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At least 847 records · Page 47

Composition-Preserving Extraction and Characterization of Biomass Extrinsic and Intrinsic Inorganic Compounds

The inorganic content of biomass impairs size reduction tool life and the conversion process. Conventional ash extraction relies on furnace combustion that inevitably alters the inorganic compounds due to oxidation and decomposition. This study developed composition-preserving methods for extracting and analyzing extrinsic and intrinsic inorganic compounds. Comprehensive characterization was carried out on selected biomass feedstocks, including corn stover, pine residue, and pine anatomical fractions, to reveal their inorganic species and morphology. The extrinsic inorganic compounds were found to be dominated by quartz, along with other minor minerals, such as albite, microcline, and gehlenite, and have particle sizes ranging from tens to hundreds of micrometers. Among the pine anatomical fractions, the needles contain the highest intrinsic silicon content while the bark trapped the most extrinsic minerals. By correlation of the total ash and extrinsic inorganic contents to the wear behavior, both the extrinsic and intrinsic inorganic compounds were concluded to have made significant contributions to the wear process. Finally, the results here validated a new approach to characterize inorganic compounds in biomass and provided fundamental insights for their potential impact on preprocessing tool wear.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Preliminary study of raw material for calcium silicate/PVA coating on Ti-6Al-4V alloy

Calcium silicate bioceramic was prepared from the rice husk and limestone resources using the sol gel method. The preparations of CaSiO{sub 3} formulation were differ from the previous study due CaO/SiO{sub 2} amount with 45:55 ratio. X-Ray Fluorescence analysis was carried out to clarify the amount of SiO{sub 2} and CaO content in the limestone and rice husk ash. The high amount of CaO was found in the limestone with the percentages of 97.22%, whereby 89% of SiO{sub 2} content of the rice husk ash. Several milling time were studied to obtain the optimized milling ti me and speed in progress to obtain nano size particle. The particle size analysis result confirms that increase in milling time does not certainly reduce the size of particle. The addition of 0.05% polyvinyl alcohol as a binder did not change the phases or composition of calcium silicates after examined by X-Ray diffraction analysis which make it suitable to be used as a binder for calcium silicate coating without changing the chemical structure.

36 MATERIALS SCIENCE↗

Self-rolling of an aluminosilicate sheet into a single walled imogolite nanotube: The role of the hydroxyl arrangement

Imogolite is an inorganic nanotube, that forms naturally in weathered volcanic ashes, and it can be synthesized in nearly monodisperse diameters. However, long after its successful synthesis, the details of the way it is achieved are not fully understood. Here we elaborate on a model of its synthesis, which starts with a planar aluminosilicate sheet that is allowed to evolve freely, by means of classical molecular dynamics, until it achieves its minimum energy configuration. The minimal structures that the system thus adopts are tubular, scrolled, and more complex conformations, depending mainly on temperature as a driving force. Here we focus on the effect that the arrangement of the hydroxyl groups in the inner wall of the nanotube have on the minimal nanotubular configurations that we obtain are monodispersed in diameter, and quite similar to both from the those of weathered natural volcanic ashes, and to the ones that are synthesized in the laboratory. In this contribution we expand on the atomic mechanisms behind those behaviors.

36 MATERIALS SCIENCE↗

Development of miniaturized, spectroscopically assisted Penning gauges for fractional helium and hydrogen neutral pressure measurements

Direct measurements of the helium (He) fractional neutral pressure in the neutral gas around fusion devices is challenging because of the small mass difference between the abundant D{sub 2} molecules and the He ash which will be produced by deuterium-tritium fusion. To study He exhaust, an in situ Penning gauge system is being developed at UW-Madison that is optimized for good pressure and high spectroscopic sensitivity. Three different anode geometries have been studied regarding their vacuum electrostatic fields, light output, and ion current. The light output of the two new anode configurations are at least one order of magnitude above the currently available designs, hence improving the spectroscopic sensitivity at similar total neutral pressure resolution.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NUCLEAR DOMINATED ACCRETION FLOWS IN TWO DIMENSIONS. I. TORUS EVOLUTION WITH PARAMETRIC MICROPHYSICS

We explore the evolution of radiatively inefficient accretion disks in which nuclear reactions are dynamically important ('Nuclear Dominated Accretion Flows' or NuDAFs). Examples of such disks are those generated by the merger of a white dwarf with a neutron star or black hole, or by the collapse of a rotating star. Here, we present two-dimensional hydrodynamic simulations that systematically explore the effect of adding a single nuclear reaction to a viscous torus. The equation of state, anomalous shear stress, and nuclear reactions are given parametric forms. Our results point to the existence of two qualitatively different regimes of NuDAF evolution: (1) steady accretion with quiescent burning or (2) detonation of the disk. These outcomes are controlled primarily by the ratio {Psi} of the nuclear energy released to the enthalpy at the burning radius. Disks detonate if {Psi} exceeds a critical value {Psi}{sub crit} {approx} 1, and if burning occurs in regions where neutrino cooling is unimportant. Thermonuclear runaways are seeded by the turbulent mixing of hot ash with cold fuel at the burning front. Disks with {Psi} < {Psi}{sub crit} do not explode, but instead power a persistent collimated outflow of unbound material composed primarily of ash, with a mass-loss rate that increases with {Psi}. We discuss the implications of our results for supernova-like counterparts from astrophysical events in the NuDAF regime. In particular, detonations following a white dwarf-neutron star merger could account for some subluminous Type Ia supernovae, such as the class defined by SN 2002cx.

79 ASTRONOMY AND ASTROPHYSICS↗

Extraction of nuclear fuels from coal using microwave induced plasma gasification and electromagnetic plasma separation processes

Coal is till today the most commonly used fuel worldwide for electricity generation, with the largest consumers being China, USA and India respectively. Coal contains small amounts of radioactive elements such as uranium, thorium, potassium-40, radium and radon, in the range of a few parts per million, which make their removal difficult and economically unfeasible through conventional industrial technologies. The concentrations gets amplified in the coal ash (fly ash), thereby presenting environmental and human health risks. In this preliminary paper, we propose an innovative clean coal technology, namely microwave induced plasma gasification (MIPG) to turn coal into syngas, while the molten residue is sent to a microwave-heated electromagnetic plasma separator for isolation of radioactive elements. With the adoption of this technology, coal producing and consuming nations will be able to satisfy a large portion of their nuclear fuel requirements from clean coal. (author)

01 COAL, LIGNITE, AND PEAT↗

Impact of Screening on Behavior During Storage and Cost of Ground Small-Diameter Pine Trees: A Case Study

Whole comminuted trees are known to self-heat and undergo quality changes during storage. Trommel screening after grinding is a process that removes fines from the screened material and removes a large proportion of high-ash, high-nutrient material. In this study, the trade-off between an increase in preprocessing cost from trommel screening and an increase in quality of the screened material was examined. Fresh lodgepole pine (Pinus contorta) was comminuted using a drum grinder with a 10-cm screen, and the resulting material was distributed into separate fines and overs piles. A third pile of unscreened material, the unsorted pile, was also examined. The three piles exhibited different characteristics during a 6-week storage period. The overs pile was much slower to heat. The overs pile reached a maximum temperature of 56.88 degrees C, which was lower than the maximum reached by the other two piles (65.98 degrees C and 63.48 degrees C for the unsorted and fines, respectively). The overs also cooled faster and dried to a more uniform moisture content and had a lower ash content than the other two piles. Both piles of sorted material exhibited improved airflow and more drying than the unsorted material. Looking at supply system costs from preprocessing through in-feed into thermochemical conversion, this study found that trommel screening reduced system costs by over $3.50 per dry matter ton and stabilized material during storage.

01 COAL, LIGNITE, AND PEAT↗

Sustainability Assessment of Coal-Fired Power Plants with Carbon Capture and Storage

Carbon capture and sequestration (CCS) has the ability to dramatically reduce carbon dioxide (CO2) emissions from power production. Most studies find the potential for 70 to 80 percent reductions in CO2 emissions on a life-cycle basis, depending on the technology. Because of this potential, utilities and policymakers are considering the wide-spread implementation of CCS technology on new and existing coal plants to dramatically curb greenhouse gas (GHG) emissions from the power generation sector. However, the implementation of CCS systems will have many other social, economic, and environmental impacts beyond curbing GHG emissions that must be considered to achieve sustainable energy generation. For example, emissions of nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM) are also important environmental concerns for coal-fired power plants. For example, several studies have shown that eutrophication is expected to double and acidification would increase due to increases in NOx emissions for a coal plant with CCS provided by monoethanolamine (MEA) scrubbing. Potential for human health risks is also expected to increase due to increased heavy metals in water from increased coal mining and MEA hazardous waste, although there is currently not enough information to relate this potential to actual realized health impacts. In addition to environmental and human health impacts, supply chain impacts and other social, economic, or strategic impacts will be important to consider. A thorough review of the literature for life-cycle analyses of power generation processes using CCS technology via the MEA absorption process, and other energy generation technologies as applicable, yielded large variability in methods and core metrics. Nonetheless, a few key areas of impact for CCS were developed from the studies that we reviewed. These are: the impact of MEA generation on increased eutrophication and acidification from ammonia emissions and increased toxicity from MEA production and the impact of increased coal use including the increased generation of NOx from combustion and transportation, impacts of increased mining of coal and limestone, and the disposal of toxic fly ash and boiler ash waste streams. Overall, the implementing CCS technology could contribute to a dramatic decrease in global GHG emissions, while most other environmental and human health impact categories increase only slightly on a global scale. However, the impacts on human toxicity and ecotoxicity have not been studied as extensively and could have more severe impacts on a regional or local scale. More research is needed to draw strong conclusions with respect to the specific relative impact of different CCS technologies. Specifically, a more robust data set that disaggregates data in terms of component processes and treats a more comprehensive set of environmental impacts categories from a life-cycle perspective is needed. In addition, the current LCA framework lacks the required temporal and spatial scales to determine the risk of environmental impact from carbon sequestration. Appropriate factors to use when assessing the risk of water acidification (groundwater/oceans/aquifers depending on sequestration site), risk of increased human toxicity impact from large accidental releases from pipeline or wells, and the legal and public policy risk associated with licensing CO2 sequestration sites are also not currently addressed. In addition to identifying potential environmental, social, or risk-related issues that could impede the large-scale deployment of CCS, performing LCA-based studies on energy generation technologies can suggest places to focus our efforts to achieve technically feasible, economically viable, and environmentally conscious energy generation technologies for maximum impact.

01 COAL, LIGNITE, AND PEAT↗

Operational and Compositional Factors that Affect the Performance Properties of ARP/MCU Saltstone Grout

The Saltstone Production Facility (SPF) receives low level waste (LLW) salt solution from Tank 50H for treatment and disposal. Tank 50H receives transfers from the Effluent Treatment Project (ETP), the H-Canyon General Purpose Evaporator, and the Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU) Decontaminated Salt Solution Hold Tank (DSS-HT). At the SPF, the LLW is mixed with premix (a cementitious mixture of portland cement (PC), blast furnace slag (BFS) and Class F fly ash (FA)) in a Readco mixer to produce fresh (uncured) saltstone that is transferred to the Saltstone Disposal Facility (SDF) vaults. The saltstone formulation (mix design) must produce a grout waste form that meets both placement and performance properties. In previous simulated saltstone studies, multiple compositional factors were identified that drive the performance properties of saltstone made from the projected ARP/MCU salt solution. This composition was selected as salt solution simulant since ARP/MCU is the primary influent into Tank 50H. The primary performance property investigated was hydraulic conductivity since it is a variable input property to the saltstone Performance Assessment (PA) transport model. In addition, the porosity, also referred to as void structure, is another variable that impacts the PA response. In addition, Young's modulus and cured density are other performance properties analyzed in this report; however they are indicators of the performance of saltstone and not direct inputs into the PA. The data from previous studies showed that the largest impact on the performance properties of saltstone was due to curing temperature, followed by aluminate concentration in the salt solution, water to premix ratio and premix composition. However, due to the scope of the previous studies, only a few mixes were cured and analyzed at higher temperatures. The samples cured at 60°C had an increased hydraulic conductivity of approximately 600 times that of the sample cured at room temperature. The hydration reactions initiated during the mixing of the premix and salt solution continue during the curing period in the vaults to produce the hardened waste form product. The heat generated from exothermic hydration reactions results in a temperature increase in the vaults that depends on the composition of the decontaminated salt solution being dispositioned, the grout formulation (mix design) and the pour frequency and volume. This heat generation is a contributing factor to the temperature increase in the vaults that leads to an increased cure temperature for the grout. This report will further investigate the impact of curing temperature on saltstone performance properties (hydraulic conductivity, Young's modulus, porosity, etc.) over a range of aluminate concentration, water to premix (w/p) ratio and weight percent fly ash in the premix processed at the SPF. The three curing temperatures selected for this study were chosen to provide data at fixed cure temperatures that represent measured temperatures in the SDF vaults. This does not represent the conditions in the vault where the temperature of the saltstone is continually changing with time. For example, it may take several days for the saltstone to reach 60°C at a given elevation. Previous results demonstrated that the rates at which a selected curing temperature is reached affect the performance properties. The approach taken in this task, a rapid increase to the curing temperature, may be conservative with respect to decreased performance. Nevertheless, the data will provide a basis from which to determine the impact of curing temperature on saltstone performance as a function of key variables. A statistical evaluation of the results for these mixes will be performed to provide the range, and associated uncertainties, of hydraulic conductivity and other properties over this factor space.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Advanced Gasification (Annual Report)

The Advanced Gasification team is addressing many factors that impact the current and future development and deployment of gasification-based power generation. For example, the service life of gasifiers does not meet the performance needs of users, failing to achieve an online gasifier availability of 85-95 percent in utility applications and 95 percent in applications such as chemical production. The inability to meet these goals has created a potential roadblock to widespread acceptance and commercialization of advanced gasification technologies, with refractory liners, sensors, and syngas coolers among key components identified as negatively impacting gasifier availability. Ash originating from impurities in gasifier carbon feedstock is the root cause of many problems; attacking or fouling components, leading to their unplanned shutdowns for repair, replacement, or cleaning. Technology gaps exist in the understanding of how fuel properties impact carbon conversion, slag viscosity, and downstream fouling. Fuel flexibility has potential advantages for gasifier operators to lower fuel cost or impact future carbon emission credits, but operators need to know how feedstock changes impact gasifier operation. Mixed feedstock combinations have not been studied as to how ash properties impact gasifier operation, efficiency, and capacity factors. Further gaps exist in technology which specifically target reducing the cost of multiple and mixed feed stocks at 90 percent capture, including low-rank coal (half the U.S. coal supply) and affordable gas clean-up technology.

Additives↗

SCM Paste Samples Exposed To Aggressive Solutions. Cementitious Barriers Partnership

This report summarizes experimental work performed by SIMCO Technologies Inc. (SIMCO) as part of the Cementitious Barriers Partnership (CBP) project. The test series followed an experimental program dedicated to the study of ordinary Portland cement (OPC) hydrated cement pastes exposed to aggressive solutions. In the present study, the scope is extended to hydrated cement pastes incorporating supplementary cementitious materials (SCM) such as fly ash and ground granulated blast furnace slag (GGBFS). Also, the range of aggressive contact solutions was expanded. The experimental program aimed at testing aggressive contact solutions that more closely mimic the chemical composition of saltstone pore solution. Five different solutions, some of which incorporated high levels of carbonate and nitrate, were placed in contact with four different hydrated cement paste mixes. In all solutions, 150 mmol/L of SO 4 2– (14 400 ppm) were present. The solutions included different pH conditions and different sodium content. Two paste mixes were equivalent to Vault 1/4 and Vault 2 concrete mixes used at SRS in storage structures. Two additional paste mixes, cast at the same water-to-cement ratio and using the same cements but without SCMs, were also tested. The damage evolution in samples was monitored using ultrasonic pulse velocity (UPV) and mass measurements. After three and twelve months of exposure conditions, samples were taken out of solution containers and analyzed to perform migration tests and porosity measurements. Globally, results were in line with the previous study and confirmed that high pH may limit the formation of some deleterious phases like gypsum. In this case, ettringite may form but is not necessarily associated with damage. However, the high concentration of sodium may be associated with the formation of an AFm-like mineral called U-phase. The most significant evidences of damage were all associated with the Vault 2 paste analog. This material proved very sensitive to high pH. All measurement techniques used to monitor and evaluate damage to samples indicated significant alterations to this mix when immersed in contact solutions containing sodium hydroxide. It was hypothesized that the low cement content, combined with high silica content coming from silica fume, fly ash and GGBFS led to the presence unreacted silica. It is possible that the pozzolanic reaction of these SCMs could not be activated due to the low alkali content, a direct consequence of low cement content. In this scenario, the material end up having a lot of silica available to react upon contact with sodium hydroxide, possibly forming a gel that may be similar to the gel formed in alkali-silica reactions. This scenario needs further experimental confirmation, but it may well explain the poor behavior of mix PV2 in presence of NaOH.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Waste-to-Energy (WTE)-derived Low-Carbon-Footprint Concrete (LCFC)

The construction industry is estimated to generate around 600 million tons of concrete and demolition waste annually in the US. In comparison, Waste-To-Energy (WTE) plants generate about 6.6 million tons of ash from the combustion of municipal solid waste.1–4 Research has been ongoing for decades to upcycle WTE-ash and C&D waste.

36 MATERIALS SCIENCE↗

Inorganic Elements in Eggs of Two Cavity-Nesting Passerine Species at and around Los Alamos National Laboratory, Los Alamos, New Mexico

Los Alamos National Laboratory (LANL) was established in 1943 as part of the Manhattan Project to build nuclear weapons, and currently operates as a national research laboratory. As part of an ongoing assessment of site-related ecological risk at LANL, western bluebird (Sialia mexicana) and ash-throated flycatcher (Myiarchus cinerascens) eggs were collected from 1997 to 2012 and analyzed for 18 inorganic elements. Concentrations of many inorganic elements in eggs were below reporting limits. Between species comparisons revealed that western bluebird eggs had higher levels of barium while ash-throated flycatcher eggs had higher levels of mercury. No statistically significant differences were observed in concentrations of inorganic elements in western bluebird eggs collected from the study area (which consists of areas within the current and historic LANL boundary) and from a non-industrial reference site; nor were any statistically significant differences observed between two canyons of interest, known to have received effluents and storm water runoff from LANL facilities, and the non-industrial reference site. Inorganic element levels detected in western bluebirds were typically within the range measured in eggs of other passerine in the published literature. Furthermore, these data suggest that concentrations of inorganic elements in passerine eggs collected from the study area appear to be at levels causing negligible risks to local bird populations.

59 BASIC BIOLOGICAL SCIENCES↗

Studies on the Encapsulation of Brine Generated from a Process Using Selective Electrodialysis Reversal

This topical report summarizes the laboratory testing, geochemical modeling, and mineralogical testing conducted to examine the efficacy of wastewater encapsulation for the brine generated from the Saltworks Flex electrodialysis reversal technology. Within the laboratory testing, the short- and long-term physical properties of seven separate mix designs were examined along with the leaching of each mix design. Additionally, geochemical thermodynamic modeling was used along with mineralogical analyses to help gain a fundamental understanding of the chemistry involved in the encapsulation process. Encapsulation is a process that results in the immobilization of constituents of interest by creating an engineered material that contains the waste within its matrix, both physically and chemically, in such a manner that the receiving environment is protected from adverse effects. Within the context of this study, encapsulation mix designs involved mixing the Saltworks brine with fly ash and various additives, principally lime (calcium oxide) and cement, to form a paste that eventually sets and hardens into a monolith upon placement in a landfill. Moisture conditioning fly ash with wastewater sources for on-site landfill disposal is a process that is in use at some sites and has been presented as a viable option to dispose of liquid wastes. However, because chemical reactions that can lead to sequestration of constituents of interest are not optimized, leaching can occur. Therefore, in this study, mixes were created to mimic moisture conditioning, as well as engineered pastes of varying mix designs. The study found that engineered encapsulation mixes provide significant resistance to leaching compared to moisture conditioning alone. The best performing encapsulation mix used lime as the additive, which proved superior to the use of cement. After 90 days of curing, this encapsulated mix was 5.5 times stronger than the moisture conditioned mix. Additionally, this mix exhibited an approximate 2.5 order of magnitude drop in hydraulic conductivity compared to the moisture conditioned mix. When comparing leaching, nearly all the chloride was found to evolve from the moisture conditioned mix, whereas only 6.7% of the chlorine contained in the best performing encapsulated mix leached out. Mineralogical analysis via X-ray diffraction (XRD) showed a significant concentration of the chloride sequestering mineral, Friedel’s salt, in the best performing encapsulation mix, whereas none was observed in the moisture conditioned mix, pointing to it being the primary chemical mechanism for chloride retention, along with the physical impermeability of the material. With respect to the modeling study, the model was successful in predicting the presence of most mineral phases observed in the XRD analysis.

01 COAL, LIGNITE, AND PEAT↗

Pre-Combustion Technique for Desulphurization of Waterberg Coalfield: Biological Treatment - 18444

The current study evaluates a microbial desulphurization of medium - sulphur type coal containing total sulphur (1.45 wt.%) and pyritic sulphur (≥ 0.51 wt. %) as a pre-combustion technique. Coal sample containing particle size in the range of - 0.85 mm was used in the experiments with bacteria isolated from nearby stockpiles of newly commissioned South African National Power Utility's (Eskom's) Medupi Power Station. After a stipulated hydraulic retention time (HRT), the coal samples were filtered, washed, dried and analyzed for total sulphur, ash content and calorific values. The calorific value of the coal significantly improved from 20.42 MJ/Kg to 24.16 MJ/Kg on the 5. day. The process removed up to 72% of the total sulphur content in the coal samples at a HRT of day 9. Furthermore, ash content reduced by 16%. This study provides a novel breakthrough of an alternative microbial desulphurization process of Waterberg steam coal as a further pre-treatment technique in order to meet stringent environmental emissions standards for SO{sub 2}. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Declaration of the Chemical Composition of Waste-products for the German Repository Konrad Using Substance Vectors - 20500

The waste acceptance criteria of the German repository Konrad require beside a radiological declaration a compositional declaration to be able to avoid negative impact on the groundwater by a presumed leakage into the groundwater after complete corrosion of the containers in the future. The declaration of the composition has to specify compounds and substances not element analyses, because the chemical behavior and toxicity especially of organic compounds varies strongly The relevant compounds have to be described and quantified using defined substance codes provided by the operator. For simple waste types like pure concrete or steel components, the definition of the composition is rather simple. The composition of more complex waste streams is generally declared using producer specific material vectors, which can be derived for defined waste types (e.g. grouted fluids, ash from combustion, super-compacted mixed waste etc.). Additional substance vectors exist for containers, drums and grout, which together with the waste composition yield the total composition of the waste packages. The substance vectors for homogeneous waste streams like cementitious demolition waste, solidified fluids and ash are mostly based on analyses provided by the waste owner. In some cases, analyses from non-radioactive analogues or data sheets can also be used to demonstrate the composition. For each qualified treatment of radioactive waste streams the material composition is described and balanced on the basis of specific material vectors, which are composed of material codes from the material and cask list provided by the Federal company for radioactive waste disposal. For mixed waste streams like super-compacted or grouted mixed waste or materials simply packed in containers an analyses cannot be used. In these cases, the compositional information from the bookkeeping can be used for the entire waste stream to calculate a mean composition including a compositional range (min / max composition). Only waste packages with an approved material description can be delivered to Konrad. Therefore, the material declaration of all waste streams and the resulting waste products is crucial for all waste owners in Germany to be able to have enough waste packages ready, when the repository is going to open in 2027. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Volcanic lightning and plume behavior reveal evolving hazards during the April 2015 eruption of Calbuco Volcano, Chile

Soon after the onset of an eruption, model forecasts of ash dispersal are used to mitigate the hazards to aircraft, infrastructure, and communities downwind. However, it is a significant challenge to constrain the model inputs during an evolving eruption. Here we demonstrate that volcanic lightning may be used in tandem with satellite detection to recognize and quantify changes in eruption style and intensity. Using the eruption of Calbuco volcano in southern Chile on 22 and 23 April 2015, we investigate rates of umbrella cloud expansion from satellite observations, occurrence of lightning, and mapped characteristics of the fall deposits. Our remote sensing analysis gives a total erupted volume that is within uncertainty of the mapped volume (0.56 ± 0.28 km3 bulk). Furthermore, observations and volcanic plume modeling further suggest that electrical activity was enhanced both by ice formation in the ash clouds >10 km above sea level and development of a low-level charge layer from ground-hugging currents.

58 GEOSCIENCES↗

Development of a hybrid shrinking‐core shrinking‐particle model for entrained‐flow gasifiers

Slagging entrained‐flow gasifiers operate above the melting temperature of the ash. As slag is highly nonwetting on the surface of char (carbon) particles, it is likely that it will agglomerate into one or several slag droplets and some of these droplets can detach from the char particles. If the slag exists in the form of droplets on the char surface rather than as a solid shell around the unreacted char particle, a shrinking particle model would be more physically realistic representation in comparison to the widely used shrinking core model (SCM). In the early section of the gasifier, the temperature remains below the ash melting temperature and, therefore, the SCM is more appropriate in this region. With this motivation, a novel hybrid shrinking‐core shrinking‐particle model has been developed. The model provides spatial profile of a number of important variables that are not available from the traditional SCM. © 2015 American Institute of Chemical Engineers AIChE J , 62: 659–669, 2016

Pednekar, Pratik↗