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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47

Grid-Following Inverters and Synchronous Condensers: A Grid-Forming Pair?: Preprint

As power systems across the globe continue to achieve higher instantaneous penetrations of power electronic converterinterfaced renewable sources, the stability of these power systems is challenged because of the removal of synchronous machines, from which stability is traditionally derived. Although technological solutions to these stability challenges are on the horizon, such as the use of grid-forming inverters, they are not yet widely applied to larger power systems, which presents operational challenges for power systems achieving these high instantaneous penetrations today. An interim solution using existing technologies is to pair synchronous condensers with grid-following inverters, which might prolong the stability of an operating power system while synchronous generators are turned off during periods of high renewable energy availability. This work examines the transient stability of such a solution using PSCAD simulations of a two-bus system coupled to a variedlength transmission line, with a synchronous condenser at one bus and a grid-following inverter with grid-support functionality at the other. The system is exposed to load step, balanced fault, and unbalanced fault perturbations. It was found that this simple system returned to a steady state for transmission line lengths up to 125 km after 10% load steps, or a variety of fault types.

14 SOLAR ENERGY↗

The Future of Fuels: Meeting Global Decarbonization Goals

Petroleum has served as the source of the vast majority of our transportation fuel for well over a century. During the past few decades, biofuels—primarily ethanol, biodiesel, renewable diesel/jet, and renewable natural gas—have steadily increased in volume though still represent a small portion of the total fuel mix. While initially driven by energy security considerations, recent policies promoting increased biofuel use have been motivated by greenhouse gas reductions. Within the past couple years, significant interest has emerged in “e-fuels”—fuels produced from a carbon source (e.g., CO2) and electricity. If sourced from renewable electrons, e-fuels have the potential to provide significant GHG reductions, though questions of scale and economics remain. This talk will discuss recent research into advanced fuels properties and production routs, as well as issues and challenges that fuels must overcome to power ICEs in the mid 21st century.

47 OTHER INSTRUMENTATION↗

The great galactic centre mystery

Gamma-ray observations of the center of the Galaxy show a varying positron-electron annihilation radiation emission, while at radio wavelengths a non-thermal compact source surrounded by ionized gas moving at high velocities can be seen. Line emission maps for atomic and ionized hydrogen and molecular gas suggest gas expulsion and a massive collapsed object. IR observations show that ionized gas in the central few parsecs of the Galactic center is concentrated in at least 14 small clouds. Charge-coupled device images show a pair of faint, very red sources within a few arc seconds of IRS 16 and the compact non-thermal radio source. The positron-electron annihilation line emission implies an annihilation rate of 10 to the 43rd per sec, compared with an observed luminosity at IR wavelengths of 10 to the 40 erg per sec. Some models are briefly discussed.

Riegler, G. R.↗

Nonlinear evolution of the auroral electron beam

The nonlinear spatial evolution, from the source to the atmosphere, of the auroral electron beam and the beam-generated electrostatic whistler noise was studied, calculating changes in beam parameters from equations for the conservation of total particle and wave energy and momentum flux density. Wave power fluxes were calculated by numerically integrating the wave kinetic equations, and the levels of beam-generated noise were determined by using thermal levels of Cerenkov radiation as a source. It was found that beam parameters evolve on ionospheric scale lengths, and their positive slope feature in velocity space is maintained over altitudes measured in thousands of kilometers of altitude, even though they can generate wave energy density fluxes sufficient to modify the ionospheric density profile.

Maggs, James E.↗

Atmospheric Electron-induced X-Ray Spectrometer (AEXS) Instrument Development

Instrument Development: The membrane properties were investigated in detail due to its critical role. A series of experiments determined that our designed membranes have high electron transmission, yet are capable of isolating high vacuum, are able to withstand differential pressure in excess of one atmosphere, survive vibrational shocks of a magnitude to be expected during a planetary mission. Our initial work has been with a 10 keV source and a 200 nm thick Silicon Nitride (SiN) encapsulation membrane micro-fabricated within a Si support frame (1.5 mm x 1.5 mm window openings. Fig 2 compares the spectra taken with the 10 keV source with spectra taken within SEM. Introduction: This paper describes the progress in the development of the AEXS instrument in our laboratory at JPL. The AEXS is a novel miniature instrument[1-3] based on the excitation of characteristic X-Ray Fluorescence (XRF) and luminescence spectra using a focused electron beam, for non-destructive evaluation of surfaces of samples in planetary ambient atmosphere. In situ operation is obtained through the use of a thin electron transmissive membrane to isolate the vacuum within the AEXS electron source from the outside ambient atmosphere. The impinging electrons excite XRF spectra from the irradiated spots on samples in external atmosphere with high-to-medium (sub-mm to cm-scale) spatial resolution at Mars atmospheric pressure. The XRF spectra are analyzed using an energy-dispersive detector to determine surface elemental composition, or in the case of electron-induced luminescence to identify unusual formations on surface that cathodo-luminescence (CL). The AEXS system (Fig 1) consists of a high-energy (>10keV) electron gun encapsulated by the isolation membrane, an EDX detection and analyzer system to determine the elemental abundance, an optional CL detection system, and a high voltage power supply. The approach to demonstrating a proof of concept of the AEXS has been through 1) demonstrating the viability of micro-fabricated membranes, 2) assembling AEXS setups with increasingly integrated functional components, and 3) simulating the AEXS observational capabilities. This paper will focus on description of the development of the instrument.

Wilcox, J. Z.↗

Uncertainty Analysis and Software Verification

Uncertainty analyses are an important part of calibrations and testing. They allow researchers insight on how to reduce and mitigate errors in testing. Each device used in testing introduces error in a system, as well as other sources such as environmental conditions, electronics, analog to digital, and random errors. Each source is carefully examined to identify how much error it introduces to a system. These sources are then combined using various methods of uncertainty calculations. To verify and validate software, a manual calculation is required to ensure the software is performing as intended. Using Excel to verify the calculations, we can identify discrepancies within the software. The root of the sum of the squares uncertainty (RSS) is used to find the combined uncertainty of a device at one and two standard deviations of the mean. Calibrations on accelerometers are performed using a vibration system along with a back-toback reference accelerometer. The vibration system takes a reference point at 100Hz frequency at 10g amplitude. The sensitivities are collected at each dialed in frequency. The sensitivity of the device represents the electrical output of the UUT (mV, pC, etc.) per unit of acceleration (g). The full history of sensitivities of selected accelerometers are used to find the averaged, standard deviation, and uncertainty of the device at each frequency tested. The uncertainty calculations from excel and the software are then compared.

97 MATHEMATICS AND COMPUTING↗

MLSPICE: Machine Learning based SPICE Modeling Platform for Power Magnetics

Electrical power converters are critical to a wide range of applications ranging from renewable integration to transportation electrification, and can be a key factor determining the size, weight, and efficiency of energy conversion systems. Magnetic components are typically the largest and least efficient components in power electronics. While there have been major strides in the modeling and analysis of power semiconductor devices and circuit simulations, the necessary advances in the design of power magnetics have lagged. In this project, we have transformed the modeling and design of power magnetics with machine learning enabled methods and catalyze simultaneous disruptive improvements for ML-based power electronics design tools. A fully automated open-source machine learning based magnetics modeling platform – the MagNet project - with innovations in full stack have been developed to greatly accelerate the design process and provide new insights to magnetic material and geometry design. The ARPA-E funded MagNet platform contains three major building blocks: 1) a ML-Integrated Data Acquisition System (MIDAS): a highly automated data acquisition testbed which is capable of measuring a large number of magnetic cores with a wide range of electrical circuit excitations; 2) a ML-integrated Core Loss Model (MICLM): a machine-learning trained modeling method for modeling the core loss and saturation effects of magnetic materials for arbitrary excitation waveforms; 3) ML-guided Magnetics SPICE Simulation Tool (PMSPICE): a fully integrated CAD tool which can simulate the magnetics in SPICE. It can help the designers to quickly model the linear and non-linear characteristics of magnetic components and evaluate their behavior in SPICE simulations. The developed MagNet system has fully demonstrated the proposed performance target and has been open sourced to the entire power electronics community to advance the modeling and design of power magnetics from many different angles.

36 MATERIALS SCIENCE↗

High Frequency Plasma Generators for Ion Thrusters

The results of a one year program to experimentally adapt two new types of high frequency plasma generators to Argon ion thrusters and to analytically study a third high frequency source concept are presented. Conventional 30 cm two grid ion extraction was utilized or proposed for all three sources. The two plasma generating methods selected for experimental study were a radio frequency induction (RFI) source, operating at about 1 MHz, and an electron cyclotron heated (ECH) plasma source operating at about 5 GHz. Both sources utilize multi-linecusp permanent magnet configurations for plasma confinement. The plasma characteristics, plasma loading of the rf antenna, and the rf frequency dependence of source efficiency and antenna circuit efficiency are described for the RFI Multi-cusp source. In a series of tests of this source at Lewis Research Center, minimum discharge losses of 220+/-10 eV/ion were obtained with propellant utilization of .45 at a beam current of 3 amperes. Possible improvement modifications are discussed.

Divergilio, W. F.↗

Modified bacterium useful for producing an organic molecule

The present invention provides for a genetically modified host cell or bacterium capable of producing an organic molecule, wherein the bacterium is capable of using hydrogen sulfide as an electron donor, carbon dioxide (CO2) as a carbon source, and/or nitrate as an electron acceptor. The present invention is useful in the wastewater treatment industry, in particular in municipal wastewater treatment plants (WWTP).

Beller, Harry R.↗

Spatially resolved measurements of electron density of a magnetically confined split-ring resonator source

Laser-collisional induced fluorescence is used to study the plasma generated by a split-ring resonator discharge under an external cusp shaped magnetic field created by permanent magnets. The electron density and electron temperature are measured for a helium plasma at different pressures, powers, and magnet field strengths. It is found that the magnetic fields produce higher electron temperatures with peak temperatures of ∼3 eV, while the no magnet case has peak temperatures of ∼0.8 eV. Conversely, the peak electron density is obtained in the no magnet case at a value of ∼1.9 × 1011 cm−3. This indicates that the cusp-field did magnetize the electrons, but contrary to expectations, it resulted in a decrease in electron density. This is believed to be due to the magnetic field having negative effects on the resonance of the plasma source.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

On the need for space tests of plasma contactors as electron collectors

An analysis is presented of laboratory experiments that have shown that hollow plasma sources can provide low-impedance contact with a background plasma. In particular, some experiments show an report an 'ignited mode' of electron collection using plasma sources where almost an ampere was collected at a potential of 100 volts. The experimental results are compared with theoretical and computational models of plasma layers. Preliminary results indicate that the measured potential profiles and collected currents during the 'ignited mode' correspond to an increase in the background plasma thermal current of more than an order of magnitude. The results imply that the 'ignited mode' results are substantially impacted by the laboratory electron source and the tank size. Only experiments performed in space will be able to provide the correct boundary conditions for reliably testing high electron collection by plasma contactors.

Katz, Ira↗

Open Source Platform for Live Processing of High Data Rate Electron Microscopy (SBIR Phase I Award Topic 15, Subtopic B, Final Scientific / Technical Report)

4D scanning transmission electron microscopy (STEM) is experiencing a revolution both in terms of data size, and data veracity, as are many other areas of experimental data acquisition. This presents enormous opportunities to make new scientific discoveries, but is also hamstrung by aging software that is no longer fit for purpose. Experimental data acquisition platforms must make the same investments in software infrastructure that the simulation community made decades ago to take advantage of high-performance computing (HPC) if they hope to realize the full potential of the latest advances made in detector technology. This requires rethinking the design and deployment of hardware, moving away from small, fixed commodity computing capabilities with closed interfaces to open, modular, scalable systems designed for parallelism and throughput. The technical approach will leverage best-in-class open source technologies, and develop new approaches strategically to build an open source platform for experimental data acquisition targeting high data rate electron microscopy. The project will develop a software platform that uses the power and performance of modern HPC resources to ingest the large volume of data produced by electron microscopes using direct electron detectors. A set of configurable pipelines will be used to enable the processing to be tailored to the problem being investigated with builtin visualization of data at interactive rates. This project will leverage investments made by the DOE and other agencies to provide a powerful software platform for the experimental data community working with most powerful electron microscopes, such as 4D STEM detectors. It will create a platform that serves as a reference for the community. Permissive open source licensing will make the platform available to all, with a simple deployment strategy offering the ability to keep data close to where it is generated. This advanced software platform will require customization for each deployment, creating opportunities for software services that are typically offered to extend open source software platforms.

97 MATHEMATICS AND COMPUTING↗

Energy Limits of Electron Acceleration in the Plasma Sheet During Substorms: A Case Study with the Magnetospheric Multiscale (MMS) Mission

We present multipoint observations of earthward moving dipolarization fronts and energetic particle injections from NASAs Magnetospheric Multiscale mission with a focus on electron acceleration. From a case study during a substorm on 02 August 2015, we find that electrons are only accelerated over a finite energy range, from a lower energy threshold at approx. 7-9 keV up to an upper energy cutoff in the hundreds of keV range. At energies lower than the threshold energy, electron fluxes decrease, potentially due to precipitation by strong parallel electrostatic wavefields or initial sources in the lobes. Electrons at energies higher than the threshold are accelerated cumulatively by a series of impulsive magnetic dipolarization events. This case demonstrates how the upper energy cutoff increases, in this case from approx. 130 keV to >500 keV, with each depolarization/injection during sustained activity. We also present a simple model accounting for these energy limits that reveals that electron energization is dominated by betatron acceleration.

Turner, D. L.↗

Controllable X-ray Pulse Trains from Enhanced Self-Amplified Spontaneous Emission

We report the demonstration of optical compression of an electron beam and the production of controllable trains of femtosecond, soft x-ray pulses with the Linac Coherent Light Source (LCLS) freeelectron laser (FEL). This is achieved by enhanced self-amplified spontaneous emission with a 2 μm laser and a dechirper device. Optical compression was achieved by modulating the energy of an electron beam with the laser and then compressing with a chicane, resulting in high current spikes on the beam which we observe to lase. A dechirper was then used to selectively control the lasing region of the electron beam. Field autocorrelation measurements indicate a train of pulses, and we find that the number of pulses within the train can be controlled (from 1 to 5 pulses) by varying the dechirper position and undulator taper. These results are a step toward attosecond spectroscopy with x-ray FELs as well as future FEL schemes relying on optical compression of an electron beam.

Duris, Joseph P↗

Saturn Neutron Exosphere as Source for Inner and Innermost Radiation Belts

Energetic proton and electron measurements by the ongoing Cassini orbiter mission are expanding our knowledge of the highest energy components of the Saturn magnetosphere in the inner radiation belt region after the initial discoveries of these belts by the Pioneer 11 and Voyager 2 missions. Saturn has a neutron exosphere that extends throughout the magnetosphere from the cosmic ray albedo neutron source at the planetary main rings and atmosphere. The neutrons emitted from these sources at energies respectively above 4 and 8 eV escape the Saturn system, while those at lower energies are gravitationally bound. The neutrons undergo beta decay in average times of about 1000 seconds to provide distributed sources of protons and electrons throughout Saturn's magnetosphere with highest injection rates close to the Saturn and ring sources. The competing radiation belt source for energetic electrons is rapid inward diffusion and acceleration of electrons from the middle magnetosphere and beyond. Minimal losses during diffusive transport across the moon orbits, e.g. of Mimas and Enceladus, and local time asymmetries in electron intensity, suggest that drift resonance effects preferentially boost the diffusion rates of electrons from both sources. Energy dependences of longitudinal gradient-curvature drift speeds relative to the icy moons are likely responsible for hemispheric differences (e.g., Mimas, Tethys) in composition and thermal properties as at least partly produced by radiolytic processes. A continuing mystery is the similar radial profiles of lower energy (<10 MeV) protons in the inner belt region. Either the source of these lower energy protons is also neutron decay, but perhaps alternatively from atmospheric albedo, or else all protons from diverse distributed sources are similarly affected by losses at the moon' orbits, e.g. because the proton diffusion rates are extremely low. Enceladus cryovolcanism, and radiolytic processing elsewhere on the icy moon and ring surfaces, are additional sources of protons via ionization and charge exchange from breakup of water molecules. But one must then account somehow for local acceleration to the observed keV-MeV energies, since moon sweeping and E-ring absorption would remove protons diffusing inward from the middle magnetosphere. Although the main rings block further inward diffusion from the inner radiation belts, the exospheric neutron-decay source, combined with much slower diffusion of protons relative to electrons, may produce an innermost radiation belt in the gap between the upper atmosphere and the D-ring. This innermost belt will first be explored in-situ during the final proximal orbits of the Cassini mission.

Cooper, John↗

Direct Cathode Recycling of End-Of-Life Li-Ion Batteries Enabled by Redox Mediation

The ongoing surge of electric vehicle (EV) adoption forecasts an unprecedented amount of lithium-ion battery wastes in the near future. Since cathode materials have the highest economic and engineering values, it is essential to recycle and reuse the end-of-life (EOL) cathode materials. Here, we show that redox mediators can deliver lithium ions and electrons from a lithium source to the cathode, efficiently relithiate the EOL cathode materials, and make them ready for new battery production after a postheat treatment. We have found that some quinone-based redox mediators, especially 3,5-di-tert-butyl-o-benzoquinone (DTBQ), can shuttle the charges very fast between Li metal and EOL cathode. Reduction of DTBQ on lithium is evidenced by chemical changes of Li metal and DTBQ, and successful relithiation of the EOL cathode by the subsequent oxidation of DTBQ is verified by electrochemical and structural evaluations.

battery recycling↗

Large Diffraction-Grade Single Crystal Diamond for Applications at New Generation Synchrotron and FEL X-Ray Sources

As a result of increasing performance of synchrotron and free-electron laser x-ray sources for high-flux applications, a new generation of optics is needed that can support the high energy densities utilized. To achieve this, the Department of Energy (DOW) has sought a commercially available, US-sourced supply of this material. Through a collaborative effort led by WD Advanced Materials (WD AM), in coordination with Euclid Beamlabs and Applied Diamond, Inc., and supported by Argonne National Laboratory, an effort has been made to begin the creation of such a diamond optic supply. Key material and optic parameters were identified, as well as characterization methods. A process of diamond synthesis that satisfies both extrinsic and intrinsic needs of the optics was formulated and demonstrated, and necessary steps to achieve high-quality epitaxy were evaluated and tested. Results of the first steps of this program are provided herein, as well as recommendations for a follow-up effort to complete the program and establish the needed supply of diamond optics for DOE x-ray applications.

36 MATERIALS SCIENCE↗