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At least 847 records · Page 47

Twinning behaviors of a rolled AZ31 magnesium alloy under multidirectional loading

The microstructure and texture evolution of an AZ31 magnesium rolled sheet during quasi-static compression at strain rates of 10{sup −3} s{sup −1} has been investigated by in situ electron backscattered diffraction. The influence of the initial and pre-deformed texture on the predominant deformation mechanisms during compression has been examined. It has been found that extensive grain reorientation due to (10 − 12) tensile twinning appeared when compressed along transverse direction. Tensile twin variants were observed under this loading condition, and different variants will cause an effect to the following deformation. Several twinning modes occurred with continuative loading along rolling direction. - Highlights: •Twinning behaviors were investigated through in situ multidirectional compressive tests. •Deformation behavior was affected by the twin variants. •Four types of twinning behaviors were observed during deformation process.

36 MATERIALS SCIENCE↗

Tensile and high cycle fatigue behaviors of high-Mn steels at 298 and 110 K

Tensile and high cycle fatigue behaviors of high-Mn austenitic steels, including 25Mn, 25Mn0.2Al, 25Mn0.5Cu, 24Mn4Cr, 22Mn3Cr and 16Mn2Al specimens, were investigated at 298 and 110 K. Depending on the alloying elements, tensile ductility of high-Mn steels either increased or decreased with decreasing temperature from 298 to 110 K. Reasonable correlation between the tendency for martensitic tranformation, the critical twinning stress and the percent change in tensile elongation suggested that tensile deformation of high-Mn steels was strongly influenced by SFE determining TRIP and TWIP effects. Tensile strength was the most important parameter in determining the resistance to high cycle fatigue of high-Mn steels with an exceptional work hardening capability at room and cryogenic temperatures. The fatigue crack nucleation mechanism in high-Mn steels did not vary with decreasing tempertature, except Cr-added specimens with grain boundary cracking at 298 K and slip band cracking at 110 K. The EBSD (electron backscatter diffraction) analyses suggested that the deformation mechanism under fatigue loading was significantly different from tensile deformation which could be affected by TRIP and TWIP effects. - Highlights: •The resistances to HCF of various high-Mn steels were measured. •The variables affecting tensile and HCF behaviors of high-Mn steels were assessed. •The relationship between tensile and the HCF behaviors of high-Mn steels was established.

36 MATERIALS SCIENCE↗

Effect of quenching rate on the microstructure and mechanical behavior of Ce75Al21Ga4 glassy alloy

Highlights: • Structural and microstructural changes with respect to quenching rate have been reported. • Ribbons synthesized at slow cooling rate shows higher hardness and yield strength. • Study is focused on the correlation between quenching rate and mechanical behavior. • Metallic glass synthesized at faster quenching rate contains the highest shear band density. - Abstract: The present study deals with the structural and microstructural changes with respect to the quenching rate and their correlation with mechanical behavior of melt-spun Ce{sub 75}Al{sub 21}Ga{sub 4} glassy alloys. The ribbons of the alloy have been synthesized at different quenching rates obtained through different wheel speeds (44, 36, 29, 22 and 15 m/s). The glass forming indicators and mechanical properties have been investigated at different quenching rates. The higher quenching rate obtained through high wheel speed (44, 36 and 29 m/s) has led to phase separation giving rise to nano-amorphous domains in a glassy matrix while the lower quenching rate obtained through lower wheel speed (22 and 15 m/s) produces nano-crystalline grains with size ranges from 25 ± 1 to 120 ± 1 nm. It has been found that the size of the nano-amorphous domains decreases with decrease in wheel speed. The mechanical behavior has been studied using micro-indentation technique. The indentation test indicates that with the same chemical composition, the ribbons synthesized at slow quenching rate exhibits higher hardness and yield strength than those synthesized at faster quenching rate. The ribbons synthesized at 44 m/s contains the large free volume and has the highest shear band density.

36 MATERIALS SCIENCE↗

Effects of LPSO/α-Mg interfaces on dynamic recrystallization behavior of Mg96.5Gd2.5Zn1 alloy

Highlights: • The effects of LPSO/α-Mg interfaces on the dynamic recrystallization (DRX) behavior of Mg{sub 96.5}Gd{sub 2.5}Zn{sub 1} (at.%) alloy during indirect extrusion at 350 °C were investigated. • The LPSO/α-Mg interfaces in Mg{sub 96.5}Gd{sub 2.5}Zn{sub 1} alloy appeared as two groups, including the basal and non-basal LPSO/α-Mg interfaces, which have various effects on the DRX behavior of Mg{sub 96.5}Gd{sub 2.5}Zn{sub 1} alloy. • Compared with the basal LPSO/α-Mg interfaces, DRX grains are preferentially nucleated near the non-basal LPSO/α-Mg interfaces where there is higher V{sub GROD} and lower required energy E{sub s} for the DRX nucleation. - Abstract: Mg-Gd-Zn alloy, which contains a long period stacking ordered (LPSO) structure, has the potential to become a high-strength Mg alloy within the automotive and aerospace industries. Two types of LPSO/α-Mg interfaces in Mg{sub 96.5}Gd{sub 2.5}Zn{sub 1} (at.%) alloy were characterized, namely, basal and non-basal LPSO/α-Mg interfaces. The effects of LPSO/α-Mg interfaces on the dynamic recrystallization (DRX) behavior during indirect extrusion at 350 °C were investigated. The grain reference orientation deviation (GROD) value (V{sub GROD}), derived from EBSD, could qualitatively characterize the dislocation density within a grain and determine the presence of DRX grain nucleation. The results suggested that the areas around non-basal LPSO/α-Mg interfaces always have higher V{sub GROD} than do basal LPSO/α-Mg interfaces. In addition, the stored energy (E{sub s}) required for DRX nucleation on the non-basal LPSO/α-Mg interface is lower than that on the basal LPSO/α-Mg interface. This is a result of the flat, sharp basal LPSO/α-Mg interface compared to the faceted non-basal LPSO/α-Mg interface. Regardless of whether the LPSO structure/α-Mg matrix interface is coherent or not, non-basal LPSO/α-Mg interfaces are favorable nucleation sites for DRX grains due to the higher V{sub GROD} and lower required energy E{sub s}.

36 MATERIALS SCIENCE↗

Precipitation behavior of stainless steel weld overlay cladding exposed to a long-term thermal aging

Highlights: • Silicide phase formation with G-phase was first time to be observed. • Precipitation behavior discrepancy existed at different locations of ferrite phase. • G-phase and silicide phase formed along dislocations and within ferrite matrix. • Heterogeneous distribution of elements induced silicide phase formation. - Abstract: Thermal aging behavior of stainless steel weld overlay cladding aged at 400 °C for 10,000 h was investigated. The results showed that the precipitates along the dislocation and within ferrite matrix contained the face-centered cubic structural G-phase and silicide phase. Silicide phase, supposed to be (Fe, Mn){sub 3}Si phase, preferred to form with G-phase along the dislocations and within ferrite matrix. Silicide phase showed a cube-on-cube relationship with ferrite phase and G-phase. Heterogeneous distribution of elements within Ni-Mn-Si clusters was responsible for silicide phase formation during thermal aging process, and the corresponding precipitation behavior discrepancy at different forming sites (dislocations, ferrite matrix and phase boundary) was discussed.

36 MATERIALS SCIENCE↗

Effect of in-situ (TiC-TiB2) reinforcement on aging and mechanical behavior of AZ91 magnesium matrix composite

Highlights: • Effect of TiC-TiB{sub 2} particles on precipitation behavior of in-situ composite was studied. • The age-hardening rate of in-situ composites is faster than that of alloy. • Faster age hardening rate is due to the presence of high dislocation density in composite. • Post aging treatment improved the mechanical properties of both base and composite. - Abstract: In the present work, influence of in-situ TiC-TiB{sub 2} reinforcement on age hardening behavior and mechanical properties of TiC-TiB{sub 2}/AZ91 composite was investigated. The base and in-situ composite materials were solution treated at 400 °C for 24 h and then aged at different temperatures up to 100 h. The kinetics of age hardening results revealed that the addition of in-situ TiC-TiB{sub 2} reinforcement increase the age hardening kinetics of the composite as compared to AZ91 magnesium alloy. The improvement in age hardening kinetics is attributed to the presence of high dislocation density resulted from the mismatch of coefficients of thermal expansion between in-situ TiC-TiB{sub 2} reinforcement and magnesium matrix. The precipitation behavior of Mg{sub 17}Al{sub 12} phase in both AZ91 alloy and TiC-TiB{sub 2}/AZ91 composites were established. After age hardening, base and in-situ composite materials show significant improvement in ultimate tensile strength by 47.72% and 66.49% respectively as compared with the base monolithic alloy. The enhancement of mechanical properties in the base and in-situ composites is explained in detail by analyzing their fractographs and microstructures.

36 MATERIALS SCIENCE↗

Effects of processing defects on the dynamic tensile mechanical behavior of laser-solid-formed Ti-6Al-4 V

Highlights: • Tensile tests are conducted under coupled effects of strain rate and temperature. • Defects act as crack initiation and propagation sites for dynamic tensile fracture. • Dynamic tension-compression asymmetry is due to different behaviors of defects. • Different deformation of defects results in tensile mechanical anisotropy. • Mechanical anisotropy and asymmetry are sensitive to strain rate and temperature. - Abstract: The initial processing defects, i.e. voids, lack-of-fusion pores and inclusions, are the inevitable and unique microstructural features in the Ti-6Al-4 V (Ti64) alloy manufactured by laser solid forming (LSF). This study was to gain insight into the influences of these processing defects on the tensile thermomechanical response of the material under various strain rates of 0.001/s, 500/s, 1000/s and 3000/s, and under a wide range of temperatures from 298 K to 1273 K. The drastic effects of processing defects on the flow stress were founded to be susceptible to tensile loading and increase with the increasing strain rate. The SEM analysis was carried out to further understand the effect of initial processing defects on the dynamic fracture behavior. These processing defects, such as voids and lack-of-fusion pores, are the most vulnerable position to release impact energy instantaneously and then evolve into the initiation site and propagation path for dynamic tensile crack. The tensile crack under high strain rate and high temperature propagates through the columnar prior-β grain boundary α colony. It was analyzed that the typical tension-compression asymmetry in strength is positively associated with the strain rate in the Ti64 alloy by LSF. Such asymmetry is due to the differences in the deformation mechanism of processing defects and in the activated slip system under tensile and compressive loading. Additionally, the anisotropy of the mechanical property was discussed by examining the positive strain rate effects in two orientations (i.e., perpendicular and parallel to the crystal growth direction). This anisotropy is caused by different mechanical behaviors of lack-of-fusion defects and β grain boundary α colony in different orientations.

36 MATERIALS SCIENCE↗

Precipitation behavior of the sigma phase with Ni and Mn content variations in superaustenitic stainless steel weld metal

Highlights: • Precipitation behaviors in the superaustenitic stainless steel welds were researched. • The fraction and size of the sigma phases decreased with addition of both Ni and Mn. • The Ni addition induced the increase of Mo content in a sigma phase. • The Mn prevented the Mo increase in the sigma, and consequently the Mo depletion. • Ni addition elevated the Mo activity, which induced clustering of Mo in the sigma. - Abstract: In this study, precipitation behavior of the sigma phase with variations of the Ni and Mn in superaustenitic stainless steel weld metal was evaluated focused on microstructure and thermodynamic analysis. Experiments were conducted with variation of Ni and Mn based on a 23Cr-17Ni-6Mo superaustenitic stainless steel weld. And GTAW welding was performed on the casted specimens for simulating the weld metal. The weld metal consisted of γ-dendrite and an amount of sigma phases at interdendritic boundaries. And the sigma phase fraction showed decreasing behavior inversely according to addition of the Ni and Mn in the weld metal. From the microstructural analysis, the Ni addition induced increase of Mo content in the sigma phase, which caused the Mo depletion zone around the sigma phase. Whereas, the Mn addition induced replacement of Mo in sigma phase by Mn, so that the Mo depletion zone was not formed. Also, from the Thermo-Calc analysis, it was revealed that Ni addition caused increase of Mo activity, which induced Mo clustering in the sigma phase, while the Mn addition showed opposite effect of the Mo activity.

36 MATERIALS SCIENCE↗

Work hardening behavior and tensile properties of a high-Mn damping steel at elevated temperatures

Highlights: • Stability of austenite and ε-martensite was varied by changing the temperature of deformation. • Work hardening behavior was affected by the effects of TRIP, TWIP, DSA and dislocation slip. • Ultimate elongation was significantly decreased when ε → α′ transformation was too hard to occur. - Abstract: An austenite/ε-martensite dual-phase high-Mn damping steel was tensile deformed at elevated temperatures to conduct a comprehensive study about the effects of transformation-induced plasticity (TRIP), twinning-induced plasticity (TWIP), dynamic strain aging (DSA) and dislocation slip (DS) on its work hardening behavior and tensile properties. The results showed that the work hardening behavior of high-Mn damping steel can be divided into two stages. In stage-I, the main factor influencing the work hardening changed from γ → ε transformation to DS as the deformation temperature was increased. In the second stage, the work hardening exponent and ultimate tensile strength were large when intense DSA occurred at 80 °C and 120 °C, although ε → α′ transformation became more difficult at elevated temperatures. Tensile deformation at 200 °C promoted ε → γ transformation, such that the work hardening exponent and ultimate elongation were significantly decreased. In the later stage of deformation at 260 °C, TWIP effect effectively enhanced the work hardening as deformation-induced ε → α′ transformation occurred at low deformation temperatures.

36 MATERIALS SCIENCE↗

The effect of boron addition on the deformation behavior and microstructure of β-solidify TiAl alloys

Highlights: • Borides could promote the DRX formation to soften TiAl alloys. • Boron addition increases firstly and then stabilizes the deformation activate energy. • The stable region expands with boron increasing in processing maps. • The DRX critical strain increases firstly and then decreases with boron increasing. • DRX softening and strengthening from solid solution and borides influence deformation behavior. - Abstract: The effect of boron addition on the deformation behavior and microstructure of Ti-43Al-6Nb-1Mo -1Cr alloys have been studied in this paper. Boron addition would induce Ti{sub 2}Al(P6{sub 3}/mmc) phase with hexagonal structure formation on the interfaces between TiB and γ phase. TiB would be the obstacles for dislocations slipping and increase the stacking fault energy. Ti{sub 2}Al could also provide the chemical foundation for DRXed γ nucleation and disappear after thermal deformation. Both these two phase could promote DRXed grains nucleation to soften the alloys during thermal deformation. With the strengthen effect of boron solid solution and TiB obstacles, the microstructure evolution, phase transformation and deformation behavior are also discussed and concluded as follow.

36 MATERIALS SCIENCE↗

Strain rate sensitivity, microstructure variations, and stress-assisted β → α" phase transformation investigation on the mechanical behavior of dual-phase titanium alloys

In this study, the microstructures of three widely used dual-phase titanium alloys: Ti-6Al-4V, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-2Sn-4Zr-6Mo are characterized using backscatter electron imaging and the deformation behaviors in their individual α and β phases are investigated using in situ high-energy X-ray diffraction during uniaxial tension experiments. This is accompanied by calculation of the strain rate sensitivity (SRS) in these alloys, as a function of applied loading. The results of the calculated SRS and the mechanical response (in terms of lattice strains and hardening behaviors) are rationalized based on the local microstructure, composition, and texture of the alloy. A stress-induced β (BCC) to α" (orthorhombic) phase transformation is observed during the in-situ diffraction experiment, which permitted analysis of the lattice strain evolution during the phase transformation. Results from this study provide insights into the relationship between microstructure, composition, applied loading, and the deformation behavior, including effects on loading with time holds. Specifically, the results show that the microstructure, and not necessarily the chemical composition (Mo content), along with the applied loading have a dominant role in the observed SRS variation in titanium alloys. Further, the evolution of the α" (orthorhombic) phase is observed for the first time during deformation of an industrially relevant titanium alloy, Ti-6246.

36 MATERIALS SCIENCE↗

Effects of sulfur loading on the corrosion behaviors of metal lithium anode in lithium–sulfur batteries

Highlights: • The effects of sulfur loading on the corrosion behaviors were investigated systematically. • The corrosion became severer with increasing sulfur loading or cycle times. • The corrosion films are porous and loose and cannot prevent further reaction between lithium and polysulfides. - Abstract: The corrosion behaviors in rechargeable lithium–sulfur batteries come from the reactions between polysulfides and metal lithium anode, and they are significantly influenced by the sulfur loading. While there are limited papers reported on the effects of sulfur loading on the corrosion behaviors. In this paper, the effects have been investigated systematically. The corrosion films consisted of insulating lithium ion conductors are loose and porous, so that the corrosive reactions cannot be hindered. The thickness of the corrosion layers, consequently, increased along with increasing sulfur loading or cycle times. For instance, the thickness of corrosion layers after 50 cycles was 98 μm in the cell with 5 mg sulfur while it reached up to 518 μm when the loading increased to 15 mg. The continuous deposition of corrosion products gave rise to low active materials utilization and poor cycling performance.

36 MATERIALS SCIENCE↗

Orientation dependence of indentation behavior in Al–SiC nanolaminate composites

Al and SiC nanolaminate films were characterized in the perpendicular, inclined and parallel orientations using nanoindentation. The deformation was dominated by buckling of the layers when the layers were parallel to the indenter and by compression of the ductile Al layers when the layers were perpendicular to the indenter, while indentation in inclined orientations showed an intermediate behavior. Finite element modeling (FEM) of indentation deformation using wavy layers showed much more compliant behavior and prominent layer buckling than the idealized flat structure, highlighting the large effect these microstructural details can have on the deformation behavior.

36 MATERIALS SCIENCE↗

Build orientation, surface roughness, and scan path influence on the microstructure, mechanical properties, and flexural fatigue behavior of Ti–6Al–4V fabricated by electron beam melting

In the present work, microstructure and fatigue behavior of Electron Beam Melted (EBM) Ti–6Al–4V have been systematically studied. Fatigue behavior was investigated using four-point bend tests of rectangular bars with internal features fabricated with different build orientations, scan paths, and surface conditions. Microstructural variations were evaluated by optical microscopy and Vickers micro-hardness indentations, both of which were found to be consistent throughout the build and within ranges reported in the literature. The fatigue performance of the EBM material was comparable to wrought Ti–6Al–4V when the loading direction was parallel to the build direction, but severely limited when loaded perpendicular to the build direction or if surface roughness defects were present. Scanning electron microscopy and interrupted fatigue tests were utilized to characterize fracture surfaces, failure mechanisms, crack initiation, and propagation behavior. Crack initiation sites in the vertically-oriented specimens were identified to be melt-related defects formed by insufficient melting.

36 MATERIALS SCIENCE↗

Linking microstructure to creep behavior in vertically and horizontally built LPBF Haynes 282 compared with wrought material via θ -projection

Laser Powder Bed Fusion (LPBF) has emerged as a promising route for fabricating intricate geometries in high-performance alloys. Haynes 282 (H282) is a strong candidate for applications such as heat exchangers or engines due to its excellent creep strength and thermal stability; however, the long-term creep behavior of LPBF-processed H282 remains poorly understood. In this study, the θ -projection method is used to analyze and extrapolate the creep behavior of vertically built LPBF, horizontally built LPBF, compared to wrought H282 tested at 816 °C. Vertically built LPBF H282 exhibits the lowest minimum creep rate (MCR), while the horizontally built condition shows a higher MCR comparable to that of wrought H282. Despite these differences, both LPBF conditions exhibit significantly shorter rupture life and reduced rupture strain than the wrought material, with the most severe degradation observed in the horizontal builds, consistent with an earlier onset of tertiary creep and accelerated strain-rate evolution. Microstructural characterization reveals that both LPBF and wrought H282 exhibit abundant twin-related boundary character; however, their grain boundary topologies differ markedly. The wrought alloy contains a higher fraction of low-angle grain boundaries and continuous twin lamellae, whereas the LPBF microstructure is characterized by a suppressed low-angle boundary population and fragmented twin-related boundaries embedded within irregular high-angle grain boundary networks. Fractographic analysis further reveals predominantly intergranular cracking in LPBF H282, accompanied by grain-boundary-decorated carbides, Al 2 O 3 inclusions, and high-aspect-ratio pores. These results demonstrate that grain boundary topology, rather than minimum creep rate alone, plays a critical role in governing creep damage accumulation and rupture behavior in LPBF and wrought H282.

Creep↗

Age-dependent behaviors, seizure severity and neuronal damage in response to nerve agents or the organophosphate DFP in immature and adult rats

Exposure to nerve agents (NAs) and other organophosphates (OPs) can initiate seizures that rapidly progress to status epilepticus (SE). While the electrographic and neuropathological sequelae of SE evoked by NAs and OPs have been characterized in adult rodents, they have not been adequately investigated in immature animals. In this study postnatal day (PND) 14, 21 and 28 rat pups, along with PND70 animals as adult controls, were exposed to NAs (sarin, VX) or another OP (diisopropylfluorophosphate, DFP). We then evaluated behavioral and electrographic (EEG) correlates of seizure activity, and performed neuropathology using Fluoro-Jade B. Although all immature rats exhibited behaviors that are often characterized as seizures, the incidence, duration, and severity of the electrographic seizure activity were age-dependent. No (sarin and VX) or brief (DFP) EEG seizure activity was evoked in PND14 rats, while SE progressively increased in severity as a function of age in PND21, 28 and 70 animals. Fluoro-Jade B staining was observed in multiple brain regions of animals that exhibited prolonged seizure activity. Neuronal injury in PND14 animals treated with DFP was lower than in older animals and absent in rats exposed to sarin or VX. In conclusion, we found that NAs and an OP provoked robust SE and neuronal injury similar to adults in PND21 and PND28, but not in PND14, rat pups. Convulsive behaviors were often present independent of EEG seizures and were unaccompanied by neuronal damage. These differential responses should be considered when investigating medical countermeasures for NA and OP exposure in pediatric populations.

Neurosciences & Neurology↗

Impact of LWR assembly structural features on cladding burst behavior under LOCA conditions

This provides an initial scoping study on clad balloon and burst behavior for burnup extension of reactor fuel. The associated issues with burnup extension are fuel fragmentation, relocation, and dispersal in the event of cladding failure. The general finding of this work is that the structural features, spacer grids and mixing vanes, locally suppress cladding deformation but have little impact on the overall clad performance during loss-of-coolant accidents. The work detailed in a previous report by Capps et al. focused on core optimization via neutronics, thermal hydraulics and thermomechanical analysis for burnups beyond 62 GWD/tU and enrichments above 5%. Uncertainty of fuel fragmentation relocation and dispersal in high-burnup rods during accident conditions was also investigated. The dispersal aspect of fuel fragmentation depends on cladding rupture. Thus, assessing uncertainties in the rupture behavior is helpful in estimating the dispersal of high-burnup fuel. This study builds on the previous work by assessing the impact of assembly structural features on cladding balloon and burst behavior in a full-length fuel rod. In this work, the BISON fuel performance code was used to generate 2D radial and height meshes containing structural features commonly used in nuclear fuel assemblies. First, meshes were generated with spacer grids. Results were then compared to the cladding burst temperature and balloon strain results from the previous work. A mesh sensitivity study was performed to ensure that mixing vanes and spacer grid effects were appropriately considered, resulting in a more refined mesh than the previous study. The balloon deformation and burst times of the cladding were compared to the original case. Consideration was also given to the effect of rod initial pressure. In conclusion, 3D quarter rod simulations were also performed and found good agreement with the 2D simulations in clad deformation and reasonable agreement in burst times.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Anomalous behavior in high-pressure carbonaceous sulfur hydride

A new experimental study reported behavior in a high-pressure carbon-sulfur-hydrogen system that has been interpreted by the authors as superconductivity at room temperature. The sudden change of electrical resistance at a critical temperature and the change of the R vs. T behavior with an applied magnetic field point to superconductivity. This is a very exciting study in one of the most important areas of science, hence, it is crucial for the community to investigate these findings and hopefully reproduce these results. In this paper, we present calculations that expand upon the arguments put forth, and offer some speculations about physical mechanisms that might explain the observed data. Here, we show that there are errors in the analysis presented in the experimental paper, and with the correct analysis, the reported R vs. T data significantly deviate from the expected behavior. In particular, the extremely sharp change in resistance at the superconducting transition is not consistent with a strongly type II superconductor.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗