players has been narrowed to two companies—one in single-system EPS (IdleAir) and the other in dual-system EPS (Shorepower Technologies). Use of EPS by truck drivers has not met initial expectations for a variety of reasons. One area where EPS has particular promise, however, is in the cost-effective provision of reliable air-conditioning. This analysis is focused strictly on cost and fuel savings; it does not consider the important benefits of reduced emissions (i.e., greenhouse gases and criteria pollutants). It is important to note that all IR options provide some emissions benefits. Even where an IR option may not have a rapid ROI, the emissions-reduction benefit may be considerable. Finally, as the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Transportation’s National Highway Traffic Safety Administration (NHTSA) set stricter standards to reduce greenhouse gas emissions and improve the fuel efficiency of medium- and heavy-duty vehicles, the emissions benefits of IR strategies will become increasingly important.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Final Report of a CRADA Between Pacific Northwest National Laboratory and Cummins, Incorporated (CRADA No.PNNL/283): “Enhanced High and Low Temperature Performance of NO x Reduction Catalyst Materials”

The NO x Storage-Reduction (NSR, also known as lean-NO x trap – LNT), is based upon the concept of storing NO x as nitrates over storage components, typically barium species, during a lean-burn operation cycle and then reducing the stored nitrates to N 2 during fuel-rich conditions over a precious metal catalyst [1]. NO x Selective Catalytic Reduction (SCR), on the other hand, is accomplished by deliberately introducing reductant urea into the engine exhaust to reduce NO x with the aid of a Cu(Fe)/zeolite catalyst [2]. These two technologies have been recognized as the most promising approaches for meeting stringent NO x emission standards for diesel vehicles within the Environmental Protection Agency’s (EPA’s) 2007/2010 mandated limits. For NSR, problems arising from either or both thermal and SO 2 deactivation must be addressed to meet durability standards. For SCR, SO 2 deactivation is less of an issue, but hydrothermal deactivation of the zeolite catalysts must be addressed. With continuing R&D efforts in advanced powertrains, highly novel operating modes for internal combustion engines (ICEs) are being researched in order to meet the very stringent new demands for fuel efficiency (e.g., U.S. ‘‘CAFE’’ standards for average miles/gallon are scheduled to increase dramatically over the next 10–15 years). These new ICE engine operation modes, while highly fuel-efficient, result in much lower exhaust temperatures than current engines; temperatures so low that it is hard to imagine how the current catalytic emission control technologies will be able to function. For example, while steady-state operation of the NO x reduction technology at 150 °C may be required, current ‘‘light-off’’ temperatures for CHA-based zeolite catalysts are closer to 200 °C. Therefore, understanding low-temperature limitations in NO x reduction has become one of the most daunting challenges in R&D on new catalyst materials and processes that can effectively eliminate emissions at these quite low exhaust temperatures. This project has two clear focuses: (1) development of potassium-based high-temperature NSR materials, and studying their key causes of deactivation and methods of regeneration. By comparing results obtained on ‘Simple Model’ Pt-K/Al 2 O 3 with ‘Enhanced Model’ Pt-K/ MgAlO x and Pt-K/TiO 2 materials, we have developed an understanding of the role of various additives on the deactivation and regeneration processes. Studies have also been performed on the real commercial samples being used in a Dodge Ram truck with a Cummins diesel emission control system. However, the results about these ‘commercial samples’ will not be covered in this report. Following a brief description of our experimental approach, we will present a few highlights from some of the work performed in this CRADA with more details about these results provided in publications/reports/presentations lists presented at the end of the report. (2) for the Cu and Fe/Chabazite SCR catalysts, since these are so newly developed and references from open literature and industry are nearly absent, our work started from zeolite synthesis and catalyst synthesis methodology development, before research on their low- and high-temperature performance, deactivation, regeneration, etc. was conducted. Again, most work reported here is based on our “model” catalysts synthesized in-house. Work done on the ‘commercial samples’ will not be covered in this report.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Water-Related Power Plant Curtailments: An Overview of Incidents and Contributing Factors

Water temperatures and water availability can affect the reliable operations of power plants in the United States. Data on water-related impacts on the energy sector are not consolidated and are reported by multiple agencies. This study provides an overview of historical incidents where water resources have affected power plant operations, discusses the various data sources providing information, and creates a publicly available and open access database that contains consolidated information about water-related power plant curtailment and shut-down incidents. Power plants can be affected by water resources if incoming water temperatures are too high, water discharge temperatures are too high, or if there is not enough water available to operate. Changes in climate have the potential to exacerbate uncertainty over water resource availability and temperature. Power plant impacts from water resources include curtailment of generation, plant shut-downs, and requests for regulatory variances. In addition, many power plants have developed adaptation approaches to reducing the potential risks of water-related issues by investing in new technologies or developing and implementing plans to undertake during droughts or heatwaves. This study identifies 42 incidents of water-related power plant issues from 2000-2015, drawing from a variety of different datasets. These incidents occur throughout the U.S., and affect coal and nuclear plants that use once-through, recirculating, and pond cooling systems. In addition, water temperature violations reported to the Environmental Protection Agency are also considered, with 35 temperature violations noted from 2012-2015. In addition to providing some background information on incidents, this effort has also created an open access database on the Open Energy Information platform that contains information about water-related power plant issues that can be updated by users.

20 FOSSIL-FUELED POWER PLANTS↗

Proceedings of the 7th US/German Workshop on Salt Repository Research, Design, and Operation.

The 7th US/German Workshop on Salt Repository Research, Design, and Operation was held in Washington, DC on September 7-9, 2016. Over fifty participants representing governmental agencies, internationally recognized salt research groups, universities, and private companies helped advance the technical basis for salt disposal of radioactive waste. Representatives from several United States federal agencies were able to attend, including the Department of Energy´s Office of Environmental Management and Office of Nuclear Energy, the Environmental Protection Agency, the Nuclear Regulatory Commission, and the Nuclear Waste Technical Review Board. A similar representation from the German ministries showcased the covenant established in a Memorandum of Understanding executed between the United States and Germany in 2011. The US/German workshops´ results and activities also contribute significantly to the Nuclear Energy Agency Salt Club repository research agenda.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Soboba Community Energy Solar Project – Phase 1

Since time immemorial the descendants of the Soboba people are those whom have lived on and occupied the land that is presently known as the cities of San Jacinto, Hemet, Valle Vista and Winchester. On June 19, 1883, President Chester Arthur by Executive Order established the Soboba Indian Reservation, a 3,172-acre tract which included the Soboba village and the adjacent hills. The President had limited authority as he was only able to set aside public land for the establishment of a reservation and had no authority to take private land. Thus the Soboba village; cultivated lands and major springs were part of Rancho San Jacinto Viejo and belonged to Matthew Byrne. Today the Soboba Indian Reservation lies in the lower reaches of the San Jacinto Mountains, across the San Jacinto River from the city of San Jacinto. The Soboba Band of Luiseño Indians was awarded a community solar grant through the U.S. Department of Energy. The incorporated cities of San Jacinto and Hemet, and the unincorporated community of Valle Vista border the Reservation. All three of these surrounding communities have experienced tremendous population growth over the past two decades, with slower growth during the recent economic downturn. The Tribal community that benefits from under this grant includes 1,161 enrolled members, the majority of which live on the reservation. Nearly 41% of the enrolled members are youth, age 18 and under. The elders and community leaders value preserving and maintaining the Luiseño and Cahuilla cultures and Tribal structure for future generations. The proposed project was administered from the Tribal Administration offices located on the reservation. The Soboba Tribal Government consists of five Tribal Members who are elected by the general membership to Tribal Council for a staggered two year term. The Chairman/Chairwoman is elected by a majority vote of the general membership but the positions for Vice-Chair, Tribal Secretary, Tribal Treasurer and Sergeant at Arms are decided by the elected council. The Soboba Tribal Administration encompasses several departments that serve the needs of the Tribe, the Reservation and the general public. They assist in day-to-day Tribal operations, public safety, Tribal family services, Native American assistance to needy families, cultural preservation, and Tribal environmental protection of natural resources, along with the monitoring of progress and needs of its Enterprises and the general public. The Tribe’s long term energy vision is to become self-sufficient and thereby attain greater control of its destiny, to control costs in view of rapidly rising electric utility expenses, and to maximize the use of renewable energy consistent with sustainable development practices. The project is a Renewable Energy System, specifically a ground mounted, fixed tilt, solar photovoltaic (PV) generating system with a rated capacity of 1.0MWac. The solar generated power serves the electric needs of the affected meters. It benefits every Tribal member since the cost of running the community Tribal facilities, including electric bills, comes out of the General Fund. The estimated 20 year project savings of $ 6,418,064 can be re-directed to other vital community needs, and the project will provide additional jobs for Tribal members. The project has been thoroughly researched and is ready to implement as soon as funding is approved.

14 SOLAR ENERGY↗

Additively Manufactured IN718 Components with Wirelessly Powered and Interrogated Embedded Sensing

A methodology is described for embedding commercial-off-the-shelf sensors together with wireless communication and power circuit elements using direct laser metal sintered additively manufactured components. Physics based models of the additive manufacturing processes and sensor/wireless level performance models guided the design and embedment processes. A combination of cold spray deposition and laser engineered net shaping was used to fashion the transmitter/receiving elements and embed the sensors, thereby providing environmental protection and component robustness/survivability for harsh conditions. By design, this complement of analog and digital sensors were wirelessly powered and interrogated using a health and utilization monitoring system; enabling real-time, in situ prognostics and diagnostics.

embedded sensing↗

Technetium, Iodine, and Chromium Adsorption/Desorption Kd Values for Vadose Zone Pore Water, ILAW Glass, and Cast Stone Leachates Contacting an IDF Sand Sequence

Performance and risk assessments of immobilized low-activity waste (ILAW) at the Integrated Disposal Facility (IDF) have shown that risks to groundwater are quite sensitive to adsorption-desorption interactions occurring in the near- and far-field environment. These interactions between the underlying sediments and the contaminants present in the leachates that descend from the buried glass, secondary waste grouts, and potentially Cast Stone low-activity waste packages have been represented in these assessments using the contaminant distribution coefficient (Kd) construct. Some contaminants (99Tc, 129I, and Cr) present in significant quantities in these wastes have low Kd values and tend to drive risk to public health and the environment. Relatively small changes in the Kd value can cause relatively large changes in the retardation factor. Thus, even relatively small uncertainty in the Kd value can result in a relatively large uncertainty in the risk determined through performance assessment modeling. The purpose of this study is to further reduce the uncertainty in Kd values for 99Tc, iodine (iodide and iodate), and Cr (chromate; CrO42-) by conducting systematic adsorption-desorption experiments using actual sand-dominated Hanford formation sediments from beneath the IDF and solutions that closely mimic Hanford vadose zone pore water and leachates from Cast Stone and ILAW glass waste forms. Twenty-four batch and 21 flow-through column experiments were conducted, yielding 261 Kd measurements for these key contaminants, and contributing to our understanding for predicting transport from wastes disposed to the IDF. While the batch Kd methodology is not well-suited for measuring Kd values for non-sorbing species (as noted by the U.S. Environmental Protection Agency), the batch Kd results presented here are not wholly inconsistent with the column Kd results, and could be used for sensitivity purposes. Results from the column experiments are consistent with the best estimate and lower range of Kd values reported by Krupka et al. and Cantrell et al.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Methodology for Outdoor Water Savings Model and Spreadsheet Tool for U.S. and Selected States

Green lawns and landscaping are archetypical of the populated American landscape, and typically require irrigation, which corresponds to a significant fraction of residential, commercial, and institutional water use. In North American cities, the estimated portion of residential water used for outdoor purposes ranges from 22-38% in cooler climates up to 59-67% in dry and hot environments, while turfgrass coverage within the United States spans 11.1-20.2 million hectares (Milesi et al. 2009). One national estimate uses satellite and aerial photography data to develop a relationship between impervious surface and lawn surface area, yielding a conservative estimate of 16.4 (± 3.6) million hectares of lawn surface area in the United States—an area three times larger than that devoted to any irrigated crop (Milesi et al. 2005). One approach that holds promise for cutting unnecessary outdoor water use is the increased deployment of “smart” irrigation controllers to increase the water efficiency of irrigation systems. This report describes the methodology and inputs employed in a mathematical model that quantifies the effects of the U.S. Environmental Protection Agency’s WaterSense labeling program for one such type of controller, weather-based irrigation controllers (WBIC). This model builds off that described in “Methodology for National Water Savings Model and Spreadsheet Tool–Outdoor Water Use” and uses a two-tiered approach to quantify outdoor water savings attributable to the WaterSense program for WBIC, as well as net present value (NPV) of that savings. While the first iteration of the model assessed national impacts using averaged national values, this version begins by evaluating impacts in three key large states that make up a sizable portion of the irrigation market: California, Florida, and Texas. These states are considered to be the principal market of “smart” irrigation controllers that may result in the bulk of national savings. Modeled water savings and net present value for these three states should be more accurate and representative than the averaged national values given state-specific inputs such as lot size, water price, and housing stock. To complete the picture of national impacts, the remaining WBIC shipments not assigned to these three states are assessed using the original methodology based on the averaged national values.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

1QCY17 Saltstone waste characterization analysis

In the first quarter of calendar year 2017, a salt solution sample was collected from Tank 50 on January 16, 2017 in order to meet South Carolina (SC) Regulation 61-107.19 Part I C, “Solid Waste Management: Solid Waste Landfills and Structural Fill – General Requirements” and the Saltstone Disposal Facility Class 3 Landfill Permit. The Savannah River National Laboratory (SRNL) was requested to prepare and ship saltstone samples to a United States Environmental Protection Agency (EPA) certified laboratory to perform the Toxicity Characteristic Leaching Procedure (TCLP) and subsequent characterization.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Milestone Report - M3FT-15OR03120213 - A Literature Survey to Identify Potentially Problematic Volatile Iodine-Bearing Species Present in Off-Gas Streams

Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet U.S. regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3 H, 14 C, 85 Kr, and 129 I. Of these, 129 I has the longest half-life and potentially highest biological impact. Accordingly, control of the release of 129 I is most critical with respect to U.S. regulations for the release of radioactive material in stack emissions. Current U.S. Environmental Protection Agency regulation governing nuclear facilities (40 CFR 190) states that the total quantity of radioactive materials entering the general environment from the entire uranium fuel cycle, per gigawatt-year of electrical energy produced by the fuel cycle, must contain less than 5 mCi of 129 I. The study of inorganic iodide in off-gas systems has been almost exclusively limited to I 2 , and the focus of organic iodide studies has been CH 3 I.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

KIVA-hpFE: Predictive turublent reactive and multiphase flow in engines : Science Supporting Mission of the Laboratory

Research and development of KIVA-hpFE for turbulent reactive and multiphase flow particularly as related to engine modeling program has relevance to National energy security and climate change. Climate change is a source problem, and energy national security is consumption of petroleum products problem. Accurately predicting engine processes leads to, lower greenhouse gas (GHG) emission, where engines in the transportation sector currently account for 26% of the U.S. GHG emissions. Less dependence on petroleum products leads to greater energy security. By Environmental Protection Agency standards, some vehicles are now reaching 42 to the 50 mpg mark. These are conventional gasoline engines. Continued investment and research into new technical innovations, the potential exists to save more than 4 million barrels of oil per day or approximately $200 to $400 million per day. This would be a significant decrease in emission and use of petroleum and a very large economic stimulus too! It is estimated with further advancements in combustion, the current emissions can be reduced up to 40%. Enabling better understanding of fuel injection and fuel-air mixing, thermodynamic combustion losses, and combustion/emission formation processes enhances our ability to help solve both problems. To provide adequate capability for accurately simulating these processes, minimize time and labor for development of engine technology, are the goals of our KIVA development program.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Wave Packet Based Statistical Approach to Complex-Forming Reactions

Combustion represents a key chemical process in energy consumption in modern societies and a clear and comprehensive understanding of the elemental reactions in combustion is of great importance to a number of challenging areas such as engine efficiency and environmental protection. In this award, we proposed to develop new theoretical tools to understand elemental chemical processes in combustion environments. With the support of this DOE grant, we have made significant advances in developing new and more efficient and accurate algorithms to characterize reaction dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Variable Renewable Energy in Long-Term Planning Models: A Multi-Model Perspective

Long-term capacity expansion models of the U.S. electricity sector have long been used to inform electric sector stakeholders and decision makers. With the recent surge in variable renewable energy (VRE) generators - primarily wind and solar photovoltaics - the need to appropriately represent VRE generators in these long-term models has increased. VRE generators are especially difficult to represent for a variety of reasons, including their variability, uncertainty, and spatial diversity. To assess current best practices, share methods and data, and identify future research needs for VRE representation in capacity expansion models, four capacity expansion modeling teams from the Electric Power Research Institute, the U.S. Energy Information Administration, the U.S. Environmental Protection Agency, and the National Renewable Energy Laboratory conducted two workshops of VRE modeling for national-scale capacity expansion models. The workshops covered a wide range of VRE topics, including transmission and VRE resource data, VRE capacity value, dispatch and operational modeling, distributed generation, and temporal and spatial resolution. The objectives of the workshops were both to better understand these topics and to improve the representation of VRE across the suite of models. Given these goals, each team incorporated model updates and performed additional analyses between the first and second workshops. This report summarizes the analyses and model 'experiments' that were conducted as part of these workshops as well as the various methods for treating VRE among the four modeling teams. The report also reviews the findings and learnings from the two workshops. We emphasize the areas where there is still need for additional research and development on analysis tools to incorporate VRE into long-term planning and decision-making.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗