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At least 847 records · Page 47

County-Level Hourly Renewable Capacity Factor Dataset for the ReEDS Model

This dataset contains hourly capacity factors for each renewable resource class and region (in this case, county). Technologies like large-scale utility PV (UPV), onshore wind, offshore wind, and concentrating solar power (CSP) are included. The dataset contains 7 years of hourly weather data (2007-2013) for different sites across the US and is used as one of the inputs to the ReEDS-2.0 model (see the "ReEDS 2.0 GitHub Repository" resource link below), developed by NREL. The weather profiles apply to any capacity that exists or is built in each region and class. This helps calculate the generation that can be provided using these resources. Open, reference, and limited are 3 scenarios based on land-use allowance, derived from the Renewable Energy Potential (reV) model developed by NREL, which helps generate supply curves for renewable technologies and assess the maximum potential of renewable resources in a designated area. Each zipped file in this dataset corresponds to a technology and contains the respective land-use scenario files required to run that technology in ReEDS. To use this dataset, download and place the extracted files in the locally cloned ReEDS repository inside one of the folders (inputs/variability/multi_year). After completing this copy, upon running the ReEDS model at the county-level spatial resolution for respective analysis purposes, the program will detect the presence of these files and will not fail.

Array↗

Assessing feasible H2–CO2 sources in the US as Feedstocks for Sustainable Aviation Fuel Precursors: Acetic Acid and Ethanol Production via Hydrogenotrophic Pathways

The environmental impact of carbon dioxide emissions is significant, and research is focused on mitigating these emissions and developing eco-friendly technologies in line with green chemistry principles. Waste-to-energy technologies play a crucial role in converting waste into renewable energy and valuable biofuels and bioproducts. This study specifically explores the utilization of waste gas emissions, particularly carbon dioxide, from various sources in the United States for the production of sustainable aviation fuel (SAF) precursors, such as ethanol and acetic acid. The study categorizes and quantifies the volumes of carbon dioxide emissions into three types: non-biogenic, biogenic, and biogenic emissions from ethanol production facilities. Stoichiometric calculations are applied to compare the amounts of carbon dioxide from each category with the available hydrogen production capacity, determining if sufficient hydrogen is present for converting carbon dioxide into SAF precursors. The study reveals two key findings. Firstly, there is a significant reserve of carbon dioxide, approximately 1648 million metric tons per year (MMTy), combining all three categories, which would require a substantial increase of approximately 35–40 times in the existing hydrogen production capacity of 4.988 MMTy. This increased hydrogen production has the potential to yield approximately 1067.82 MMTy of acetic acid and 189.19 MMTy of ethanol annually. Secondly, upon analyzing the quality and application of the three sources of carbon dioxide with the currently available hydrogen production capacity, it is found that biogenic carbon dioxide from ethanol plants is the most suitable choice for immediate production of SAF precursors. This would theoretically result in an annual production of 1.36 MMTy of ethanol and 1.772 MMTy of acetic acid. The other two sources of carbon dioxide can be considered potential reserves for future utilization when additional hydrogen production facilities are established. The study provides a foundation for assessing the aggregation potential required for acetic acid and ethanol production. By optimizing the use of waste gases as raw materials, the study not only enables the production of SAF precursors but also contributes to the passive reduction of greenhouse gas emissions.

Carbon Dioxide↗

A Framework for Dimensioning VDL-2 Air-Ground Networks

This paper describes a framework developed at MITRE for dimensioning a Very High Frequency (VHF) Digital Link Mode 2 (VDL-2) Air-to-Ground network. This framework was developed to support the FAA's Data Communications (Data Comm) program by providing estimates of expected capacity required for the air-ground network services that will support Controller-Pilot-Data-Link Communications (CPDLC), as well as the spectrum needed to operate the system at required levels of performance. The Data Comm program is part of the FAA's NextGen initiative to implement advanced communication capabilities in the National Airspace System (NAS). The first component of the framework is the radio-frequency (RF) coverage design for the network ground stations. Then we proceed to describe the approach used to assess the aircraft geographical distribution and the data traffic demand expected in the network. The next step is the resource allocation utilizing optimization algorithms developed in MITRE's Spectrum ProspectorTM tool to propose frequency assignment solutions, and a NASA-developed VDL-2 tool to perform simulations and determine whether a proposed plan meets the desired performance requirements. The framework presented is capable of providing quantitative estimates of multiple variables related to the air-ground network, in order to satisfy established coverage, capacity and latency performance requirements. Outputs include: coverage provided at different altitudes; data capacity required in the network, aggregated or on a per ground station basis; spectrum (pool of frequencies) needed for the system to meet a target performance; optimized frequency plan for a given scenario; expected performance given spectrum available; and, estimates of throughput distributions for a given scenario. We conclude with a discussion aimed at providing insight into the tradeoffs and challenges identified with respect to radio resource management for VDL-2 air-ground networks.

Aviation↗

Porous Materials for Water Purification

Water pollution is a growing threat to humanity due to the pervasiveness of contaminants in water bodies. Significant efforts have been made to separate these hazardous components to purify polluted water through various methods. However, conventional remediation methods suffer from limitations such as low uptake capacity or selectivity, and current water quality standards cannot be met. Recently, advanced porous materials (APMs) have shown promise in improved segregation of contaminants compared to traditional porous materials in uptake capacity and selectivity. These materials feature merits of high surface area and versatile functionality, rendering them ideal platforms for the design of novel adsorbents. Here, this Review summarizes the development and employment of APMs in a variety of water treatments accompanied by assessments of task-specific adsorption performance. Finally, we discuss our perspectives on future opportunities for APMs in water purification.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Refractory-based thermal energy storage for industrial process heat: one-dimensional modeling, control, and optimization

The variable and weather-dependent output of wind and solar power plants present a substantial challenge for planning and operating electricity-systems, particularly in the absence of cost-effective and dispatchable energy storage technologies. This study investigates a high-temperature, electrically heated, refractory-based thermal energy storage (RTES) system that stores electrical energy as sensible heat in dense ceramic bricks over the 950–1800 °C range. The stored heat can be discharged as a controlled hot-gas stream for industrial heating, fuel substitution in high-temperature processes, or electricity generation. The main novelty is a comprehensive modelling, control, mapping, and optimization framework that integrates one-dimensional transient gas–solid heat transfer, fan-assisted discharge, bypass-flow regulation, reheating logic, fan-power evaluation, insulation-loss assessment, and genetic-algorithm-based design optimization. The model uses feedback from outlet temperature and delivered power to regulate discharge, while a two-stage genetic algorithm optimizes brick-channel geometry, gas-flow operation, and multilayer insulation thicknesses. Storage capacities below 50 MWh and discharge powers of 5–30 MW are analyzed to evaluate hold time, thermal delivery, fan-power penalty, heat loss, state-of-charge evolution, and indicative capital cost. Results demonstrate that optimized and well-insulated refractory-based thermal energy storage units can provide stable, efficient, and repeatable heat delivery over multiple discharge cycles. The generated performance and cost maps support modular refractory thermal energy storage as a practical option for large-scale integration of wind and solar generation and for high-temperature industrial process heat.

25 ENERGY STORAGE↗

Carbonation reaction of recycled concrete aggregates (RCA): CO 2 mass consumption under various treatment conditions

Concrete is a key building material around the world due to its excellent strength and durability. Recycling demolished concrete for new construction materials may play a significant role in sustainable development. Producing recycled concrete aggregates (RCA) from waste concrete is one approach for such an initiative. However, using RCA may pose challenges, such as reduced density, lower elastic modulus and strength, and increased water absorption. Recently, the carbonation of RCA has emerged as a method to address those concerns. This study explores the carbon sequestration capacity of RCA through carbonation, examining various parametric conditions, including initial CO 2 pressure, relative humidity, temperature, and pre-treatment approach. Both lab-scale and large-scale carbonation tests were conducted. Additionally, a cost analysis and CO 2 footprint assessment were performed. The findings showed that applying higher initial CO 2 pressures (e.g., 40–60 psi) and optimal relative humidity (~55 %) could significantly enhance the carbonation efficiency of RCA. Elevating temperature also led to accelerated CO 2 consumption, being more effective on the lab scale. The economic analysis presented potential cost benefits when substituting natural aggregates with CO 2 -treated RCA. All in all, these results suggest that the carbonation of RCA may provide significant environmental benefits through carbon sequestration, promoting sustainable construction practices.

36 MATERIALS SCIENCE↗

Buffering the impacts of extreme climate variability in the highly engineered Tigris Euphrates river system

More extreme and prolonged floods and droughts, commonly attributed to global warming, are affecting the livelihood of major sectors of the world’s population in many basins worldwide. While these events could introduce devastating socioeconomic impacts, highly engineered systems are better prepared for modulating these extreme climatic variabilities. Herein, we provide methodologies to assess the effectiveness of reservoirs in managing extreme floods and droughts and modulating their impacts in data-scarce river basins. Our analysis of multiple satellite missions and global land surface models over the Tigris-Euphrates Watershed (TEW; 30 dams; storage capacity: 250 km 3 ), showed a prolonged (2007–2018) and intense drought (Average Annual Precipitation [AAP]: < 400 km 3 ) with no parallels in the past 100 years (AAP during 1920–2020: 538 km 3 ) followed by 1-in-100-year extensive precipitation event (726 km 3 ) and an impressive recovery (113 ± 11 km 3 ) in 2019 amounting to 50% of losses endured during drought years. Dam reservoirs captured water equivalent to 40% of those losses in that year. Additional studies are required to investigate whether similar highly engineered watersheds with multi-year, high storage capacity can potentially modulate the impact of projected global warming-related increases in the frequency and intensity of extreme rainfall and drought events in the twenty-first century.

54 ENVIRONMENTAL SCIENCES↗

Resilience Analytics for Interdependent Power and Water Distribution Systems

The occurrence of large-scale outages in power distribution systems (PDSs) caused, for instance, by extreme weather events has raised concerns on the cascading impact of the power outages on the resilience of other critical infrastructures, including water distribution systems (WDSs), whose healthy operation highly relies on the availability of power from PDSs. Here, this paper proposes an analytics model for quantifying the interdependence between the resilience of power and water distribution systems. The proposed model first performs spatio-temporal outage analysis on the PDS and WDS to determine the PDS power serving capability and the resulting cascading impact on the WDS water serving capability during the occurrence of disruptions. The resilience interdependence is then determined by a proposed set of six metrics calculated using the power and water serving capability profiles, which trace and quantify the cascading impacts of power outages in the operation of WDSs during the degradation and recovery stages. The proposed analytics model is implemented on the IEEE 33-bus power distribution system supplying power for pumping stations of a 15-node test WDS, considering multiple cases of water storage capacity, single and multiple outage scenarios, and availability of distributed generation. The numerical results demonstrate that the proposed metrics track the temporal and spatial interdependence between the resilience of power and water distribution systems, providing a mechanism to identify weak spots, and assess options to enhance the resilience of the critical water infrastructure.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Engineering aspects of a thermal control subsystem for the 25 kW power module

The paper presents the key trade study results, analysis results, and the recommended thermal control approach for the 25 kW power module defined by NASA. Power conversion inefficiencies and component heat dissipation results in a minimum heat rejection requirement of 9 kW to maintain the power module equipment at desired temperature levels. Additionally, some cooling capacity should be provided for user payloads in the sortie and free-flying modes. The baseline thermal control subsystem includes a dual-loop-pumped Freon-21 coolant with the heat rejected from deployable existing orbiter radiators. Thermal analysis included an assessment of spacecraft orientations, radiator shapes and locations, and comparison of hybrid heat pipe and all liquid panels.

Schroeder, P. E.↗

Assessment of regional biomass-soil relationships using vegetation indexes

The development of photosynthetic active biomass in different ecological conditions, as indicated by normalized difference vegetation indices (NDVIs) is compared by performing a stratified sampling (based on soil assocations) on data acquired over Indiana. Data from the NOAA-10 AVHRR were collected for the 1987 and 1988 growing seasons. An NDVI transformation was performed using the two optical bands of the sensor (0.58-0.68 microns and 0.72-1.10 microns). The NDVI is related to the amount of active photosynthetic biomass present on the ground. Samples of NDVI values over 45 fields representing eight soil associations throughout Indiana were collected to assess the effect of soil conditions and acquisition date on the spectral response of the vegetation, as shown by the NDVIs. Statistical analysis of results indicate that land-cover types (forest, forest/pasture, and crops), soil texture, and soil water-holding capacity have an important effect on vegetation biomass changes as measured by AVHRR data. Acquisition dates should be selected with condideration of the phenological stages of vegetation. Sampling of AVHRR data over extended areas should be stratified according to physiographic units rather than man-made boundaries. This will provide more homogeneous samples for statistical analysis.

Lozano-Garcia, D. Fabian↗

Risk Model for EM Decision Support Toolsets

The Government Office of Accountability (GAO) has published several reports identifying the need for the Department of Energy (DOE) Office of Environmental Management (EM) to address mounting costs for DoE's cleanup program. DOEEM could greatly benefit from independent decision tool-sets/models that would allow them to evaluate options and inform business decision at the enterprise level considering site-specific life cycle costs and system plans. Program goals: Develop a tool-set that enables EM to independently evaluate alternatives, assess outcomes from different contracting strategies, and inform critical decisions for the enterprise. Project goals: Adaption of a Risk Model for integration with complimentary tool-sets for project level decision making. Operational Events: Discrete event model that evaluates operational variables (e.g. capacity, throughput, maintenance constraints) and identify bottlenecks. Identifying and Bounding Project Risk: Identify risks that impact confidence in meeting goals (e.g. production). Life cycle Cost: Evaluate impacts of staffing levels, inventory, and capital investments on life cycle costs. Methods and approach: Monte Carlo Analysis is being executed to generate results: Input derives from Risk Register Data; Tied to Projected and Target Schedules; Incorporates float duration within the model. Assumes associated risk mitigation actions being completed within a timeline of five fiscal years. Metrics include: Confidence in Meeting Production Goal; Confidence in Safety Standards; Confidence in Continuous Operation; Other Metrics can be added as appropriate regarding specific site needs. The adapted risk model can be used as a stand alone decision tool or can be integrated complementary tool-sets (i.e. process and cost models) for project-specific decisions. These support tool-sets can then be integrated with others for site- and complex- level evaluations. Future work includes designing an adaptable and modular framework that would allow integration of multiple tool-sets for holistic and/or targeted evaluation of alternative strategies for decision making that could lead to risk and cost reduction across the enterprise.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Activated Internetwork Pathways in Partially‐Disordered Spinel Cathode Materials with Ultrahigh Rate Performance

Abstract In this study, a class of earth‐abundant, cation‐excess partially disordered spinel materials which demonstrate superior rate performance as Li‐ion cathodes compared to disordered rocksalt materials is computationally investigated. These results show that the partial disorder creates solid solution lithiation with spinel‐like features at the atomic level. A low‐voltage capacity gain is possible with lithiation past the rock salt stoichiometry. It is argued that high rate in partially disordered spinel materials comes from newly activated 16c/16d internetwork pathways which are not possible in normal spinel where only 16c intranetwork diffusion occurs. The assessment and understandings motivate the incorporation of some degree of partial spinel ordering in future disordered rocksalt electrodes to enable superior rate performance.

Yang, Julia H.↗

Influence of extreme temperature conditions on CO 2 direct air capture using amino-acid solutions

Geological features play a pivotal role in determining the feasibility of deploying CO₂ direct air capture (DAC) technologies, primarily because they influence the availability of cost-effective energy sources, such as natural gas and geothermal energy, and also due to the potential for CO₂ sequestration. Many regions face challenges due to variable weather conditions including seasonal temperature fluctuations, high or low humidity, and sub-ambient temperatures. These extremes can reduce DAC performance or even lead to catastrophic events. Aqueous solvents considered for DAC systems are particularly vulnerable to seasonal variations in colder climates, where the solvent may underperform or freeze. It is therefore essential to investigate the CO₂ capture efficiency of aqueous solvents across a broad range of environmental temperatures, spanning sub-zero to hot conditions (>30 °C). In this study, DAC operation is examined using a high-flux solvent–air crossflow contactor under two major weather scenarios: (i) cold conditions below 0 °C and (ii) hot conditions above 30 °C. A parametric study is conducted to investigate the contactor performance regarding CO₂ removal efficiency, uptake capacity, and reaction kinetics versus temperature when the air velocity through the contactor exceeds 1 m/s. The efficacy of the contactor is systematically investigated using various anti-freeze amino-acid solvent formulations. A mass-transfer mechanistic model is developed to assess the process performance over a wide temperature range and propose scalable design guidelines. Machine learning is also employed to identify key parameters affecting the CO₂ capture efficiency. It is shown that air velocity and temperature are the primary factors influencing CO₂ uptake. Based on performance data obtained under subfreezing temperatures, a technoeconomic analysis is conducted to evaluate the feasibility of using aqueous solvents in seasonal cold regions. In conclusion, the findings of this study provide valuable insights into siting considerations for deploying solvent-based DAC, thereby contributing to the advancement of sustainable carbon removal solutions.

Air–liquid contactor↗

Multi-model Hydroclimate Projections for the Alabama-Coosa-Tallapoosa River Basin in the Southeastern United States

Abstract This study uses a high-resolution, process-based modeling framework to assess the impacts of changing climate on water resources for the Alabama-Coosa-Tallapoosa River Basin in the southeastern United States. A 33-member ensemble of hydrologic projections was generated using 3 distributed hydrologic models (Precipitation-Runoff Modeling System, Variable Infiltration Capacity, and Distributed Hydrology Soil Vegetation Model) of different complexity. These hydrologic models were driven by dynamically downscaled and bias-corrected future climate simulations from 11 Coupled Model Intercomparison Project Phase 5 global climate models under Representative Concentration Pathway 8.5 emission scenario, with 40 years each in baseline (1966–2005) and future (2011–2050) periods. The hydroclimate response, in general, projects an increase in mean seasonal precipitation, runoff, and streamflow. The high and low flows are projected to increase and decrease, respectively, in general, suggesting increased likelihood of extreme rainfall events and intensification of the hydrologic cycle. The uncertainty associated with the ensemble hydroclimate response, analyzed through an analysis of variance technique, suggests that the choice of climate model is more critical than the choice of hydrologic model for the studied region. This study provides in-depth insights of hydroclimate response and associated uncertainties to support informed decisions by water resource managers.

54 ENVIRONMENTAL SCIENCES↗

Volume 10: Flow Test Facilities

Adding additional flow testing facilities has been considered as part of the High Flux Isotope Reactor (HFIR) Sustaining and Enhancing Neutron Science (SENSe) Initiative at Oak Ridge National Laboratory (ORNL) to support HFIR operations and experiments. This prospect has prompted many ideas and discussions regarding potential features, configurations, locations, and applications for the facilities. A working group of ORNL staff members was formed in fiscal year 2022 to recommend one or more configurations to best support future HFIR operations and scientific capacities and to develop order-of magnitude cost estimates and timing. The ideas discussed in this report include options ranging from upgrading existing small-scale testing facilities to building a full-scale HFIR mockup for detailed thermohydraulic testing and fuel assessment.

07 ISOTOPE AND RADIATION SOURCES↗

Distributed Mafic Rock Resources for Carbon Mineralization in Arizona

Ex-situ carbon mineralization is a process by which CO2 is reacted with alkaline silicate minerals and rocks to produce stable carbonate materials, which can be used for other industrial processes. Arizona, U.S.A., hosts abundant surficial mafic rocks in three young volcanic fields, Geronimo-San Bernardino, San Francisco, and Springerville, and other distributed locations throughout the state. We created a Mafic Rock Resource Inventory (MRRI) that categorizes geochemical, physical, and textural characteristics of a diverse suite of surficial mafic rock samples and provide a benchmark reaction dataset parameterizing the temperature, pressure, and pH conditions best suited ex-situ mineralization in different rock types. MRRI data is publicly available online via a map-viewer. We establish two reaction condition sets, varied in temperature, pressure, and pH, where crystal-rich and glassy rocks reach maximum reaction extent and different carbonate phases are formed. Systematic ex-situ mineralization experiments on 21 diverse rock types show trends in geochemical, mineralogical, and reactivity behavior and establish maximum effective capture capacity. From this, scoria cones in three Arizona volcanic fields have a ~62 Gt effective CO₂ storage capacity with one of the fields having a ~42 Gt storage capacity in lava flows. Reactivity results have applications to alkaline mafic rock resources exposed globally, including producing additional effective storage capacity estimates and scaled commercialization of mafic rock ex-situ mineralization, should reaction extents be improved through advances in mineralization techniques. MRRI data were used to create a Direct Air Capture to Mineralization (DACM) systems model, technoeconomic analysis, and life-cycle assessment. These documents are presented as three appendices.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

OAST Space Theme Workshop. Volume 3: Working group summary. 2: Data handling, communications (E-2). A. Statement. B. Technology needs (form 1). C. Priority assessment (form 2)

Technologies required to support the stated OAST thrust to increase information return by X1000, while reducing costs by a factor of 10 are identified. The most significant driver is the need for an overall end-to-end data system management technology. Maximum use of LSI component technology and trade-offs between hardware and software are manifest in most all considerations of technology needs. By far, the greatest need for data handling technology was identified for the space Exploration and Global Services themes. Major advances are needed in NASA's ability to provide cost effective mass reduction of space data, and automated assessment of earth looking imagery, with a concomitant reduction in cost per useful bit. A combined approach embodying end-to-end system analysis, with onboard data set selection, onboard data processing, highly parallel image processing (both ground and space), low cost, high capacity memories, and low cost user data distribution systems would be necessary.

Source record↗

Solar-energy-system performance evaluation: Honeywell OTS 44, Ocmulgee, Georgia

The operation and technical performance of the solar operational test site (OTS 44) are described, based on data collected between April, 1981 and August, 1981. The following topics are discussed: system description, performance assessment, operating energy, energy savings, system maintenance, and conclusions. The solar energy system at OTS 44 is a hydronic heating and cooling system consisting of 5040 square feet of liquid cooled flat plate collectors; a 4000 gallon thermal storage tank; one 25 ton capacity organic Rankine cycle engine assisted water chillers; a forced draft cooling tower; and associated piping, pumps, valves, controls and heat rejection equipment. The solar system has eight basic modes of operation and several combination modes for providing space conditioning and hot water to the building. Data monitored during the 4 months of the operational test period found that the solar system collected 285 MMBtu of thermal energy of the total incident solar energy of 1040 MMBtu and provided 210 MMBtu for cooling and 10 MMBtu for heating and hot water. The net electrical energy saving due to the solar system was approximately 2600 kWh(e), and fossil energy saving was about 20 million Btu (MMBtu).

Mathur, A. K.↗