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At least 847 records · Page 47

Advanced sorbents for modular oxygen production for REMS gasifiers

Under a DOE funded effort, Thermosolv LLC has been developing a sorbent-based oxygen production technology for gasification and oxy-combustion applications. The sorbents utilize oxygen-storage properties of certain perovskites to (1) selectively adsorb oxygen at moderate temperature from compressed air and (2) release the adsorbed oxygen into a vacuum or a sweep gas such as CO2 and/or steam. Through cyclic operations of multiple sorbent beds such a process can be made continuous. Pressure drop across the sorbent bed and other similar design considerations dictate that the sorbent be in the form of a high surface-area-to-volume pellet and yet still possess sufficient crush strength and integrity. Process efficiency is determined by the sorption and desorption kinetics and sorbent capacity. Typical process involves cycle times in the order of 100 seconds, a time too short to fully utilize the full volume of the sorbent and the sorption capacity of the sorbent pellets. As a part of this project, Thermosolv LLC undertook the development of oxygen sorbents as a high-surface area supported sorbent on a light-weight inert support to (1) reduce the cost, (2) increase the productivity, and (3) reduce the overall weight of the reactor. Using a previously developed perovskite (LSCF 1991) with its well-characterized performance, composite sorbent pellets each consisting of an inert core coated by a thin layer of the functional perovskite material were produced. Several low-density, inexpensive inert solids supports in the 1/8”-1/4” size were selected to keep the pressure drop across the sorbent bed in the acceptable range. A number of commercial technologies including spray coating, dip coating, incipient impregnation of porous substrate followed by thermal annealing at various temperatures and duration were employed and tested to produce robust composite supported sorbent pellets. A sense of optimum coating thickness was developed by testing sorbent pellets of various increasing diameter pellets. LSCF-1991extrudates ranging in size from 1/32” to 3/16” were tested in a TGA and in a fixed-bed pressure swing test set-up for sorption/desorption cycles of interest. The data show that for the operational conditions of interest the coating thickness for a supported sorbent pellet needs to be approximately 1/32” (about 0.8 mm). Subsequent work thereby concentrated on developing composite pellets of various substrates, shapes and sizes with coating layer of about this size range. Candidate support materials were chosen based on cost, inertness, mechanical strength, thermal expansion and chemical stability with sorbent material, and in a size range to give an acceptable pressure drop in fixed-bad reactor configurations. Coating application methods used for application of the sorbent onto the support included precipitation, spray coating and dip coating from sorbent slurries and sol gels. For all coated supports where we could successfully apply a uniform coating of desired thickness with an acceptable handling performance in terms of exfoliation, TGA-based cyclic sorption/desorption testing was performed to determine cycling capacity of oxygen. Among nearly twenty different support materials tested, best adhesion performance was obtained from stainless saddle supports. In the bench-scale fixed-bad tests stainless steel saddle support composite pellets with a coating thickness in the 0.6 mm or so range, the composite sorbent pellet performance approached up to 95% of that of the 2 mm parent material pellets. In a parallel approach to reducing the cost of the sorbent, alternate sorbent formulations replacing/reducing the amount of cobalt in the LSCF family were also investigated. Successful formulations that could match the performance of LSCF 1991 were identified based on TGA cyclic tests as LSCF 1919 and LSF 1910. In the range of operational envelop of cycle times and other relevant process operating conditions, the reduced Co formulations showed comparable performance in the bench-scale fixed-bad cyclic operations. As a part of this project, we also attempted substitution of La and Sr with Ca and Ba, and Co with Mn, Ni and Cu with little success, but the overall project goal of reducing sorbent cost in terms of raw material and manufacturing expenses was successful.

01 COAL, LIGNITE, AND PEAT↗

Advances in Engineering Science, Volume 4

The following areas of flight science are discussed in detail; (1) inviscid flow, (2) viscous flow, (3) aircraft aerodynamics, (4) fluid mechanics, (5) propulsion and combustion, and (6) flight dynamics and control.

Source record↗

Advanced Gas Turbine (AGT) powertrain system development for automotive applications

Topics covered include the AGT 101 engine test; compressor design modification; cold air turbine testing; Mod 1 alloy turbine rotor fabrication; combustion aspects; regenerator development; and thermal screening tests for ceramic materials. The foil gas bearings, rotor dynamics, and AGT controls and accessories are also considered.

Source record↗

Spatially calibrating polycyclic aromatic hydrocarbons (PAHs) as proxies of area burned by vegetation fires: Insights from comparisons of historical data and sedimentary PAH fluxes

Many regions worldwide have experienced increasing wildfire activity in recent years and climate changes are predicted to result in more frequent and severe fires. Reconstruction of past fire activity offers paleoenvironmental context for modern and future burning. Pyrogenic polycyclic aromatic hydrocarbons (PAHs) have been increasingly used as a molecular biomarker for fire occurrence in the paleorecord and offer opportunity for nuanced reconstructions of fire characteristics. A suite of PAHs are produced during combustion, and the emission amount and assemblage is influenced by many variables including fuel type, fire temperature, and oxygen availability. Despite recent advances in understanding the controls and taphonomy of these biomass burning markers, the spatial scale of this proxy is unknown. In this paper, measurements of PAH fluxes preserved in a lake sediment archive from the Sierra Nevada, California were compared with a historical geographic information system dataset of area burned up to 150 km distance from the lake to determine the spatial scales for which these biomarkers are reliable proxies of burning. Comparisons of PAH fluxes with charcoal accumulation rates in the same sediments suggest that pyrogenic particulate transport modulates low to mid-molecular weight PAHs via adsorption. Overall, the results indicate that PAH records integrate a combination of spatial signals of area burned and measurement of individual PAHs may enable cross-scale paleofire reconstructions.

54 ENVIRONMENTAL SCIENCES↗

Power Technologies for Rail Decarbonization Workshop: Summary Report

Argonne National Laboratory organized the Power Technologies for Rail Decarbonization Workshop for the U.S. Department of Energy (DOE) Vehicle Technologies Office. The workshop offered an inclusive venue for different stakeholders to convey their perspective on challenges and opportunities in decarbonizing the rail sector. The first day of the workshop focused on (1) rail decarbonization efforts in the DOE and collaboration opportunities, (2) technology pathways to decarbonize rail, and (3) prime mover and low-carbon options for rail. The second day was devoted to (1) prime mover and zero-carbon options for rail, and (2) rail logistics, infrastructure, and safety. Each day raised challenges and solutions through presentations from national leaders and discussions among panel members and the audience. Through this engagement with different stakeholders, we will produce a cross-disciplinary recommendation for the role of government agencies to contribute meaningful research to address current technology gaps. The workshop included up 139 active participants and featured keynote speakers and panelists from Association of American Railroads, Progress Rail Locomotive, Wabtec, Burlington Northern Santa Fe Railroad, Amtrak, Caterpillar, Cummins, Renewable Energy Group-Chevron, DOE’s Bioenergy Technologies Office, California Air Resources Board, Federal Railroad Administration and multiple DOE national laboratories. This summary report presents highlights from participant discussions covering the topics of technology pathways to decarbonize rail, prime mover and low-carbon options, prime mover and zero-carbon options, as well as rail logistics, infrastructure, and safety. The variety of input gathered from the stakeholder attendees is vital, as it helps inform DOE on rail decarbonization challenges and opportunities. Stakeholder feedback is balanced against DOE strategic directions and priorities with consideration of the roles of government and industry.

33 ADVANCED PROPULSION SYSTEMS↗

Decarbonization of Off-Road, Rail, Marine, and Aviation (DORMA) Program (2022 Annual Progress Report)

This document summarizes the progress of VTO's Decarbonization of Off-Road, Rail, Marine, and Aviation (DORMA) program during the fiscal year 2022. DORMA's R&D focus was on research, development, and demonstration of new propulsion and vehicle technologies that will reduce greenhouse gas emissions in difficult-to-decarbonize transportation applications.

33 ADVANCED PROPULSION SYSTEMS↗

Advanced Rankine and Brayton cycle power systems: Materials needs and opportunities

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long time property data must be obtained under environments of interest to assure high component reliability.

Grisaffe, S. J.↗

Advanced Rankine and Brayton cycle power systems - Materials needs and opportunities

Conceptual advanced potassium Rankine and closed Brayton power conversion cycles offer the potential for improved efficiency over steam systems through higher operating temperatures. However, for utility service of at least 100,000 hours, materials technology advances will be needed for such high temperature systems. Improved alloys and surface protection must be developed and demonstrated to resist coal combustion gases as well as potassium corrosion or helium surface degradation at high temperatures. Extensions in fabrication technology are necessary to produce large components of high temperature alloys. Long-time property data must be obtained under environments of interest to assure high component reliability.

Grisaffe, S. J.↗

Advanced expander test bed engine

The Advanced Expander Test Bed (AETB) is a key element in NASA's Space Chemical Engine Technology Program for development and demonstration of expander cycle oxygen/hydrogen engine and advanced component technologies applicable to space engines as well as launch vehicle upper stage engines. The AETB will be used to validate the high pressure expander cycle concept, study system interactions, and conduct studies of advanced mission focused components and new health monitoring techniques in an engine system environment. The split expander cycle AETB will operate at combustion chamber pressures up to 1200 psia with propellant flow rates equivalent to 20,000 lbf vacuum thrust.

Mitchell, J. P.↗

Advanced expander test bed program

The Advanced Expander Test Bed (AETB) is a key element in NASA's Space Chemical Engine Technology Program for development and demonstration of expander cycle oxygen/hydrogen engine and advanced component technologies applicable to space engines as well as launch vehicle upper stage engines. The AETB will be used to validate the high-pressure expander cycle concept, investigate system interactions, and conduct investigations of advanced mission focused components and new health monitoring techniques in an engine system environment. The split expander cycle AETB will operate at combustion chamber pressures up to 1200 psia with propellant flow rates equivalent to 20,000 lbf vacuum thrust. Contract work began 27 Apr. 1990. During 1992, a major milestone was achieved with the review of the final design of the oxidizer turbopump in Sep. 1992.

Riccardi, D. P.↗

Microgravity Production of Nanoparticles of Novel Materials Using Plasma Synthesis

The research goal is to study the formation in reduced gravity of high quality nanoparticulate of novel materials using plasma synthesis. Particular emphasis will be placed on the production of powders of non-oxide materials like diamond, SiC, SiN, c-BN, etc. The objective of the study is to investigate the effect of gravity on plasma synthesis of these materials, and to determine how the microgravity synthesis can improve the quality and yield of the nanoparticles. It is expected that the reduced gravity will aid in the understanding of the controlling mechanisms of plasma synthesis, and will increase the yield, and quality of the synthesized powder. These materials have properties of interest in several industrial applications, such as high temperature load bearings or high speed metal machining. Furthermore, because of the nano-meter size of the particulate produced in this process, they have specific application in the fabrication of MEMS based combustion systems, and in the development and growth of nano-systems and nano-structures of these materials. These are rapidly advancing research areas, and there is a great need for high quality nanoparticles of different materials. One of the primary systems of interest in the project will be gas-phase synthesis of nanopowder of non-oxide materials.

Frenklach, Michael↗

Active Control of High Frequency Combustion Instability in Aircraft Gas-Turbine Engines

Active control of high-frequency (greater than 500 Hz) combustion instability has been demonstrated in the NASA single-nozzle combustor rig at United Technologies Research Center. The combustor rig emulates an actual engine instability and has many of the complexities of a real engine combustor (i.e. actual fuel nozzle and swirler, dilution cooling, etc.) In order to demonstrate control, a high-frequency fuel valve capable of modulating the fuel flow at up to 1kHz was developed. Characterization of the fuel delivery system was accomplished in a custom dynamic flow rig developed for that purpose. Two instability control methods, one model-based and one based on adaptive phase-shifting, were developed and evaluated against reduced order models and a Sectored-1-dimensional model of the combustor rig. Open-loop fuel modulation testing in the rig demonstrated sufficient fuel modulation authority to proceed with closed-loop testing. During closed-loop testing, both control methods were able to identify the instability from the background noise and were shown to reduce the pressure oscillations at the instability frequency by 30%. This is the first known successful demonstration of high-frequency combustion instability suppression in a realistic aero-engine environment. Future plans are to carry these technologies forward to demonstration on an advanced low-emission combustor.

Corrigan, Bob↗

Reciprocating Feed System Development Status

The reciprocating feed system (RFS) is an alternative means of providing high pressure propellant flow at low cost and system mass, with high fail-operational reliability. The RFS functions by storing the liquid propellants in large, low-pressure tanks and then expelling each propellant through two or three small, high-pressure tanks. Each RFS tank is sequentially filled, pressurized, expelled, vented, and refilled so as to provide a constant, or variable, mass flow rate to the engine. This type of system is much lighter than a conventional pressure fed system in part due to the greatly reduced amount of inert tank weight. The delivered payload for an RFS is superior to that of conventional pressure fed systems for conditions of high total impulse and it is competitive with turbopump systems, up to approximately 2000 psi. An advanced version of the RFS uses autogenous pressurization and thrust augmentation to achieve higher performance. In this version, the pressurization gases are combusted in a small engine, thus making the pressurization system, in effect, part of the propulsion system. The RFS appears to be much less expensive than a turbopump system, due to reduced research and development cost and hardware cost, since it is basically composed of small high- pressure tanks, a pressurization system, and control valves. A major benefit is the high reliability fail-operational mode; in the event of a failure in one of the three tank-systems, it can operate on the two remaining tanks. Other benefits include variable pressure and flow rates, ease of engine restart in micro-gravity, and enhanced propellant acquisition and control under adverse acceleration conditions. We present a system mass analysis tool that accepts user inputs for various design and mission parameters and calculates such output values payload and vehicle weights for the conventional pressure fed system, the RFS, the Autogenous Pressurization Thrust Augmentation (APTA) RFS, and turbopump systems. Using this tool, a preliminary design of a representative crew exploration vehicle (CEV) has been considered. The design parameters selected for a representative system were modeled after the orbital maneuvering system (OMS) on the Shuttle Orbiter, with an increase of roughly a factor of ten in the delta- V capability and a greater thrust (30,000 lbs, vs. 12,000 lbs). Both storable and cryogenic propellants were considered. Results show that a RFS is a low mass alternative to conventional pressure fed systems, with a substantial increase in payload capability and that it is weight-competitive with turbopump systems at low engine pressure (a few hundred psi); at high engine pressures, the APTA RFS appears to offer the highest payload. We also present the status of the RFS test bed fabrication, assembly, and checkout. This test bed is designed to provide flow rates appropriate for engines in the roughly 10,000 to 30,000 lb thrust range.

Trewek, Mary↗

Design, Fabrication, and Test of a LOX/LCH4 RCS Igniter at NASA

A workhorse liquid oxygen-liquid methane (LOX/LCH4) rocket igniter was recently tested at NASA Glenn Research Center s (GRC) Research Combustion Laboratory (RCL). These tests were conducted in support of the Reaction Control Engine (RCE) development task of the Propulsion and Cryogenics Advanced Development (PCAD) project. The igniter was a GRC in-house design used to evaluate the ignition processes for LOX/LCH4. The test matrix was developed to examine the flammability of LOX/LCH4 over a range of oxidizer-to-fuel mixture ratios, both in the core fuel flow and total flow. In addition, testing also examined the durability of the hardware by accumulating ignition pulses. Over the course of testing, a total of 1402 individual ignition pulses were successfully demonstrated over the range of mixture ratios. Testing was halted after the failure of the ceramic in the igniter spark plug.

Schneider, Steven J.↗

Cost and Performance Estimates for State-of-the-Art and Advanced 1×1 H-Class Natural Gas-Fired Power Plants

As an extension of NETL's Fossil Energy Baseline for Electricity Generating Units Volume 1: Coal and Natural Gas to Electricity (FEB Rev 4a, this study develops cost and performance estimates for analogous NGCC cases using a state-of-the-art 2023 vintage H-Class CT in a 1×1 configuration, where a single combustion turbine and heat recovery steam generator are coupled to a single steam turbine on a common shaft. These 1×1 H-Class cases are used to develop cost and performance estimates of X-Class 1×1 NGCC cases with advanced performance characteristics, analogous to NETL’s cost and performance projections report.

20 FOSSIL-FUELED POWER PLANTS↗

Flametube Evaluation of a Lean-Lean Combustor Concept Developed for Supersonic Cruise Aircraft

Gaseous emissions were measured in single-cup flametube tests of an advanced low-NOx combustor concept at simulated supersonic cruise conditions. The combustor concept is a low technology readiness level (TRL), lean front-end design developed under the NASA Fundamental Aeronautics/Supersonics project to minimize NOx emissions at supersonic cruise. The flametube conditions matched or approached combustor conditions at supersonic cruise, with combustor inlet temperatures up to 920 K, inlet pressures up to 19 bar, and combusted gas temperatures up to 2,120 K. Whether these conditions met or just approached supersonic cruise conditions depended on the type of engine the combustor would be installed in. Two types of engines were considered here: a “derivative” engine based on a current technology and an “advanced” engine with a higher operating pressure ratio and higher temperature limits. For the “derivative” engine, the combustor is expected to be at least close to meeting the NASA NOx emissions goal of 10 g-NOx/kg-fuel at supersonic cruise. However, with the higher combustor inlet and flame temperatures of the advanced engine, NOx emissions are expected to be well above the goal.

combustion↗

Advanced high temperature materials for the energy efficient automotive Stirling engine

The Stirling Engine is under investigated jointly by the Department of Energy and NASA Lewis as an alternative to the internal combustion engine for automotive applications. The Stirling Engine is an external combustion engine that offers the advantage of high fuel economy, low emissions, low noise, and low vibrations compared to current internal combustion automotive engines. The most critical component from a materials viewpoint is the heater head consisting of the cylinders, heating tubes, and regenerator housing. Materials requirements for the heater head include compatibility with hydrogen, resistance to hydrogen permeation, high temperature oxidation/corrosion resistance and high temperature creep-rupture and fatigue properties. A continuing supporting materials research and technology program has identified the wrought alloys CG-27 and 12RN72 and the cast alloys XF-818 and NASAUT 4G-A1 as candidate replacements for the cobalt containing alloys used in current prototype engines. Based on the materials research program in support of the automotive Stirling engine it is concluded that manufacture of the engine is feasible from low cost iron-base alloys rather than the cobalt alloys rather than the cobalt alloys used in prototype engines. This paper will present results of research that led to this conclusion.

Titran, R. H.↗

Advanced Manufacturing Techniques Demonstrated for Fabricating Developmental Hardware

NASA Glenn Research Center's Engineering Development Division has been working in support of innovative gas turbine engine systems under development by Glenn's Combustion Branch. These one-of-a-kind components require operation under extreme conditions. High-temperature ceramics were chosen for fabrication was because of the hostile operating environment. During the designing process, it became apparent that traditional machining techniques would not be adequate to produce the small, intricate features for the conceptual design, which was to be produced by stacking over a dozen thin layers with many small features that would then be aligned and bonded together into a one-piece unit. Instead of using traditional machining, we produced computer models in Pro/ENGINEER (Parametric Technology Corporation (PTC), Needham, MA) to the specifications of the research engineer. The computer models were exported in stereolithography standard (STL) format and used to produce full-size rapid prototype polymer models. These semi-opaque plastic models were used for visualization and design verification. The computer models also were exported in International Graphics Exchange Specification (IGES) format and sent to Glenn's Thermal/Fluids Design & Analysis Branch and Applied Structural Mechanics Branch for profiling heat transfer and mechanical strength analysis.

Redding, Chip↗