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At least 847 records · Page 47

Composite Solid Electrolyte For Lithium Cells

Composite solid electrolyte material consists of very small particles, each coated with thin layer of Lil, bonded together with polymer electrolyte or other organic binder. Material offers significant advantages over other solid electrolytes in lithium cells and batteries. Features include high ionic conductivity and strength. Composite solid electrolyte expected to exhibit flexibility of polymeric electrolytes. Polymer in composite solid electrolyte serves two purposes: used as binder alone, conduction taking place only in AI2O3 particles coated with solid Lil; or used as both binder and polymeric electrolyte, providing ionic conductivity between solid particles that it binds together.

Peled, Emmanuel↗

Coronal propagation and storage at energies approximately 1 MeV/nucleon

Energetic particle events relating to quasi-stationary particle populations, solar flare events, and solar composition are discussed in the context of similar observations likely to be made during solar probe encounter. Particlar emphasis is given to interrelationships with coronal magnetic structure and plasma processes. General instrumental requirements are listed, and it is concluded that energetic particle detectors meeting these requirements will successfully complement other essential experiments on the Solar Probe.

Roelof, E. C.↗

Iridescence Reveals the Formation and Growth of Ice Aerosols in Martian Noctilucent Clouds

Water and carbon dioxide each form mesospheric clouds on Mars. At such altitudes (40–100 km), clouds may remain sunlit for part of the night. We describe a previously unreported, visually spectacular season of iridescent, noctilucent clouds visible in early southern autumn from the Curiosity rover's site in Gale crater. Ice nucleation begins near sunset with a narrow range of particle sizes, and the ice aerosols grow and precipitate. The iridescence, visible through three-color imaging, arises from locally uniform particle sizes resulting from similar growth histories. Colorful fall streaks show the clouds evolving, and a scattering corona shows size uniformity over large areas. The terminator was observed on the clouds, allowing the determination of cloud altitudes and a likely CO2 composition. This is the first observation of particle size variations within individual Martian clouds, allowing a new probe of Martian cloud physics.

M T Lemmon↗

Cosmic rays in the Galaxy.

Galactic cosmic rays, discussing chemical composition, isotopic separation, proton and alpha particles energy spectra, propagation, interactions, etc

Meyer, P.↗

CMB-13 research on carbon and graphite

Preliminary results of the research on carbon and graphite accomplished during this report period are presented. Included are: particle characteristics of Santa Maria fillers, compositions and density data for hot-molded Santa Maria graphites, properties of hot-molded Santa Maria graphites, and properties of hot-molded anisotropic graphites. Ablation-resistant graphites are also discussed.

Smith, M. C.↗

Missions to comets

Missions to comets are outlined that form the basis for a new program to send a space probe to a comet. Simple flythroughs of the comet head will provide information about the composition of the ionized and neutral particles that make up the cometary atmosphere and on effects of solar-wind interaction with the comet. Projected are missions to the comets Grigg-Skjellerup, Encke, and Halley.

Farquhar, R. W.↗

Progress in our understanding of cometary dust tails

Various analytical techniques are employed to analyze observations on the character, composition, and size distribution of solid particles in cometary dust tails. Emphasized is the mechanical theory that includes solar gravitational attraction and solar radiation pressure to explain dust particle motions in cometary tails, as well as interactions between dust and plasma.

Sekanina, Z.↗

Evaluation of micron size carbon fibers released from burning graphite composites

Quantitative estimates were developed of micron carbon fibers released during the burning of graphite composites. Evidence was found of fibrillated particles which were the predominant source of the micron fiber data obtained from large pool fire tests. The fibrillation phenomena were attributed to fiber oxidation effects caused by the fire environment. Analysis of propane burn test records indicated that wind sources can cause considerable carbon fiber oxidation. Criteria estimates were determined for the number of micron carbon fibers released during an aircraft accident. An extreme case analysis indicated that the upper limit of the micron carbon fiber concentration level was only about half the permissible asbestos ceiling concentration level.

Sussholz, B.↗

Qualification of black electrically conductive paint

A paint having low electrical resistance has been developed. Using a low outgassing polyurethane resin, specific amounts of conductive carbon particles were added to produce paint compositions having a range of electrical resistance. Methods of testing for electrical resistance are discussed. The adhesion of these paints has been tested successfully over the temperature range from liquid nitrogen temperature up to 80 C (176 F).

Park, J. J.↗

Control of volume resistivity in inorganic-organic separators

Control of resistivity in NASA inorganic-organic separators is achieved by incorporating small percentages of high surface area, fine-particle silica with other ingredients in the separator coating. The volume resistivity appears to be predictable from coating composition, that is, from the surface area of filler particles in the coating. The approach has been applied to two polymer-'plasticizer'-filler coating systems, where the filler content of each is below the generally acknowledged critical pigment volume concentration of the coating. Application of these coating systems to 0.0254 cm thick (10 mil) fuel-cell grade asbestos sheet produces inexpensive, flexible, microporous separators that perform at least as well as the original inorganic-organic concept, the Astropower separator.

Sheibley, D. W.↗

Formation of metallic and metal hydrous oxide dispersions

The formation, via hydrothermally induced precipitation from homogeneous solution, of a variety of well-defined dispersions of metallic and hydrous metal in the conditions under which the particles are produced (e.g., pH and composition of the growth medium, aging temperature, rate of heating, or degree of agitation) can be readily discerned by following changes in the mass, composition, and morphology of the final solid phase. The generation of colloidal dispersions in the absence of gravity convection or sedimentation effects may result in the appearance of morphological modifications not previously observed in terrestrially formed hydrosols.

Matijevic, E.↗

Refractory minerals in interplanetary dust

A newly studied interplanetary dust particle contains a unique set of minerals that closely resembles assemblages in the refractory, calcium- and aluminum-rich inclusions in carbonaceous chondrite meteorites. The set of minerals includes diopside, magnesium-aluminum spinel, anorthite, perovskite, and fassaite. Only fassaite has previously been identified in interplanetary dust particles. Diopside and spinel occur in complex symplectic intergrowths that may have formed by a reaction between condensed melilite and the solar nebula gas. The particle represents a new link between interplanetary dust particles and carbonaceous chondrites; however, the compositions of its two most abundant refractory phases, diopside and spinel, differ in detail from corresponding minerals in calcium- and aluminum-rich inclusions.

Christoffersen, Roy↗

Dendritic microstructure in argon atomized superalloy powders

The dendritic microstructure of atomized nickel base superalloy powders (Ni-20 pct Cr, NIMONIC-80A, ASTROALOY, and ZHS6-K) was studied. Prealloyed vacuum induction melted ingots were argon-atomized, the powders were cooled to room temperature, and various powder-size fractions were examined by optical metallography. Linear correlations were obtained for the powder size dependence of the secondary dendrite arm spacing, following the expected d-alpha (R) to the m power dependence on the particle size for all four superalloy compositions. However, the Ni-20 pct Cr alloy, which had much coarser arm spacing as compared to the other three alloys, had a much larger value of m.

Tewari, S. N.↗

Magnetospheric particle injection and the upstream ion event of September 5, 1984

Energetic particle data from the AMPTE Charge Composition Explorer (CCE) spacecraft in the outer dayside magnetosphere are examined during the period of an upstream ion event observed by the AMPTE Ion Release Module (IRM) spacecraft on September 5, 1984. The CCE data reveal the following: (1) an ion enhancement was observed at about 0040 UT in near coincidence with a substorm onset at about 0035 UT, approximately 15 minutes prior to the onset of the event upstream of the shock; (b) ions of both solar-wind - H(2+) Fe-group - and ionospheric O(+) - origin over a broad energy range (about 20 keV to greater than 1350 keV) were injected at substorm onset; (3) the time evolution of the H(+), He(2+), and O(+) pitch angle distributions markedly differed, with O(+) exhibiting mostly enhancements at off-90-deg angles for the first hour after injection; (4) an enhancement in the Fe-group ions inside the magnetosphere at L = about 6.4 occurred simultaneously with the appearance of an O(+) burst upstream of the shock. The CCE observations, taken together with the simultaneously observed IRM ion event, suggest that a plausible explanation for the appearance of upstream ions is leakage from the magnetosphere into the upstream region, rather than the alternative explanation which requires in situ acceleration of solar wind ions via the Fermi Mechanims.

Krimigis, S. M.↗

Directional solidification of Al-Ni/SiC composites during parabolic trajectories

Aluminum-6.1 wt. pct. nickel-silicon carbide composites containing varying volume fractions and particle sizes of SiC were directionally solidified at different translation rates and temperature gradients, under variable gravity levels. High-gravity, high-volume fractions of particles or high effective viscosity of liquid favored the engulfment of particles by the melt interface. Solidification under low gravity seemed to deflocculate the SiC particle agglomerates, while opposite results were obtained when solidifying under high gravity. Intercellular spacings were higher under low gravity solidfication.

Dhindaw, B. K.↗

Grinding Si3N4 Powder In Si3N4 Equipment

Three methods of grinding compared. Report based on study of grinding silicon nitride powder in preparation for sintering into solid ceramic material. Attrition, vibratory, and ball mills lined with reaction-bonded silicon nitride tested. Rates of reduction of particle sizes and changes in chemical compositions of powders measured so grinding efficiences and increases in impurity contents from wear of mills and media evaluated for each technique.

Herbell, Thomas P.↗

Preliminary analysis of observations of the Pinatubo volcanic plume with a polarization-sensitive lidar

A dual-polarization lidar aboard the NASA Electra aircraft was used in July 1991 to survey the stratospheric plume from the recent Mt. Pinatubo eruption. Both depolarizing and non-depolarizing volcanic layers were observed, ranging from 17 to 26 km in altitude. Differences in the depolarization signatures of the layers indicates differences in the composition or physical state of the particles in the layers.

Winker, D. M.↗