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NASA NTRS1988

Electron Diffraction Evidence for the Ordering of Excess Nickel Atoms by Relation to Stoichiometry in Nickel-Rich Beta'-Nial Formation of a Nickel-Aluminum (Ni2al) Superlattices

In electron diffraction patterns of nickel-rich beta-NiAl alloys, many anomalies are observed. One of these is the appearance of diffuse intensity maxima between the reflexions of the B2 structure. This is explained by the short-range ordering of the excess nickel atoms on the simple cubic sublattice occupied only by aluminum atoms in the stoichiometric, perfectly ordered NiAl alloy. After annealing Ni 37.5 atomic percent Al and Ni 37.75 atomic percent Al for 1 week at 300 and 400 C, the diffuse intensity maxima transformed into sharp superstructure reflexions. These reflexions are explained by the formation of the four possible variants of an ordered hexagonal superstructure corresponding to the Ni2Al composition. This structure is closely related to the Ni2Al3 structure (same space group) formed by the ordering of vacancies on the nickel sublattice in aluminum-rich beta-NiAl alloys.

Reynaud, F.↗

NASA NTRS1988

Land mobile satellite propagation results

During the Fall of 1987 a land mobile satellite demonstration using the MARECS B2 satellite at 26 degrees W was performed. While all the data have not been digested, some observations are in order. First, the system worked remarkably well for the margins indicated. Second, when the system worked poorly, the experimenters could almost always identify terrain or other obstacles causing blockage. Third, the forward link seems relatively more reliable than the return link, and occasional return link problems occured which have not been entirely explained.

Nicholas, David C.↗

NASA NTRS1988

Land mobile satellite demonstration system

A land mobile satellite demonstration system is described. It ulilizes the INMARSAT MARECS B2 satellite at 26 degrees W. The system provides data transmission using a poll-response protocol with error detection and retransmission at 200 b/s rate. For most tests a 1.8 inch monopole antenna was used, along with a satellite EIRP normally used for four voice channels. A brief summary of the results are given and the overall system consisting of three elements in addition to the satellite (the mobile unit, the base station, and the office terminal and map display) is described. Throughput statistics from one trip are summarized.

Gooch, Guy M.↗

NASA NTRS1987

Detection of interstellar PN - The first phosphorus-bearing species observed in molecular clouds

Phosphorus nitride (PN) has been detected in the interstellar medium. The J = 2-1, 3-2, 5-4, and 6-5 rotational lines of this species have been observed toward Orion-KL, and the J = 2-1 transition in Sgr B2 and W51. The PN line profiles in Orion indicate that the molecule's emission arises from the 'plateau' or 'doughnut' region associated with the outflow from IRc2. The species is thus primarily present in hot, dense gas. Column densities derived for PN toward Orion-KL are (3-4) x 10 to the 13th/sq cm, but may be as high as 10 to the 14th/sq cm, if the species is located in a 10-arcsec region. These column densities imply a fractional abundance for PN in the Orion 'plateau' of (1-4) x 10 to the -10th. Such a large abundance for PN is not predicted by quiescent cloud ion-molecule chemistry and suggests that high-temperature processes are responsible for the synthesis of PN in the KL outflow.

Ziurys, L. M.↗

NASA NTRS1988

Low luminosity radio galaxies - Effects of gaseous environment

X-ray data from the Einstein Observatory have been collected for a number of low luminosity B2 radio galaxies, in order to study the effect of gas pressure on radio sources. Generally, the thermal pressure of the X-ray emitting gas is sufficient to confine most of the radio components. Various possibilities are given for sources where thermal pressure significantly exceeds the nonthermal pressure. For radio lobes, an inverse correlation is found between the central densities of the cluster gas and the size of the radio structures. For jets, a study of the pressure ratios is given for different distances from the radio core. In a few cases, pressure imbalance is found in the outer regions of the jets. However, from depolarization data, this is unlikely to be produced by a large thermal component inside the radio jets.

Morganti, R.↗

NASA NTRS1988

A computational study of the TiO2 molecule

A computational investigation of the ground 1A1 and lowest energy B2 states of the titanium dioxide molecule has been carried out. The treatment utilized SCF calculations in an extended basis followed by a CI treatment for each geometry. The ground state geometry agrees well with experiment, while the agreement between the computed vibrational frequency nu1 and the experimental value for a matrix isolated TiO2 is less satisfactory. Population analysis for the ground state indicates less than one excess electron on each oxygen atom. The first excited state has a linear geometry and the singlet and triplet are essentially degenerate.

Ramana, M. V.↗

NASA NTRS1988

The influence of grain size and composition on 1000 to 1400 K slow plastic flow properties of NiAl

The compressive slow plastic flow behavior of several B2 crystal structure NiAl intermetallics has been studied in air between 1000 and 1400 K. Small grain-sized Ni-48.25 at. pct Al (of about 10 microns) was found to be stronger than the previously studied 17 microns diameter material. While grain refinement improved the strength at all test temperatures, the exact mechanism is not clear. Experiments at lower temperature revealed that composition as well as grain size can be an important factor, since Ni-49.2Al was weaker than Ni-48.25Al. Pronounced yield points were found during slow strain-rate testing at 1000 K; however, continued deformation appears to take place by the same mechanism(s) as found at high temperatures. Small changes in thermomechanical processing (TMP) schedules to fabricate Ni-49.2Al indicated that basic deformation characteristics (stress exponent and activation energy) are not affected; however, the preexponential term could be modified if TMP alters the grain structure.

Whittenberger, J. Daniel↗

NASA NTRS1988

An improved photometric analysis of SX Aurigae

A new analysis of existing photometric data on SX Aurigae is presented which changes current conclusions in the literature concerning the star. It is concluded, based on fitting of the continuous spectrum to Kurucz model atmospheres and simplex optimization procedure utilized, that the system consists of two normal main-sequence stars of spectral types B2 and slightly earlier than B5. The components are very close to the inner Roche limiting surface. The secondary component is unevolved, and the primary component is extremely close to contact with its inner Roche lobe. The evidence indicates that mass flow from the primary to the secondary has not yet begun. Allowing the bolometric albedo of the secondary to be a free parameter produces a solution with an excellent fit to the B, V data. The derived value, A2 = 0.40, disagrees with the theoretical value for radiative atmospheres and agrees with the value for convective equilibrium.

Linnel, Albert P.↗

NASA NTRS1987

High-temperature ordered intermetallic alloys II; Proceedings of the Second Symposium, Boston, MA, Dec. 2-4, 1986

The papers presented in this volume provide on overview of recent theoretical and experimental research in the field of high-temperature ordered intermetallic alloys. The papers are gouped under the following headings: ordering behavior and theory, microstructures, mechanical behavior, alloy design and microstructural control, and metallurgical properties. Specific topics discussed include antiphase domains, disordered films and the ductility of ordered alloys based on Ni3Al; kinetics and mechanics of formation of Al-Ni intermetallics; deformability improvements of L1(2)-type intermetallic compounds; B2 aluminides for high-temperature applications; and rapidly solidified binary TiAl alloys.

Stoloff, N. S.↗

NASA NTRS1987

Two-phase nickel aluminides

The as-extruded microstructures of two alloys in the two phase field consisting of Ni3Al and NiAl in the Ni-Al phase diagram exhibit fibrous morphology and consist of Ll(2) Ni3Al and B2 NiAl. These as-extruded microstructures can be modified dramatically by suitable heat treatments. Martensite plus NiAl or martensite plus Ni3Al microstructures are obtained upon quenching from 1523 K. Aging of martensite at 873 K results in the recently identified phase Ni5Al, whereas aging at 1123 K reverts the microstructures to Ni3Al plus NiAl. The microstructures with predominantly martensite of Ni5Al3 phases are brittle in tension at room temperature. The latter microstructure does not deform plastically even in compression at room temperature. However, some promise of room temperature tensile ductility is indicated by the Ni3Al plus NiAl phase mixtures.

Khadkikar, P. S.↗

NASA NTRS1988

Evidence for accretion disks in highly polarized quasars

The results of a search for thermal components in 11 highly polarized quasars (HPQs) using UVBRI polarimetry and photometry are reported. The 2000-2500 A luminosities of the thermal components are calculated and the estimated luminosities of the broad-line region (BLR) are given in the same wavelength for comparison. The observed optical continua are modeled as a combination of polarized synchrotron emission, unpolarized emission from the BLR, and an unpolarized flat spectral component that may be optically thick thermal emission from an accretion disk. Evidence for thermal emission components is found in three HPQs: PKS 0420-014, B2 1156+295, and 3C 454.3, with marginal evidence in another two, PKS 1510-089 and PKS 2345-167.

Smith, Paul S.↗

NASA NTRS1988

HCO emission from H II-molecular cloud interface regions

A survey of well-known molecular clouds in the four strongest HCO N(k-,k+) = 1(01)-O(60) hyperfine transitions has been carried out to determine the prevalence of HCO and to study its chemistry. HCO emission was observed in seven molecular clouds. Three of these, NGC 2264, W49, and NGC 7538, were not previously known sources of HCO. In addition, NGC 2024 and Sgr B2 were mapped and shown to have extensive HCO emission. The survey results show the HCO abundance to be enhanced in H II-molecular cloud interface regions and support a correlation between C(+) and HCO emission. The strength of the HCO emission in NGC 2024 is interpreted in terms of this enhancement and the source structure and proximity to Earth.

Schenewerk, M. S.↗

NASA NTRS1988

Galactic interstellar abundance surveys with IUE. III - Silicon, manganese, iron, sulfur, and zinc

This paper continues a survey of intestellar densities, abundances, and cloud structure in the Galaxy using the IUE satellite. A statistical data set of 223 O3-B2.5 stars is constructed, including 53 stars in the Galactic halo. It is found that S II lines in B stars, of luminosity classes IV and V, have possible contamination from stellar S II, particular for stars with v sin i less than 200 km/s. The mean logarithmic depletions are -1.00, -1.19. -0.63, and -0.23 (Si, Mn,Fe,S, Zn). Depletions of Si, Mn, and Fe correlate with the mean hydrogen density n-bar along the line of sight, with a turnover for n-bar greater than 1/cm. Sulfur depletions correlate with n-bar along the line of sight. The slight Zn depletion correlation also appears to be statistically insignificant. No correlation of depletion is found with the physical density derived from H2 rotational states in 21 lines of sight. Depletion variations in the disk are consistent with a Galactic abundance gradient or with enhanced mean depletions in the anticenter region.

Van Steenberg, Michael E.↗

NASA NTRS1988

Mg I as a probe of the solar chromosphere - The atomic model

This paper presents a complete atomic model for Mg I line synthesis, where all the atomic parameters are based on recent experimental and theoretical data. It is shown how the computed profiles at 4571 A and 5173 A are influenced by the choice of these parameters and the number of levels included in the model atom. In addition, observed profiles of the 5173 A b2 line and theoretical profiles for comparison (based on a recent atmospheric model for the average quiet sun) are presented.

Mauas, Pablo J.↗

NASA NTRS1988

Laboratory detection of a new interstellar free radical CH2CN(2B1)

An asymmetric-top free radical CH2CN with a 2B1 ground state was detected by laboratory microwave spectroscopy. The radical was produced in a free-space absorption cell by a DC glow discharge in pure CH3CN gas. About 60 fine-structure components were observed for the N = 11-10 to 14-13 a-type rotational transitions in the frequency region of 220-260 GHz. Hyperfine resolved components for the N = 4-3 and 5-4 transitions were resolved in the 80 and 100 GHz regions, respectively. Molecular constants were determined and U100602 and U80484 from Sgr B2, and U40240 and U20120 from TMC-1 were assigned to the N = 5-4, 4-3, 2-1, and 1-0 transitions with K(-1) = 0 of the CH2CN radical.

Saito, Shuji↗

NASA NTRS1989

The VV Cephei star V641 Cassiopeiae

Ultraviolet spectra of the variable star V641 Cas taken with the IUE satellite have confirmed the VV Cephei nature of this object. The observations are consistent with the variable being a M3 I + B2 V-III system with E(B-V) = 0.55 mag lying in the Perseus arm of the Galaxy. In spite of V641 Cas having the largest light variation in the visible of any VV Cephei type star, no correlation was found between variation in ultraviolet line or continuum and light variation in the visible wavelength region.

Shaw, J. Scott↗

NASA NTRS1989

High power density performance of WPt and WRh electrodes in the alkali metal thermoelectric converter

The properties of the alkali metal thermoelectric converter (AMTEC) are discussed together with those of an efficient AMTEC electrode. Three groups of electrodes were prepared and tested for their performance as AMTEC electrodes, including WPt-T3, WRh-B1, and WRh-B2. The best electrodes of both WPt and WRh types typically exhibited low porosity, and thickness greater than 0.8 micron, which indicated that transport in these electrodes does not occur by a purely free-molecular flow mode. The observed values of the exchange current were found to be within the range of those observed for oxide-free Mo electrodes under similar conditions.

Williams, R. M.↗

NASA NTRS1988

Potential for NiAl based alloys for high temperature applications

The B2 nickel aluminide, NiAl, is of potential use for high temperature structural applications because of its high melting point, low density, and oxidation resistance. An overview of recent attempts to improve the low temperature ductility as well as the high temperature strength of this alloy is presented. Room temperature tensile ductility of 2.5 percent can be obtained in a stoichiometric binary alloy by careful control of the composition and processing conditions. Alloying additions to improve high temperature creep resistance are most effective when fine distributions of ternary intermetallic phases can be obtained. A promising direction for exploiting the advantages of this alloy may be as a matrix for composite materials.

Vedula, K.↗