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At least 847 records · Page 47

NIST: Soil Respiration, Moisture, Temperature, Chemistry; and Fine Root Measurements from a Transect Through a Forest Edge, Gaithersburg, Maryland, 2017-2021

This dataset contains soil respiration, moisture, temperature, and chemistry, as well as fine root measurements from the National Institute of Standards and Technology (NIST) Forested Optical Reference for Evaluating Sensor Technology (FOREST) research facility at Gaithersburg, Maryland. Measurements were taken at an existing transect array that begins in a grassy meadow, crosses a sharp forest edge, then a small stream, and finally extends upwards in the interior of the forest at the top of a ridge. There are 6 different landscape positions replicated across three transects in the array. Soil respiration was measured during growing seasons in 2017-2019 (2017-06-02 to 2020-02-27). Pedons (1 m3) were isolated from surrounding tree roots using trenching and a fabric to inhibit root ingrowth. Flux measurements inside the pedons were thus assumed to represent heterotrophic only respiration in 2019, and these fluxes were paired with nearby fluxes assumed to represent total respiration. Deep vertical probes measured volumetric moisture content and temperature at the same points in the array every 10 cm in depth to either 90 cm or 120 cm total depth, at 15 minute intervals, from 2019-2021 (2019-07-09 to 2021-09-10). Soil core samples were collected from each of the array points for three different months in early- to mid-2019 (2019-03-19 to 2019-07-10), at three depths each. Soils were analyzed for gravimetric moisture content; pH; total carbon, nitrogen, and phosphorus; texture; microbial biomass carbon, nitrogen, and phosphorus; extractable dissolved organic carbon, nitrogen, and phosphorus; extractable nitrate and ammonia; and extracellular hydrolytic enzyme activities. The fine roots were separated from the cores and segregated by plant functional type (grass or tree species) and if they were dead or alive. Fine roots were then measured for length, surface area, diameter, and dry mass. This dataset contains four data files in comma separated (*.csv) format. These data serve to deepen our understanding of root and soil processes at forest edges and in transitional zones.

54 ENVIRONMENTAL SCIENCES↗

Interrelationships among methods of estimating microbial biomass across multiple soil orders and biomes: Supporting data

This dataset contains environmental and soil measurements from 18 different locations across the globe including the SPRUCE experiment site and multiple sampling depths, with 17 of these locations having samples processed between 2012-2013 and one location (SPRUCE) collected in 2021 and processed in 2022. Environmental measurements include: mean annual temperature, mean annual precipitation, and 30-day presampling temperature. Soil physicochemical measurements include: particle size analysis (PSA), pH, gravimetric moisture content (GMC), bulk soil carbon (C) and nitrogen (N), total organic C and N, C:N ratio, and dissolved organic carbon (DOC). Soil biological measurements include: microbial biomass carbon (MBC) measured through chloroform fumigation extraction (CFE), gene copy numbers (GCN) of bacteria, fungi, and archaea measured through quantitative polymerase chain reaction (qPCR), DNA yield measured through Nanodrop spectrophotometry, and phospholipid fatty acids (PLFA) of bacteria and fungi measured through PLFA analysis. This data set contains one file in comma separate (*.csv) format.

archaea gene copy number↗

The International Space Station Environment Triggers Molecular Responses in Aspergillus niger

Due to immense phenotypic plasticity and adaptability, Aspergillus niger is a cosmopolitan fungus that thrives in versatile environments, including the International Space Station (ISS). This is the first report of genomic, proteomic, and metabolomic alterations observed in A. niger strain JSC-093350089 grown in a controlled experiment aboard the ISS. Whole-genome sequencing (WGS) revealed that ISS conditions, including microgravity and enhanced irradiation, triggered non-synonymous point mutations in specific regions, chromosomes VIII and XII of the JSC-093350089 genome when compared to the ground-grown control. Proteome analysis showed altered abundance of proteins involved in carbohydrate metabolism, stress response, and cellular amino acid and protein catabolic processes following growth aboard the ISS. Metabolome analysis further confirmed that space conditions altered molecular suite of ISS-grown A. niger JSC-093350089. After regrowing both strains on Earth, production of antioxidant—Pyranonigrin A was significantly induced in the ISS-flown, but not the ground control strain. In summary, the microgravity and enhanced irradiation triggered unique molecular responses in the A. niger JSC-093350089 suggesting adaptive responses.

59 BASIC BIOLOGICAL SCIENCES↗

Organo-Nanocups Assist the Formation of Ultra-Small Palladium Nanoparticle Catalysts for Hydrogen Evolution Reaction

Ultra-small palladium nanoparticles were synthesized and applied as catalysts for a hydrogen evolution reaction. The palladium metal precursor was produced via beta-cyclodextrin as organo-nanocup (ONC) capping agent to produce ultra-small nanoparticles used in this study. The produced ~3 nm nanoparticle catalyst was then characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis), and Fourier transform infrared spectroscopy (FTIR) to confirm the successful synthesis of ~3 nm palladium nanoparticles. The nanoparticles’ catalytic ability was explored via the hydrolysis reaction of sodium borohydride. The palladium nanoparticle catalyst performed best at 303 K at a pH of 7 with 925 μmol of sodium borohydride having an H 2 generation rate of 1.431 mL min -1 mL cat -1 . The activation energy of the palladium catalyst was calculated to be 58.9 kJ/mol.

36 MATERIALS SCIENCE↗

Restoration Insights Gained from a Field Deployment of Dithionite and Acetate at a Uranium In Situ Recovery Mine

Mining uranium by in situ recovery (ISR) typically involves injecting an oxidant and a complexing agent to mobilize and extract uranium in a saturated ore zone. This strategy involves less infrastructure and invasive techniques than traditional mining, but ISR often results in persistently elevated concentrations of U and other contaminants of concern in groundwater after mining. These concentrations may remain elevated for an extended period without remediation. Here, we describe a field experiment at an ISR facility in which both a chemical reductant (sodium dithionite) and a biostimulant (sodium acetate) were sequentially introduced into a previously mined ore zone in an attempt to establish reducing geochemical conditions that, in principle, should decrease and stabilize aqueous U concentrations. While several lines of evidence indicated that reducing conditions were established, U concentrations did not decrease, and in fact increased after the amendment deployments. We discuss likely reasons for this behavior, and we also discuss how the results provide insights into improvements that could be made to the restoration process to benefit from the seemingly detrimental behavior.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Editorial for Special Issue “Environmentally Sound In Situ Recovery Mining of Uranium”

This Special Issue features seven articles that cover a range of topics pertaining to the environmentally sound in situ recovery mining of uranium (U ISR). The topics include: (1) methods for assessing the potential environmental impacts of future U ISR operations using historical operational records and available geohydrologic, geochemical and climate data in a specific regional setting; (2) laboratory column studies to parameterize a uranium surface complexation model that can be used to predict uranium fate and transport in groundwater; and (3) a field evaluation of both a chemical reductant and a biostimulant to promote reducing geochemical conditions after oxidative mining at a U ISR facility.

54 ENVIRONMENTAL SCIENCES↗

Point Sensor Networks Struggle to Detect and Quantify Short Controlled Releases at Oil and Gas Sites

This study evaluated multiple commercially available continuous monitoring (CM) point sensor network (PSN) solutions under single-blind controlled release testing conducted at operational upstream and midstream oil and natural gas (O&G) sites. During releases, PSNs reported site-level emission rate estimates of 0 kg/h between 38 and 86% of the time. When non-zero site-level emission rate estimates were provided, no linear correlation between the release rate and the reported emission rate estimate was observed. The average, aggregated across all PSN solutions during releases, shows 5% of the mixing ratio readings at downwind sensors were greater than the site’s baseline plus two standard deviations. Four of seven total PSN solutions tested during this field campaign provided site-level emission rate estimates with the site average relative error ranging from −100% to 24% for solution D, −100% to −43% for solution E, −25% for solution F (solution F was only at one site), and −99% to 430% for solution G, with an overall average of −29% across all sites and solutions. Of all the individual site-level emission rate estimates, only 11% were within ±2.5 kg/h of the study team’s best estimate of site-level emissions at the time of the releases.

42 ENGINEERING↗

Cosmic-ray anisotropies in right ascension measured by the Pierre Auger Observatory

We present measurements of the large-scale cosmic-ray anisotropies in right ascension, using data collected by the surface detector array of the Pierre Auger Observatory over more than 14 years. We determine the equatorial dipole component, $\vec{d}_\perp$, through a Fourier analysis in right ascension that includes weights for each event so as to account for the main detector-induced systematic effects. For the energies at which the trigger efficiency of the array is small, the ``East-West'' method is employed. Besides using the data from the array with detectors separated by 1500 m, we also include data from the smaller but denser sub-array of detectors with 750 m separation, which allows us to extend the analysis down to $\sim 0.03$ EeV. The most significant equatorial dipole amplitude obtained is that in the cumulative bin above 8~EeV, $d_\perp=6.0^{+1.0}_{-0.9}$%, which is inconsistent with isotropy at the 6$\sigma$ level. In the bins below 8 EeV, we obtain 99% CL upper-bounds on $d_\perp$ at the level of 1 to 3 percent. At energies below 1 EeV, even though the amplitudes are not significant, the phases determined in most of the bins are not far from the right ascension of the Galactic center, at $\alpha_{\rm GC}=-94^\circ$, suggesting a predominantly Galactic origin for anisotropies at these energies. The reconstructed dipole phases in the energy bins above 4 EeV point instead to right ascensions that are almost opposite to the Galactic center one, indicative of an extragalactic cosmic ray origin.

79 ASTRONOMY AND ASTROPHYSICS↗

A Search for Ultra-high-energy Neutrinos from TXS 0506+056 Using the Pierre Auger Observatory

Results of a search for ultra-high-energy neutrinos with the Pierre Auger Observatory from the direction of the blazar TXS 0506+056 are presented. They were obtained as part of the follow-up that stemmed from the detection of high-energy neutrinos and gamma rays with IceCube, Fermi-LAT, MAGIC, and other detectors of electromagnetic radiation in several bands. The Pierre Auger Observatory is sensitive to neutrinos in the energy range from 100 PeV to 100 EeV and in the zenith-angle range from θ = 60° to θ = 95°, where the zenith angle is measured from the vertical direction. No neutrinos from the direction of TXS 0506+056 have been found. The results were analyzed in three periods: one of 6 months around the detection of IceCube-170922 A, coinciding with a flare period of TXS 0506+056, a second one of 110 days during which the IceCube collaboration found an excess of 13 neutrinos from a direction compatible with TXS 0506+056, and a third one from 2004 January 1 up to 2018 August 31, over which the Pierre Auger Observatory has been taking data. The sensitivity of the Observatory is addressed for different spectral indices by considering the fluxes that would induce a single expected event during the observation period. For indices compatible with those measured by the IceCube collaboration the expected number of neutrinos at the Observatory is well below one. Spectral indices as hard as 1.5 would have to apply in this energy range to expect a single event to have been detected.

79 ASTRONOMY AND ASTROPHYSICS↗

A Search for Photons with Energies Above 2 × 10 17 eV Using Hybrid Data from the Low-Energy Extensions of the Pierre Auger Observatory

Ultra-high-energy photons with energies exceeding 10 17 eV offer a wealth of connections to different aspects of cosmic-ray astrophysics as well as to gamma-ray and neutrino astronomy. The recent observations of photons with energies in the 10 15 eV range further motivate searches for even higher-energy photons. In this paper, we present a search for photons with energies exceeding 2 × 10 17 eV using about 5.5 yr of hybrid data from the low-energy extensions of the Pierre Auger Observatory. The upper limits on the integral photon flux derived here are the most stringent ones to date in the energy region between 10 17 and 10 18 eV.

79 ASTRONOMY AND ASTROPHYSICS↗

Arrival Directions of Cosmic Rays above 32 EeV from Phase One of the Pierre Auger Observatory

A promising energy range to look for angular correlations between cosmic rays of extragalactic origin and their sources is at the highest energies, above a few tens of EeV (1 EeV ≡ 10$^{18}$ eV). Despite the flux of these particles being extremely low, the area of ∼3000 km$^{2}$ covered at the Pierre Auger Observatory, and the 17 yr data-taking period of the Phase 1 of its operations, have enabled us to measure the arrival directions of more than 2600 ultra-high-energy cosmic rays above 32 EeV. We publish this data set, the largest available at such energies from an integrated exposure of 122,000 km$^{2}$ sr yr, and search it for anisotropies over the 3.4π steradians covered with the Observatory. Evidence for a deviation in excess of isotropy at intermediate angular scales, with ∼15° Gaussian spread or ∼25° top-hat radius, is obtained at the 4σ significance level for cosmic-ray energies above ∼40 EeV.

79 ASTRONOMY AND ASTROPHYSICS↗

Search for Ultra-high-energy Photons from Gravitational Wave Sources with the Pierre Auger Observatory

A search for time-directional coincidences of ultra-high-energy (UHE) photons above 10 EeV with gravitational wave (GW) events from the LIGO/Virgo runs O1 to O3 is conducted with the Pierre Auger Observatory. Due to the distinctive properties of photon interactions and to the background expected from hadronic showers, a subset of the most interesting GW events is selected based on their localization quality and distance. Time periods of 1000 s around and 1 day after the GW events are analyzed. No coincidences are observed. Upper limits on the UHE photon fluence from a GW event are derived that are typically at ~7 MeV cm -2 (time period 1000 s) and ~35 MeV cm -2 (time period 1 day). Due to the proximity of the binary neutron star merger GW170817, the energy of the source transferred into UHE photons above 40 EeV is constrained to be less than 20% of its total GW energy. These are the first limits on UHE photons from GW sources.

79 ASTRONOMY AND ASTROPHYSICS↗

Large-scale Cosmic-ray Anisotropies with 19 yr of Data from the Pierre Auger Observatory

Results are presented for the measurement of large-scale anisotropies in the arrival directions of ultra–high-energy cosmic rays detected at the Pierre Auger Observatory during 19 yr of operation, prior to AugerPrime, the upgrade of the observatory. The 3D dipole amplitude and direction are reconstructed above 4 EeV in four energy bins. Besides the established dipolar anisotropy in R.A. above 8 EeV, the Fourier amplitude of the 8–16 EeV energy bin is now also above the 5σ discovery level. No time variation of the dipole moment above 8 EeV is found, setting an upper limit to the rate of change of such variations of 0.3% yr$^{−1}$ at the 95% confidence level. Additionally, the results for the angular power spectrum are shown, demonstrating no other statistically significant multipoles. The results for the equatorial dipole component down to 0.03 EeV are presented, using for the first time a data set obtained with a trigger that has been optimized for lower energies. Finally, model predictions are discussed and compared with observations, based on two source emission scenarios obtained in the combined fit of spectrum and composition above 0.6 EeV.

79 ASTRONOMY AND ASTROPHYSICS↗

The Distribution of Ultrahigh-energy Cosmic Rays along the Supergalactic Plane Measured at the Pierre Auger Observatory

Ultrahigh-energy cosmic rays are known to be mainly of extragalactic origin, and their propagation is limited by energy losses, so their arrival directions are expected to correlate with the large-scale structure of the local Universe. In this work, we investigate the possible presence of intermediate-scale excesses in the flux of the most energetic cosmic rays from the direction of the supergalactic plane region using events with energies above 20 EeV recorded with the surface detector array of the Pierre Auger Observatory up to 2022 December 31, with a total exposure of 135,000 km 2 sr yr. The strongest indication for an excess that we find, with a posttrial significance of 3.1σ, is in the Centaurus region, as in our previous reports, and it extends down to lower energies than previously studied. We do not find any strong hints of excesses from any other region of the supergalactic plane at the same angular scale. In particular, our results do not confirm the reports by the Telescope Array Collaboration of excesses from two regions in the Northern Hemisphere at the edge of the field of view of the Pierre Auger Observatory. With a comparable integrated exposure over these regions, our results there are in good agreement with the expectations from an isotropic distribution.

Abdul Halim, A. [Univ. of Adelaide, SA (Australia)↗

Scaler Rates from the Pierre Auger Observatory: A New Proxy of Solar Activity

The modulation of low-energy galactic cosmic rays reflects interplanetary magnetic field variations and can provide useful information on solar activity. An array of ground-surface detectors can reveal the secondary particles, which originate from the interaction of cosmic rays with the atmosphere. In this work, we present an investigation of the low-threshold rate (scaler) time series recorded in 16 yr of operation by the Pierre Auger Observatory surface detectors in Malargüe, Argentina. Through an advanced spectral analysis, we detected highly statistically significant variations in the time series with periods ranging from the decadal to the daily scale. We investigate their origin, revealing a direct connection with solar variability. Thanks to their intrinsic very low noise level, the Auger scalers allow a thorough and detailed investigation of the galactic cosmic-ray flux variations in the heliosphere at different timescales and can, therefore, be considered a new proxy of solar variability.

79 ASTRONOMY AND ASTROPHYSICS↗

A Catalog of the Highest-energy Cosmic Rays Recorded during Phase I of Operation of the Pierre Auger Observatory

A catalog containing details of the highest-energy cosmic rays recorded through the detection of extensive air showers at the Pierre Auger Observatory is presented with the aim of opening the data to detailed examination. Descriptions of the 100 showers created by the highest-energy particles recorded between 2004 January 1 and 2020 December 31 are given for cosmic rays that have energies in the range 78–166 EeV. Details are also given on a further nine very energetic events that have been used in the calibration procedure adopted to determine the energy of each primary. A sky plot of the arrival directions of the most energetic particles is shown. No interpretations of the data are offered.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗